Arkosic Sandstones Research Articles

Recycling of the Proterozoic crystalline basement in the Coastal Block (Moroccan Meseta): New insights for understanding the geodynamic evolution of the northern peri-Gondwanan realm

Detrital zircon age spectra from the siliciclastic rocks of the Lalla Mouchaa Calcschists and El Jadida Dolomitic formations (the Coastal Block of the Moroccan Meseta) are dominated by Paleoproterozoic and Ediacaran ages. The provenance of these two formations is a composite Proterozoic crystalline basement. El Jadida rhyolite (584.2 ± 4.8 Ma) represents the Ediacaran crystalline basement of the El Jadida dome. El Jadida rhyolite is unconformably overlain by the microbreccia, arkosic sandstone and dolostone of the El Jadida Dolomitic Formation with a maximum depositional age of ca. 539 Ma (Lower Cambrian). Detrital zircon-age spectra from El Jadida Dolomitic Formation (ca. 583–582 Ma) suggest direct recycling of El Jadida rhyolite as an exclusive original primary source. However, in the Western Rehamna massif, detrital zircon-age spectra from pre-Middle Cambrian microbreccia and arkosic sandstone of the Lalla Mouchaa Calcschists Formation (ca. 2.05–2.03 Ga) indicate exclusive recycling of the ca. 2.05 Ga-aged crystalline basement rocks (original primary source). Detrital zircon contents of the siliciciclastic rocks from these two formations of the Coastal Block are consistent with derivation from either Eburnian (Paleoproterozoic) or Cadomian/Pan-African (Ediacaran) igneous rocks. The discovery of this composite Proterozoic crystalline basement in the Moroccan Meseta stresses that Cadomian/Pan-African magmatic arcs were built on an Eburnian basement in a paleoposition close to the West African craton, as part of the northern peri-Gondwanan realm.

Lithostratigraphy of Tabul Formation and Onshore Geology of Nunukan Island, North Kalimantan

Nunukan Island is located in Northeast Kalimantan Basin, one of prolific basin in western Indonesia. However, this island lies in northern verge of the basin and hydrocarbon exploration were limited before the 1940s. No detail geological fieldworks has been published. This paper attempts to share geological information obtained from few accessible outcrops, particularly from the western part of the island where previous oil drilling were carried out. Most of the island have been built by Tabul Formation, which was also the main objective of reservoir for hydrocarbon exploration. It is composed of claystones, siltstones, and sandstones interbeds, deposited in transitional environment during Late Miocene. They exhibit coarsening upward sequence, the lower part composed of heterolitic sandstones deposited in tidal flats, and the upper part composed of arkosic sandstones deposited in distributary channels and mouthbars. The eastern coastal strip was constructed by Tarakan conglomerates, which have been deposited in fluvio-deltaic environment in Pliocene, unconformably over the Tabul clastics. Those Neogene deposition of paleo-Simengaris Delta apparently deformed and inverted in Plio-Pleistocene, contemporaneously with basaltic volcanism which spread widely over northeastern Borneo, which also observed in the northern half of the Nunukan Island

Radium mobility and the age of groundwater in public-drinking-water supplies from the Cambrian-Ordovician aquifer system, north-central USA

High radium (Ra) concentrations in potable portions of the Cambrian-Ordovician (C-O) aquifer system were investigated using water-quality data and environmental tracers (3H, 3Hetrit, SF6, 14C and 4Herad) of groundwater age from 80 public-supply wells (PSWs). Groundwater ages were estimated by calibration of tracers to lumped parameter models and ranged from modern (<50 yr) in upgradient, regionally unconfined areas to ancient (>1 Myr) in the most downgradient, confined portions of the potable system. More than 80 and 40 percent of mean groundwater ages were older than 1000 and 50,000 yr, respectively. Anoxic, Fe-reducing conditions and increased mineralization develop with time in the aquifer system and mobilize Ra into solution resulting in the frequent occurrence of combined Ra (Rac = 226Ra + 228Ra) at concentrations exceeding the USEPA MCL of 185 mBq/L (5 pCi/L). The distribution of the three Ra isotopes comprising total Ra (Rat = 224Ra + 226Ra + 228Ra) differed across the aquifer system. The concentrations of 224Ra and 228Ra were strongly correlated and comprised a larger proportion of the Rat concentration in samples from the regionally unconfined area, where arkosic sandstones provide an enhanced source for progeny from the 232Th decay series. 226Ra comprised a larger proportion of the Rat concentration in samples from downgradient confined regions. Concentrations of Rat were significantly greater in samples from the regionally confined area of the aquifer system because of the increase in 226Ra concentrations there as compared to the regionally unconfined area. 226Ra distribution coefficients decreased substantially with anoxic conditions and increasing ionic strength of groundwater (mineralization), indicating that Ra is mobilized to solution from solid phases of the aquifer as adsorption capacity is diminished. The amount of 226Ra released from solid phases by alpha-recoil mechanisms and retained in solution increases relative to the amount of Ra sequestered by adsorption processes or co-precipitation with barite as adsorption capacity and the concentration of Ba decreases. Although 226Ra occurred at concentrations greater than 224Ra or 228Ra, the ingestion exposure risk was greater for 228Ra owing to its greater toxicity. In addition, 224Ra added substantial alpha-particle radioactivity to potable samples from the C-O aquifer system. Thus, monitoring for Ra isotopes and gross-alpha-activity (GAA) is important in upgradient, regionally unconfined areas as downgradient, and GAA measurements made within 72 h of sample collection would best capture alpha-particle radiation from the short-lived 224Ra.

