Arrangement Of Layers Research Articles

Structural Analysis and Processing Characterization of Chitins Extracted from Different Sources.

The characteristics of three different types of chitin extracted from commonly used seafood organisms; namely crabs, shrimps, and squids were investigated. X-ray powder diffraction (XRPD) and scanning electron microscopy (SEM) were employed to analyze these chitins' polymorphic structure and morphology. Bulk and tapped density measurements, along with Kawakita analysis, were used to assess the flowability and compression behaviour of the chitin powders. Chitin extracted from crabs and shrimp exhibited the α-polymorphic form, while chitin from squid showed the β-polymorphic form. SEM images of the two forms revealed distinct differences in chitin layer arrangement, with the α-form appearing more compact due to the anti-parallel alignment of its polymer chains. Both bulk and tapped density measurements and the calculated Hausner ratio (HR) and Carr Index (CI) indicated poor flowability for these chitins. However, Kawakita's analysis of compression and compaction properties demonstrated that both polymorphs are compressible, though they differ in their extent of compaction. Regardless of their source, chitin compacts exhibited high crushing strength. Based on the observed morphology, flowability, and compression characteristics, a blend of α- and β-polymorphic chitin could be an effective excipient for pharmaceutical solid dosage forms.

Miniaturized silicon-based capacitive six-axis force/torque sensor with large range, high sensitivity, and low crosstalk

Miniaturized six-axis force/torque sensors have potential applications in robotic tactile sensing, minimally invasive surgery, and other narrow operating spaces, where currently available commercial sensors cannot meet the requirements because of their large size. In this study, a silicon-based capacitive six-axis force/torque sensing chip with a small size of 9.3 × 9.3 × 0.98 mm was designed, fabricated, and tested. A sandwich decoupling structure with a symmetrical layered arrangement of S-shaped beams, comb capacitors, and parallel capacitors was employed. A decoupling theory considering eccentricity and nonlinear effects was derived to realize low axial crosstalk. The proposed S-shaped beams achieved a large measurement range through stress optimization. The results of a coupled multiphysics field finite-element simulation agreed well with those of theoretical analyses. The test results show that the proposed sensing chip can detect six-axis force/torque separately, with all crosstalk errors less than 2.59%FS. Its force and torque measurement ranges can reach as much as 2.5 N and 12.5 N·mm, respectively. The sensing chip also has high sensitivities of 0.52 pF/N and 0.27 pF/(N·mm) for force and torque detection, respectively.

Ultrathin Ti3C2Tx MXene/Cellulose nanofiber composite film for enhanced mechanics & EMI shielding via freeze-thaw intercalation

Developing high-performance and cost-effective microwave-absorbing materials for large-scale production is crucial in addressing the current electromagnetic pollution problem. This has become a focus of scientific research. This study proposes a cost-effective freeze-thaw method to enable large-scale production of MXene-based flexible films. This method streamlines the preparation process and produces ultrathin flexible MXene/CNF composite films with a multidimensional layered structure. The multidimensional layered structure provides additional scattering and reflecting paths for electromagnetic waves, increasing the interaction time between electromagnetic waves and the material. Additionally, the redistributed interfacial charge enhances the dielectric loss and electromagnetic shielding performance for the shielding material, thereby improving microwave absorption efficiency. Owing to these advantages, the MXene/CNF composite films prepared using the freeze-thaw method exhibit excellent electromagnetic shielding and mechanical properties. The conductivity of the composite film can reach 165.9 S cm−1 with a shielding effectiveness of 54.7 dB, and a high efficiency of 99.74 %. According to the simulations using a finite element method (FEM), the arrangement and rotation angles of all CNF layers significantly affect the electromagnetic shielding effectiveness of the MXenen/CNF composite films.

MXene Manipulating the Electronic and Photoelectric Properties of a Fullerene-Layered Heterojunction.

An in-depth study of the substrate effect is crucial for optimizing and designing the performance of two-dimensional (2D) materials in practical applications. Fullerene monolayers (FMs), a new pure carbon system successfully prepared recently, have prompted renewed interest in the question of whether FMs might be exploited to create carbon-based functional materials with improved performance. Here, the electronic structure of a MXene-supported FM was investigated by first-principles calculations. Various band offset types, including types I, II, and III, exist in the FM/M2X heterostructures, which are determined by the energy level arrangement of individual layers. Interestingly, strain also plays an important role in the band offset of the FM/M2X heterostructures. From the selection of a specific substrate and introduction of proper strain in the substrate, the desired band structure can be obtained. Our results offer profound physical insights into the mechanism of electronic structure tuning of FM by substrates.

