AbstractInvestigations of the ignition of cathode spots by arcs operated in atmospheric pressure noble gas atmosphere on electrodes made of Al, Cu, Ti and graphite are extended to electrodes made of Au, Pd and Pt. Rods with a diameter of 2 mm are inserted in a UHV tight stainless steel vessel filled with Ar 5.6 or Kr 4.8. The negatively biased electrodes are brought into interaction with arc plasma by a magnetic blast field. Their end faces are mostly polished with diamond grinding powder, some Pd electrodes are additionally glowed, and other Pd electrodes are pasted with Pd powder. The arc spot ignition is observed by short time photography, streak camera records and temporally highly resolved optical spectroscopy for a lower and higher voltage applied between the arc plasma and the commutation electrode. Measurements of the commutation time tc elapsing between a signal generated by the arc plasma in front of the commutation electrode and the start of the commutation current show that at low voltages tc is in parts drastically increased by oxide layers. The measurements of tc for different electrode materials demonstrate that tc decreases with decreasing boiling temperature of the material. It confirms that not only ions of the filling gas but also of vaporized electrode material in front of the commutation electrode initiate and promote the arc spot ignition. SEM records show that different electrode treatments cause primarily different arc traces on the electrode surface.