Asbestos-cement Products Research Articles

Modelling the Spatial Distribution of Asbestos—Cement Products in Poland with the Use of the Random Forest Algorithm

The unique set of physical and chemical properties of asbestos has led to its many industrial applications worldwide, of which roofing and facades constitute approximately 80% of currently used asbestos-containing products. Since asbestos-containing products are harmful to human health, their use and production have been banned in many countries. To date, no research has been undertaken to estimate the total amount of asbestos–cement products used at the country level in relation to regions or other administrative units. The objective of this paper is to present a possible new solution for developing the spatial distribution of asbestos–cement products used across the country by applying the supervised machine learning algorithm, i.e., Random Forest. Based on the results of a physical inventory taken on asbestos–cement products with the use of aerial imagery, and the application of selected features, considering the socio-economic situation of Poland, i.e., population, buildings, public finance, housing economy and municipal infrastructure, wages, salaries and social security benefits, agricultural census, entities of the national economy, labor market, environment protection, area of built-up surfaces, historical belonging to annexations, and data on asbestos manufacturing plants, best Random Forest models were computed. The selection of important variables was made in the R v.3.1.0 program and supported by the Boruta algorithm. The prediction of the amount of asbestos–cement products used in communes was executed in the randomForest package. An algorithm explaining 75.85% of the variance was subsequently used to prepare the prediction map of the spatial distribution of the amount of asbestos–cement products used in Poland. The total amount was estimated at 710,278,645 m2 (7.8 million tons). Since the best model used data on built-up surfaces which are available for the whole of Europe, it is worth considering the use of the developed method in other European countries, as well as to assess the environmental risk of asbestos exposure to humans.

Environmental and Occupational Exposure to Asbestos as a Result of Consumption and Use in Poland.

Asbestos is harmful to human health; exposure to asbestos causes a wide range of asbestos-related diseases. Aim: Malignant mesothelioma (MM) is unique to occupational and environmental asbestos exposure. Methods: Environmental asbestos exposure was examined in relation to asbestos use and manufacturing, the quantity of the asbestos-containing products still in use, the concentrations of asbestos fibres in the air and the number of MM cases diagnosed each year per county. Results: The correlation coefficient of the measurements of the asbestos fibre concentrations in the air and the quantity of asbestos-cement products in use is high and amounts to 0.68. Meanwhile, the correlation coefficient of the measurements of asbestos fibre concentrations in air and MM morbidity rate resulting from environmental exposure calculated for particular counties in provinces is low and amounts to 0.37. The highest MM morbidity rate was observed for Małopolskie and Śląskie, a typical industrial area of Poland. Conclusions: There are MM cases which are still attributable to occupational asbestos exposure, although MM cases resulting from environmental exposure to asbestos have an increased MM risk. Poland is among those countries with a low MM incidence rate, which seems to be an underestimation of environmental asbestos exposure. As long as asbestos-cement products are used in the environment, actions should be undertaken to protect public health.

About the assessment of the chrisothal asbestos dust slip into the atmosphere as a random function

The paper presents the study of the fractional efficiency of asbestos-cement dust slip from the aspiration system as a random function. Total slip was considered as a random variable. Also dispersed analysis of dust from the aspiration systems serving the process equipment and processes was performed. Examples of the function of the dust passage in the production of asbestos-cement products before cleaning in the CSF apparatus and after cleaning showed that the total dust slip in CSF apparatuses as a random value corresponds to the normal distribution law. The density characteristics and the distribution function for the total asbestos cement dust slip penetration are determined. The range of variation of the random dust slip function for CSF-150 and CSF-300 apparatuses is presented. Recommendations are given to reduce the negative impact of the dust factor in the air of enterprise working areas.

Pleural mesothelioma in Poland: Spatial analysis of malignant mesothelioma prevalence in the period 1999-2013.

