Transport Of Atmospheric Pollutants Research Articles

Atmospheric Transport and Bulk Deposition of Organochlorine Compounds at Leigongshan Nature Reserve in Southwestern China

ABSTRACT Atmospheric and bulk deposition samples collected at Leigongshan Nature Reserve (LNR) were analyzed to explore the status, transport, and deposition of atmospheric pollution—specifically, organochlorine compounds—in the foggy mountains of southwestern China. Prohibiting and restricting persistent organic pollutants in the surrounding areas has led to a decline in organochlorine pesticides and polychlorinated biphenyls (PCBs), but not hexachlorobenzene (HCB), in the air. Wet deposition is a factor that strongly influences the atmospheric input at LNR. Despite the relatively low atmospheric concentration levels of hexachlorocyclohexanes (HCHs) and HCB, heavy precipitation can increase the deposition of these compounds in summer. The airborne HCHs exhibited a “bimodal” pattern, with higher concentrations in spring and autumn and lower concentrations in summer, the latter of which are results of high surface input into the ground along the transport routes of these compounds from South and Southeast Asia to southwestern China. The HCB at LNR mainly originates in mainland China. The deposition fluxes are influenced by the enhanced washout of atmospheric particles in the rainy season and increased particle-associated content in winter. The potential sources of o,pʹ-DDT, p,pʹ-DDT, and PCBs are distributed widely over low-latitude western areas and eastern China. Atmospheric transport and deposition in spring and summer contribute a significant proportion of the total fluxes annually when air masses originating in Southeast Asia arrive, increasing rainfall at LNR. The foggy local weather may also enhance this deposition, eventually leading to the accumulation of pollutants at LNR.

Health Effects of Asian Dust Events: A Literature Review Update of Epidemiological Evidence

Asian dust is a phenomenon involving the long-range transport of atmospheric pollutants originating from the desert areas of China and Mongolia. In recent years, the health effects of Asian dust have raised public concerns. Numerous studies on the health effects of Asian dust have been published since the last review in 2010. Thus, a literature review was conducted to shed light on the latest epidemiologic findings. PubMed and Science Direct databases were used for the review of epidemiologic studies published between June 2009 and April 2018. We identified 53 epidemiologic studies. Mortality, ambulance transportation, hospitalization/medical examination, changes in symptomatic, functional, and examination findings, as well as birth outcomes have been reported as outcomes. When the outcomes were categorized by disease, the effects of Asian dust on respiratory, cardiovascular, and allergic diseases raised concerns. The common evidences of causation between Asian dust and these diseases were the consistency of findings and temporal sequence of association. As results of research on dose-response relationships have become available, and the possibility that the health effects of Asian dust may vary depending on its chemical composition has been pointed out, further research using the exposure level indicators of Asian dust or its chemical composition should be conducted. Furthermore, with focus on the crucial issue of reducing exposure, research related to prevention and raising awareness should be further promoted.

Analysis of air mass back trajectories with present and historical volcanic activity and anthropogenic compounds to infer pollution sources in the South Shetland Islands (Antarctica)

Abstract This work analyses atmospheric transport of natural and anthropogenic pollution to the South Shetland Islands (SSI), with particular reference to the period September 2015 – August 2017. Based on data from the Global Volcanism Program database and air mass back trajectories calculated using the HySPLIT model, it was found that it is possible that in the analysed period volcanic pollution was supplied via long-range transport from South America, and from the South Sandwich Islands. Air masses flowed in over the South Shetland Islands from the South America region relatively frequently – 226 times during the study period, which suggests the additional possibility of anthropogenic pollution being supplied by this means. In certain cases the trajectories also indicated the possibility of atmospheric transport from the New Zealand region, and even from the south-eastern coast of Australia. The analysis of the obtained results is compared against the background of research by other authors. This is done to indicate that research into the origin of chemical compounds in the Antarctic environment should take into account the possible influx of pollutants from remote areas during the sampling period, as well as the possible reemission of compounds accumulated in snow and ice.