Investigation of non-reciprocity and behavior of defect modes in photonic crystals incorporating Weyl semimetals

Abstract The ability to control the frequency of defect modes in photonic crystals has led to the emergence of novel applications. Researchers have recognized the unique properties of Weyl semimetals and explored their utilization in photonic crystals. This study investigates the non-reciprocal properties in photonic crystals incorporating Weyl semimetals and examines the behavior of defect modes within these crystals. This paper employs a photonic crystal containing Weyl semimetals with two different structures. Initially, the non-reciprocal properties in both structures are examined, followed by an analysis of the behavior of defect modes. The results indicate that only utilizing Weyl semimetal in the photonic crystal does not result in non-reciprocity. The arrangement of layers next to each other, or the geometry, plays a crucial role in non-reciprocity. Additionally, the behavior of defect modes varies depending on the structure type and propagation direction.

A numerical investigation of the structural behavior of reinforced concrete beams fully or partially encased with UHPC layers in flexure

Weakness in the structural facilities appears due to design faults, poor construction, usage change, maintenance lack, material defects, and environmental conditions. Therefore, strengthening structures becomes necessary for deteriorated concrete and enhancing aging concrete elements to achieve satisfactory performance perfectly. This study numerically investigated the structural behavior of conventional concrete beams reinforced with Ultra-High Performance Concrete (UHPC) layers on different sides. The arrangement of UHPC layers, bonding method between traditional concrete and UHPC, layer thickness, and reinforcement ratio were examined using Abaqus software. The interface between the UHPC layer and conventional concrete sustains compressive, tensile, and shear stresses, which cause weak resistance to the stresses at the contact surfaces. Therefore, the simulation of contact face in Abaqus needs a proper numerical model relying on practical methods. However, using the bonding models available in Abaqus is crucial for reaching logical results comparable to the practical ones. The practical bonding approaches are highly consequential, such as roughening surfaces by sandblasting to attain a firm connection between the contact surfaces, which permits using a surface-based tie constraint for simulation. Further, epoxy resin conducts as a thin coating between contact surfaces, making it possible to simulate via a cohesive surface. The results proved that increasing the area encased by the UHPC layer improves load capacity further and reduces the deflection at the maximum load. Surrounding the beam on whole sides with a UHPC raises load capacity by 108 % and reduces deflection by 46 %. Adding a UHPC layer to the beam delays crack initiation and reduces their number and spacing. Increasing the UHPC layer thickness or reinforcement ratio enhances the load capacity of the beam at cracking and the ultimate state.

Enhanced electrical and mechanical properties of graphene/copper composite through reduced graphene oxide-assisted coating

Modifying the surface of metallic materials with graphene (Gr) holds significant potential for achieving high electrical conductivity in metal-based composites, leveraging the synergistic effect of the high carrier concentration in metals and the high carrier mobility of Gr. However, the strong van der Waals forces and large specific surface area of Gr sheets often lead to agglomeration in slurrys, adversely affecting the arrangement of Gr layers within the coating structure. In this study, we introduce reduced Gr oxide (rGO) into the Gr slurry to enhance the electrostatic stability and dispersion of Gr sheets through π-π interactions. By precisely controlling the composition of the coating, a compact, low-roughness coating was prepared on the surface of the copper (Cu) wire. The fabricated Gr/rGO/Cu composite wire exhibited a high conductivity of 104.2% IACS, with a tensile strength of 266.1 MPa and the elongation of 36.3%, respectively. This study demonstrates that the addition of rGO improves the dispersibility of Gr in the slurry, leading to a more compact and effective composite structure. The Gr/rGO/Cu composite wires exhibit superior electrical and mechanical properties, making them promising candidates for high-performance applications in electrical and electronic industries.