Malignant mesothelioma (MM), a rare and very deadly tumour, can be due to asbestos exposure. To better understand the cause of incidence of MM, spatial autocorrelation analysis with reference to the quantity of asbestos-cement products in use and the localisation of former asbestos manufacturing plants was applied. Geostatistical analysis shows that strong spatial clustering of MM incidence (referring to the general population as well as females and males separately) during the period 1999-2013 in the administrative units of Poland (provinces and counties). Incidence hotspots were found to be concentrated primarily in southern Poland but also seen in the county of Szczecin, which stands out in local autocorrelation analysis in north-western Poland. High incidence rates were discovered, in particular with reference to counties around former plants manufacturing asbestos-containing products, mainly asbestos-cement manufacturers. The highest frequency of MM incidence rate was found in within a 55 km radius of plants in or near the towns Trzebinia, Ogrodzieniec and Szczucin in the South, where asbestos-cement products had been manufactured for close to 40 years. Areas with significantly high incidence rates were also discovered in the provinces of Śląskie, Małopolskie and Świętokrzyskie in southern Poland.

Spatial analysis of asbestos exposure and occupational health care in Poland during the period 2004-2013.

Asbestos is carcinogenic to humans and exposure to this substance can cause a wide range of diseases. In Poland 1997, a statutory ban was introduced on the production, use and marketing of products containing asbestos. The National Programme for Asbestos Abatement for 2009-2032 includes scheduled activities considering asbestos exposure assessment and health protection. As there are several data sources for asbestos exposure in Poland, which are not linked, the aim of this study was to gather and order them developing a PostgreSQL database, an open-source, objectrelational system. The data gathered combines the following information: the quantity of asbestos-cement products in use, details of asbestos manufacturing plants, the results of the measurements of asbestos fibre concentrations in the air and cases of asbestos-related diseases. The relational database was then used to develop a spatial analysis of asbestos monitoring and exposure in Poland to demonstrate the current state of realisation of the National Asbestos Abatement Programme in the country for 2009-2032 with the use of geoinformation techniques. The use of a database on health aspects of occupational and environmental asbestos exposure was also proposed in Asbestos, Asbestosis, and Cancer: Helsinki Criteria update 2014.

Hydraulic Binder from Hazardous Waste

Since asbestos has been classified as a hazardous chemical, it is desirable to propose a practical and safe procedure for the disposal of asbestos-cement products, or even better to re-use them. In this work, the temperature conditions of degradation of samples of various types of asbestos and products containing asbestos were examined. Samples were burnt at different temperatures and monitored by XRD, DTA, light and electron microscopy. By evaluation of changes at different burning temperatures, the previous findings on the decomposition of asbestos minerals have been confirmed. It has been found that the burning of asbestos cement materials alone or with the addition of limestone at the temperature above 1100 °C leads to the decomposition of hazardous asbestos and, with or without the addition of a setting regulator, hydraulic binder is formed with technological parameters suitable for the building industry.

Asbestos Ban in Italy: A Major Milestone, Not the Final Cut.

Background and history: Italy was the main asbestos producer and one of the greatest consumers in 20th century Europe until the asbestos ban was introduced in 1992. Asbestos exposure affected the population in a wide range of working environments, namely mining and marketing of asbestos, asbestos cement production, shipyards and textile industries. This also determined a widespread environmental asbestos exposure affecting the surrounding communities. Methods: To investigate the drivers and difficulties of the process leading to the asbestos ban and its subsequent implementation, we focused on stakeholder involvement, environmental health policies, capacity building and communication. Results: In the past three decades, stakeholder involvement has been instrumental in advancing the industrial asbestos replacement process, prevention and remediation interventions. Furthermore, involvement also contributed to the integration of environmental and health policies at national, regional and local levels, including capacity building and communication. In a global public health perspective, international scientific cooperation has been established with countries using and producing asbestos. Discussion and Conclusions: Key factors and lessons learnt in Italy from both successful and ineffective asbestos policies are described to support the relevant stakeholders in countries still using asbestos contributing to the termination of its use.

