Atmospheric Lead Research Articles

Caribbean Lead and Mercury Pollution Archived in a Crater Lake.

Lead and mercury have long histories of anthropogenic use and release to the environment extending into preindustrial times. Yet, the timing, magnitude, and persistence of preindustrial emissions remain enigmatic, especially for mercury. Here, we quantify tropical lead and mercury deposition over the past ∼3000 years using a well-dated sediment core from a small crater lake (Lake Antoine, Grenada). Preindustrial increases in lead and mercury concentrations can be explained by varying inputs of watershed mineral and organic matter, which in turn reflect climate-driven changes in the lake level. We find no evidence that preindustrial lead and mercury use raised deposition rates in this remote ecosystem, and our results underscore the need to carefully evaluate common normalization approaches for changing lithogenic inputs and sedimentation rates. Industrial-era lead and mercury accumulation rates in Lake Antoine have been accelerated by land use and land cover change within the crater rim, yet global industrial pollution remains evident. After correcting for watershed inputs, we find that recent atmospheric lead and mercury deposition rates averaged 2925 and 24 μg/m2/y, respectively, which are in close agreement with monitoring data. Our results challenge recent assessments suggesting preindustrial mercury use raised atmospheric deposition rates globally, highlighting the unique nature of 20th Century industrial pollution.

Performance and retention mechanisms of corn silk to atmospheric heavy metal lead

Atmospheric heavy metals are seriously harmful, and porous materials have unique advantages in the control of air pollutants. However, the direct use of plant porous materials to purify atmospheric heavy metals are rare. So agricultural waste corn silk with porous structures was selected to analyze the retention capability and mechanism to the atmospheric lead. The results show that the corn silk can effectively retain atmospheric lead in natural growing state or fixed experimental conditions. The analysis of a total of 765 corn silk samples from 17 different regions in Shandong province, China, shows that atmospheric lead is the main source of lead in the corn silk, and corn silk can be used for biological monitoring of atmospheric lead to some extent. Based on the analysis with different techniques including scanning electron microscope (SEM), energy spectrum dispersive X-ray spectrometer (EDS), Fourier infrared spectrometer (FTIR) and Zeta potential, the effective retention of lead by corn silk is due to a variety of mechanisms, including physical adsorption, electrostatic adsorption, complexation, chelation and ion exchange. So agricultural waste corn silk has great potential in the application of biosorption or preparation of porous materials in purification of atmospheric heavy metals.

The atmospheric lead emission, deposition, and environmental inequality driven by interprovincial trade in China

Lead (Pb) as a hazardous air pollutant has raised widespread concerns due to its adverse and toxic effects on the ecological environment and human health. Here we integrated the multi-regional input-output (MRIO) model and an atmospheric transport model to examine regional environmental inequality (REI) index induced by Pb emission transfers, and to evaluate the impacts of interprovincial trade on regional atmospheric Pb concentrations and dry deposition fluxes in China in 2012. In 2012, approximately 57.4% ~ 72.6% of Pb emissions in well-developed eastern regions (Beijing-Tianjin, Yangtze River Delta (YRD)) and the southern seaboard of China were embodied in other regions in China subject to the demands from these well-developed regions to industrial products and services. Our results, based on the net virtual flows of Pb emission and value-added, indicate that most provinces in the eastern seaboard of China outsource Pb emission and benefit from the interprovincial trade by reducing their Pb emissions. REI indexes show that the well-developed Guangdong province outsources its Pb emission but has low economic gains. Many less-developed provinces in central China enhance virtual Pb emission inflow but have high economic gains. Whereas, inland provinces in western China not only experience Pb emission increase, but also suffer from indirect economic loss due to trade with well-developed provinces to meet their increasing demands to Pb emission abundant industrial products from these provinces in eastern China which are mostly provided by less-developed but energy and mineral product abundant provinces in western China. For example, the province pair with highest REI index was Jiangsu-Inner Mongolia (REI = 2.47), which revealed that Jiangsu was the largest beneficiary which exported 37.2 t of net Pb emission and gained value-added of 521.4 billion RMB through trade with Inner Mongolia which suffered from both virtual Pb inflow and economic loss in 2012. As a result of interprovincial trade, Pb dry deposition in central and eastern China was decreased but increased in western China. Overall, interprovincial trade reduced 17.6% of atmospheric Pb dry deposition in China.

