Atomic Beam Research Articles

Reaction of an Ion and a Free Radical near 0 K: He++NO→He+N++O.

The reactions between ions and free radicals are among the fastest chemical reactions. They are predicted to proceed with large rates, even near 0 K, but so far, this prediction has not been verified experimentally. We report on measurements of the rate coefficient of the reaction between the ion He+ and the free radical NO at collision energies in the range between 0 and ∼ kB·10 K. To avoid heating of the ions by stray electric fields, the reaction is observed within the large orbit of a Rydberg electron of principal quantum number n ≥ 30, which shields the ion from external electric fields without affecting the reaction. Low collision energies are reached by merging a supersonic beam of He Rydberg atoms with a supersonic beam of NO molecules and adjusting their relative velocity using a chip-based Rydberg-Stark decelerator and deflector. We observe a strong enhancement of the reaction rate at collision energies below ∼kB·2 K. This enhancement is interpreted on the basis of adiabatic-channel capture-rate calculations as arising from the near-degenerate rotational levels of opposite parity resulting from the Λ-doubling in the X 2Π1/2 ground state of NO. With these new results, we examine the reliability of broadly used approximate analytic expressions for the thermal rate constants of ion-molecule reactions at low temperatures.

Direct loading of Yb atoms into a 3D magneto-optical trap from a dispenser atomic source

The realization of cold atoms using a compact and low-power-consumption experimental setup is indispensable for cold atom experiments, including optical clocks and quantum simulations. We demonstrate the direct loading of Yb atoms into a 3D magneto-optical trap (MOT) from a dispenser atomic source without using a Zeeman slower. The power consumption of the dispenser was ∼3 W. Spectroscopy of the atomic beam from the dispenser on the 6s2 1S0–6s6p 1P1 Yb transition at 399 nm shows that the flux of the atomic beam reaches 1.4 × 1013 s−1 cm−2. We can load up to 4.1 × 107 atoms into the MOT with slowing and trapping laser powers of 20.3 and 35.0 mW, respectively. The realized cold atom system is reliable and can be adapted for experiments on alkaline earth and other alkaline earth-like atoms.

1S–3S cw spectroscopy of hydrogen/deuterium atom

We study the 1S-3S two-photon transition of hydrogen in a thermal atomic beam, using a homemade cw laser source at 205 nm. The experimental method is described, leading in 2017 to the measurement of the 1S-3S transition frequency in hydrogen atom with a relative uncertainty of $9 \times 10^{-13}$. This result contributes to the "proton puzzle" resolution but is in disagreement with the ones of some others experiments. We have recently improved our setup with the aim of carrying out the same measurement in deuterium. With the improved detection system, we have observed a broadened fluorescence signal, superimposed on the narrow signal studied so far, and due to the stray accumulation of atoms in the vacuum chamber. The possible resulting systematic effect is discussed.

Ultrasensitive and Wide‐Range Flexible Hydrogen Sensor Based on Pd Nanoparticles Decorated Ultrathin SnO2 Film

AbstractHighly sensitive and reliable hydrogen detection is prerequisite for the large‐scale implementation of green energy hydrogen. It remains a tough challenge to get a highly selective H2 sensor to low concentration H2 gas with low working temperature. In this work, high performance flexible hydrogen sensor using ultrathin SnO2 film decorated by Pd nanoparticles (NPs) on polyimide (PI) was developed based on versatile atomic layer deposition (ALD) and cluster beam deposition (CBD). The influence of Pd NPs loading amount and operating temperature on the performance of hydrogen sensors was studied. The sensors obtain an extremely high response over 20000 to 30 ppm H2 at the relatively low operating temperature of 75–125 °C. The Pd NPs@SnO2/PI sensor achieves a wide detection range of 0.1‐5000 ppm with the limit of detection (LOD) of 100 ppb at 125 °C. A low LOD of 250 ppb can still be achieved at room temperature. The sensors also exhibit outstanding sensing selectivity for hydrogen over interfering gases and excellent mechanical resistance after 2000 bending cycles. The mechanism for improved sensing performance of ALD ultrathin film with CBD‐derived noble metal NPs decoration may be a feasible strategy for the construction of highly sensitive, selective, and flexible hydrogen sensors.

