Ambient Oxygen Concentration Research Articles

Evaporation and combustion of low asphaltene heavy oil droplets under conditions representative of practical applications

The evaporation and burning characteristics of isolated heavy fuel oil (HFO) droplets are experimentally studied at conditions representative of practical applications, producing novel, detailed results on the effect of oxygen concentration. Also, and for the first time for HFO, the temporal evolution of the flame stand-off ratio (based on CH* emission) and the cenosphere burning size are presented along with the droplet size histories. The effect of ambient oxygen concentration is first analyzed qualitatively, identifying different sub-stages. Later, a quantitative analysis is presented in terms of ignition delay time, micro-explosion regimes, shell swelling ratio, cenosphere size and several time metrics. The results show that, as ambient oxygen changes, the liquid and solid stages show marked differences not only in terms of time scales but also in the transitions of burning regimes. Cenospheres generated in oxygen-free conditions are found to be ∼1.4 times larger than those in droplet combustion. Although similar in size, the solid-to-liquid consumption time ratio in 5% O2 is found to be significantly longer, about twice than for the 10% O2 ambient. The characterization of these differences is thought to be relevant not only for oil flames but also for the promising future of heavy oil gasification applications.

Hypoxia-induced mitochondrial fission regulates the fate of bone marrow mesenchymal stem cells by maintaining HIF1α stabilization

For mesenchymal stem cells derived from bone marrow, a controlled reduction in ambient oxygen concentration has been recognized as a facilitator of osteogenic differentiation and the formation of calcium nodules. However, the specific molecular mechanisms underlying this phenotype remain unclear. The aim of this study was to elucidate the impact of hypoxia on the osteogenic differentiation of bone marrow mesenchymal stem cells (BMSCs) and to explore the involvement of mitophagy and the regulation of mitochondrial dynamics mediated by the mitochondrial dynamic regulatory factor FUN14 domain-containing 1 (FUNDC1). Our findings suggest that FUNDC1 is required for promoting osteogenic differentiation in BMSCs under hypoxic conditions. However, this effect was not dependent on FUNDC1-mediated mitophagy but rather on FUNDC1-mediated regulation of mitochondrial fission. At the mechanistic level, FUNDC1 binds more DNM1L and less OPA1 under hypoxic conditions, leading to an upsurge in mitochondrial division. This heightened mitochondrial division culminates in the increased translocation of Parkin to mitochondria, diminishing its interactions with HIF1α in the cytoplasm and consequently facilitating HIF1α deubiquitination and stabilization. In summary, FUNDC1-regulated mitochondrial division in hypoxic culture emerges as a critical determinant for the translocation of Parkin to mitochondria, ultimately maintaining HIF1α stabilization and promoting osteogenic differentiation.

High-performance Multi-stage Baffled A2O Treatment Process for Domestic Sewage on Plateaus

At high altitudes, the low air pressure, low atmospheric oxygen content, and cryogenic environment during the cold season greatly limit the treatment efficiency of wastewater treatment plants (WWTPs). A novel pilot-plant configuration of the multi-stage baffled A2O wastewater treatment process was proposed and tested in Xizang. Different operational conditions involving at different influent loads and at low temperatures (10.0–11.0°C) were tested. When the influent flowrate increased to 4 m3∙d−1, the hydraulic retention time (HRT), internal and external reflux ratio, dissolved oxygen (DO), and aeration demands (gas to water ratio) all decreased to 34.2 h, 3.5/7, a stable 2.0–2.5 mg∙L−1, and 17.5, respectively. The effluent chemical oxygen demand (COD), total nitrogen (TN), ammonia nitrogen (NH+4−N), and total phosphorus (TP) all met the requirements of Class 1 Grade A of the China National Municipal Wastewater Discharge Standards (GB 18918-2002). The contribution of denitrifying phosphorus removal (DPR) to the removal of both nitrogen and phosphorus was over 50%. The alpha diversity and abundance of the top genera in the microbial community structure were both higher than the plateau WWTP. The reaction activity of the DPR process was significantly enhanced via the increased abundance of key functional genes within the metabolism pathway of ammonia-oxidizing bacteria (AOB) and nitrogen-oxidizing bacteria (NOB). The special multi-stage baffled structure featured a strategy of high sludge storage that improved the system tolerance for low temperatures and ensured favorable and stable performance for nitrogen and phosphorus removal at low temperatures. A short, periodic, and cyclically intermittent operation mode, with each cycle lasting only 20 minutes, effectively inhibited filamentous bacteria sludge bulking, resulting in a sludge volume index (SVI) that decreased to within 120 mL∙g−1 during the first 15 days of system start-up. A long sludge retention time (SRT) with no sludge discharging over 169 days and reduced aeration demands contributed to lower operation costs. The investigation revealed that the system had a high capacity for storing sludge phosphorus, possessing a TP content within a range of 23.45–28.99 mg∙g−1. This study provides a feasible solution for efficiently and economically treating wastewater in high-altitude areas.