Differences between peritoneal and pleural mesothelioma in Lombardy, Italy

BackgroundWe examined characteristics of peritoneal (PEM) and pleural (PLM) mesothelioma in Lombardy, Italy. MethodsFrom the Lombardy Mesothelioma Registry we selected PEM (N=300) and PLM (N=5011) cases diagnosed in 2000–2014. We investigated asbestos exposure and presence of asbestosis or pleural plaques. ResultsIncidence rates (per 1,000,000 person-years, world standardized) of PEM were 1.2 (men) and 0.9 (women), compared with 22.6 and 8.4 for PLM.Asbestosis (both genders) and pleural plaques (men) were more frequent among PEM cases. Occupational asbestos exposure was similar in PEM and PLM cases. We found higher proportions of PEMs employed in the asbestos cement production. ConclusionThe higher frequency of pleural plaques in PEM cases confirm the association between asbestos and peritoneal mesothelioma. The higher proportions of asbestosis and of past employment in the asbestos-cement sector among PEM cases suggest a possible role of high exposures to asbestos in the peritoneal mesothelioma genesis.

Criminality and Asbestos in Industry.

Criminal prosecutions of individuals in the asbestos industry are reviewed, particularly the case of asbestos owner-executive Stephan Schmidheiny. Italian courts sentenced Schmidheiny to sixteen to eighteen years in jail for creating an environmental disaster causing three thousand deaths. The convictions were overturned on a technicality, and a murder case against Schmidheiny has started. His firm, Eternit, made asbestos-cement building products in many countries. Schmidheiny directed a cover-up that the Italian Court of Appeal blamed for delaying the ban of asbestos in Italy by ten years. Today, the asbestos industry is a criminal industry, profiting only by minimizing its costs for the prevention and compensation of occupational and environmental illness. The asbestos industry should only be consulted by governments for the purpose of closing it and dealing with the legacy of in-place asbestos.

Application of Microwave Energy at Treatment of Asbestos Cement (Eternit)

Asbestos is the common name applied to a group of natural, fibrous silicate minerals, which were once one of the most popular raw materials to be used in building materials. Asbestos was mainly used for the production of assortment asbestos cement products. Today it is generally known that asbestos belongs to the group of hazardous materials and shows carcinogenic activity. It is therefore advisable to attempt to dispose of asbestos minerals in asbestos-containing materials and to convert them into a harmless material. One of methods may be microwave thermal decomposition of asbestos minerals. The research was used for old etemit roof ceiling. X-ray analysis indicated the presence of undesirable chrysotile. Its thermal destruction was carried out in a microwave oven in the power of 2500 W. In case the heating time was 15 min, X-ray analysis was confirmed chrysotile change into harmless minerals. Thermal analysis was used for characterization and the thermal behaviour of the asbestos cement sample.

SENTIERI - Epidemiological study of residents in national priority contaminated sites: incidence of mesothelioma