Algorithms for the inverse modelling of transport and transformation of atmospheric pollutants

When studying air quality, a key parameter for assessment and forecast is information on emission sources. In applications, this information is not fully available and can be compensated by air quality monitoring data and inverse modelling algorithms. Because of the rapid development of satellite chemical monitoring systems, they are becoming more useful in air quality studies. Such systems provide measurements in the form of concentration field images. In this paper, we consider an inverse source problem and a corresponding data assimilation problem for a chemical transport model. The problem of assimilation of data given as images is considered as a sequence of linked inverse source problems. Each individual inverse problem solution is carried out by variational and Newton-Kantorovich type algorithms. In the numerical experiment presented, an emission source of a primary pollutant is reconstucted via the concetration field of a secondary pollutant. Both data assimilation and inverse problem solution algorithms are capable of approximating the unknown source.

Mapping carbon monoxide pollution from space down to city scales with daily global coverage

Abstract. On 13 October 2017, the European Space Agency (ESA) successfully launched the Sentinel-5 Precursor satellite with the Tropospheric Monitoring Instrument (TROPOMI) as its single payload. TROPOMI is the first of ESA's atmospheric composition Sentinel missions, which will provide complete long-term records of atmospheric trace gases for the coming 30 years as a contribution to the European Union's Earth Observing program Copernicus. One of TROPOMI's primary products is atmospheric carbon monoxide (CO). It is observed with daily global coverage and a high spatial resolution of 7×7 km2. The moderate atmospheric resistance time and the low background concentration leads to localized pollution hotspots of CO and allows the tracking of the atmospheric transport of pollution on regional to global scales. In this contribution, we demonstrate the groundbreaking performance of the TROPOMI CO product, sensing CO enhancements above cities and industrial areas and tracking, with daily coverage, the atmospheric transport of pollution from biomass burning regions. The CO data product is validated with two months of Fourier-transform spectroscopy (FTS) measurements at nine ground-based stations operated by the Total Carbon Column Observing Network (TCCON). We found a good agreement between both datasets with a mean bias of 6 ppb (average of individual station biases) for both clear-sky and cloudy TROPOMI CO retrievals. Together with the corresponding standard deviation of the individual station biases of 3.8 ppb for clear-sky and 4.0 ppb for cloudy sky, it indicates that the CO data product is already well within the mission requirement.

Smoke aerosols dispersion and transport from the 2013 New South Wales (Australia) bushfires.

Environmental monitoring and modelling, especially in the regional context, has seen significant progress with the widely usage of satellite measurement in conjunction with local meteorological and air quality monitoring to understand the atmospheric dispersion and transport of air pollutants. This paper studies the application of these data and modelling tools to understand the environment effects of a major bushfire period in the state of New South Wales (NSW), Australia, in 2013. The bushfires have caused high pollution episodes at many sites in the greater Sydney metropolitan areas. The potential long-range transport of aerosols produced by bushfires to other region and states has been seen by regulators as a major concern. Using data and images collected from satellites, in addition to the results obtained from different simulations carried out using HYSPLIT trajectory model and a regional meteorological model called Conformal Cubic Atmospheric Model (CCAM), we were able to identify at least 2days on which the smoke aerosols from bush fires in NSW has been transported at high altitude to the northern state of Queensland and the Coral Sea. As a result, widespread high particle concentration in South East Queensland including the Brisbane area, as measured by nearly all the air quality monitoring stations in this region, occurred on the day when the smoke aerosols intruded to lower altitude as indicated by the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) Lidar measurements on the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) satellite. The use of meteorological or air quality modelling to connect the ground-based measurements with satellite observations as shown in this study is useful to understand the pollutant transport due to bushfires and its impact on regional air quality.

