When concrete is used for neutron and gamma shielding, its shielding effectiveness for gamma radiation can be improved by addition of iron. However, secondary gamma radiation will be produced as a result of inelastic scattering of fast neutrons and capture of thermal neutrons by iron nuclei. The spectral distribution of the secondary gamma radiation in ilmenite-limonite concrete with addition of steel fibres was investigated. It is shown that the linear attenuation coefficient for secondary gamma radiation has its maximum at a steel fibre concentration of 2 per cent