Modeling of transient interference phenomena in colinear laser spectroscopy

Colinear laser spectroscopy of fast atomic beams has been established as one of the main tools to perform precision experiments with atoms containing short-lived nuclei. Although highly sensitive, the spectral resolution of these techniques is typically limited to several MHz. Here, we study the use of transient interference phenomena to potentially improve the experimental resolution. Previous attempts to implement Ramsey-type measurements with fast beams were limited by the lack of understanding of the observed line shapes. By using a simple model, we provide a satisfactory description of the previously observed line shapes and propose alternative experimental schemes to improve the resolution in fast ion-beam experiments.

Ultra-high vacuum compatible full metal atom beam shutter for optical lattice clocks.

We developed a shutter driven by a solenoid to switch on/off the atomic beam of optical lattice clocks developed at KRISS [C. Y. Park etal., Metrologia 50, 119 (2013), S. Lee etal., New J. Phys. 18, 033030 (2016), H. Kim etal., Jpn. J. Appl. Phys. 56, 050302 (2017), and H. Kim etal., Metrologia 58, 055007 (2021)]. The shutter design was focused on long lifetime and compatibility with an ultra-high vacuum (UHV) environment. Thus, the solenoid was designed to be easily installed and removed from the air-side of a CF flange of the shutter. The flag in the vacuum-side moves only with the simple spring action of a sheet of a metal plate without any frictional movement of mechanical parts. All parts in the vacuum-side were made of metals (stainless steel and pure iron) to be baked over the temperature of 200 °C for UHV. The flag head of the shutter displaces up to 10mm (5mm) with a response time of 50 (30ms) and 80ms (10ms) for the opening-action and the closing-action, respectively. The lifetime was tested up to 6 × 106 cycles with no performance degradation. We expect the actual lifetime to be much longer than this by virtue of its friction-free design.

Measurement of Rb isotope ratio by atomic absorption spectroscopy with multi-microchannel array structure cavity

Rubidium (Rb) isotope analysis has important applications in geological exploration and environmental detection. Based on tunable laser atom absorption spectroscopy technology combined with thermal decomposition of the sample, a Rb isotope absorption spectroscopy measurement device is built to detect the Rb isotope ratio stability. And the atomic generator is designed by a new micro-channel array structure, which enhances atomic beam collimation capability, effectively suppresses the doppler effect of the spectrum, and improves the resolution of Rb isotope absorption spectrum. The device adopts tantalum metal to make the atomic generator with a diameter of 6 mm, and the micro-channel array with a diameter of 1 mm is stacked inside the atomic generator which can be heated resistively to 3000 ℃. In this experiment, the Rb carbonate sample is catalyzed to release Rb atom beam at a high temperature of 600 ℃, while a probe laser is used to obtain high resolution Rb absorption spectrum. The Rb isotope ratio (<sup>85</sup>Rb∶<sup>87</sup>Rb) of natural abundance Rb carbonate samples is 2.441±0.02 by combining the inversion of the spectral line parameters, the detection error is 5.9%, and the detection limit of <sup>87</sup>Rb is 1.76‰ (3<i>σ</i>). The experimental results show that the multi-microchannel structure reduces the linewidth of Rb atoms by 450 MHz (half height full width) compared with the counterparts of the single-channel structure, which can effectively distinguish the absorption characteristics of Rb isotopes. The device has a high detection accuracy and a high spectral resolution, which provides a possibility for the metal isotope abundance analysis, and has a broad application prospect.

Resonance multiphoton ionization of alkaline Earth Ca, Ba, Sr atoms

In this work, we study the process of three-photon resonant ionization of alkaline earth atoms Ca, Sr, and Ba. To carry out the experiments, a frequency-tunable laser setup was created. An effusive beam of alkali atoms served as an atomic target.

