Abstract. Polychlorinated biphenyls (PCBs) are nowadays mainly unintentionally produced, since their use and manufacture has been banned. PCBs, especially those dioxin-like compounds, have been proven harmful to ecosystems and human health. Detailed information about the spatiotemporally distribution of unintentionally produced PCBs (UP-PCBs) is crucial for understanding the environmental fate and associated health risks. However, research estimating UP-PCBs emission in China is limited. In this study, a source-specific and year-varying emission factor (EF) dataset was used to compile provincial emissions of 12 dioxin-like UP-PCBs congeners for 66 sources in the Chinese mainland from 1960 to 2019. In addition to that, emissions for 2019 were allocated into 0.1∘×0.1∘ grids. The results indicated that historical national UP-PCBs emission represented an increasing trend until around 1995 and then showed an overall decreasing trend from 1995 to 2019. Cement production was the largest UP-PCBs emission source in the Chinese mainland. Geographically, East and North China contributed the largest UP-PCBs emission across the Chinese mainland. High emission densities occurred mainly in the densely populated and well-developed regions such as Yangtze River Delta Urban Agglomeration and Pearl River Delta. Furthermore, highly positive correlations of emission densities with population and GDP densities were identified.