Seasonal Variations of Groundwater Chemistry in the Basement and Sedimentary Rocks of Ibadan and Lagos Areas, Southwestern Nigeria

Hydrochemical investigation of forty boreholes drilled on the basement and sedimentary rocks in Ibadan and Lagos metropolis southwestern Nigeria respectively were carried out in order to determine the portability of the groundwater in both areas and to highlight differences in their chemical characters and variations with seasons. Data obtained indicated that the groundwater in Ibadan area is mainly the Na + Ca – HCO­­3type, while that of Lagos is Na + Ca – C1 + SO4 type. The groundwater chemistry reflects weathering of sodic plagioclase feldspars in the basement rocks as well as arkosic sandstone in the sedimentary terrain. The higher chloride (ca. 124.2 mg/L) content of the Lagos water is probably due to salt-water intrusion along the coastal area. Elevated Na+ (58.5-1021.2), Fe2+ (0.3-2.8) and Mn2+ (0.04-2.34) mg/L concentrations, particularly during the dry season, adversely affect the portability of the water from both localities. Apart from making the water unsuitable for irrigation, high Na+ content is considered harmful to persons suffering from cardiac, renal and circulatory diseases. The Fe2+and Mn2+ contents could also create staining problem. It is therefore desirable to remove these elements from the borehole water prior to consumption.

Urucum Neoproterozoic–Cambrian manganese deposits (MS, Brazil): Biogenic participation in the ore genesis, geology, geochemistry, and depositional environment

The Urucum region (Mato Grosso do Sul, Brazil) contains Neoproterozoic–Cambrian manganese ore in the layers Mn-1, Mn-2, and Mn-3, which are interbedded with iron formations (IFs) from the Santa Cruz Formation (Jacadigo Group) and surrounded by carbonate rocks from the Bocaina and Tamengo Formations (Corumbá Group). These rocks fill an ancient graben, with sediments from the Santa Cruz Formation overlying fluvial deposits from the Urucum Formation and limestones from the Bocaina and Tamengo Formations deposited in the shallow marginal regions. As the graben deepened, it was flooded with microbe-rich seawater and hydrothermalism began. Iron and manganese precipitated within the pores in arkosic sandstones, thereby forming the clastic Lower Mn-1 ore layer. The remaining manganese was simultaneously deposited on the basin floor with clastic clay and silt from turbidity currents, thereby forming the Upper Mn-1 clastic–chemical ore layer. The sedimentation of Mn-1 and its host IFs was controlled by seawater saturation and homogeneous oxidation, which caused manganese and iron sedimentation and the death of microorganisms, generating mangano-ferriferous sediments with high P, Co and Ni contents. Mn-2 formed during periods of tectonic quiescence through water influxes that carried abundant microbes, Fe(II), Mn(II), and SiO2. Under UV radiation, these microbes oxidized Mn(II) and Fe(II) to form hydroxides and died, thereby forming biomass that was enriched in P, Co and Ni and minor carbonate adjacent to and below the oxycline. These microbes also formed kremydilites, oblate structures that resemble manganese stromatolites, within the biomass and produced CH4 and/or H2 gas bubbles. During early diagenesis, wormlike organisms inhabited the biomass and probably separated iron from manganese to produce cryptomelane microbialites, which agglutinated to form manganese micronodules that coalesced to form the massive layer Mn-2. This process ended with the disappearance of microorganisms and the sedimentation of the IFs, and a new water influx generated layer Mn-3 via the same process. The final seawater upwelling precipitated IFs in the basin depocenter, whereas limestone from the Tamengo Formation was deposited along the basin’s edges. The diagenesis initially transformed the manganese oxides into cryptomelane and then into hollandite.