Toxic anthropogenic signature in Antarctic continental shelf and deep sea sediments

Industrial activity generates harmful substances which can travel via aerial or water currents thousands of kilometers away from the place they were used impacting the local biota where they deposit. The presence of harmful anthropogenic substances in the Antarctic is particularly surprising and striking due to its remoteness and the apparent geophysical isolation developed with the flows of the Antarctic Circumpolar current and the ring of westerly winds surrounding the continent. However, long-range atmospheric transport (LRAT) of pollutants has been detected in the Antarctic since the 70’s along the Antarctic trophic food web from phytoplankton to birds. Still, no information exists on the presence of cytotoxic compounds in marine sediments neither at basin scales (thousands of kilometers) nor in water depths (hundreds of meters) beyond shallow coastal areas near research stations. Our results showed for the first time that there is cytotoxic activity in marine sediment extracts from water depths >1000 m and along thousands of kilometers of Antarctic continental shelf, in some cases comparable to that observed in Mediterranean areas. Ongoing anthropogenic pressure appears as a serious threat to the sessile benthic communities, which have evolved in near isolation for millions of years in these environments.

A novel method to retrieve the nocturnal boundary layer structure based on CCD laser aerosol detection system measurements

Mixing layer height (MLH) is a key parameter for evaluating the transport and diffusion of atmospheric pollutants in both air quality forecasting and satellite data retrieval. However, there is a lack of methods for obtaining the nocturnal MLH. In this study, a novel instrument named the charge-coupled device-laser aerosol detection system (CCD-LADS) was developed to study the nocturnal MLH and boundary layer structure from the surface. The system mainly includes a continuous laser and a charge-coupled device camera with a fisheye lens. Structures of atmospheric layers characterized by the CCD-LADS were compared with those measured by a ceilometer. The heights of two atmospheric layers quantified by measurements with the CCD-LADS and the ceilometer show good agreement, with a relative difference of 5%. The results of this comparison demonstrated that the CCD-LADS is capable of distinctly identifying the nocturnal vertical structure of the atmosphere. The advantage of the CCD-LADS in retrieving the nocturnal MLH is that the CCD-LADS can provide the boundary layer structures under 100 m, while the ceilometer and other lidar measurements cannot retrieve the atmospheric structures below that altitude. CCD-LADS was deployed in a comprehensive field campaign measuring air pollution in the University of Chinese Academy of Sciences, located at the border between the North China Plain and Yanshan Mountain, during January 2016. The fine characteristics and patterns of the nocturnal boundary layer structures were derived with the CCD-LADS measurements.

Seasonal variations of low molecular weight hydroxy-dicarboxylic acids and oxaloacetic acid in remote marine aerosols from Chichijima Island in the western North Pacific (December 2010–November 2011)

Concentrations of homologous hydroxy-dicarboxylic acids (diacids) (hC3-hC6) and keto-diacid (oxaloacetic acid) were measured in the atmospheric aerosols collected at Chichijima Island (27.04° N, 142.13° E) in the western North Pacific from December 2010 to November 2011. The monthly averaged concentrations of hydroxy-diacids and oxaloacetic acid were significantly higher in spring followed by winter and autumn. Molecular distributions of hydroxy-diacids demonstrated that malic acid was the most abundant species in all four seasons, followed by tartronic acid in winter and spring and 3- and 2-hydroxyglutaric acids in summer and autumn. Hydroxy-diacids and keto-diacid maximized in spring and winter when air masses originated from the Asian continent with westerly winds. The concentrations of total hydroxy-diacids and oxaloacetic acid ranged from 0.1 to 27.3 ng m−3 and <0.005 to 2 ng m−3, respectively. The enhanced concentrations of diacids and their intermediates in winter and spring are associated with a long-range atmospheric transport of pollutants from East Asia to remote Chichijima Island followed by photochemical processing of organic aerosols. Seasonal molecular distribution of hydroxy-diacids and oxaloacetic acid was found to be dependent on the source strengths and plausible photochemical processing to form smaller diacids. Moderate to strong correlations among hydroxy-diacids, oxaloacetic acid and low molecular weight (LMW) diacids suggest that hydroxy-diacids and oxaloacetic acid are the intermediates in the photochemical oxidation of LMW diacid. Hence, photochemical formation of the most abundant LMW diacids, i.e., oxalic acid, could be produced from hydroxy- and keto-diacid as intermediates.