The impact of childhood lead exposure on adult personality: Evidence from the United States, Europe, and a large-scale natural experiment

Childhood lead exposure has devastating lifelong consequences, as even low-level exposure stunts intelligence and leads to delinquent behavior. However, these consequences may be more extensive than previously thought because childhood lead exposure may adversely affect normal-range personality traits. Personality influences nearly every aspect of human functioning, from well-being to career earnings to longevity, so effects of lead exposure on personality would have far-reaching societal consequences. In a preregistered investigation, we tested this hypothesis by linking historic atmospheric lead data from 269 US counties and 37 European nations to personality questionnaire data from over 1.5 million people who grew up in these areas. Adjusting for age and socioeconomic status, US adults who grew up in counties with higher atmospheric lead levels had less adaptive personality profiles: they were less agreeable and conscientious and, among younger participants, more neurotic. Next, we utilized a natural experiment, the removal of leaded gasoline because of the 1970 Clean Air Act, to test whether lead exposure caused these personality differences. Participants born after atmospheric lead levels began to decline in their county had more mature, psychologically healthy adult personalities (higher agreeableness and conscientiousness and lower neuroticism), but these findings were not discriminable from pure cohort effects. Finally, we replicated associations in Europeans. European participants who spent their childhood in areas with more atmospheric lead were less agreeable and more neurotic in adulthood. Our findings suggest that further reduction of lead exposure is a critical public health issue.

Dynamic substance flow analysis of lead in the fossil fuel system of China from 1980 to 2018

Lead is mostly found with zinc ores, but is also abundant in fossil fuels. However, the anthropogenic cycle of lead in fossil fuel system has rarely been reported. This study expounds on the evolution of lead metabolism in China's fossil fuel system from 1980 to 2018 through dynamic substance flow analysis. The quantities and structures of lead flows and stocks in the system changed significantly. After the prohibition of leaded gasoline, raw coal became the main source of lead in the system, reaching 101 kt Pb/yr in 2018. The lead outflow of the system underwent a transformation from gas phase to solid phase. The atmospheric lead emission dropped from the highest 20 kt/yr to 4 kt/yr. Most of the lead in the system accumulated in coal-based solid waste. In the past 40 years, 677 kt of lead accumulated in constructions due to the utilization of coal-based solid waste, and 657 kt of lead was left in the redundant coal-based solid waste. The main lead emission stage gradually shifted from the use stage to the waste management stage. Although the flow of lead in fossil fuels is small, there is no significant difference between unintentional (consider only fossil fuels) and intentional use of lead emissions to the atmosphere and landfills. China should improve the utilization of coal-based solid waste, and strengthen the management of landfills and dumps and the surrounding environmental monitoring.

Terrain-modulated deposition of atmospheric lead in the soils of alpine forest, central China

Alpine ecosystem has a potential to intercept the transport of atmospheric metals, while the regulation mechanisms with variations in altitude and slope direction remain unclear. In this study, the soil and moss samples on the northern and southern slopes of Shennongjia Mountain were collected with altitude to quantitatively identify the sources of lead (Pb) and to decipher the regulation mechanisms of altitude and slope on the Pb distribution. The results showed that the concentrations of Pb decreased evidently with soil depth, and in the O (organic soils) and A (surface mineral soils) horizons they increased with altitude. The Pb isotopes and moss biomonitoring revealed that Pb was mainly from atmospheric deposition, and the sources included fossil fuel combustion, ore mining and smelting. Based on a binary mixing model of Pb isotopes, the percentage of atmospheric Pb in the O and A horizons and mosses averaged 58.8%, 43.7% and 71.0%, respectively. Atmospheric wet deposition strikingly controlled the distribution of soil Pb along the altitude. Canopy filtering and leaching also impacted the accumulation of Pb in the forest floor. The significant difference in the atmospheric Pb accumulation in the soils between the two slopes was not observed as expected, since atmospheric dry deposition from northwestern China contributed to the Pb accumulation on the northern slope according to the Pb isotopic ratios and air mass trajectories. The results of this study indicate that altitude determines the distribution pattern of atmospheric Pb, while slope direction screens the source region of Pb in alpine ecosystems.