Petrographic Characteristics and Depositional Environment Evolution of Middle Miocene Sediments in the Thien Ung - Mang Cau Structure of Nam Con Son Basin

DOI: 10.17014/ijog.4.3.143-157This paper introduces the petrographic characteristics and depositional environment of Middle Miocene rocks of the Thien Ung - Mang Cau structure in the central area of Nam Con Son Basin based on the results of analyzing thin sections and structural characteristics of core samples. Middle Miocene sedimentary rocks in the studied area can be divided into three groups: (1) Group of terrigenous rocks comprising greywacke sandstone, arkosic sandstone, lithic-quartz sandstone, greywacke-lithic sandstone, oligomictic siltstone, and bitumenous claystone; (2) Group of carbonate rocks comprising dolomitic limestone and bituminous limestone; (3) Mixed group comprising calcareous sandstone, calcarinate sandstone, arenaceous limestone, calcareous claystone, calcareous silty claystone, dolomitic limestone containing silt, and bitumen. The depositional environment is expressed through petrographic characteristics and structure of the sedimentary rocks in core samples. The greywacke and arkosic sandstones are of medium grain size, poor sorting and roundness, and siliceous cement characterizing the alluvial and estuarine fan environment expressed by massive structure of core samples. The mixed calcareous limestone, arenaceous dolomitic limestone, and calcareous and bituminous clayey siltstone in the core samples are of turbulent flow structure characterizing shallow bay environment with the action of bottom currents. The dolomitic limestones are of relatively homogeneous, of microgranular and fine-granular texture, precipitated in a weakly reducing, semi-closed, and relatively calm bay environment.

Chemostratigraphic insights into fluvio-lacustrine deposition, Yanchang Formation, Upper Triassic, Ordos Basin, China

A chemostratigraphic study of a 300 m long core recovered from the southeastern central Ordos depocenter reveals thick ([Formula: see text]) intervals of fine-grained, organic-rich lacustrine strata, interpreted to represent deepwater deposition under meromictic conditions (incomplete watermass overturn) during lake highstand phases, interspersed with thick (10–30 m) intervals of arkosic sandstones, reflective of fluvio-deltaic deposition during lake lowstand phases. Along with elevated concentrations of %Al, traditionally a proxy for clay content, maximum total-organic-carbon (TOC) values in the deepwater lacustrine facies reach 8%, with average values of approximately 3%. The fine-grained, organic-rich facies is also characterized by elevated S (up to 6%) and As concentrations, both proxies for pyrite, an indicator of more stagnant, reducing conditions in the hypolimnion (the volume of the lake below the surface mixing zone) during lake highstand phases. Enrichment factors for redox-sensitive trace elements (RSTEs) are not significantly elevated throughout the TOC-rich intervals, but they are punctuated in thinner intervals. Punctuated enrichments in RSTEs reflect episodes of enhanced suboxia/anoxia in the hypolimnion during lake highstand phases resulting from sustained meromixis (protracted episodes of incomplete watermass turnover). Although dramatic shifts between fluvio-deltaic and deepwater lacustrine deposition are recorded in the Yanchang strata, no evidence indicates that the lacustrine system ever built up a significant salt concentration, suggesting that an outlet was maintained throughout much of the depositional history. A chemofacies framework for the Yanchang Formation is developed based on hierarchical cluster analysis and ranking of major element chemostratigraphic results. The outcome of chemofacies analysis is similar to the lithofacies analysis, subdividing the stratigraphic record of calcite-cemented sandstone/siltstone lithologies (fluvio-deltaic facies) and silty to finer grained mudstone lithologies (deep-water lacustrine facies) based on changes in elemental concentrations that equate to shifts in the relative abundance of mineral contents (e.g., clays, quartz, feldspars, pyrite, and carbonates).