Manipulation of ionic transport behavior in smart nanochannels by diffuse bipolar soft layer

Soft bipolar nanochannels provide distinct and valuable understanding of the intricate relationship among shape, charge distribution, concentration, and flow dynamics. This study investigates the intriguing realm of nanoscale structures, where two distinct configurations of soft layers with varying charges provide an intricate but appealing setting for the movement and management of ions, as well as the regulation and control of ionic species in nanochannels with five various geometries. It generates cylindrical, trumpet, dumbbell, hourglass, and conical forms. The nanochannels are coated with a diffuse polyelectrolyte layer, and the charge density distribution in the soft layer is described using the soft step distribution function. To enhance accuracy, the impact of ionic partitioning is taken into account. To investigate the effect of soft layer polarity, two types were considered: Type I and Type II. In Type I, the negative pole is at the start, while in Type II, the positive pole is at the start. Thus, Type I features a bipolar soft layer arrangement of negative–positive (NP), whereas Type II has a positive–negative (PN) configuration. The research was conducted under stationary conditions using the finite element method, Poisson–Nernst–Planck, and Navier–Stokes equations. By manipulating variables such as the arrangement order, charge density of the soft layer, and bulk concentration, a numerical analysis was performed to investigate the impact of these variables on current–voltage parameters. The results demonstrate the soft layer with a positive charge serves as a more effective receiver layer for generating greater rectification. For instance, the dumbbell-shaped nanochannel exhibits a rectification of 2046 at a concentration of 1 mM and the lowest charge density in the soft layer. From an alternative perspective, the conductivity in bipolar nanochannels is significantly influenced by the bulk concentration. The study's findings on the fundamental principles of soft bipolar nanochannels have profound implications for the diverse applications of nanochannels. The capacity to regulate and manipulate ion transport through these nanochannels can result in enhanced efficiency, selectivity, and performance in various processes.

Effect of layering and pre-loading on the dynamic properties of sand-rubber specimens in resonant column tests

AbstractSeveral studies show that scrap tyre rubber mixed with sand is an effective and sustainable method for mitigating vibrations. The dynamic and cyclic response of this composite soil has already been investigated. However, layered sand-rubber configurations have not been considered yet. This study reports findings of resonant column tests on three types of specimen: (a) sand-only or rubber-only, (b) layered sand-rubber, and (c) sand-rubber mixtures. The analysis allowed for an evaluation of the maximum shear modulus and its degradation with strain over a wide range of confining stress and shear strain. The evolution of the damping ratio with strain was determined analogously. Effects of pre-loading and pre-straining were also considered. The results show that the behaviour of layered specimens is much more similar to that of pure rubber than to sand-rubber mixtures, with very low shear modulus values, smaller degradation of stiffness with strain and pre-loading, and higher damping. For example, at the confining stress of 100 kPa and rubber content of 0/33.3/50/67.7/100% by volume, the small strain shear moduli for sand-rubber mixtures are equal to 98.3/30.4/15.4/7.1/1.3 MPa and 98.3/3.6-4.2/2.4-2.8/2.1/1.3 MPa for sand-rubber layered specimens, depending on the arrangement of layers. A shear beam model is shown to be adequate for calculating the response of the layered specimens comprising layers of large stiffness contrast.

Modulation of bandgap and transport properties by stacking symmetry in bilayer binary materials

The interlayer interactions in layered two-dimensional materials, which are formed by Van der Waals forces, significantly influence the control of electronic and transport properties. The manipulation of the stacking order can modulate these interlayer interactions by altering the atomic arrangement in different layers. In this study, we conducted a systematic examination of the bandgap modulation of bilayer two-dimensional binary materials at high symmetry stackings. A general trend of bandgap modulation has been proposed through a tight-binding model and corroborated by density functional calculations. The mechanisms of bandgap modulation can be leveraged to control the transport properties of devices built with bilayer two-dimensional binary materials. Our research findings offer valuable insights for the control of bandgap in layered two-dimensional materials and their application in transport devices.