High spatiotemporal resolution optical measurements of two-stage ignition and combustion in Engine Combustion Network Spray D flames

This study explores flame structures and combustion dynamics in high-pressure n-dodecane fuel sprays, focusing on the formation and consumption of formaldehyde (CH2O) during autoignition and the development of poly-aromatic hydrocarbons (PAH) as soot precursors. These processes are crucial for optimizing combustion efficiency and reducing emissions. However, traditional approaches, which rely on single-shot measurements or ensemble-averaged visualizations, often overlook critical early-stage processes during low-temperature ignition. To overcome these challenges, we employed an innovative high-speed planar laser-induced fluorescence (PLIF) technique at 50 kHz using a pulse-burst Nd:YAG laser system with an excitation wavelength of 355 nm. This approach, applied for the first time to Engine Combustion Network (ECN) Spray D flames, provides unprecedented insights into the combustion processes at varying ambient temperatures and oxygen concentrations. Additionally, simultaneous high-speed schlieren imaging at 100 kHz was used to visualize spray penetration, first-stage ignition, and thermal expansion zones. Our findings reveal that, similar to Spray A flames, CH2O forms in cold, fuel-rich zones well upstream of the combustion zone. However, in Spray D flames, the schlieren signal softening observed in the jet's head does not lead to complete disappearance, and the CH2O signal is absent from the full head of the spray. During the second-stage ignition, CH2O consumption accelerates due to high-temperature reactions, leading to a significant reduction in its signal. Unlike the mushroom-shaped structure seen in Spray A flames, Spray D flames exhibit a quasi-steady PAH phase structure, with lean peripheral mixtures insufficient for soot precursor formation. Notably, reducing ambient oxygen concentration to 13 % while maintaining or increasing temperature prolongs the presence of CH2O, highlighting its influence on ignition dynamics and oxidation processes in dodecane spray flames. This study provides new insights into the combustion mechanisms of high-pressure sprays and offers valuable data for developing next-generation combustion technologies, including models, aimed at improving efficiency and reducing emissions.

Partial gravity flammability of cast PMMA rods in concurrent axial stagnation flow

Testing was performed in a partial gravity centrifuge drop vehicle in the Zero Gravity Research Facility with cast PMMA rods in concurrent axial buoyant stagnation flow to determine flammability limits as a function of partial gravity level. The partial gravity levels studied varied from 0.04 g to a simulated 1g for ambient oxygen concentrations from 13.2 % to 15.2 % O2 by volume at an average 57.6 kPa (8.4 PSIA) ambient pressure, which is very close to the anticipated Lunar habitat pressure. The PMMA flammability boundary as a function of oxygen concentration and gravity level has been determined at five gravity levels. Coriolis effects appear to be minimal in the stagnation region where the flame is stabilized while the tips of the flame do show some bending at the higher gravity levels. Lunar gravity levels are near the minimum in the oxygen - gravity level flammability boundary. This suggests that fire is a significant safety risk for future exploration missions to the Moon since materials are screened in normal gravity to evaluate their safe use in space. If normal gravity screening is not conservative, a material derating method will need to be applied to ensure the material is not flammable on the Moon. Since the blowoff boundary appears to be linear with forced flow velocity, it may be possible to conduct elevated forced flow blowoff testing that could then be extrapolated down to effective Lunar gravity levels to provide an oxygen delta between 1g and Lunar flammability limits to derate the material.

