Asymmetric Transport Research Articles

Topological Anderson insulators by homogenization theory

. A central property of (Chern) topological insulators is the presence of robust asymmetric transport along interfaces separating two-dimensional insulating materials in different topological phases. A topological Anderson Insulator is an insulator whose topological phase is induced by spatial fluctuations. This article proposes a mathematical model of perturbed Dirac equations and shows that for sufficiently large and highly oscillatory perturbations, the system is in a different topological phase than the unperturbed model. In particular, a robust asymmetric transport indeed appears at an interface separating perturbed and unperturbed phases. The theoretical results are based on careful estimates of resolvent operators in the homogenization theory of Dirac equations and on the characterization of topological phases by the index of an appropriate Fredholm operator.

Tunable Rectification in 2D Porphyrinic Metal–Organic Framework Nanosheets Molecular Heterojunctions

AbstractAs functional electrical devices advance, new strategies for regulating electrical properties are essential for achieving diverse electrical performance. In this study, molecular heterojunction rectifiers are constructed by connecting porphyrinic 2D metal–organic framework (2D MOF) nanosheets and oligophenylene thiols self‐assembled monolayers (OPT SAMs) within metal electrodes. The rectification characteristics can be tuned by the molecular length of OPT and the coordinated metal atom in the center of 2D MOFs. Specifically, a rectification ratio of more than 1.67 orders of magnitude is achieved in the heterojunction composed of 2D Zn‐TCPP MOF nanosheet (TCCP, tetrakis(4‐carboxyphenyl) porphyrin) and OPT3 SAM. Combining Kelvin probe force microscopy measurements and first‐principles calculations of the 2D MOF nanosheets, it elucidates that the rectification variations come from the adjustment of energy level alignment at OPT SAMs//2D MOF interface, leading to asymmetric charge transport with the voltage polarities. This strategy can be further extended to Cu‐MOF nanosheets, which also exhibit rectification behaviors when placed on OPT2 SAMs. This work provides a universal and flexible strategy for regulating the electrical behaviors of MOFs without the need for specific design and synthesis, paving the way for the development of MOF‐based functional electronic devices.

Achieving "Ion Diode" Salt Resistance in Solar Interfacial Evaporation by a Tesla Valve-Like Water Transport Structure.

Salt deposition is a disturbing problem that limits the development of passive solar-driven interfacial evaporation. Inspired by the passive fluid control mechanism of the Tesla valve, a novel solar evaporator is proposed with a Tesla valve-like water transport structure to prevent salt accumulation at the evaporation interface. A unique "ion diode" salt resistance of this evaporator is significantly achieved by optimizing the two asymmetric water transport structures, consisting of one Tesla valve-like side and one wide-leg side, which establish a reverse-suppressing and forward-accelerating water transport channel. In contrast to the limited ion migration of the typical symmetric solar evaporator, such a channel caused by the water/salt ions transport difference between two water supply structures, reinforces the water/salt ions supply on the wide-leg side, thus leading to an apparent unidirectional salt ions migration from the wide-leg side to bulk water through the Tesla valve-like side. Consequently, an evaporation rate of 3.25kg m-2h-1 and a conversion efficiency of 83.27% under 2suns are achieved in 16wt% NaCl solution. The development of the Tesla Valve-like evaporator provides a new perspective for solving salt deposition and realizing scalable applications of solar-driven interfacial evaporation.

