Atmospheric Element Concentrations Research Articles

Evaluation of the Efficiency of Arundo donax L. Leaves as Biomonitors for Atmospheric Element Concentrations in an Urban and Industrial Area of Central Italy

Washed and unwashed Arundo donax L. (A. donax) leaves were analyzed for elements, and results were compared with element concentrations detected in river water and particulate matter (PM) Samples were collected along a river in an urban and industrial hot spot of Central Italy, where element concentrations show relevant spatial gradients both in air and river water. The aim of this study is to identify the role of the two environmental matrices on leaves composition. Element concentrations of washed and unwashed leaves were compared to differentiate between the superficial deposition and the uptake into leaf tissues of elements. Water-soluble and -insoluble element concentrations were measured in PM10 samples collected on membrane filters by using innovative high spatial resolution samplers. The comparison among leaf and atmospheric concentrations of PM10 elements showed a similar trend for Ni, Mo, Cr, Ti, and Fe, which are reliable tracers of the PM10 contribution by steel plant and vehicular traffic. Soluble species appeared to be mainly bounded into leaf tissues, while insoluble species were deposited on their surface. On the other hand, element concentrations detected in washed A. donax leaves were poorly correlated with those measured in river water samples. The obtained results proved that A. donax leaves can be used as reliable biomonitors for the evaluation of the atmospheric concentrations of some PM10 elemental components.

Lichen transplants as indicators of atmospheric element concentrations: a high spatial resolution comparison with PM10 samples in a polluted area (Central Italy)

Lichen transplants Evernia prunastri (L.) Ach. and recently available low-cost PM10 samplers were placed side-by-side for one year at twenty-three sites located in an urban-industrial hot-spot of Central Italy, thus enabling the construction of an extensive and dense air quality monitoring network. Accumulation levels of the elements in lichens after five months and thirteen months of exposure were compared with the means of the element concentrations determined in the PM10 sampled during the same monitoring periods. Water-soluble and insoluble fractions of the elements in the PM10 were separately analysed. Correlations between lichen and PM10 element concentrations were examined by considering Pearson coefficients and by performing principal component analysis. The study allowed us to evaluate the reliability of lichen transplants as biomonitors for the assessment of the spatial variability of atmospheric element concentrations and for the individuation of the elements tracers of PM emission sources. Lichen transplants appeared to be reliable for high spatial resolution measurements of PM10 elemental components emitted at high concentrations by intense local PM emission sources such as the steel plant (Co, Cr, Fe, Mn, Mo, Nb, Ni, Ti and W) and the rail network (Cu, Sb and Sn), less reliable for spatially-resolved analyses of elements released by vehicular traffic (Cu, Sb and Sn) and not reliable for other elements emitted by the power plant, by industrial and domestic biomass heating and/or by other less intense emission sources (Ba, Bi, Cd, Cs, Mg, Pb, Rb and Tl). In general, bioaccumulation of the elements appeared to be more correlated with the total and insoluble fractions of the analysed elements than with the water-soluble one and reflected the solubility of the chemical species emitted by the main local PM emission sources.

Lichen elemental composition distinguishes anthropogenic emissions from dust storm inputs and differs among species: Evidence from Xilinhot, Inner Mongolia, China

To test the applicability of lichens in the biomonitoring of atmospheric elemental deposition in a typical steppe zone of Inner Mongolia, China, six foliose lichens (Physcia aipolia, PA; P. tribacia, PT; Xanthoria elegans, XE; X. mandschurica, XM; Xanthoparmelia camtschadalis, XPC; and Xp. tinctina, XPT) were sampled from the Xilin River Basin, Xilinhot, Inner Mongolia, China. Twenty-five elements (Al, Ba, Cd, Ce, Cr, Cs, Cu, Fe, K, La, Mn, Mo, Na, Ni, P, Pb, Sb, Sc, Sm, Tb, Th, Ti, Tl, V and Zn) in the lichens were analysed using inductively coupled plasma mass spectrometry (ICP-MS). The results show that Cd, Pb and Zn were mainly atmospheric in origin, whereas the other elements were predominantly of crustal origin. Compared with other studies, our data were higher in crustal element concentrations and lower in atmospheric element concentrations, matching with the frequent, severe dust storms and road traffic in the area. The elemental concentrations in lichens are both species- and element-specific, highlighting the importance of species selection for biomonitoring air pollution using lichens. We recommend PT, XE, XM and XPT for monitoring atmospheric deposition of crustal elements; XPC and XPT for Cd and Pb; PA for Cd and Zn; and PT for Cd.

Elemental composition of tropospheric aerosols in Hanoi, Vietnam and Nairobi, Kenya

Air pollution problems in major cities within the developing countries need to be studied. There are scanty measurements from the developing countries on airborne particles despite their adverse implications to human health, visibility and climate. One of the major sources of anthropogenic air pollution is energy production. Energy demand is bound to increase as population increases, especially in major cities of the world. Fine particles, particles with aerodynamic diameter ≤2.5 μm, are mainly anthropogenic and these particles were collected in the capital cities of Vietnam and Kenya. A cyclone airborne particle collector was used to sample in Hanoi during the months of May to October 2000 and a dichotomous virtual impactor in Nairobi in February 2000. The samples were analysed for elemental content by an energy dispersive X-ray fluorescence (EDXRF) spectrometer. S, Cl, K and Fe exceeded atmospheric concentrations of 100 ng m −3 at both cities. Atmospheric elemental concentrations in both Hanoi and Nairobi were orders of magnitude higher than their respective rural towns. Traffic, biomass and waste burning emissions were implicated as the main sources of air pollution in Nairobi, while coal combustion and road transport were the major sources in Hanoi. Regional air pollution had a major impact over Hanoi, whereas an influence of that kind was not identified in Nairobi. Pb and other toxic elements had concentration levels below WHO guideline, however, the two cities are threatened by future high levels of air pollution due to the high rate of population growth. Long-term measurements are required in both areas to evaluate if the alarming situation is deteriorating.

Comprehensive characterisation of atmospheric aerosols in Budapest, Hungary: physicochemical properties of inorganic species

As part of an air pollution project in Budapest, aerosol samples were collected by stacked filter units and cascade impactors at an urban background site, two downtown sites, and within a road tunnel in field campaigns conducted in 1996, 1998 and 1999. Some criteria pollutants were also measured at one of the downtown sites. The aerosol samples were analysed by one or more of the following methods: instrumental neutron activation analysis, particle-induced X-ray emission analysis, a light reflection technique, gravimetry, thermal profiling carbon analysis and capillary electrophoresis. The quantities measured or derived include atmospheric concentrations of elements (from Na to U), of particulate matter, of black and elemental carbon, and total carbonaceous fraction, of some ionic species (e.g., nitrate and sulphate) in the fine ( <2 μm equivalent aerodynamic diameter, EAD) or in both coarse (10– 2 μm EAD) and fine size fractions, atmospheric concentrations of NO, NO 2, SO 2, CO and total suspended particulate matter, and meteorological parameters. The analytical results were used for characterisation of the concentration levels, elemental composition, time trends, enrichment of and relationships among the aerosol species in coarse and fine size fractions, for studying their fine-to-coarse concentration ratios, spatial and temporal variability, for determining detailed elemental mass size distributions, and for examining the extent of chemical mass closure.