Spatial and seasonal variability in benthic impact of mussel farms: Predicting and mitigating impacts using ambient oxygen conditions

Environmental impacts are a cause for concern when developing and expanding aquaculture and to be sustainable potential negative effects need to be addressed. The intensity and extent of these impacts likely vary among sites and seasons, depending on multiple factors including the physical and biological setting and operational aspects. Using a combination of sampling techniques, we investigated the spatial variability in epibenthic impacts in eleven commercial mussel farms, on the Swedish west coast. We found increased levels of organic content, changes in epibenthic macrofauna and increased cover of Beggiatoa sp., a documented indicator of hypoxia. The extent of these impacts was generally limited to the extent of the farms. Because the cover of Beggiatoa sp. was particularly clear and because oxygen conditions in the sediment is of great importance to the structure and function of these habitats, we analysed spatial patterns using an index of the benthic footprint (BFI) accounting for both intensity and extent of impacts. In the summer, the BFI varied strongly among farm-sites and subsequent analyses showed that it highly correlated with ambient bottom oxygen concentration. Repeated sampling during early spring, however, showed that impacts were quickly reversible also in the most impacted sites. Thus, we conclude that in Swedish coastal waters the benthic footprint calculated on the % cover of Beggiatoa sp. is highly dependent on ambient oxygen concentration. We suggest that knowledge about spatial and temporal patterns of oxygen in the bottom water can be used to predict the severity of impacts and provide an important criterion in a site-selection process aimed at developing a sustainable food industry.

Oxygen regulation of microbial communities and chemical compounds in cigar tobacco curing.

Curing is a critical process that determines the sensory quality of cigars. The impact of oxygen on cigar curing and the mechanisms by which it regulates microbial changes affecting cigar quality are not well understood. In this study, we selected handmade cigars from the same batch and conducted curing experiments in environments with varying oxygen concentrations (equivalent to 0.1%, 6-12, and 15% of atmospheric oxygen concentration). We collected samples over 60 days and analyzed the distribution of microbial communities using high-throughput sequencing. Combined with the analysis of total sugars, proteins, flavor substances, and other chemical compounds, we elucidated how different oxygen concentrations affect the cigar curing process, influence microbial community succession, and ultimately impact cigar quality. Our results revealed significant differences in bacterial community composition under different oxygen conditions. Under aerobic conditions, Cyanobacteria were the dominant bacteria, while under oxygen-limited conditions, Staphylococcus and Corynebacterium predominated. As oxygen concentration decreased, so did the richness and diversity of the bacterial community. Conversely, oxygen concentration had a lesser impact on fungi; Aspergillus was the dominant genus in all samples. We also found that Enterococcus showed a positive correlation with aspartic acid, alanine, and 4-aminobutyric acid and a negative correlation with cysteine. Cigars cured at 15% oxygen concentration for 60 days exhibited optimal quality, particularly in terms of flavor richness and sweetness. These findings suggest that oxygen concentration can alter cigar quality by regulating aerobic and anaerobic microbial community succession. The relationship between specific microbial communities and flavor compounds also provides a theoretical reference for developing artificial control technologies in the cigar curing process.