Asymmetric vertical transport in weakly forced shallow flows

In this paper, we report on an investigation of the vertical transport of tracer particles released within a shallow, continuously-forced flow by means of numerical simulations. The investigation is motivated by the shallow flows encountered in many environmental situations and inspired by the laboratory experiments conducted in electromagnetically forced shallow fluid layers. The flow is confined to a thin fluid layer by stress-free top and no-slip bottom walls. The dynamics and the transport properties of the shallow flow are investigated under various flow conditions characterized by a Reynolds number related to the forcing, ReF, and the aspect ratio of vertical and horizontal length scales δ. The forcing generates an array of vortices that becomes unsteady when ReFδ2≳10. These vortices are accompanied by upwellings in their cores which are surrounded by narrower, stronger downwellings. Hence, upwellings occur where the horizontal flow is vorticity-dominated, while downwellings where it is strain-dominated. The magnitude of the asymmetry in strength and size of the vertical flows and their correlation with horizontal structures depends on the flow conditions and significantly influences the vertical spreading of particles within the fluid volume. Under conditions leading to a large asymmetry, particles within updrafts are transported slowly upwards, while particles within downdrafts rapidly move downwards. In addition, particles are trapped for longer within the updrafts than downdrafts because of their correlation with vorticity-dominated regions. However, when the flow becomes fully three-dimensional and highly unsteady for large ReFδ2 values, this transport asymmetry subsides because the updrafts and downdrafts exhibit similar strength and size in such flow conditions. Consequently, similar amounts of particles are transported upwards and downwards at similar rates.

In situ noninvasive monitoring of cell secretions based on MOFs/AAO hybrid membrane induced asymmetric ion transport

Nanofluidic hybrid membranes display distinct ionic current rectification (ICR) properties and provide high surface area for immobilizing probes on the outer surface, exhibiting great potential in detection of biomolecules. Herein, we fabricated MOFs/AAO hybrid membrane with aptamers functionalized on the outer surface for in situ detection of living cells released secretions. TNF-α (a small molecular protein secreted by macrophages) was used as a model. After TNF-α was specifically captured by aptamers on the membrane surface, the asymmetry of surface charge on the hybrid membrane was amplified, the ICR was increased from 3.89 to 18.85. According to the ICR change, TNF-α was sensitively measured with a detection limit of ∼0.49 pM, which was significantly lower than other reported methods. When the hybrid membrane was clamped in the middle of self-made device, PET membrane incubated macrophages was rolled up and inserted into the chamber to mimic cellular microenvironment. Macrophages released TNF-α could be real time monitored with ionic current, macrophages and normal cells could be effectively distinguished according to the released TNF-α level. Thus, we proposed a nanofluidic platform for accurately measuring cell secretions in an engineered cellular microenvironment with a direct manner, without the need for labels or amplification steps.

Cytosolic protein translation regulates cell asymmetry and function in early TCR activation of human CD8+ T lymphocytes.

CD8+ cytotoxic T lymphocytes (CTLs) are highly effective in defending against viral infections and tumours. They are activated through the recognition of peptide-MHC-I complex by the T-cell receptor (TCR) and co-stimulation. This cognate interaction promotes the organisation of intimate cell-cell connections that involve cytoskeleton rearrangement to enable effector function and clearance of the target cell. This is key for the asymmetric transport and mobilisation of lytic granules to the cell-cell contact, promoting directed secretion of lytic mediators such as granzymes and perforin. Mitochondria play a role in regulating CTL function by controlling processes such as calcium flux, providing the necessary energy through oxidative phosphorylation, and its own protein translation on 70S ribosomes. However, the effect of acute inhibition of cytosolic translation in the rapid response after TCR has not been studied in mature CTLs. Here, we investigated the importance of cytosolic protein synthesis in human CTLs after early TCR activation and CD28 co-stimulation for the dynamic reorganisation of the cytoskeleton, mitochondria, and lytic granules through short-term chemical inhibition of 80S ribosomes by cycloheximide and 80S and 70S by puromycin. We observed that eukaryotic ribosome function is required to allow proper asymmetric reorganisation of the tubulin cytoskeleton and mitochondria and mTOR pathway activation early upon TCR activation in human primary CTLs. Cytosolic protein translation is required to increase glucose metabolism and degranulation capacity upon TCR activation and thus to regulate the full effector function of human CTLs.

