A neutron diffraction study has been performed on newly synthesized v-B 2O 3 and 75B 2O 3–25Na 2O glasses. The structure factor has been measured over a broad momentum transfer range, 0.4–30 Å −1, which made fine r-space resolution available for real space analyses. The reverse Monte Carlo (RMC) method was successfully applied to calculate a possible 3-dimensional atomic configuration that is consistent with the measured structure factor. The partial atomic pair-correlation functions, nearest neighbor atomic distances, coordination number distributions, average coordination number values and three-particle bond angle distributions have been revealed. It was established that addition of 25 mol% Na 2O to v-B 2O 3 transforms 41% of the 3-fold oxygen coordinated boron atoms into 4-fold coordinated ones. The first neighbor B–O distance is at 1.37 Å in v-B 2O 3, while two well resolved distances are at 1.38 and 1.50 Å in the 75B 2O 3–25Na 2O glass. The three-particle 〈O–B–O〉 and 〈B–O–B〉 bond angle distributions show an extra peak at around 90° in the 75B 2O 3–25Na 2O glass, which may be attributed to the BO 4 units, in addition to the peak at 120° characteristic for BO 3 trigonal units. The ring size distribution of the v-B 2O 3 network indicate that only 12% of boron atoms form boroxol group (B 3O 6), while the fraction of the larger 7–11 boron membered rings is 52%, and a tail of the distribution extends up to 20-membered rings.
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