The purpose of SENTIERI-ReNaM Project is to describe mesothelioma incidence in the Italian National Priority Contaminated Sites (NPCSs). The present report deals with 39 NPCSs (20 in Northern Italy, 8 in Central Italy and 11 in Southern Italy). Asbestos is specifically mentioned in the regulatory acts of recognition for 10 NPCSs and it is the only agent that has determined environmental contamination in 3 of them (Casale Monferrato, Broni, and Bari). The timeframe of the study is 2000-2011 for 34 out of 39 sites. The corresponding reference periods for the sites of Latium, Campania, Umbria, and Bolzano Province are, respectively, 2001-2011, 2005-2011, and 2006-2011. Standardized Incidence Ratios (SIRs) for mesothelioma, with their corresponding 90% Confidence Intervals, have been estimated for all sites. The interpretation of the study findings has been based on anamnestic information made available by the Italian National Mesothelioma Registry (ReNaM), and completed thanks to knowledge derived from the international scientific literature. In men, mesothelioma incidence has shown excesses in 27/39 sites and defects in the remaining 12; in women, excesses have been reported in 20 sites, defects in 15, and no cases have been detected in the remaining 4 sites. The highest annual incidence rates have been observed in the sites characterized only by the presence of asbestos- cement factories (Broni and Casale Monferrato): respectively, 98.0 and 68.6 per 100,000 per year in men, 72.1 and 45.8 in women. Besides these two sites, the highest rates have been observed in the sites with naval shipyards: 13.2 in men and 2.5 in women. Excesses of mesothelioma incidence have been confirmed (with respect to previous observations) in the sites of Broni, Casale Monferrato, Balangero, and in the coastal areas of Trieste, La Spezia, Venice, and Leghorn. Balangero has been the major European chrysotile quarry, while the other sites are characterized by the presence of naval shipyards with demonstrated use of asbestos before it was banned in 1992. An excess of mesothelioma incidence has also been confirmed in the site of Biancavilla, characterized by the presence of the fluoro-edenite fibrous amphibole, classified as carcinogenic to humans by the International Agency for Research on Cancer (IARC). An increased incidence of mesothelioma was also observed in the areas where no direct use of asbestos had previously been documented, like Cengio and Saliceto (chemical industry), Falconara on Sea (oil refinery), and Litorale Domizio Flegreo and Agro Aversano (a large area including multiple hazardous waste dumping sites). These findings show that a relevant proportion of Italian mesothelioma cases is concentrated in NPCSs. About 1,500 extra cases of mesothelioma have been estimated in the overall series of 39 sites (2000-2011), corresponding to 125 extra cases per year. The excess has concerned the sites with manufacture of asbestos-cement products, but also the areas with asbestos quarries, naval shipyards, illegal hazardous waste dumping sites with asbestos-containing materials, petrochemical industries, refineries and steel plants. In some sites, particularly Casale Monferrato and Broni, analytical epidemiological studies have shown the causal role of not only occupational, but also environmental exposures, with special reference to paving of gardens and courtyards with asbestos-cement industry by-products. The main novelty generated by the collaborative SENTIERI-ReNaM Project concerns the detection of significant mesothelioma excesses not only in sites where asbestos is explicitly reported as a source of contamination, but also in a number of areas defined "of national interest" for environmental cleanup due to other sources of pollution. This confirms that the range of economic activities and working and living environments affected by asbestos exposure is very wide and it is not restricted to the industrial sectors characterized by the direct use of this material.

Environmentally related diseases and the possibility of valuation of their social costs.

The risks of the morbidity of the asbestos-related lung cancer was estimated in the general population of Poles as the result of increased exposure to asbestos fibers during the removal of asbestos-cement products and the possibility of the valuation of the social costs related to this risk. The prediction of the new incidences was made using linear regression model. The forecast shows that to the end of 2030 about 3,500 new cases of lung cancer can be expected as a result of occupational exposure to asbestos in the past which makes together with paraoccupational exposure about 14.000 new cases. The forecast shows the increasing number of asbestos-related lung cancer in Poland and indicates the priority areas where preventive action should be implemented.

Thermal decomposition of asbestos-containing materials

Asbestos is the common name applied to a group of natural, fibrous silicate minerals, which were once one of the most popular raw materials to be used in building materials. Asbestos was mainly used for the production of assortment asbestos–cement products. Today it is generally known that asbestos belongs to the group of hazardous materials and shows carcinogenic activity. In Poland, asbestos-containing materials are stored in special landfills. This is not the final solution to the asbestos problem because the fibrous structure of asbestos is still maintained. Therefore, methods based on recycling must be found which will be able to destroy asbestos’ dangerous fibrous structure. One of these methods may be thermal decomposition, where chemically combined water is released from the asbestos materials during heating. This leads to changes in the crystal structure and to the formation of new mineral phases. The aim of the preliminary research presented in this study was to determine the thermal behaviour as well as the structural and phase transformations of asbestos–cement materials during heating to high temperature. In the present study, three different types of asbestos-containing materials from Poland were examined. Differential thermal analysis, thermogravimetry with evolved gas analysis, X-ray diffraction, infrared spectroscopy and scanning electron microscopy were used to study the thermal decomposition of asbestos–cement samples. It was found that there were no significant differences between the type of asbestos–cement samples used—their thermal decomposition takes place in a similar way.