Double-side super-hydrophilic/superspreading fabric for ultrafast asymmetric sweat transport and in-situ power generation

Asymmetric (viz. Janus or one-way transport) fabrics that can promote directional sweat transport from the next-to-the-skin surface to the outer surface by the hydrophobic-hydrophilic difference across the fabric thickness have been developed. However, the hydrophobic next-to-the-skin surface inevitably increases the inherent resistance to sweat transportation into the fabric, fundamentally hampering its moisture management property. In this work, by selectively coating a poly-pyrrole (ppy) film with Turing patterns on one side of the fabric to achieve superspreading property, we demonstrated an all-hydrophilic asymmetric fabric with outstanding one-way liquid sweat transport property. Benefiting from the low resistance of sweat absorption, the all-hydrophilic fabric exhibited a dramatically increased directional sweat transport rate of 13.6 mm/s, which is 5.9 times that of the untreated fabric, and significantly enhanced sweat evaporation rate (1.56 times of the untreated fabric) and cooling performance. Furthermore, the conductive ppy-fabric, during the process of ultra-fast sweat transport, generated a potential of 150 mV over an area of 2×2 cm2 or scalable electrical energy output of 2.5 mW/m2 under continuous sweat transportation. The finding in this work not only provided new insight into the design and development of asymmetric fabric for ultrafast sweat transport but also proposed a novel method for the in-situ energy harvesting during the sweat transportation process, which has potential applications in self-powered smart wearables and functional clothing.

Surface Segregated Monolayers of Fluoroalkylated Rod-like Molecule for Asymmetric Charge Transport at Organic Semiconductor Interfaces

Surface Segregated Monolayers of Fluoroalkylated Rod-like Molecule for Asymmetric Charge Transport at Organic Semiconductor Interfaces

Extended Skyrme momentum-dependent potential in asymmetric nuclear matter and transport models

Extended Skyrme momentum-dependent potential in asymmetric nuclear matter and transport models

Bioinspired green fabricating design of ultra-breathable and moisture wicking fabric via a sustainable route

Functional textiles with breathability, thermal conductivity and moisture wicking performance are critical to achieving human comfort and reducing energy consumption. However, conventional finishing processes used for fabricating moisture wicking fabrics are usually highly polluting and exhibit poor durability as well as low recyclability, which may be detrimental to environmental sustainability. Inspired by the shorebird's beak with a conical-shaped liquid pathway for transporting liquid drops, a novel biomimetic porous fabric is proposed by using natural cotton fibers through industrial and eco-friendly knitting technology, featuring ultra-breathability, thermal conductivity and moisture wicking properties. Moreover, the effects of the pore size and arrangement on the thermal conductivity and air resistance are investigated. Obvious linearities can be obtained (R2 = 0.99). In addition, the synergistic effects of basic pore and biomimetic pore can create surface energy gradients, which result in the asymmetric pressure and water transport. As a result, when the biomimetic pore distances are 3 mm and 5 mm, respectively, high linearities of 0.99 between biomimetic pore diameter and the wicking height can be found. More importantly, the resultant biomimetic pore fabric exhibits good water absorption rate of 350%, an outstanding water vapor transmission (>10000 g/m2/24 h) and high recyclability. The green fabricating design of biomimetic porous fabric opens up a pathway to develop air, thermal, moisture regulating fabric through a sustainable route for more diverse applications, e.g., athletic apparel, industrial workwear and medical garments.

Flexible wavefront manipulation using exceptional points generated by non-interleaved metasurfaces

Precise modulation of the optical wavefront is the main way in which metasurfaces act, and the exceptional point (EP) topological phase provided by non-Hermitian metasurfaces offer an additional degree of freedom for the metasurface design. Here, we design an F-shaped non-interleaved metasurface whose unit cell consists of two basic resonators – a nanowire and a split ring resonator (SRR). By adjusting the strength and coupled-mode of these two resonators, the 2π phase accumulation enclosing the EP, the asymmetric transport properties, and the evolution of wavelength-dependent EP are observed. These properties allow for flexible wavefront manipulation in polarization, amplitude and wavelength dimensions. We simulate and demonstrate a spin-decoupled metasurface hologram, a dual-wavelength decoupled metasurface hologram, as well as a dual-wavelength metasurface for near-field nanoprinting and far-field holography. Non-Hermitian topological metasurfaces can be conveniently combined with other wavefront manipulation mechanisms, showing promising applications in the design of nanophotonic devices.