Ground-based and satellite optical investigation of the atmosphere and surface of Antarctica

This presentation contains the results of the 10-year research of Belarusian Antarctic expeditions. The set of instruments consists of a lidar, an albedometer, and a scanning sky radiometer CIMEL. Besides, the data from satellite radiometer MODIS were used to characterize the snow cover. The works focus on the study of aerosol, cloud and snow characteristics in the Antarctic, and their links with the long range transport of atmospheric pollutants and climate changes.

Assessment of integrated index of environmental units of the transport system

Transport-technological complex environmental impact, drivers and participants in the transport process exhaust gases, products of wear of tires, road surface, brake pads and discs and other harmful substances.. Proposed air pollution on roads and highways to estimate the complex index of atmospheric pollution transport and technological complex (APITTC).

Quantifying regional consumption-based health impacts attributable to ambient air pollution in China

Serious air pollution has caused about one million premature deaths per year in China recently. Besides cross-border atmospheric transport of air pollution, trade also relocates pollution and related health impacts across China as a result of the spatial separation between consumption and production. This study proposes an approach for calculating the health impacts of emissions due to a region's consumption based on a multidisciplinary methodology coupling economic, atmospheric, and epidemiological models. These analyses were performed for China's Beijing and Hebei provinces. It was found that these provinces' consumption-based premature deaths attributable to ambient PM2.5 were respectively 22,500 and 49,700, which were 23% higher and 37% lower than the numbers solely within their boundaries in 2007. The difference between the effects of trade and trade-related emissions on premature deaths attributable to air pollution in a region has also been clarified. The results illustrate the large and broad impact of domestic trade on regional air quality and the need for comprehensive consideration of supply chains in designing policy to mitigate the negative health impacts of air pollution across China.

Spatiotemporal distribution of nitrogen dioxide within and around a large-scale wind farm – a numerical case study

Abstract. As a renewable and clean energy source, wind power has become the most rapidly growing energy resource worldwide in the past decades. Wind power has been thought not to exert any negative impacts on the environment. However, since a wind farm can alter the local meteorological conditions and increase the surface roughness lengths, it may affect air pollutants passing through and over the wind farm after released from their sources and delivered to the wind farm. In the present study, we simulated the nitrogen dioxide (NO2) air concentration within and around the world's largest wind farm (Jiuquan wind farm in Gansu Province, China) using a coupled meteorology and atmospheric chemistry model WRF-Chem. The results revealed an edge effect, which featured higher NO2 levels at the immediate upwind and border region of the wind farm and lower NO2 concentration within the wind farm and the immediate downwind transition area of the wind farm. A surface roughness length scheme and a wind turbine drag force scheme were employed to parameterize the wind farm in this model investigation. Modeling results show that both parameterization schemes yield higher concentration in the immediate upstream of the wind farm and lower concentration within the wind farm compared to the case without the wind farm. We infer this edge effect and the spatial distribution of air pollutants to be the result of the internal boundary layer induced by the changes in wind speed and turbulence intensity driven by the rotation of the wind turbine rotor blades and the enhancement of surface roughness length over the wind farm. The step change in the roughness length from the smooth to rough surfaces (overshooting) in the upstream of the wind farm decelerates the atmospheric transport of air pollutants, leading to their accumulation. The rough to the smooth surface (undershooting) in the downstream of the wind farm accelerates the atmospheric transport of air pollutants, resulting in lower concentration level.

