This work aims to study the nonlinear transient coupled thermo-electromechanical dynamic responses of the piezoelectric structure with the high-order temperature-dependent material properties. The multi-field coupling nonlinear model is established based on the non-Fourier thermoelasticity theories by introducing the function of high-order temperature dependency of the arbitrary material property. The virtual work principle and the nonlinear finite element approach are proposed to investigate the two-dimensional case of the orthotropic rectangular piezoelectric plate of the crystal class mm2 subjected to the zonal transient heating loads. The influences of the high-order temperature-dependent material parameters on the structural responses and wave propagations are discussed.