Sources of atmospheric lead (Pb) after quarter century of phasing out of leaded gasoline in Bangkok, Thailand

After global phasing out of leaded gasoline, anthropogenic sources of atmospheric lead (Pb) are dominated by coal combustion emissions, high-temperature metallurgical processes, and vehicle exhausts. Thailand was one of the first countries in Southeast Asia to completely phase out leaded gasoline by the year 1994. This study investigates the sources of atmospheric Pb in Thai aerosols, a quarter-century after phasing out of leaded gasoline using a multiproxy approach, Pb isotopes in conjunction with trace metal composition of PM2.5. Aerosol samples were collected for 1 year from January 2018 to April 2019 from Bangkok and Chonburi to understand the influence of seasonal variation on aerosol chemistry. Bangkok is the only megacity in Thailand and notorious for traffic congestion and Chonburi is a coastal town, 80 km southeast of Bangkok where the inter monsoon winds make landfall. Aerosol Pb concentrations significantly decreased in 25 years from 74 ± 5 ng/m3 in 1994–1995 to 14 ± 13 ng/m3 measured in Bangkok during Northeast (NE) monsoon winds. Concentrations of all the metals are higher in Chonburi compared to Bangkok in the NE monsoon wind, owing to the addition of local emissions from the megacity over the long-range transported metals before the winds reach the coastal town. The Pb isotope ratios have a wide range (206Pb/207Pb range 1.1343–1.1685 and 208Pb/207Pb range 2.4138–2.4450) but the average ratios are not significantly different in Bangkok and Chonburi for all three seasons. However, present day 206Pb/207Pb ratios are more radiogenic than those measured 25 years ago in Bangkok. The Pb isotopes from both locations in all seasons have considerable overlap with unleaded gasoline and diesel used in Southeast Asia indicating automobile exhaust as an important source. Additionally, the NE monsoon winds are influenced by mixing of crustal dust (Al/Pb ratios correlates well with 206Pb/207Pb, r2 = 0.63) with coal combustion emission (strong inter-correlation of Pb, Zn, As and Cd, r2 from 0.72 to 0.94) from China and Vietnam. Pb isotopes of the Southwest (SW) monsoon winds are also influenced by crustal dust and falls on the mixing line between coal combustion and ore processing emission from India in a Pb triple isotope plot. Chemical composition of aerosols in the inter-monsoon winds are similar to SW monsoon winds. After a quarter-century of leaded gasoline banning in Thailand, the atmospheric Pb sources have changed from less radiogenic leaded gasoline exhaust and Chinese ore processing to more radiogenic unleaded gasoline and diesel exhaust and coal combustion.

Potential Source Areas for Atmospheric Lead Reaching Ny-Ålesund from 2010 to 2018

Lead content, enrichment factors, and isotopic composition (208Pb/206Pb and 207Pb/206Pb) measured in atmospheric particulate matter (PM10) samples collected for nine years at Ny-Ålesund (Svalbard islands, Norwegian Arctic) during spring and summer are presented and discussed. The possible source areas (PSA) for particulate inferred from Pb isotope ratio values were compared to cluster analysis of back-trajectories. Results show that anthropogenic Pb dominates over natural crustal Pb, with a recurring higher influence in spring, compared to summer. Crustal Pb accounted for 5–16% of the measured Pb concentration. Anthropogenic Pb was affected by (i) a Central Asian PSA with Pb isotope signature compatible with ores smelted in the Rudny Altai region, at the Russian and Kazakhstan border, which accounted for 85% of the anthropogenic Pb concentration, and (ii) a weaker North American PSA, contributing for the remaining 15%. Central Asian PSA exerted an influence on 71–86% of spring samples, without any significant interannual variation. On the contrary, 59–87% of summer samples were influenced by the North American PSA, with higher contributions during 2015 and 2018. Back-trajectory analysis agreed on the seasonal difference in PSA and highlighted a possible increased influence for North American air masses during summer 2010 and 2018, but not for summer 2015.