창원시 의창지역 보난자형 금광상 성인 : 반응경로 모델링에 의한 지구화학적 해석

의창지역의 삼정광산과 용장광산의 금광화작용은 보난자(Bonanza)형 금광상의 특성을 나타낸다. 광상은 퇴적암 내의 장석질 사암과 석영맥의 접촉부에서 주로 산출되며, 금과 은을 함유하는 광물은 에렉트럼과 더불어 은황화광물 및 황산염광물로 산출된다. 반면, 광상의 모암이 쳐트질 암석과 안산암인 경우에는 금광화작용이 장석질 사암의 경우보다 미약하게 발달된다. 이 연구에서는 금의 침전 특성을 파악하기 위하여 열수용액과 장석질 사암 및 안산암간의 수치모델링에 의한 다성분 다상계 평형계산을 실시하였다. 모델링에서는 함금은 광물인 에렉트럼 및 수용액상 또는 기상 원소들이 사용되었다. 반응경로 모델링 결과, pH가 증가함에 따라 석영, 녹니석, 견운모, 황동석, 방연석, 황철석, 에렉트럼, 양기석과 장석이 침전되었다. 또한, 에렉트럼은 모암과 광화용액 간의 반응에 의한 급격한 pH 증가와 탈황화작용에 의해 침전되었음을 확인하였다. 금 은비는 용액의 pH 조건이나 아칸다이트와 폴리바사이트와 같은 은황화 광물 침전에 의해 변화되었다. 한편, 안산암과 열수용액과의 반응에서 침전된 광물은 열수용액과 장석질 사암과의 반응에서 침전된 광물과 유사하지만 상대적으로 적은 양의 에렉트럼이 침전되었다. 이러한 연구결과로 미루어 볼 때 의창지역 보난자형 금광화작용의 부광대는 모암 규제에 의해 형성되었다고 판단된다. Gold mineralization of Samjeong and Yongjang gold mines in Uichang area shows characteristics of Bonanza-type gold deposits. Ores are mainly developed along the contact parts between quartz vein and arkosic sandstone beds(Fe-rich bed) in sedimentary rock. Electrum, silver sulfide and sulfate minerals are mainly in the ores. On the other hand, gold mineralization is less developed in cherty rock and andesitic rock than arkosic sandstone. The study highlights characteristics of gold precipitation in the deposit on the basis of numerical modelling of the reactions between the assumed hydrothermal ore fluids with multicomponent heterogeneous equilibrium calculations. Aqueous species, gases and minerals, containing electrum are included in the calculations. The reaction result between hydrothermal ore fluids and arkosic sandstone show that pH increasing in the ore-forming fluid would trigger precipitation of quartz, chlorite, sericite, chalcopyrite, galena, pyrite, electrum, actinolite and feldspar. The numerical modelling also illustrates the drastic increase of pH and desulfidation lead to precipitation of electrum. Ag/Au ratios in the ore vary with pH conditions and subsequently precipitation of silver-bearing sulfides such as acanthite and polybasite. The modelling of the reaction between andesitic rock and ore-forming fluid shows that mineral assemblages of the case are analogous to ones of the reaction between arkosic sandstone and fluid except the latter has little portion of electrum. The abovementioned modelling results suggest that gold-silver mineralization is bounded by host rocks at the study area.

Experimental interaction of hydrothermal Na-Cl solution with fracture surfaces of geothermal reservoir sandstone of the Upper Rhine Graben

The Upper Rhine Graben (URG) is a Tertiary rift structure in central Europe offering favorable conditions for geothermal energy utilization. Relatively high heat flow combines with sufficiently high permeability of the hydrothermal reservoirs. One of the target stratigraphic levels is the lower Triassic sandstone formation (Buntsandstein), where hot water resources at temperatures up to 250 °C can be utilized. Extensional neotectonics and hydraulic stimulation form new fracture surfaces in the reservoir rocks (enhanced geothermal system, EGS). The exposed fresh rock fracture surface reacts with the highly saline reservoir brines (Na-Cl up to 200 g l−1) with consequences for the permeability of the reservoir.In order to better understand the dynamic evolution of fault systems caused by fluid-rock interaction, we conducted batch-type experiments in a stirred autoclave system and reacted arkosic sandstone with synthetic 2 molal Na-Cl solution at temperatures of 200 °C and 260 °C. After 45–55 days reaction time altered rock samples were compared with the starting material and the geochemical-mineralogical processes were deduced with the help of XRD, SEM methods and EMP measurements. Fluid compositions were examined by ICP-MS, ICP-OES and IC.The arkosic sandstones show a surprisingly high reactivity during the experiments. Quartz grain surfaces show deep dissolution features and all reaction fluids were saturated with respects to quartz. Illite and kaolinite from the primary sandstone cementation completely dissolved from the sample surface. Perfectly euhedral crystals of metastable analcime formed during the experiment as separate crystals on quartz, as groups or clusters and as surface covering mats. The overall net transfer process dissolves quartz + illite + kaolinite ± K-feldspar and precipitates analcime + chlorite ± albite. The process is accompanied by a total volume increase of the solids of 20–30 vol%. K-feldspar dissolution is hampered by albitization rims shielding K-feldspar and efficiently preventing an equilibration of the Na–K exchange with the fluid. The experiments show changes on the rock surface, leading to an increase of the aperture of a single fracture during the early phases of reaction and later to a decrease as the fluid-rock reaction progresses. Alteration of the fracture surface also generates loose fragments and altered minerals. This fine material may efficiently reduce the fracture aperture at narrow points along the fracture.