Exploring wave–particle behaviors of entangled Bragg diffracted neutral atoms

In this paper, we theoretically study the concept of the wave–particle duality of two entangled neutral Bragg diffracted atoms. This is an extension of a recent study where the same idea was proposed in the photonic setup [Man et al., Sci. Rep. 7, 42539 (2017)] using two independent Mach–Zehnder interferometers. Now, we propose a similar scheme using the cavity-QED based setup, which comprises two independent atomic de Broglie Mach–Zehnder–Bragg interferometers, a source cavity that generates two external momenta state entangled atoms. Once the atoms pass through the source cavity initially prepared in the superposition of zero and one photon, they emerge out of the cavity in entangled momenta state such that if one atom is transmitted to the upper interferometer, then the second atom must traverse the lower interferometer, and vice versa. The final atomic de Broglie beam splitter at the top interferometer is prepared in the superposition of zero and one photon and facilitates observing the wave or particle aspect in a single setting. This entire setup functions in off-resonant Bragg diffraction and the proposed schematics are shown to be experimentally feasible under contemporary research scenarios.

Interaction between the substrate and probe in liquid metal Ga: experimental and theoretical analysis.

Interaction between two bodies in a liquid metal is an important topic for development of metallic products with high performance. We conducted atomic force microscopy measurements and achieved the interaction between the substrate and the probe in liquid Ga of an opaque and highly viscous liquid. The interaction cannot be accessed with the normal atomic force microscopy, electron microscopy, and beam reflectometry. We performed a theoretical calculation using statistical mechanics of simple liquids by mixing an experimentally derived quantum effect. From both experiment and theory, we found an unusual behaviour in the interaction between the solvophobic substances, which has never been reported in water and ionic liquids. Shapes of the interaction curves between several solvophobic and solvophilic pairs in liquid Ga are also studied.

Prototype of a unidirectional magnetic field-applied fast atom beam source for surface-activated bonding

Prototype of a unidirectional magnetic field-applied fast atom beam source for surface-activated bonding

Investigating the thermal stability of ultra-small Ag, Au and AuAg alloy nanoparticles embedded in a silica matrix.

Thermal growth kinetics of embedded bimetallic (AuAg/SiO2) nanoparticles are explored and compared with their monometallic (Au/SiO2 and Ag/SiO2) counterparts, as their practical applicability demands stability and uniformity. The plasmonic properties of these nanoparticles (NPs) significantly improve when their size falls in the ultra-small region (diameter < 10 nm), owing to their large active surface area. Interestingly, the bimetallic NPs exhibit better optical properties and structural stability as compared to their monometallic counterparts. This calls for a thorough understanding of the nucleation and temperature-dependent growth to ensure size stability against thermal coarsening that most bimetallic NPs completely lack. Herein, the atom beam sputtered AuAg NPs are systematically analysed over a wide range of annealing temperatures (ATs), and the results are compared with those of Au and Ag NPs. The X-ray photoelectron spectroscopy spectra and other experimental results confirm the formation of AuAg alloy NPs inside the silica matrix. Furthermore, techniques like transmission electron microscopy and grazing-incidence small-/wide-angle X-ray scattering were used to explore the temperature-dependent structural and morphological stability of the NPs. Our results show that the deposited AuAg NPs retain their spherical shape and remain as an alloy for the entire range of ATs. When the AT increases from 25 °C to 800 °C, the size of the NPs also increases from 3.5 to 4.8 nm; beyond that, their size grows substantially to 13.6 nm at 900 °C. We observed that the NPs remain in the ultra-small size range (∼5 nm) until an AT of 800 °C. Beyond that Ostwald ripening is ascribed to be the major cause of particle growth, resulting in an active surface area loss. Based on the outcomes, a three-step nucleation and growth mechanism is proposed.

Surface Modifications of High-Performance Polymer Polyetheretherketone (PEEK) to Improve Its Biological Performance in Dentistry.

