A block-on-slip ring-type wear tester was used to investigate the tribological behavior of copper-impregnated metallized carbon against a Cu–Cr–Zr alloy under 2 to 6N applied load and 0 to 20A electrical current. The sliding speed was maintained at 25km/h. The wear loss of copper-impregnated metallized carbon increased with greater electrical current. Under a certain applied load, the wear loss with electrical current was minimized. The tribo-layer had an apparent effect on the friction coefficient. The wear mechanisms were complex, consisting of adhesive wear, abrasive wear and arc erosion.