Reactive transport modeling of coupled feldspar dissolution and secondary mineral precipitation and its implication for diagenetic interaction in sandstones

Dissolution of feldspars and precipitation of secondary minerals (kaolinite, illite and quartz) are significant diagenetic processes in arkosic sandstones. We examined moderately buried sandstones in the Eocene Shahejie Formation from two sags in the Bohai Bay Basin, East China. Three different types of mineral assemblages (MA) were identified: extensively leached feldspars with a large amount of authigenic kaolinite and quartz cement (MA-1), extensively leached feldspars with a large amount of authigenic kaolinite and minor quartz cement (MA-2), and extensively leached feldspars with a small amount of both authigenic kaolinite and quartz cement (MA-3).Numerical simulations at the continuum scale using Geochemist’s Workbench 9.0 were conducted to decipher the origin of the different mineral assemblages. The physicochemical reactions including feldspar dissolution, transport of Al3+ and SiO2(aq), and precipitation of kaolinite and quartz are coupled together in these simulations, with constraints of chemical reactions, kinetic law, dispersion, and advection. Modeling results suggest that a dissolution zone, a transitional zone, and a precipitation zone can be formed in a sandstone unit with suitable constraints of temperature, flow rate, fluid composition and mineral reaction rate. And MA-3, MA-2, and MA-1 assemblages develop in these three zones respectively. The higher SiO2(aq) concentration required for the saturation of quartz than for kaolinite and the low Al3+ concentration needed for the saturation of kaolinite lead to the precipitation of only kaolinite in the transitional zone in a geochemical system with feldspar dissolution serving as the dominant source of SiO2(aq) and Al3+.Comparisons between modeling results and observations of natural sandstone diagenesis suggest that an MA-1 assemblage is likely to occur in buried sandstones at high temperatures (>70–80°C) and low flow rates. An MA-2 assemblage may occur in moderately buried sandstones at moderate temperatures (40–70°C), in deeply buried sandstones with faults and fractures serving as conduits of meteoric freshwater, or in shallow sandstones where meteoric water is not abundant. An MA-3 assemblage tends to occur in shallow sandstones at low temperatures (<40–50°C) and high flow rates, or in buried sandstones where faults and fractures develop widely and serve as freshwater conduits. These proposals are valid in natural arkosic sandstones and of great significance in deciphering the diagenetic environments where the feldspar dissolution and secondary mineral precipitation have occurred.

A review and new descriptions of Elk Point Group outcrops in the Athabasca Oil Sands mining region