Non-uniformity of fluctuation characteristics inside an edge magnetic island in Heliotron J

Non-uniform fluctuation characteristics are observed within an edge magnetic island in Heliotron J. The island possesses a long connection length comparable to the confined region. These fluctuations are measured using a Langmuir probe. The island’s presence is confirmed through the plasma response, observed in the modulation amplitude of electron temperature and its phase delay relative to the heat source in a heat modulation experiment. Within the island, the electron density is notably high, accompanied by distinct profiles of electron temperature and electric field, likely attributable to the magnetic island. Contrary to expectations, density fluctuations within the edge magnetic island are not locally minimized, despite the reduced gradient of the profile within the island. Statistical analysis shows a suppression of intermittent transport inside the island, while intermittent fluctuations increase towards the exterior. A further analysis to segregate turbulence-driving and spreading factors reveals that both turbulence-driven and spreading contributions are comparably significant inside the island. Additionally, the non-uniform turbulence results in a spatially structured fluctuation-driven particle flux. Overall, the experimental findings indicate that fluctuation characteristics exhibit notable non-uniformity both inside and near the island. This non-uniformity potentially complicates heat transport and may lead to three-dimensional, asymmetric transport within and at the periphery of the islands.

Asymmetric transport for magnetic Dirac equations

Asymmetric transport for magnetic Dirac equations

Asymmetrical benzothiadiazole core-based hole transport materials for planar perovskite solar cell

For the purpose of fabricating high performance hole transport materials (HTMs) for n-i-p planar perovskite solar cells (PSCs), two asymmetric and one symmetric structured donor-acceptor-donor (D-A-D) type small molecules (a-BTC, a-BTBC and BTDC) were synthesized by introducing two different peripheral groups toward benzothiadiazole core. The a-BTBC with longer π conjugation lengths shows good film formation property, higher hole mobility and conductivity, and achieves power conversion efficiency (PCE) of 23.5 %. It can retain 80 % of the initial PCE after aging 30 days in an ambient condition with relative humidity of 40–60 %. Our results show the potential and provides reference for molecular design of asymmetric structured HTMs.

Transmittance contrast‐induced photocurrent: A general strategy for self‐powered photodetectors based on MXene electrodes

AbstractThe regulation of carrier generation and transport by Schottky junctions enables effective optoelectronic conversion in optoelectronic devices. A simple and general strategy to spontaneously generate photocurrent is of great significance for self‐powered photodetectors but is still being pursued. Here, we propose that a photocurrent can be induced at zero bias by the transmittance contrast of MXene electrodes in MXene/semiconductor Schottky junctions. Two MXene electrodes with a large transmittance contrast (84%) between the thin and thick zones were deposited on the surface of a semiconductor wafer using a simple and robust solution route. Kelvin probe force microscopy tests indicated that the photocurrent at zero bias could be attributed to asymmetric carrier generation and transport between the two Schottky junctions under illumination. As a demonstration, the MXene/GaN ultraviolet (UV) photodetector exhibits excellent performance superior to its counterpart without transmittance contrast, including high responsivity (81 mA W–1), fast response speed (less than 31 and 29 ms) and ultrahigh on/off ratio (1.33 × 106), and good UV imaging capability. Furthermore, this strategy has proven to be universal for first‐ to third‐generation semiconductors such as Si and GaAs. These results provide a facile and cost‐effective route for high‐performance self‐powered photodetectors and demonstrate the versatile and promising applications of MXene electrodes in optoelectronics.image

Dynamic and Asymmetrical Ion Concentration Polarization in Dual Nanopipettes.

Dual nanopipettes with two channels have been receiving great attention due to the convenient experimental setup and multiple measuring channels in sensing applications at nanoscale, while the involved dynamic and asymmetrical ion transport processes have not been fully elucidated. In this paper, both experimental and simulation methods are used to investigate the dynamic mass transport processes inside dual nanopipettes with two well-separated channels. The results present that the ion transport resistance through the two channels (R12) is always the add-up of the individual ones (R13 + R23) with respect to the bulk solutions, at various ionic strengths and scan rates. A constant zero-current potential is obtained when loading an asymmetrical electrolyte concentration in the two channels, and the zero-potential current displays a good linear relationship with the bulk concentration outside the pipet. Besides revealing the dynamic and asymmetrical concentration polarization in the dual nanopipettes, these results would also further promote the better usage of dual nanopipettes in electrochemical sensing and imaging applications.