Оценка канцерогенной опасности асбоцементного производства Украины

Оценка канцерогенной опасности асбоцементного производства Украины

The Continuous Use of Asbestos in Ghana Despite Its Hazards (Case Study Area: Sekondi-Takoradi)

This paper reported on a research work conducted with the aims of investigating the regulatory position regarding the use of asbestos and also of assessing the evidence of the continuous use of asbestos cement products in the construction industries in Ghana, using Sekondi-Takoradi as a case study area. This paper adopted both quantitative and qualitative research approach to seek information from, landlords, and manufacturers of asbestos cement products, parliament and other Government Agencies. Data was obtained through questionnaire, interview and field work survey. In all, a total of 20 questionnaires were distributed. The research emerged that about 1200 housing units roofed with asbestos cement roofing sheet were constructed by the state owned construction company between 1976 and 2000 in the Sekondi-Takoradi Metropolis (about 12,000 nationwide), a period when the risk of asbestos was known in Ghana. The study in the newly developing areas in the Sekondi-Takoradi Metropolis indicated that, out of every 100 housing unit being built, at least 40 of these were roofed with asbestos cement corrugated roofing sheet. It was also emerged from this research that there were no laws prohibiting the use, manufacturing or importation of asbestos products in Ghana. And this exposes maintenance workers in the building construction industries to the risk of asbestos related diseases. The research recommended that those who have asbestos materials present in their premises should take action to manage the risk so that no one will unknowingly disturb it and also provide information about the material to those who are likely to disturb it.

Environmental asbestos pollution — Situation in Poland

Environmental exposure of the general population to asbestos in Poland is mainly due to degradation of very popular asbestos-cement products and the resultant release of the elementary asbestos fibres into the ambient air. Assessments of environmental pollution by asbestos were based on the volume of the raw material used, amount of manufactured asbestos products, and measuring the concentration of fibres in the air. Under the governmental program intended to remove asbestos, measurements of the concentration of asbestos fibres were performed in 2004-2010 in all provinces of Poland. Considering that potential sources of asbestos dust emissions were present in residential areas, 1634 sampling sites were designated. From 2 to 4 air samples were collected at each sampling site. A total of 5962 samples were collected during seven years. A single dose of air collected by 25 mm 0.8 μm pore Sartorius filter was 1,300 litres. The fibres were counted using optical microscopy with phase contrast (PCM) on a polarizing microscope (PLM) at a total magnification of 600×.; method was adapted to determine the concentration of asbestos fibres in non-occupational environment. Mean concentration of asbestos fibres was 492 f/m(3) (95% CI: 467-518). In 82% of the sampling sites, the mean concentrations did not exceed 800 f/m(3). As much as 25.8% of the samples were found to be below the detection limit of the method. Estimated mean concentrations of fibres in different provinces ranged from 146 (95% CI: 106-203) to 709 f/m(3) (95% CI: 591-851). In the areas affected by former asbestos-processing plants, mean concentration was 732 f/m(3) (95% CI: 527-1016) and was significantly higher than levels recorded in other areas of Poland. Asbestos consumption per capita and the recorded moderate levels of asbestos fibres concentration in atmospheric air point to a relatively low level of environmental asbestos pollution in Poland.