This comprehensive review focuses on polyetheretherketone (PEEK), a synthetic thermoplastic polymer, for applications in dentistry. As a high-performance polymer, PEEK is intrinsically robust yet biocompatible, making it an ideal substitute for titanium-the current gold standard in dentistry. PEEK, however, is also inert due to its low surface energy and brings challenges when employed in dentistry. Inert PEEK often falls short of achieving a few critical requirements of clinical dental materials, such as adhesiveness, osseoconductivity, antibacterial properties, and resistance to tribocorrosion. This study aims to review these properties and explore the various surface modification strategies that enhance the performance of PEEK. Literatures searches were conducted on Google Scholar, Research Gate, and PubMed databases using PEEK, polyetheretherketone, osseointegration of PEEK, PEEK in dentistry, tribology of PEEK, surface modifications, dental applications, bonding strength, surface topography, adhesive in dentistry, and dental implant as keywords. Literature on the topics of surface modification to increase adhesiveness, tribology, and osseointegration of PEEK were included in the review. The unavailability of full texts was considered when excluding literature. Surface modifications via chemical strategies (such as sulfonation, plasma treatment, UV treatment, surface coating, surface polymerization, etc.) and/or physical approaches (such as sandblasting, laser treatment, accelerated neutral atom beam, layer-by-layer assembly, particle leaching, etc.) discussed in the literature are summarized and compared. Further, approaches such as the incorporation of bioactive materials, e.g., osteogenic agents, antibacterial agents, etc., to enhance the abovementioned desired properties are explored. This review presents surface modification as a critical and essential approach to enhance the biological performance of PEEK in dentistry by retaining its mechanical robustness.

An optically pumped atomic clock based on a continuous slow cesium beam

Herein, we report the scheme of an optically pumped atomic clock based on a cold cesium atomic beam source. We propose the laser system and physical mechanism of this atomic clock, wherein the atomic beam travels in an upper parabolic trajectory, thereby eliminating the light shift effect. In the experiments, when the length of the free evolution region was 167 mm, the line width of the Ramsey fringe was 37 Hz. When the expected signal-to-noise ratio of the Ramsey fringe that can be achieved is 36,000, the expected short-term frequency stability is about 3.6 × 10–14/√τ, which is significantly higher than that of a conventional optically pumped cesium clock of similar volume.

Combined Treatment of Parts Produced by Additive Manufacturing Methods for Improving the Surface Quality

To improve the quality of a part manufactured by the additive method, it is necessary to eliminate the porosity and high roughness of its surface, as well as to deposit a coating on it. For this purpose, in the present work, we studied the combined processing in a gas discharge plasma of complex shape parts obtained by the additive manufacturing method, which includes explosive ablation of surface protrusions when voltage pulses are applied to the part immersed in the plasma; polishing with a concentrated beam of fast neutral argon atoms at a large angle of incidence on the surface of the part, and magnetron deposition of a coating on it with assistance by fast argon atoms. Combined processing made it possible to completely get rid of porosity and reduce the surface roughness from Ra ~ 5 µm to Ra ~ 0.05 µm.

Prospects of a superradiant laser based on a thermal or guided beam of Sr88

The prospects of superradiant lasing on the 7.5-kHz-wide $^{1}S_{0}\text{\ensuremath{-}}^{3}P_{1}$ transition in $^{88}\mathrm{Sr}$ is explored by using numerical simulations of two systems based on realistic experimental numbers. One system uses the idea of demonstrating continuous superradiance in a simple, hot atom beam with high flux, and the other system is based on using ultracold atoms in a dipole guide. For the hot-beam system we consider a range of atom beam parameters as well as the impact of a scheme to discard fast atoms along the cavity axis. We find that the system achieves lasing above a flux of $2.5\ifmmode\times\else\texttimes\fi{}{10}^{12}$ atoms/s and that it is capable of outputting hundreds of nanowatts and suppressing cavity noise by a factor of 20--30. The relativistic transverse Doppler shifts cause a shift in the lasing frequency on the order of 500 Hz. For the cold-atom beam we account for decoherence and thermal effects when using a repumping scheme for atoms confined in a dipole guide. This is done by treating recoils and state-dependent forces acting on atoms in the dipole guide within the framework of the stochastic master equation. We find that the output power is on the order of hundreds of picowatts; however, transverse Doppler shifts can be neglected, and cavity noise can be suppressed on the order of a factor of 50--100. Additionally, we show that both systems exhibit local insensitivity to fluctuations in atomic flux.