Abstract Elk Point Group outcrops in the Athabasca Oil Sands mining region (AOSMR) and adjacent areas include exposures of the La Loche, Contact Rapids, Keg River, and Prairie Evaporite formations. Here, we review prior investigations of these formations in outcrop, followed by new descriptions of some outcrops, including those previously unpublished or newly discovered. The fluvial to marginal marine sandstone and conglomerate of the La Loche Formation, informally known as the granite wash, outcrops along the Clearwater River in Saskatchewan, where it is sandwiched between the Precambrian basement and the Contact Rapids Formation. In Alberta, the La Loche Formation is exposed at a locality along Whitemud Falls, where it directly underlies the Keg River Formation as a lithic sandstone and fills paleokarst crevices in the Keg River dolostone. From these two outcrops we recognize three facies in the La Loche Formation: regolith, lithic conglomerate, and lithic to arkosic sandstone. The marginal marine shale, silt, and dolomite of the Contact Rapids Formation outcrops in Saskatchewan at its namesake Contact Rapids, but is exposed only as a slumped bank of grey to greenish mud. We examined Keg River Formation dolostone from three outcrops along the Clearwater River at Contact Rapids in Saskatchewan and Whitemud Falls and Cascade Rapids in Alberta. We also describe an outcrop on the Firebag River in Alberta. From these outcrops, we recognize three general facies: bedded to laminated cryptalgal dolomitized bindstone (originating from an intertidal paleoenvironment), coral and stromatoporoid-bearing dolomitized floatstone to rudstone (originally a reef), and crinoid and brachiopod dolomitized floatstone (from off-reef or inter-reef areas). A newly recognized outcrop of the collapse residue from the dissolved Prairie Evaporite Formation occurs along the Clearwater River, where cobbles and boulders of breccia and other less soluble Prairie Evaporite rock weather out of the river bank between several sulfur springs.

Provenance Signatures Recorded In Transgressive Sandstones of the Upper Cretaceous Iberian Seaway

Abstract: Maximum Mesozoic transgressions flooded many continental areas worldwide, forming a wide and shallow seaway on the Iberian Microplate during the Late Cretaceous. Several siliciclastic and mixed siliciclastic–carbonate units developed along the Iberian Massif (cratonic area) while, at the same time, epeiric carbonate platforms spanned Iberia. These siliciclastic deposits unconformably cover the Variscan basement, as well as the Permian and Triassic deposits. This study focuses on sandstone provenance in central Spain, in a transgressive, relatively quiet tectonic setting with a wide rock variety in the potential source areas. Results shown in this paper can be applied in analogue systems; transgressive sandstones often form important hydrocarbon reservoirs due to their high primary porosity. The Cretaceous siliciclastic deposits are included in four formations ranging in age from the Cenomanian to the early Coniacian. The deposits were initially of fluvial origin, followed by a coastal-tidal setting. Quantitative petrographic analysis of sandstones from these formations reveals compositional variations related to provenance and weathering degree. The oldest formation (Utrillas Fm.) was deposited on a paleorelief surface. Sandstone composition changes from arkosic sandstones in the depressed area (Petrofacies P1a) to younger quartzarenites when sediments were deposited on top of the paleotopographic high (Petrofacies P1b). Quartz grains in both sub-petrofacies are angular to subangular, and the framework is poorly sorted. Intense weathering conditions are deduced for Petrofacies P1b, manifested by grain infiltration, clay coatings, and the absence of plagioclase grains and alteration features on K-feldspars. All these observations have been related to wetter conditions during P1b deposition. Main source areas of the Utrillas Fm were Ordovician metasediments and orthogneisses, Permian volcanic rocks, and Triassic Buntsandstein facies. Petrofacies 2 encompasses the three coastal-tidal formations, constituted mainly by subarkoses generally showing a subangular and poorly sorted framework. The deduced source areas are mainly associated with Variscan granitoids, pre-Ordovician schists and paragneisses, and Ordovician metasediments. Glauconite and carbonate grains support intrabasinal inputs. The low degree of sorting of this petrofacies related to a low-energy sedimentary environment produced lower values of original porosity compared to transgressive sandstone hydrocarbon reservoirs. Also, intrabasinal inputs promoted carbonate cementation and contribute to almost occlude the porosity.

The Pawnee Aquifer, Denver-Julesburg Basin, Northeastern Colorado

A partially defined and largely unexplored confined aquifer in Colorado, Nebraska, and Wyoming is identified regionally through interpretation of geophysical logs, well drilling, coring, petrographic analysis, and GIS interpretation. The aquifer is a fine-grained arkosic sandstone, with thickness ranging up to 1000 ft in some areas. The aquifer represents a significant water resource for ranching and other development in northeastern Colorado and may be a resource for Wyoming, and Nebraska. Nomenclature for this aquifer is suggested. Water wells penetrating the entire aquifer have produced up to 200 gpm. Water quality data is presented including total dissolved solids, boron, and microbial methane.