Supplementary material for Potential source areas for atmospheric lead reaching Ny-Ålesund from 2010 to 2018

Supplementary material for Potential source areas for atmospheric lead reaching Ny-Ålesund from 2010 to 2018

Supplementary material for Potential source areas for atmospheric lead reaching Ny-Ålesund from 2010 to 2018

Supplementary material for Potential source areas for atmospheric lead reaching Ny-Ålesund from 2010 to 2018

Atmospheric lead pollution in a typical megacity: Evidence from lead isotopes.

Atmospheric lead (Pb) pollution has adverse health effects on humans, while the sources and atmospheric process of Pb are key scientific problems. In this study, the concentrations and isotopic composition of Pb in fine particulate matter (PM2.5), coal and street dust samples collected from a typical megacity Beijing were analyzed to identify the sources of atmospheric Pb. Results showed that the Pb concentrations in PM2.5 were high in winter (168.1±32.0ng/m3) and low in summer (27.7±9.1ng/m3), whereas Pb isotopic values presented opposite variation trends. The abnormally elevated Pb concentrations in winter were probably related to coal combustion, while declined Pb concentration in summer may be attributed to favorable meteorological parameters such as high temperature, high wind speed, and frequent rain events. Pb isotopic ratios indicated that anthropogenic sources (coal combustion and vehicle exhaust) and natural sources were the main contributors to Pb in PM2.5. Combined with the binary model, the anthropogenic sources predominantly contributed to Pb in the Beijing atmosphere by approximately 85% annually, while the natural sources accounted for the rest of 15%. More specifically, the contribution of natural sources was about 9.4% in spring, 29.7% in summer, 16.0% in autumn and 6.1% in winter, suggesting that natural sources might contribute more lead into the atmosphere during clear days. Furthermore, the contribution of the vehicle exhaust to atmospheric Pb was nonnegligible in megacity, highlighting that the ownership of motor vehicles in megacity should be regulated and more efforts should be paid to strengthen vehicle emission standard. This study may enrich the reservoir of Pb isotopic composition in nature and provides a new method to investigate the Pb migration and transformation in the environment, and also serve as a theoretical reference for pollution control measures.

Supplementary material for Potential source areas for atmospheric lead reaching Ny-Ålesund from 2010 to 2018

Supplementary material for Potential source areas for atmospheric lead reaching Ny-Ålesund from 2010 to 2018

Evaluation of long-term trend of atmospheric lead pollution in western Japan based on lead isotope ratios and Pb/Zn ratio as indicators of long-range transport of aerosols from the Asian continent

In this study, we evaluated the long-term trend of atmospheric lead pollution in western Japan based on lead isotope ratios and Pb/Zn ratio as indicators of long-range transport of aerosols from the Asian continent. First, recent seasonal changes (May 2013–April 2015) in atmospheric lead concentration, lead isotope ratios, and Pb/Zn ratio were investigated in Hirado City on the Asian continent side of Japan. Each parameter increased during winter and decreased during summer. The increase during winter was due to the enhanced long-range transport of lead from the Asian continent based on the back-trajectory analysis and lead isotope ratios of aerosols in major cities of China. Then, the long-term trends (approximately after 1990) of lead concentration, lead isotope ratios, and Pb/Zn ratio during winter in several sites in western Japan were evaluated using the data from this study and literature. The lead concentration and Pb/Zn ratio tended to decrease over the years, whereas the lead isotope ratios in 2013–2015 were lower than the ratios before 2001. These long-term trends were attributable to the long-term changes in atmospheric emissions and sources of lead in China. Moreover, it is likely that the rapid increase in zinc emissions in China also contributed to the decreasing trend of Pb/Zn ratio over the years. This study confirmed that atmospheric lead pollution in western Japan has improved over the years owing to the decrease in the amounts of lead transported from the Asian continent.