Cryogenic buffer gas beams of AlF, CaF, MgF, YbF, Al, Ca, Yb and NO – a comparison

ABSTRACT Cryogenic buffer gas beams are central to many cold molecule experiments. Here, we use absorption and fluorescence spectroscopy to directly compare molecular beams of AlF, CaF, MgF and YbF molecules, produced by chemical reaction of laser ablated atoms with fluorine rich reagents. The beam brightness for AlF is measured as molecules per steradian per pulse in a single rotational state, comparable to an Al atomic beam produced in the same setup. The CaF, MgF and YbF beams show an order of magnitude lower brightness than AlF and far below the brightness of Ca and Yb beams. The addition of either or to the cell extinguishes the Al atomic beam, but has a minimal effect on the Ca and Yb beams. reacts more efficiently than , as a significantly lower flow rate is required to maximise the molecule production, which is particularly beneficial for long-term stability of the AlF beam. We use NO as a proxy for the reactant gas as it can be optically detected. We demonstrate that a cold, rotationally pure NO beam can be generated by laser desorption, thereby gaining insight into the dynamics of the reactant gas inside the buffer gas cell.

Compression of a Beam of Fast Argon Atoms for Surface Polishing

The results of studying a beam source of fast argon atoms obtained by neutralizing charges of accelerated ions during their flight through an accelerating grid in the form of a set of plane–parallel plates are presented. Ions are accelerated from the plasma emitter by a voltage of negative polarity at the grid, fly into the gaps between its plates, and, when approaching their surfaces, cause the emission of electrons that neutralize the ion charge. The equivalent beam current of fast atoms emitted from the grid is up to 90% of the current in its circuit, and their energy is equal to the ion energy that corresponds to the accelerating voltage between the plasma emitter and the grid. To increase the beam current density of fast atoms on the treated surface, the sections of the grid plates facing the plasma emitter are made in the form of a segment of a circle. The movement of ions and fast atoms that are formed inside the grid to the center of this circle makes it possible to reduce the beam width by an order of magnitude and increase the flow density of fast atoms without reducing the angle of their incidence on the treated surface. The beam compression significantly improves the efficiency of polishing a surface with a beam of fast neutral argon atoms with an angle of incidence on the surface of 80°.

Bi-color atomic beam slower and magnetic field compensation for ultracold gases

Transversely loaded bidimensional-magneto-optical-traps (2D-MOTs) have been recently developed as high flux sources for cold strontium atoms to realize a new generation of compact experimental setups. Here, we discuss on the implementation of a cross-polarized bi-color slower for a strontium atomic beam, improving the 2D-MOT loading and increasing the number of atoms up to ∼109 atoms in the 461 nm MOT. Our slowing scheme addresses simultaneously two excited Zeeman substates of the 88Sr 1S0→ 1P1 transition at 461 nm. We also realized a three-axis active feedback control of the magnetic field down to the microgauss regime. Such a compensation is performed thanks to a network of eight magnetic field probes arranged in a cuboid configuration around the atomic cold sample and a pair of coils in a quasi-Helmholtz configuration along each of three Cartesian directions. Our active feedback is capable of efficiently suppressing most of the magnetically induced position fluctuations of the 689 nm intercombination-line MOT.

Receiver Calorimeter of Fast Atom Beam Injector in Megawatt Range

Receiver Calorimeter of Fast Atom Beam Injector in Megawatt Range