Investigating the effect of fuel properties and environmental parameters on low-octane gasoline-like fuel spray combustion and emissions using machine learning-global sensitivity analysis method

The gasoline compression ignition mode is an advanced combustion mode that achieves high efficiency with low emissions. This study constructs a global sensitivity analysis (GSA) by coupling machine learning (ML) algorithms and conducts a comprehensive investigation into the statistical correlations between research octane number (RON), fuel sensitivity (S), three initial ambient parameters, and the spray combustion characteristics of gasoline-like fuels. Eighty sets of CFD numerical simulation data were used for training the machine learning model. Results show liquid length (LL) is most sensitive to changes in ambient pressure while ambient temperature significantly influences vapor penetration length (VPL). Regarding combustion behaviors, ignition delay (ID) and flame lift-off length (LOL) show the highest sensitivity to ambient temperature. The occurrence of distinct ignition points in the domain also advances from 1.75 ms to 0.42 ms as the ambient temperature rises from 1000K to 1200K. Additionally, the ambient temperature has higher-order interaction effects with ambient pressure on LOL. The production of NOx in the field is also more closely correlated with ambient temperature, with higher temperatures promoting its generation. Furthermore, ambient temperature exhibits a positive interaction effect with both ambient pressure and oxygen concentration on NOx emissions.

Marine redox and nutrient dynamics linked to the Cambrian radiation of animals

Abstract The early Cambrian witnessed an increase in metazoan ecosystem complexity, likely linked to enhanced oxygen and nutrient availability. However, while improved stratigraphic and geochemical records suggest that the Cambrian explosion occurred under highly dynamic redox conditions, mechanistic links to nutrient availability and early Cambrian evolutionary innovations are poorly constrained. Here, we report paleoredox and nutrient data for two drill cores documenting late Cambrian Stage 2 to Stage 3 (ca. 522–514 Ma) strata from the Yangtze block, South China. The development of water-column euxinia during Cambrian Stage 2 led to extensive recycling of P, fueling elevated primary production and hence an increase in atmospheric and shallow-marine oxygen concentrations. The resulting expansion of oxygenated shelf area promoted sedimentary P retention and, in combination with a diminished supply of P from upwelling, drove a transition to oligotrophic shallow-marine conditions during Cambrian Stage 3. Reduced primary production and limited water-column oxygen consumption allowed for the stabilization of oxygenated continental shelf habitats that supported a burgeoning biotic complexity.

O-214 The effect of constant 5% versus gradient 8%, 5%, 2% oxygen concentration on the development of sibling human embryos in vitro to the blastocyst stage

Abstract Study question Does a physiological gradient of oxygen concentration in embryo culture atmosphere yield a higher percentage of fertilized oocytes developing into morphologically optimal blastocysts? Summary answer Study favours sustaining a static 5% oxygen level, instead of a gradient, during extended embryo culture, resulting in more viable embryos for cryopreservation and transfer. What is known already To date, there’s ongoing research about the optimal oxygen concentration for embryo culture. The available data from studies based on animal models show that the O2 level in the fallopian tube is around 8%, and the in-utero O2 level is at around 2% (Wale & Gardner, 2010). Data on oxygen measurement in the human uterus is scarce, yet aligns with similar findings in other mammalian species (Ng et al., 2018). These findings support the use of sequential O2 levels for embryo culture. Our study stands as the first to implement such dynamic oxygen culture conditions within an in vitro setting. Study design, size, duration A prospective sibling-split oocyte study, analyzing 44 ICSI cycles from January 2022 to January 2023, with alternate allocation into a static 5% (Control group) during entire culture period or under an oxygen gradient (intervention group), starting with 8% from day-0 to day-3, continuing with 5% on day-3 and following with 2% of oxygen from the end of day-3 to day-5/6. Participants/materials, setting, methods 44 ICSI cycles, which produced a total of 521 metaphase II oocytes. A total of 353 2PN embryos were cultured and annotated in time-lapse for morphokinetic and morphometric analysis. Main results and the role of chance While morphological outcomes slightly favored the intervention group for day 2 and day 3 embryos, the trend reversed by day 5. The control group (5% O2) showed a notably higher proportion of zygotes developed to clinically utilized blastocysts (47% vs. 37%, p = 0.016) and consequently more of them were used for transfer on day 5 (10% vs. 4%, P = 0.008) compared to the intervention group. Additionally, though not statistically significant, the control group showed a higher percentage of morphologically optimal blastocysts on day 5 (10.3% vs. 14.7%, p = 0.1233). Morphokinetic timings, as revealed by time-lapse analysis, indicated a delayed development in the intervention group, notably seen in the initiation of blastulation (p = 0.0024), initiation of expansion (p < 0.0001), and full blastocyst formation (p < 0.0001). The speed of blastulation, however, does not necessarily reflect differences in implantation potential, as implantation (58.6% vs 57.1% p > 0.92) and clinical pregnancy rates (55.2% vs 57.1%, p > 0.92) after transferring blastocysts from either group were comparable. Limitations, reasons for caution Measuring the in vivo O2 levels in female reproductive tract should take into account possible oscillations and dynamic nature of gas and nutrient exchange. It’s also important to acknowledge the complexity of embryo’s adaptive response, making it challenging to attribute observed outcomes solely to the impact of targeted oxygen concentration. Wider implications of the findings Based on these clinical results, we will analyze the metabolomic footprint in spent embryo culture under static 5% or gradient 8-5-2% oxygen concentration, employing non-invasive NMR and chromatography methods. A randomized control trial should be conducted to explore the effect of different oxygen regimes on clinical outcomes. Trial registration number NCT05898178