The Potential of Tabebuya as Phytoremediator of Lead (Pb) in Atmosphere

Lead (Pb) is one of the heavy metals that causes pollution in ecosystems, heavy metal Pb can cause disturbances to humans, including plants and animals. In Indonesia, especially in Surabaya, Tabebuya grows on main roads as a shade tree as well as an ornamental plant; This plant can be exposed to Pb metal, among others, from motor vehicle exhaust. This study aimed to determine the levels of Pb in Tabebuya and to study chlorophyll in the leaves. Pb levels in plant leaves were measured using an atomic absorption spectrophotometer (AAS), and chlorophyll levels using a spectrophotometer. Data in the form of Pb and chlorophyll levels at various locations were analyzed by analysis of variance (Anova). The results showed that the location of plant species affected the content of Pb metal and there is no effect of chlorophyll content in the leaves. The results also showed that the absorption of lead (Pb) content by the tabebuia 0.25-0.44 ppm and content of chlorophyll 12.89-14, 94. Lead (Pb) content do not affect the amount of leave chlorophyll produced and the plant had capabilities in absorbing lead like pollutants (Pb).

High variability between regional histories of long-term atmospheric Pb pollution

The advent of metal processing was one of the key technological evolutions presaging the development of modern society. However, the interplay between metal use and the long-term changes it induced in the development and functioning of past societies remains unclear. We present a compilation of global records of anthropogenic atmospheric lead (Pb) spanning the last 4000 years, an effective indirect proxy for reliably assessing Pb emissions directly linked to human activities. Separating this global Pb pollution signal into regionally representative clusters allows identification of regional differences in pollution output that reflect technological innovations, market demands, or demise of various human cultures for last 4000 years. Our European reconstruction traces well periods of intensive metal production such as the Roman and Medieval periods, in contrast to clusters from the Americas, which show low levels of atmospheric Pb until the Industrial Revolution. Further investigation of the European synthesis results displays clear regional variation in the timing and extent of past development of polluting activities. This indicates the challenges of using individual reconstructions to infer regional or global development in Pb output and related pollution.

Dispersion Effects of Particulate Lead (Pb) from the Stack of a Lead Battery Recycling Plant

The contribution of emissions from the stack of a lead battery recycling plant to atmospheric lead concentrations and, eventually, to the topsoil of the surrounding area, were studied. A Gaussian dispersion model, of the American Meteorological Society/United States Environmental Protection Agency Regulatory Model, (AERMOD) was used to determine atmospheric total suspended particulate lead dispersion, which originated from stack emissions, over the wider study area. Stack emission parameters were obtained from online measurements of the industry control sensors. AERMOD simulated two scenarios for four calendar years, 2015 to 2018, one for the typical stack measured operating conditions and one for the legal limit operating conditions (emissions from the stack set by legislation to 0.5 mg m−3). Deposition fluxes modeled the input of atmospheric total suspended particulate Pb to the topsoil of the area. X-ray fluorescence (XRF) analyses were used to determine lead concentrations in the topsoil. The modeling results were compared with topsoil of six inhabited locations downwind from the stack in the direction of the prevailing winds to estimate the influence of lead deposition on topsoil near the industrial area.

Postprocessing ensemble forecasts of vertical temperature profiles

Abstract. Weather forecasts from ensemble prediction systems (EPS) are improved by statistical models trained on past EPS forecasts and their atmospheric observations. Recently these corrections have moved from being univariate to multivariate. The focus has been on (quasi-)horizontal atmospheric variables. This paper extends the correction methods to EPS forecasts of vertical profiles in two steps. First univariate distributional regression methods correct the probability distributions separately at each vertical level. In the second step copula coupling re-installs the dependence among neighboring levels by using the rank order structure of the EPS forecasts. The method is applied to EPS data from the European Centre for Medium-Range Weather Forecasts (ECMWF) at model levels interpolated to four locations in Germany, from which radiosondes are released to measure profiles of temperature and other variables four times a day. A winter case study and a summer case study, respectively, exemplify that univariate postprocessing fails to preserve stable layers, which are crucial for many atmospheric processes. Quantile resampling and a resampling that preserves the relative distance between individual EPS members improve the calibration of the raw forecasts of the temperature profiles as shown by rank histograms. They also improve the multivariate metrics of energy score and variogram score and retain the stable layers. Improvements take place over all times of the day and all seasons. They are largest within the atmospheric boundary layer and for shorter lead times.

