The creep resistance of 9% chromium high temperature steels is determined by the alloy content and structure resulting from heat treatment. This paper describes the analysis of the phase composition using CALPHAD numerical modelling methods, of known modifications of 9% high temperature chromium steel: 9Cr–0·1C, 0·9Mo, 0·21V, 0·1Nb, 0·04N (P91) and 9Cr–0·1C, 2W, 0·5Mo, 0·21V, 005Nb, 0·05N, 0·005B (P92). The effect of alloying elements on the phase composition of the steel and the mutual effect of the composition on the nature and quantity of the phases Me23C6 and Me(CN) in the temperature range 570–620°C is described. On the basis of calculated data and experimental results, a composition for new high temperature steels with additional Co alloying (up to 3%) and varying carbon contents in the range 0·02–0·10% is proposed. Results are shown for investigations on high temperature chromium steels containing cobalt, including: effect of complex alloying with tungsten, molybdenum, and cobalt on the service properties and structural composition of steels; heat treatment processes for alloy variants and kinetics of structural change during creep and prolonged thermal aging. Data have been obtained comparing calculated and experimental data for the phase composition in chromium steel, also the effect of the phase composition on creep characteristics. On the basis of a complex laboratory investigation and industrial pilot heats, optimal composition variants for the alloy content of high temperature Cr–Mo–V–Co steels have been determined for practical applications. CNIITMASH has developed a chromonitriding technology for improving the corrosion, wear and scratch behaviour, as well as for protection against self-welding and other service characteristics of austenitic steel components and nickel alloys. Chromonitriding technology includes saturation of the component surface with chromium and nitrogen. The technology is intended for strengthening valves and bushings, water pump components, and components operating in liquid metal, burnt fuel residue, and other aggressive environments. The conditions governing the formation of the strengthening layers, consisting of an austenitic matrix (γ solid solution) and containing Cr2N with a depth of up to 250 μm and a hardness of 750–950 HV have been determined. Thermodynamic analysis of phase formation conditions during the chromising and subsequent nitriding process over a wide range of temperatures and saturating media has been carried out. The technology has been optimised for process and media composition leading to a structure with maximum surface properties.
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