Numerical investigation of diesel spray combustion characteristics in the ammonia/air atmosphere

Ammonia/diesel dual-fuel combustion mode is a promising strategy for decarbonizing internal combustion engines. However, the impact of a premixed ammonia/air atmosphere on diesel spray combustion characteristics is not fully understood. This study analyzes the effects of premixed ammonia/air atmosphere, including premixed equivalence ratio, the cooling effect of liquid ammonia vaporization, and ambient oxygen concentration on the ignition and combustion characteristics and soot yield potential of diesel spray. Numerical simulations using n-heptane as a single-component diesel surrogate reveal that increasing the premixed ammonia equivalence ratio and lowering ambient oxygen concentration extend the ignition delay times and flame lift-off length of n-heptane spray. Liquid ammonia vaporization further prolongs the ignition delay by lowering the ambient temperature during n-heptane auto-ignition. Moreover, there is a trade-off between ignition delay and soot yield potential as longer ignition delays allow more thorough mixing of diesel and premixed gas, reducing soot formation. Given the substantial extension of ignition delay in ammonia/air atmospheres, it is recommended that ammonia/diesel dual-fuel engines operate with higher charged gas temperatures to ensure stable and repeatable ignition events. The negative effects of increased soot yield could be mitigated by using ammonia to reduce soot precursors. Overall, these results underline the need for further fundamental studies on ammonia/diesel co-combustion to facilitate the commercial adoption of ammonia/diesel dual-fuel engines.

Flow characteristics and resistance coefficients of local components of building heat-moisture-oxygen transport pipelines in the Tibetan Plateau

The Tibetan Plateau is characterized by low-pressure, cold, hypoxic, and dry ambient conditions. Thus, in addition to heating, buildings in the region need humidification and oxygenation. It is noted here that the existing specifications of the resistance coefficients of the gas flow in the HVAC pipeline do not consider the effect of the variation in air components on the local resistance of the pipeline due to the low air pressure conditions as well as the humidification and oxygenation. In this paper, the effects of various parameters on the local resistance loss are investigated and reported, including the atmospheric pressure, inlet velocity, humidity, oxygen concentration, pipe diameter, wall roughness, velocity ratio, and area ratio between the branch and the main pipes. The results showed that the decrease in atmospheric pressure leads to a shorter longitudinal distance of effective dissipation of the secondary flow, primarily concentrated in 25D-27D. Additionally, the resistance losses generated in the elbow, the tee straight branch pipe, and the side branch pipe are reduced, with a maximum reduction of 42 %, 33 %, and 46 %, respectively, under low pressure conditions. Also, with the increase in the inlet velocity and the decrease in the pipe diameter, the local resistance of the elbow pipe is increased by a maximum of 14 times and 22 %. Moreover, when the velocity ratio increases and the area ratio between the branch pipe and the main pipe decreases, the local resistance loss of the straight branch pipe and the side branch pipe increases. Based on this study, the recommended value of the local resistance coefficient of the elbow and tee under low pressure is identified. This can provide a reference for the proper design of heat-moisture-oxygen transport pipelines in the plateau area.