Observation of Strong Winds on the Northern Slopes of Mount Everest in Monsoon Season

ABSTRACTAn analysis of the local atmospheric circulation in a northern Himalayan valley in the region of Mount Everest is presented. Data were collected using an automatic weather station over a one-year period in 2014. A ground-based wind profiler radar (WPR) and an in situ GPS radiosonde (RS) were also employed. This study focuses on the characteristics of afternoon strong wind events in the downstream of Rongbuk Valley. We found that: (1) The occurrence of the southwesterly wind during non-monsoon was in good consistency with high values of westerly wind at high levels over this region and confirmed to be driven by the strong westerly jet aloft. (2) The strong afternoon wind in monsoon season has a persistent southeasterly direction, which differs from the prevailing direction of the strong wind in non-monsoon. This flow was found to be independent of the wind aloft and was strongly seasonal, developing at Qomolangma Station (QOMS) when the subtropical jet stream had moved northward and was most stable and strongest in the early monsoon season but before the rainy season. (3) The southeasterly wind in monsoon is colder than local air, suggesting that it is driven by a strong thermal gradient from the Arun Valley to QOMS. Our results contribute to improving our knowledge of local circulation patterns in the Himalayas, and also to gaining a detailed understanding of the mountain chain’s role in both the monsoon system and regional transport of atmospheric pollutants.

Industrial-era lead and mercury contamination in southern Greenland implicates North American sources

To study the long-range transport of atmospheric pollutants from lower latitude industrial areas to the Arctic, we analysed a peat core spanning the last ~700cal.yr (~1300–2000CE) from southern Greenland, an area sensitive to atmospheric pollution from North American and Eurasian sources. A previous investigation conducted in the same location recorded atmospheric lead (Pb) pollution after ~1845, with peak values recorded in the 1970s, and concluded that a North American source was most likely. To confirm the origin of the lead, we present new Pb isotope data from Sandhavn, together with a high-resolution record for mercury (Hg) deposition. Results demonstrate that the mercury accumulation rate has steadily increased since the beginning of the 19th century, with maximum values of 9.3μgm−2yr−1 recorded ~1940. Lead isotopic ratios show two mixing lines: one which represents inputs from local and regional geogenic sources, and another that comprises regional geogenic and pollution sources. Detrending the Pb isotopic ratio record (thereby extracting the effect of the geogenic mixing) has enabled us to reconstruct a detailed chronology of metal pollution. The first sustained decrease in Pb isotope signals is recorded as beginning ~1740–1780 with the lowest values (indicating the highest pollution signature) dated to ~1960–1970. The 206Pb/207Pb ratio of excess Pb (measuring 1.222, and reflecting pollution-generated Pb), when compared with the Pb isotopic composition of the Sandhavn peat record since the 19th century and the timing of Pb enrichments, clearly points to the dominance of pollution sources from North America, although it did not prove possible to further differentiate the emissions sources geographically.

Impact of excess NOx emissions from diesel cars on air quality, public health and eutrophication in Europe

Diesel cars have been emitting four to seven times more NOx in on-road driving than in type approval tests. These ‘excess emissions’ are a consequence of deliberate design of the vehicle’s after-treatment system, as investigations during the ‘Dieselgate’ scandal have revealed. Here we calculate health and environmental impacts of these excess NOx emissions in all European countries for the year 2013. We use national emissions reported officially under the UNECE Convention for Long-range Transport of Atmospheric Pollutants and employ the EMEP MSC-W Chemistry Transport Model and the GAINS Integrated Assessment Model to determine atmospheric concentrations and resulting impacts. We compare with impacts from hypothetical emissions where light duty diesel vehicles are assumed to emit only as much as their respective type approval limit value or as little as petrol cars of the same age. Excess NO2 concentrations can also have direct health impacts, but these overlap with the impacts from particulate matter (PM) and are not included here. We estimate that almost 10 000 premature deaths from PM2.5 and ozone in the adult population (age >30 years) can be attributed to the NOx emissions from diesel cars and light commercial vehicles in EU28 plus Norway and Switzerland in 2013. About 50% of these could have been avoided if diesel limits had been achieved also in on-road driving; and had diesel cars emitted as little NOx as petrol cars, 80% of these premature deaths could have been avoided. Ecosystem eutrophication impacts (critical load exceedances) from the same diesel vehicles would also have been reduced at similar rates as for the health effects.