Isotopic analysis of snow from Dome C indicates changes in the source of atmospheric lead over the last fifty years in East Antarctica

Lead (Pb) concentration and Pb isotope ratios have been determined in 109 snow pit samples collected at Dome C, on the East Antarctic Plateau, corresponding to the period 1971–2017. The Pb concentration was 8.2 ± 1.0 pg g−1 (mean ± 95%-confidence interval), with a decreasing trend from the early 1990s (the median Pb concentration halved from 9.0 pg g−1 in 1970–1980 to 4.4 pg g−1 in 2010–2017). The 206Pb/207Pb and 208Pb/207Pb ratios were 2.419 ± 0.003 and 1.158 ± 0.003 (mean and 95%-confidence interval), respectively. The temporal variations of Pb isotopic composition from 1970 to mid-1990s reflect the changes in the consumption of Pb-enriched gasoline in the Southern Hemisphere, whereas the subsequent increase of the Pb isotope ratios is ascribed to a shift toward the natural isotopic signature. Accordingly, the anthropogenic Pb contribution decreased from (61 ± 3)% in 1980–1990 to (49 ± 10)% in 2010–2017. The measured ratios suggest that Australia has been a significant source of anthropogenic Pb to Antarctica, even in recent times. Differences and similarities among Pb content and isotopic composition in various sites across Antarctica have been displayed by principal component analysis, indicating that the altitude and the distance from the coast significantly affect the Pb content, while the Pb isotopic signatures are not influenced by these parameters.

Lead Distribution in Ground-Level Atmospheric Aerosol of Zaporizhia City

The results of long-term observations on the geochemical peculiarities of technogenic lead distribution in atmospheric aerosol of Zaporizhia, as well as in soils, bottom sediments, suspended matter from Dnipro river and substance from wet gas filters of open-hearth furnaces PJSC Zaporizhstal are presented. The actual material was obtained on the basis of comprehensive field monitoring during 2015-2019. Simultaneous involvement of data on hydrometeorological conditions (seasonality, precipitation, wind speeds, directions and duration) in the study area provided a integral approach to the processing and generalization of research results. A number of peculiarities of sedimentary substance distribution in air, interrelations of its anthropogenic and natural components are defined. Correlations were revealed between lead concentrations changes and aeolian mineral component distribution, seasonality, and a number of other factors. The highest concentration of lead was found in solid aerosol particles accumulated by the sedimentary trap at the monitoring site. It was revealed that the average concentration of investigated element in river suspension of Dnipro exceeds significantly background values, and for soils exceeds more than 3.5 times the permissible norms. At the same time, the fixed form of lead in atmospheric aerosol, in contrast to other environmental objects, loses its domination, giving the way to easily soluble forms, so the evidence of environmental hazard. Monitoring of seasonal patterns of the element distribution in the city air showed excess concentrations in the cold period of the year, which, according to the authors, is due to both meteorological conditions and redistribution of natural and anthropogenic factors that serve the driving force in processes of arriving and conversion of lead in atmosphere during different seasons of the year.

Lead isotopic ratios in the Arctic environment

Environmental contextLead is a toxic trace element, widely distributed in the Arctic environment as the result of both natural and anthropogenic processes. High-precision measurements of lead’s isotopic composition are used to distinguish the possible sources and track the transport pathways of this toxic metal. These measurements can provide unique global information on the history and status of lead contamination. AbstractPublished data of lead isotopic ratios in the Arctic environment have been gathered in a dataset file (available as supplementary material) and reviewed to summarise the main information obtained for the different environmental compartments (atmosphere, cryosphere, lithosphere, hydrosphere and biosphere). The analytical procedures applied to achieve the precise measurement of this important environmental proxy are also illustrated and discussed. Finally, a general overview of the sources of atmospheric lead across the Arctic is provided.