Reduction of oxygen content in laser powder bed fusion process atmosphere – Effects on stochastic defect formation and mechanical properties

Stochastic defects in materials manufactured via laser powder bed fusion (LPBF) can severely compromise mechanical performance and are challenging to predict and detect, thus motivating the development of defect mitigation strategies. Particle oxidation is a factor well-known to generate defects by disturbing melt pool dynamics. If the particles are spatters, additional disturbances increase the likelihood of defect formation. In this study, restricting oxygen content in the process atmosphere to 50 ppm is investigated to minimize stochastic spatter-induced defects and improve the mechanical properties of Hastelloy X. Specimens were manufactured under this condition at two nominal layer thicknesses, analyzed for internal defects, and mechanically tested. Contrary to expectations, reducing the oxygen content did not prevent spatter-induced defect formation; rather, it could exacerbate the formation of more numerous and larger defects. Nevertheless, this tighter control of the process atmosphere led to significant microstructural refinement, which, when combined with sparse defects, resulted in improved fatigue performance. Despite the inherent ductility of Hastelloy X, the presence of abundant defects significantly larger than the microstructural characteristic size proved detrimental to fatigue performance. Notably, the occurrence of defects exhibited considerable variation across the build area, contributing to scatter in fatigue data. However, quantitative analysis of in-situ monitoring data enabled prediction of variability in defect content and mechanical performance.

Geochemical Characteristics of Trace Elements and Mineralization Model of the Ediacaran-Early Cambrian Phosphorites, South China.

As a nonrenewable resource, phosphate rock is an important support for the development and survival of the national economy. The regional distribution and output of phosphate rock in China are extremely uneven, and the amount of high-quality ore resources is relatively poor, which seriously restricts the development and utilization of phosphate rock resources in China. This paper briefly summarizes the distribution characteristics of phosphate rock resources and summarizes the characteristics and research progress of Ediacaran-early Cambrian phosphorus mineralization types, geological characteristics, and deposit genesis of the Yangtze platform in South China. The Ediacaran-early Cambrian sedimentary phosphorite deposits in China are mainly distributed in Yunnan, Guizhou, Hubei, Sichuan and Hunan provinces of the Yangtze platform, in which the early Cambrian phosphate deposits are also rich in rare earth elements, associated with uranium, nickel, molybdenum, vanadium, and other beneficial metal elements. The increase of atmospheric oxygen content at the Ediacaran-Cambrian boundary may have promoted the extensive oxygenation of the late Neoproterozoic oceans, so the Ediacaran-early Cambrian oceans generally showed a reductive environment, and there may be dynamic chemical stratification of the oxidation zone-sulfide zone-iron zone. Up to the early Cambrian, the redox stratified structure of Precambrian seawater may still be inherited, showing that the surface water is an oxidizing environment, changing to a reduction environment, and even wedge-shaped sulfide water is developed at the bottom of the deep basin. The main phosphorus sources are deep phosphorus-rich seawater, continental weathering, and deep hydrothermal activity of Ediacaran-early Cambrian marine sedimentary phosphorite deposits in South China. The genetic mechanisms of phosphorite deposits in the Yangtze platform in South China are mainly biogenic, upwelling phosphorus-forming theory, mechanical mineralization, and syn-sedimentary hot water mixed genesis. In the future, it is still necessary to further explore the internal relationship between phosphorus deposits and major geological events, the in situ analysis of microstructure of phosphate rock ores, and the genetic mechanism of phosphate deposits and the reconstruction of paleo-marine environment.

The relation between the Givetian and Serpukhovian biotic crises and long-term environmental trend changes

Explanations for major catastrophes in the history of life commonly focus on their time-spans. Less biotic crises are worth attention as well, however, which requires their investigation in a longer-lasting context. The present study relates the Taghanic (Givetian) and mid-Carboniferous (Serpukhovian) biotic crises to some long-term changes in their environmental developments. The trends in these developments are interpreted on the basis of changes of the global sea level, the global average temperatures, the total surface area of exposed land, the total number of lithospheric plates, and the concentration of atmospheric oxygen. It is found that the Taghanic and mid-Carboniferous biotic crises can be related directly or indirectly to some long-term environmental changes.