Querns and mills during Roman times at the northern frontier of the Roman Empire (Belgium, Northern France, Southern Netherlands, Western Germany): Unraveling geological and geographical provenances, a multidisciplinary research project

This paper presents the results of a multi-disciplinary provenance study of querns and millstones during the Roman period (1st-4th century CE) in the northern part of the Roman Empire (provinces of Gallia Belgica and Germania Inferior). Comparative petrographical, mineralogical and geochemical analysis allowed an international team of archaeologists and geologists to identify the different raw materials used for the manufacturing of querns and millstones. As a result, (litho-) stratigraphic assignments as well as geological-geographical provenances are suggested or corroborated for the broad spectrum of these natural geo-materials. We give evidence for the exploitation of at least seven different rock types. They include sedimentary rocks (fine- to coarse-grained quartzitic and arkosic sandstones, conglomerates, limestones) and volcanic rocks (vesicular lavas) derived from different geological strata in the following geological-geographical settings: the volcanic Eifel area (Pleistocene lava), the Ardennes Massif (Palaeozoic sedimentary rocks) and the Paris and Northern Sea Basin (Cenozoic sedimentary rocks). Furthermore we show that a large diversity existed within different productions (different types of hand-mills and mechanical powered mills) and distribution patterns. This paper provides new data which will lead to new insights into the socio-economics of the local “Gallo-Roman” communities and into their networks within the northern Roman Empire.

Taphonomy of mammalian fossil bones from the debris-flow deposits of Somosaguas-North (Middle Miocene, Madrid Basin, Spain)

Debris-flow hosted assemblages dominated by mammalian remains are very scarce in the fossil record and few examples are reported. Herein we present a detailed taphonomic study of Somosaguas-North (Madrid Basin, Spain), a Middle Miocene mammalian-dominated site embedded in debris-flow deposits, in order to increase our knowledge of the mode of formation of fossiliferous assemblages in this depositional context. The assemblage includes 6592 large-mammal remains belonging to at least 10 different species. Fossils are found in matrix-supported, poorly-sorted coarse arkosic sandstones and fine conglomerates, which are interpreted as the result of successive debris-flow deposits. Breakage constitutes a pervasive taphonomic alteration in the bone assemblage; however, together with unidentifiable bone fragments, we also found complete to almost complete skeletal elements. Bone remains are isolated, a fact that is indicative of a time of exposure of the carcasses long enough to enable decay and complete disarticulation. There are no associations of elements belonging to the same individual, which suggests that, prior to or during debris-flow transport, bones were profusely dispersed. Based on the taphonomic evidence, we suggest that Somosaguas-North assemblage was formed by successive debris-flow transport and burial of pre-existing thanatocoenoses. Bones from those thanatocoenoses were modified by biostratinomic agents (trampling, weathering) in varying degrees depending on their time of exposure. Debris-flow transport produced further abrasion and breakage in collagen-depleted bones. Our results are congruent with an environmental context of semiarid landscapes presenting long arid periods and highly irregular hydrological seasonality. Finally, we compared the Somosaguas-North assemblage with other debris-flow hosted vertebrate assemblages. Although Somosaguas-North shares taphonomic features with some of these sites, it is not possible to define consistent and single taphonomic patterns for debris-flow assemblages, given the varied taphonomic histories of the remains prior to and during debris-flow transport.

Source apportionment of the sediments entering dam using lithological and mineralogical studies

The present study was carried out to determine the possible origins of sediments entering Taleghan Dam in northern part of Iran, in order to avoid further sedimentation and helping in extension of the useful life of the proposed dam. This was performed by XRD analysis. To do so, first of all, sediment sampling points were positioned along the Taleghan River. The collected samples, after coding, were transferred to the laboratory for mineralogical testing. Then, the samples were exposed to X-ray diffraction analysis. The experimental results were compared with data from geology, land cover land use and slope maps in order to find the possible primary origins of deposits in the Taleghan Dam. Furthermore, the geological formations and physiographical parameter such as slope were also analyzed to test erodibility of the formations. The results showed that most sediment samples in Taleghan are of sedimentary sandstone, mainly containing the quartz and plagioclase minerals (quartz sandstone and arkose sandstone). The findings also showed that calcite and dolomite were abundant in the collected samples, while aragonite and anthracite were found to a lesser extent in the samples. Accordingly, acidic and alkaline formations, mudstone, and siltstone of Karaj area formations, the gypsum of upper red formation, particularly at places with steep slope with a dominance of rangeland land use type, are main origins of sediments in the Taleghan reservoir. In another hand, the control of sediments at these areas would substantially decrease total sediment yields of the entire basin as in the dam reservoir.