Hydrogen‐bond‐regulated mechanochemical synthesis of covalent organic frameworks: cocrystal precursor strategy for confined assembly

Two‐dimensional imine covalent organic frameworks (2D imine‐COFs) are crystalline porous materials with broad application prospects. Despite the efforts into their design and synthesis, the mechanisms of their formation are still not fully understood. Herein, a one‐pot two‐step mechanochemical cocrystal precursor synthetic strategy is developed for efficient construction of 2D imine‐COFs. The mechanistic investigation demonstrated that the cocrystal precursors of 4,4',4''‐(1,3,5‐triazine‐2,4,6‐triyl)trianiline (TAPT) and p‐toluenesulphonic acid (PTSA) sufficiently regulate the crystalline structure of COF. Evidenced by characterizations and theoretical studies, a helical hydrogen‐bond network was constructed by the N‐H···O supramolecular synthons between amine and sulfate in TAPT‐PTSA, demonstrating the role of cocrystals in promoting the organized stacking of interlayer π‐π interactions, layer arrangement, and interlayer spacing, thus facilitating the orderly assembly of COFs. Moreover, the protonation degree of TAPT amines, which tuned nucleophilic directionality, enabled the sequential progression of intra‐ and interlayer imine condensation reactions, inhibiting the formation of amorphous polymers. The transformation from cocrystal precursors to COFs was achieved through comprehensive control of hydrogen bond and covalent bond sites. This work significantly advances the concept of hydrogen‐bond‐regulated COF assembly and its mechanochemical method in the design and synthesis of 2D imine‐COFs, further elucidating the mechanistic aspects of their mechanochemical synthesis.

Hydrogen-Bond-Regulated Mechanochemical Synthesis of Covalent Organic Frameworks: Cocrystal Precursor Strategy for Confined Assembly.

Two-dimensional imine covalent organic frameworks (2D imine-COFs) are crystalline porous materials with broad application prospects. Despite the efforts into their design and synthesis, the mechanisms of their formation are still not fully understood. Herein, a one-pot two-step mechanochemical cocrystal precursor synthetic strategy is developed for efficient construction of 2D imine-COFs. The mechanistic investigation demonstrated that the cocrystal precursors of 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TAPT) and p-toluenesulphonic acid (PTSA) sufficiently regulate the crystalline structure of COF. Evidenced by characterizations and theoretical studies, a helical hydrogen-bond network was constructed by the N-H⋅⋅⋅O supramolecular synthons between amino and sulfonic groups in TAPT-PTSA, demonstrating the role of cocrystals in promoting the organized stacking of interlayer π-π interactions, layer arrangement, and interlayer spacing, thus facilitating the orderly assembly of COFs. Moreover, the protonation degree of TAPT amines, which tuned nucleophilic directionality, enabled the sequential progression of intra- and interlayer imine condensation reactions, inhibiting the formation of amorphous polymers. The transformation from cocrystal precursors to COFs was achieved through comprehensive control of hydrogen bond and covalent bond sites. This work significantly advances the concept of hydrogen-bond-regulated COF assembly and its mechanochemical method in the design and synthesis of 2D imine-COFs, further elucidating the mechanistic aspects of their mechanochemical synthesis.

Ballistic properties of bioinspired nacre-like ceramic/polyurea staggered composite structures

We proposed a bioinspired ceramic/polyurea composite plate that draws on a “brick-mortar” arrangement of nacre layer, with a periodic three-dimensional structure and interlayers polyurea elastomers. We fired a 12.7 mm armor-piercing incendiary bullet using a ballistic gun to conduct depth-of-penetration (DOP) experiments. We analyzed the damage, fracture morphology, and residual DOP of ceramic/polyurea-staggered composite structures (CPSCS), with a theoretical prediction model for the residual DOP. Using the adaptive FEM-SPH algorithm, we compared the damage morphology of CPSCSs. We analyzed projectile penetration process and summarized four toughening modes using stress wave propagation. Based on simulation fitting and theoretical calculations, we obtained the residual DOP curves at different projectile velocities and analyzed the toughening effect of the CPSCSs through the energy dissipation of each structural component. When the areal density was the same, the residual DOP of the CPSCSs decreased by 33.9 %, and the critical velocity theoretically increased by 32.72 %. The error between the model calculations and experimental results was 11 %. The CPSCSs enabled the ceramic to increase the energy absorption efficiency by 179.70 %. With the same structural form, changing the thickness of only one component did not have the same effect on the structural energy-absorption efficiency as changing the entire form.

Induced Pluripotent Stem Cell-Derived Parathyroid Organoids Resemble Parathyroid Morphology and Function.