Carrier-Phase DNS of Ignition and Combustion of Iron Particles in a Turbulent Mixing Layer

Three-dimensional carrier-phase direct numerical simulations (CP-DNS) of reacting iron particle dust clouds in a turbulent mixing layer are conducted. The simulation approach considers the Eulerian transport equations for the reacting gas phase and resolves all scales of turbulence, whereas the particle boundary layers are modelled employing the Lagrangian point-particle framework for the dispersed phase. The CP-DNS employs an existing sub-model for iron particle combustion that considers the oxidation of iron to FeO and that accounts for both diffusion- and kinetically-limited combustion. At first, the particle sub-model is validated against experimental results for single iron particle combustion considering various particle diameters and ambient oxygen concentrations. Subsequently, the CP-DNS approach is employed to predict iron particle cloud ignition and combustion in a turbulent mixing layer. The upper stream of the mixing layer is initialised with cold particles in air, while the lower stream consists of hot air flowing in the opposite direction. Simulation results show that turbulent mixing induces heating, ignition and combustion of the iron particles. Significant increases in gas temperature and oxygen consumption occur mainly in regions where clusters of iron particles are formed. Over the course of the oxidation, the particles are subjected to different rate-limiting processes. While initially particle oxidation is kinetically-limited it becomes diffusion-limited for higher particle temperatures and peak particle temperatures are observed near the fully-oxidised particle state. Comparing the present non-volatile iron dust flames to general trends in volatile-containing solid fuel flames, non-vanishing particles at late simulation times and a stronger limiting effect of the local oxygen concentration on particle conversion is found for the present iron dust flames in shear-driven turbulence.

Insight into the reaction mechanism of photocatalytic production of solketal

In this work, the behavior of a commercial TiO2 (Evonik P25) and synthesized CeO2 and Bi2WO6 photocatalysts in the photoacetalization of glycerol with acetone to obtain solketal under simulated sunlight was studied. The solids were characterized by X-ray diffraction (XRD), N2 adsorption desorption isotherms, Raman spectroscopy and UV–Vis spectroscopy techniques. The influence of the oxygen content in the reaction atmosphere (1–40% O2) was analyzed. It was concluded that oxygen is essential for the reaction taking place, suggesting the participation of the superoxide radical as an intermediate in the transfer of electrons. To confirm this point, p-benzoquinone, a known superoxide radical scavenger, was used to evaluate the role of O2. However, two opposite effects were observed for p-benzoquinone depending on the amount added to the reaction medium. Thus, for small amounts of p-benzoquinone a negative effect on the yield of solketal was observed, in agreement to its superoxide radical scavenger character. On the contrary, at high concentrations, p-benzoquinone enhanced the solketal yield obtained in the process. A mechanism is proposed by which the semiquinone radical formed acts as an intermediate capable of facilitating the transfer of electrons in the process, thereby improving the overall process. The catalyst showing the lowest catalytic activity was CeO2, whereas Bi2WO6 had a higher reaction rate and activity than TiO2 (P25), with both reaching approximately 78% conversion under optimum conditions. These results are promising because the conversion achieved is comparable to that obtained by acid catalysis, using sunlight as energy source.

