The formation and decay of cluster ions, (CO 2) n +, (CO(CO 2) n ) +, H 2O(CO 2) n ) +, (H(H 2O)(CO 2) n ) +, and (H(H 2O) 2(CO 2) n ) + in atmospheric pressure carbon dioxide are observed with a time-resolved atmospheric pressure ionization mass spectrometer (TRAPI). It was found that the reaction of the cluster ions is not always analogous to that of the corresponding bare ions, and that a trace amount of impurities, i.e. H 2O and CO, causes a decisive effect on the reaction course of cluster ions. Relevance of these observations is discussed to the radiolysis of carbon dioxide.
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