The primary role of the parathyroid glands is to maintain calcium homeostasis through the secretion of parathyroid hormone (PTH). The limited proliferative capacity and differentiation of parathyroid cells hinder the generation of cell therapy options. In this study, parathyroid organoids are successfully generated from human-induced pluripotent stem cells (hiPSCs). At the end of the 20 days of differentiation, the parathyroid organoids exhibited distinct parathyroid morphology. Stereomicroscope, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) analysis demonstrated the 3D arrangement of the cell layers in which intracellular structures of parathyroid cells resemble human parathyroid cellular morphology. Comprehensive molecular analyses, including RNA sequencing (RNA-Seq) and liquid chromatography/mass spectrometry (LC-MS/MS), confirmed the expression of key parathyroid-related markers. Protein expression of CasR, CxCr4, Gcm2, and PTH are observed in parathyroid organoids. Parathyroid organoids secrete PTH, demonstrate active intercellular calcium signaling, and induce osteogenic differentiation via their secretome. The tissue integration potential of parathyroid organoids is determined by transplantation into parathyroidectomized rats. The organoid transplanted animals showed significant elevations in PTH-related markers (CasR, CxCr4, Foxn1, Gcm2, and PTH). PTH secretion is detected in organoid-transplanted animals. The findings represent a significant advancement in parathyroid organoid culture and may offer a cellular therapy for treating PTH-related diseases, including hypoparathyroidism.

Orthogonal cutting of 3D printed multi-material workpiece: numerical investigation of machining forces, stress, and temperature distribution

AbstractWith the development of 3D metal printers for rapid prototyping and industrial component production, heightened attention was directed towards post-processing operations for achieving precise surface quality and geometrical tolerances for these components. This paper investigated the orthogonal cutting of multi-material 3D printed workpieces using a coated cutting tool through finite element simulation. The workpieces featured different horizontal and vertical arrangements of layers composed of aluminum 7075-T6 alloy (Al), stainless steel 316 low alloy (SS), and Ti6Al4V alloy (Ti). The study explored the impacts of multi-material composition, coating thickness, and the rake angle of the cutting tool on machining forces, stress distribution, temperature distribution, and chip formation geometry. The results revealed a bimodal chip morphology in the machining process of horizontally arranged SS layers combined with other alloys. The SS layer resulted in a relatively uniform chip formation, while layers with two other materials exhibited a serrated chip formation. In contrast, a discontinuous chip formed when combining Al and Ti materials, as well as in the horizontally arranged layers made of Al, SS, and Ti alloys. The cutting force increased by 2.26 times when cutting workpieces with the horizontal arrangement of SS and Al layers compared to those with a single Al material. For the horizontal and vertical arrangement of layers made of Al and SS, von Mises stress values over the edge of the coated cutting tool significantly increased where the tool contacted the SS layer. Additionally, the horizontal arrangement of layers made of Al and SS materials caused the coated cutting tool to exhibit an extensive temperature distribution, with the maximum recorded temperature reaching 1448 °K. Increasing coating thickness led to a decrease in maximum principal stress at the surface of the tool and a rise in temperature at the cutting edge of the insert.

Design and optimization of broadband near-perfect absorber based on transition metal nitrides thin-films for solar energy harvesting

Broadband metamaterial absorbers hold promise for solar energy harvesting, but their complex designs and use of expensive noble metals hinder scalability and thermal stability. Additionally, traditional design methods are time-consuming. We propose a novel approach that combines a genetic algorithm with the transfer matrix method to optimize both material composition and layer structure for large-scale, cost-effective, and thermally stable solar absorbers. This method enables the design of near-perfect absorbers with an average absorptance exceeding 90 % and over 80 % across a broad wavelength range (0.3–2.5 μm) within the key solar spectrum. By optimizing the arrangement of metal and insulator layers using nitride materials (e.g., vanadium nitride), we achieve superior performance compared to traditional metal–insulator and insulator–metal structures. This optimization utilizes resonant absorption and the inherent absorption of metal layers. Our work paves the way for efficient and scalable solar energy harvesting devices.

High-Sensitivity Janus Sensor Enabled by Multilayered Metastructure Based on the Photonic Spin Hall Effect and Its Potential Applications in Bio-Sensing.