Potentially Toxic Trace Metals in Water and Lake-Bed Sediment of Panchpokhari, an Alpine Lake Series in the Central Himalayan Region of Nepal

This study assessed the level of potentially toxic trace metals (PTMs), seasonal variations, and their possible sources from the surface water and lake-bed sediment of Panchpokhari lake series, an alpine and glacial lake at 4160 m a.s.l. in Central Nepal. The lake series have five lakes, with Lake-1 larger than others. So, Lake-1 was investigated thoroughly during pre-monsoon and post-monsoon seasons. Sediment core was collected from the deepest basin of the Lake-1 during pre-monsoon. Most of the PTM concentrations were higher in the pre-monsoon season; however, Sc, Cr, Cu, Zn, As, and Ag were higher in the post-monsoon. This is an indication that the lake has been impacted either by natural or long-range transported atmospheric pollutants. Ti, Sb, and Ag had extremely high enrichment factor (EF) in waters, whereas Cd, Zn, and As had high EF in sediments indicating that these metals originated from anthropogenic sources. Furthermore, PTM concentrations in the sediment were in the increasing order of Hg < Cd < Ag < Mo < Sb < Sn < As < U < Sc < Co < Cs < Cu < Pb < Ni < Cr < V < Zn < Rb < Mn < Ti < Fe and showed that the upper layer (top 10 cm) of lake sediment has been receiving a higher load of PTMs in the recent period. he observed EF values also suggested that major sources of PTMs in the sediment were from crustal origin except for a few metals (Ti, V, Sb, and Ag) which were enriched anthropogenically due to long-range transport of atmospheric pollutants, deposited at the higher elevations. Nevertheless, the level of pollution in sediments was low as indicated both by EF and geo-accumulation index.

Persistent organic pollutants in subarctic lakes in the extreme North of European Russia

The paper presents data on the concentrations of persistent organic pollutants in bottom sediments of subarctic lakes on Vaygach Isl. and in the Polar Cis-Urals in the Northern European Russia. Dioxin pollution is estimated at the background level, and the recorded levels of hexachlorobenzene fall within the concentration range identified in the bottom sediments of small lakes in the southwestern Arkhangelsk region. The specific character of the congener profile of polychlorinated dibenzo-p-dioxins and dibenzofurans in bottom sediments is demonstrated, suggesting a relationship between the pollution that forms under the effect of atmospheric transport of persistent organic pollutants from low latitudes in the past and present and the application of dioxin-containing organochlorine chemicals in timber industry.

Long-range transport of plumes of atmospheric emissions from regional coal power plants to the South Baikal water basin

We compare cases of actually observed regional transport of atmospheric pollutants to Lake Baikal against calculations according to a mathematical model. The observational data suggest that the most severe atmospheric pollution over the Lake is associated with atmospheric transport of sulfur and nitrogen dioxides from large coal-fired power plants both from the direction of Irkutsk and Angarsk, and from the direction of Buryatia (Ulan-Ude and Gusinoozersk). Transport of sulfur and nitrogen oxides to the Baikal atmosphere is especially strong at nighttime, under inversion-type meteorological conditions, in the form of weakly dispersed plumes from tall stacks of power plants. Data of automatic measurements of sulfur and nitrogen oxides demonstrate that actual mechanisms of anthropogenic pollutant transport to Lake Baikal are more complex and multiform as compared to model results. Model estimates of SO2 concentrations over the Lake are close to monthly average measurements; however, they fail to explain certain specific cases of increased pollutant concentrations in the Baikal atmosphere.

Forecasting the transport and transformation of atmospheric pollutants with the COSMO-ART model

The COSMO-ART model is used at the Hydrometcenter of Russia for the routine forecast of air pollutant concentrations. The COSMO-Ru7-ART system is able to simulate adequately the values of concentration of impurities in the atmosphere. The system includes the module for estimating the emission of pollutants to the atmosphere from forest fires that was successfully tested on the case of forest fires occurred in the summer of 2010 for the European part of Russia. The accurate forecast of pollutant concentration has also a positive effect on the air temperature forecast due to taking into account the aerosol feedback on radiation.