The continued operation of aging Boiling Water Reactors (BWRs) worldwide requires gradually increasing cost of inspection, maintenance, and repair. Intergranular Stress Corrosion Cracking (IGSCC) in sensitized austenitic stainless steel piping first became a major issue for BWRs in the 1980s, resulting in recognition of the susceptibility of reactor internals to IGSCC. Shroud cracking identified in 1993–1994 confirmed that IGSCC of internals is a significant issue for BWRs. IGSCC is a time-dependent, material degradation process, which is caused and accelerated by the presence of residual stresses, material sensitization, irradiation, cold work, elevated temperature, and corrosive environments. This paper emphasizes the importance of accounting for corrosive environments, or more exactly, electrochemical phenomena in modelling IGSCC and predicting the service life of BWR in-vessel components, and stresses the necessity of performing such modeling not just for a single state point under full power conditions, but for the whole operating history of the reactor, including startups and shutdowns. This paper demonstrates that ignoring electrochemical considerations may result in underestimating component lifetime and lead to unnecessary expenses for inspection and repair.