Occurrence of tosudite in the Guezouman, Tarat and Tchirezrine 2 formations, hosts of uranium deposits in Niger (Tim Mersoï basin)

AbstractTosudite, a regularly interstratified chlorite-smectite, crystallizes as an alteration mineral of several preexisting Al-bearing silicates (feldspars, kaolin minerals, chlorites) present in arkosic sandstones hosted in uranium deposits in Niger. X-ray diffraction patterns show a sharp superstructure at 29–29.6 Å for an air-dried state and a peak at 30.8–31.6 Å following ethylene glycol solvation. The 060 reflection at 1.507–1.509 Å indicates an overall dioctahedral character, and the very low coefficient of variation of the d00l reflections for the solvated mineral (0.03–0.13) permits validation of the regular interstratification justifying its identification as tosudite. Microprobe analysis allowed specification of the component layers of this mixed-layer mineral. The chlorite is a di-trioctahedral type analogous to sudoite (Si3Al4Mg2(OH)8), and the smectite component is a low-charge montmorillonite type Tosudite is characterized by large Al2O3 and MgO contents and small Fe content; its composition corresponds approximately to the formula where octahedral occupancy is ∼7. Scanning electron microscope (SEM) observations show that tosudite is closely associated with some uranium minerals: tosudite crystallization occurred during a late alteration event which post-dates burial diagenesis and during which uranium was remobilized by Mg-rich oxidizing fluids.

Ideas on the origin of concave features in Carboniferous arkose sandstones in Central and Western Bohemia

Ideas on the origin of concave features in Carboniferous arkose sandstones in Central and Western Bohemia

Ideas on the origin of concave features in Carboniferous arkose sandstones in Central and Western Bohemia

Ideas on the origin of concave features in Carboniferous arkose sandstones in Central and Western Bohemia

Carboniferous basin in Holm Land records local exhumation of the North-East Greenland Caledonides: Implications for the detrital zircon signature of a collisional orogen

Carboniferous strata of the Wandel Sea Basin unconformably overlie the Laurentian Precambrian crystalline rocks of the Caledonian hinterland at its northernmost exposures in Holm Land (∼80°N). Complex zircon from an intermediate gneiss gives an upper-intercept age of 1878 ± 71 Ma, a protolith age which fits with the regional 1.8–2.0 Ga calc-alkaline arc. A strongly deformed pegmatite was intruded at 435 ± 17 Ma, and it is a rare example of Caledonian magmatism in the northern sector of the orogen. Omphacite confirms the presence of eclogite (sensu stricto) lenses in the basement complex, thus documenting the northern extent of the North-East Greenland eclogite province formed during the Caledonian collision with Baltica. Holm Land lies in the eastern block of the eclogite province, where an ultrahigh-pressure (UHP) metamorphic event took place at 365–350 Ma. Zircon from a Holm Land eclogite lacks a Eu anomaly, has a flat heavy rare earth element pattern, and gives a sensitive high-resolution ion microprobe U-Pb age of 423 ± 7 Ma, and it is thus interpreted as the time of high-pressure (HP) metamorphism. This age overlaps with the established age of widespread HP metamorphism for the eclogite province (i.e., 415–395 Ma), rather than the younger UHP metamorphism. Westward thrusting of the North-East Greenland eclogite province onto the Laurentian margin after 395 Ma and subsequent exhumation of this uppermost thrust sheet provided a substrate for Carboniferous deposition. Detrital zircon age spectra from arkosic sandstones of the late Visean (ca. 330–340 Ma) Sortebakker and early Moscovian (ca. 310–315 Ma) Kap Jungersen Formations record the progressive unroofing of the North-East Greenland Caledonides. All seven samples have a major peak at 1.8–2.0 Ga, and five also have a 1.75 Ga peak, matching the Paleoproterozoic arc and later anorogenic granitoids that comprise the crystalline basement. Paleozoic grains are sparse in the Sortebakker sandstones, but they constitute a pronounced 400 Ma peak in the younger Kap Jungersen Formation. The composition of the detritus—including garnet clasts, the high amount of discordant zircon (40%), and the large numbers of grains with metamorphic rims that cluster around 410 Ma—reflects a local provenance sourced in the North-East Greenland eclogite province, with some input from the overlying thrust sheets. Other Devonian and Carboniferous basins within and peripheral to the Caledonides also show distinct signatures, demonstrating that there is not a simple, representative detrital zircon signature for the Caledonian orogen.