Asymmetric Electronic Transport in Porphine: Role of Atomically Precise Tip Electrode

Electronic conductance through a single molecule is sensitive to its structural orientation between two electrodes, owing to the distribution of molecular orbitals and their coupling to the electrode levels, that are governed by quantum confinement effects. Herein, the contact geometry of the porphine molecule is varied by attaching two Au tip electrodes that resemble the mechanical break junction, via thiol anchoring groups, is varied. The current–voltage characteristics of all the contact geometries are investigated using nonequilibrium Green's function formalism along with density functional theory and tight‐binding framework. Varying current responses are observed with changing contact sites, originating from varied wave‐function delocalization and quantum interference effect. The calculations show asymmetric current–voltage characteristics under forward and reverse biases due to structural asymmetry of the tip electrodes on either side of the molecule. This phenomenon is established as a universal feature for any molecular electronic device, irrespective of the inherent structural symmetry of a molecule. These findings provide fundamental insights into electronic transport through single molecules in the real experimental setup. Furthermore, the observations of varying current response can further motivate the fabrication of sensor devices with porphine‐based biomolecules that control important physiological activities, in view of their applications in advanced diagnostics.

Preferential transport of synaptic vesicles across neuronal branches is regulated by the levels of the anterograde motor UNC-104/KIF1A in vivo.

Asymmetric transport of cargo across axonal branches is a field of active research. Mechanisms contributing to preferential cargo transport along specific branches in vivo in wild type neurons are poorly understood. We find that anterograde synaptic vesicles preferentially enter the synaptic branch or pause at the branch point in Caenorhabditis elegans Posterior Lateral Mechanosensory neurons. The synaptic vesicle anterograde kinesin motor UNC-104/KIF1A regulates this vesicle behavior at the branch point. Reduced levels of functional UNC-104 cause vesicles to predominantly pause at the branch point and lose their preference for turning into the synaptic branch. SAM-4/Myrlysin, which aids in recruitment/activation of UNC-104 on synaptic vesicles, regulates vesicle behavior at the branch point similar to UNC-104. Increasing the levels of UNC-104 increases the preference of vesicles to go straight toward the asynaptic end. This suggests that the neuron optimizes UNC-104 levels on the cargo surface to maximize the fraction of vesicles entering the branch and minimize the fraction going to the asynaptic end.

Switchable Asymmetric Water Transport in Dense Nanocomposite Membranes.

Directional water transport is technologically relevant in separation processes, functional clothing, and other applications. While asymmetric water transport characteristics are a vital feature of leaf cuticles, examples of artificial membranes that display this effect are limited. Here, we report compositionally asymmetric membranes that are based on hydrophobic poly(styrene)-block-poly(butadiene)-block-poly(styrene) (SBS) and hydrophilic poly(vinyl alcohol) (PVA) nanofibers and display directional water transport when a high relative humidity (RH) gradient is applied. This effect is caused by the asymmetric structure of the membrane and the fact that the water permeability of PVA depends on the water pressure applied and the extent of plasticization that it causes. The transport characteristics can be tuned by varying the composition of the membranes. Such materials with switchable asymmetric water transport may be useful for smart packaging applications in which the take-up or release of water is regulated as needed.

The bosonic skin effect: Boundary condensation in asymmetric transport

We study the incoherent transport of bosonic particles through a one dimensional lattice with different left and right hopping rates, as modelled by the asymmetric simple inclusion process (ASIP). Specifically, we show that as the current passing through this system increases, a transition occurs, which is signified by the appearance of a characteristic zigzag pattern in the stationary density profile near the boundary. In this highly unusual transport phase, the local particle distribution alternates on every site between a thermal distribution and a Bose-condensed state with broken U(1)U(1)-symmetry. Furthermore, we show that the onset of this phase is closely related to the so-called non-Hermitian skin effect and coincides with an exceptional point in the spectrum of density fluctuations. Therefore, this effect establishes a direct connection between quantum transport, non-equilibrium condensation phenomena and non-Hermitian topology, which can be probed in cold-atom experiments or in systems with long-lived photonic, polaritonic and plasmonic excitations.