The refractive index (RI) of biological tissues is a fundamental material parameter that characterizes how light interacts with tissues, making accurate measurement of RI crucial for biomedical diagnostics and environmental monitoring. A Janus sensor (JBS) is designed in this paper, and the photonic spin Hall effect (PSHE) is used to detect subtle changes in RI in biological tissues. The asymmetric arrangement of the dielectric layers breaks spatial parity symmetry, resulting in significantly different PSHE displacements during the forward and backward propagation of electromagnetic waves, thereby realizing the Janus effect. The designed JBS can detect the RI range of 1.3~1.55 RIU when electromagnetic waves are incident along the +z-axis, with a sensitivity of 96.29°/refractive index unit (RIU). In the reverse direction, blood glucose concentrations are identified by the JBS, achieving a sensitivity of 18.30°/RIU. Detecting different RI range from forward and backward scales not only overcomes the limitation that single-scale sensors can only detect a single RI range, but also provides new insights and applications for optical biological detection through high-sensitivity, label-free and non-contact detection.

Limit states of thin-walled composite structures with closed sections under axial compression

The subjects of the study were thin-walled composite columns with closed cross sections manufactured using the autoclave technique. The composite profiles were characterized by the fact that they had a constant height and arrangement of laminate layers, however, varied cross-sectional shapes. The study was conducted using several interdisciplinary experimental research methods and advanced numerical simulations. In the course of the research, both forms of structural stability loss were registered, and damage to composite structures was assessed. In the course of the research, the influence of the shape of the cross-section on the stability and load-carrying capacity of the structure was evaluated. A measurable effect of the conducted research was the determination of the structure's post-buckling equilibrium paths, which made it possible to determine the structure's behavior in the full range of loading. In addition, the author's numerical models developed enabled validation of parallel experimental studies. The developed numerical models were based on a failure criterion known as progressive failure analysis - which allowed a thorough assessment of the failure mechanism of the composite material.

Synthetic ground motions in heterogeneous geologies from various sources: the HEMEWS-3D database

Abstract. The ever-improving performances of physics-based simulations and the rapid developments of deep learning are offering new perspectives to study earthquake-induced ground motion. Due to the large amount of data required to train deep neural networks, applications have so far been limited to recorded data or two-dimensional (2D) simulations. To bridge the gap between deep learning and high-fidelity numerical simulations, this work introduces a new database of physics-based earthquake simulations. The HEterogeneous Materials and Elastic Waves with Source variability in 3D (HEMEWS-3D) database comprises 30 000 simulations of elastic wave propagation in 3D geological domains. Each domain is parametrized by a different geological model built from a random arrangement of layers augmented by random fields that represent heterogeneities. Elastic waves originate from a randomly located pointwise source parametrized by a random moment tensor. For each simulation, ground motion is synthesized at the surface by a grid of virtual sensors. The high frequency of waveforms (fmax⁡=5 Hz) allows for extensive analyses of surface ground motion. Existing and foreseen applications range from statistical analyses of the ground motion variability and machine learning methods on geological models to deep-learning-based predictions of ground motion that depend on 3D heterogeneous geologies and source properties. Data are available at https://doi.org/10.57745/LAI6YU (Lehmann, 2023).

A Dual-Carbon Potassium-Ion Capacitor Enabled by Hollow Carbon Fibrous Electrodes with Reduced Graphitization.

The large size of K+ ions (1.38 Å) sets a challenge in achieving high kinetics and long lifespan of potassium storage devices. Here, a fibrous ZrO2 membrane is utilized as a reactive template to construct a dual-carbon K-ion capacitor. Unlike graphite, ZrO2-catalyzed graphitic carbon presents a relatively disordered layer arrangement with an expanded interlayer spacing of 0.378nm to accommodate K+ insertion/extraction. Pyridine-derived nitrogen sites can locally store K-ions without disrupting the formation of stage-1 graphite intercalation compounds (GICs). Consequently, N-doped hollow graphitic carbon fiber achieves a K+-storage capacity (primarily below 1V), which is 1.5 time that of commercial graphite. Potassium-ion hybrid capacitors are assembled using the hollow carbon fiber electrodes and the ZrO2 nanofiber membrane as the separator. The capacitor exhibits a high power of 40 000 W kg-1, full charge in 8.5 s, 93% capacity retention after 5000 cycles at 2 A g-1, and a low self-discharge rate of 8.6mV h-1. The scalability and high performance of the lattice-expanded tubular carbon electrodes underscores may advance the practical potassium-ion capacitors.