우리나라 일부 석면 함유제품에 대한 실태조사

This study was performed to investigate the current status, in Korea, of the production of asbestos containing products (ACPs) such as asbestos cement products, asbestos friction materials, asbestos joint sheets, asbestos textile products, and other asbestos-containing products from May 2 to July 30, 2007. The information on ACPs was obtained through written questionnaires from 16 of the 27 companies that produce ACPs in Korea. The production amounts of asbestos containing gaskets were 70 tons in 2004, 90 tons in 2005, and 55 tons in 2006 in 4 companies and that of asbestos friction materials were 435.5 tons in 2004, 540.4 tons in 2005, and 454.3s ton in 2006 in 10 companies. The type and number of ACPs were:- 19 asbestos cement products, produced by 2 companies; 47 asbestos friction materials produced by 18 companies; 12 asbestos joint sheets productes by 4 companies; 18 asbestos textile products from 3 companies, and 6 other asbestos products from 5 companies. The database of ACPs was constructed to include the products name, identification number, name of company, production year, composition, asbestos content (%), usage, specification, and a picture. The database will be used to efficiently identify ACPs and to avoid asbestos exposure in workers and the general population.

Analysis of latency time and its determinants in asbestos related malignant mesothelioma cases of the Italian register

Italy was an important producer of raw asbestos until 1992 (when it was banned) and it is now experiencing severe public health consequences due to large-scale industrial use of asbestos in shipbuilding and repair, asbestos-cement production, railways, buildings, chemicals and many other industrial sectors. Latency of malignant mesothelioma generally shows a large variability and the relationship with the modality of asbestos exposure is still not fully clarified. We present an analysis of latency period among the case list collected by the Italian mesothelioma register (ReNaM) in the period of diagnosis 1993–2001 (2544 malignant mesothelioma (MM) cases with asbestos exposure history). Exposure is assessed retrospectively by interview. Statistical univariate analyses were performed to estimate median and variability measures of latency time by anatomical site, gender and diagnosis period. The role of diagnostic confidence level, the morphology of the tumour and the modalities of asbestos exposure were verified in a regression multivariate model. We found a median latency period of 44.6 years increasing in recent years with a linear trend. Anatomical site, gender and morphology were not relevant for MM latency time whereas a shorter latency period was documented among occupationally exposed subjects (43 years) with respect to environmentally and household exposed ones (48 years).

Анализ канцерогенной опасности аля работающих на асбестоцементных производствах (аналитическое исследование с использованием мета-анализа)

Анализ канцерогенной опасности аля работающих на асбестоцементных производствах (аналитическое исследование с использованием мета-анализа)

Asbestos Ban in India

Rapidly industrializing India is described by the International Monetary Fund as a young, disciplined, and vibrant economy with a projected growth of 6.7% for 2005. The total workforce of 397 million has only 7% of workers employed in the organized sector with construction, where asbestos exposure is prevalent, employing 4.4%. The domestic production of asbestos declined from 20,111 tons in 1998-1999 to 14,340 tons in 2002-2003. The imports from Russia and Canada increased from 61,474 tons in 1997-1998 to 97,884 tons in 2001-2002. The production of asbestos cement products went up from 0.68 million tons in 1993-1994 to 1.38 million tons in 2002-2003. The asbestos industry has been delicensed since March 2003. The number of asbestos-based units stood at 32, with the western state of Maharashtra having the largest number. According to official figures, the industry employs 8000 workers. The occupational exposure standard is still 2 fibers/mL, worse still, mesothelioma is not recognized as an occupational disease. The latest cancer registry data have no information on mesothelioma. The health and safety legislation does not cover 93% of workers in the unorganized sector where asbestos exposures are extremely high. Workers remain uninformed and untrained in dealing with asbestos exposure. Enforcement agencies are not fully conscious of the risks of asbestos exposure. Industrial hygiene assessment is seldom carried out and pathologists do not receive training in identifying mesothelioma histopathologically. The lack of political will and powerful influence of the asbestos industry are pushing India toward a disaster of unimaginable proportion.