Characteristics of the transient heat transfer of impinging flames and correlation analysis using a new characteristic velocity under CI engine-like conditions

Understanding the transient heat transfer mechanism of impinging flames is a crucial pathway for further improving the thermal efficiency of already efficient compression ignition (CI) engines. In this paper, the investigation of the transient heat transfer of wall-impinging flames was performed in a high-pressure constant-volume vessel. Fast-response thermocouples were installed in the impinging wall to record the transient heat flux. Two-color pyrometry was employed to estimate the mean temperature inside the flame region. Firstly, the transient heat transfer characteristics were investigated under varied ambient density, oxygen concentration, temperature, and injection pressure conditions. The optical flame velocity calculation method was applied to this extensive dataset to develop a heat transfer correlation between Nu and Re with which transient heat transfer coefficients were calculated and compared with the experimental results. From this analysis, cumulative fuel injection velocity was developed as the new characteristic parameter to characterize the transient heat transfer of the wall-impinging flames. Results indicate that the effect of fuel injection pressure on the heat flux is more significant than that of ambient gas conditions, with higher injection pressure causing higher heat flux through the impinging wall. No obvious linear tendency of transient Nu and Re was found when using the optical measurement results of the wall-impinging flame as the characteristic parameter. Instead, the cumulative fuel injection velocity shows a strong linear trend of transient Nu and Re during the transient heat transfer processes of the wall-impinging flame. Moreover, the heat transfer coefficients from the new cumulative fuel injection velocity well fit the experimental results.

Understanding the ignition process and flame structure of conventional and oxygenated fuels under engine relevant conditions – An optical study

Renewably generated synthetic fuels such as poly-oxymethylene ethers (OME) have a significant potential to effectively break the soot-NOX trade-off in compression ignition engines by using exhaust gas recirculation (EGR) to maintain low nitrogen oxide (NOX) emissions while maintaining good efficiency and simultaneously contributing to circular carbon economy. However, owing to the fundamental differences in properties of OME when compared to fossil-based diesel fuels, it is critical to fully understand its ignition and combustion phenomenology to take advantage of this fuel to its utmost potential. In this context, this work outlines the results of a systematic experimental study performed in a heavy-duty, single-cylinder, optical engine probing the spatial and temporal progression of fuel decomposition and ignition behavior of OME when compared to n-dodecane, a diesel-fuel surrogate. Thermodynamic analysis and optical diagnostics techniques including simultaneous HCHO-PLIF and OH-PLIF complemented by high-speed OH* chemiluminescence were employed along with parametric sweeps of intake temperature and EGR dilution rates. OME does not exhibit any observable low temperature heat release irrespective of the ambient oxygen concentration. Differences in the observed diffusive flame structure such as longer flame lift-off length, less pronounced combustion recession, faster premixed burn at ignition (“volumetric” ignition), non-sooting behavior suggest that the inherent presence of fuel-bound oxygen in OME can skew the air-fuel ratio (AFR) distribution within the jet thereby reducing the reliance of combustion on mixing and air entrainment. This leads to rapid late-cycle oxidation leading to shorter combustion duration and favorable combustion phasing. Results also suggest that OME exhibits relatively weak negative temperature coefficient (NTC) behavior, however, the OME fuel-decomposition kinetic-pathways produce significant concentration of HCHO, which might be erroneously interpreted as a product of cool-flames.

Combustion characteristics of oxymethylene dimethyl ether-diesel blends: An experimental investigation using a constant-volume combustion chamber

The combustion characteristics of oxymethylene dimethyl ether (OMEx) and its blends with diesel have been investigated using a multi-hole injector in a constant-volume combustion chamber. The results show OMEx addition can reduce the ignition delay, especially when blends of more than 50 vol% are used, at low chamber temperature. Two individual heat-release peaks are observed for OMEx during premixed combustion at 750 K, due to a pronounced low-temperature heat-release phase. The chamber temperature of 800 K can be regarded as a transition point for the behavior of burn duration as well as maximum ROHR peak, mostly caused by combustion regime transition from premixed- to diffusion combustion. It appears that there is an approximate linear relation between maximum ROHR peak and the time at which this peak occurs with injection pressure. The ignition delay of OMEx is almost insensitive to a decrease in ambient oxygen concentration. And the premixed ROHR profile, due to its high oxygen content, is very similar and only ignition delay and burn duration increase slightly. Additionally, comparisons of natural luminosity results for OMEx and diesel indicate that OMEx produces near-zero soot values. Luminosity is expected to be caused by chemiluminescence alone, which increases with injection pressure.