The transmit/receive-receive (T/R-R) synergetic High Frequency Surface Wave Radar (HFSWR) has increasingly attracted attention due to its high localization accuracy, but multi-target pairing needs to be performed before localization in multi-target scenarios. However, existing multi-target parameter matching methods have primarily focused on track association, which falls under the category of information-level fusion techniques, with few methods based on detected points. In this paper, we propose a multi-target pairing method with high computational efficiency based on angle information for T/R-R synergetic HFSWR. To be more specific, a dual-receiving array signal model under long baseline condition is firstly constructed. Then, the amplitude and phase differences of the same target reaching two subarrays are calculated to establish the cross-correlation matrix. Subsequently, in order to extract the rotation factor matrices containing pairing information and improve angle estimation performance, we utilize the conjugate symmetry properties of the uniform linear array (ULA) manifold matrix for generalized virtual aperture extension. Ultimately, azimuths estimation and multi-target pairing are accomplished by combining the propagator method (PM) and the ESPRIT algorithm. The proposed method relies solely on angle information for multi-target pairing and leverages the rotational invariance property of Vandermonde matrices to avoid peak searching or iterations, making it computationally efficient. Furthermore, the proposed method maintains superb performance regardless of whether the spatial angles are widely separated or very close. Simulation results validate the effectiveness of the proposed method.