Current extraction technologies for rare earth elements at ambient conditions are reagent and energy intensive, giving rise to significant quantities of secondary waste streams. Exploration of the removal of common cations from aqueous streams has been undertaken with carbon materials and have shown promising results. However, those promising materials have not been explored extensively for rare earth element capture from aqueous process streams. In this study, a carbon electrode was investigated for the adsorption and immobilization of REE elements from aqueous solutions. Cyclic voltammetry studies of the carbon electrode displayed a pseudocapacitive behavior where it was verified that cation adsorption is accompanied by an electron transfer process. Preliminary tests showed that a current density of 89.1 mA. g−1, allowed for the pseudocapacitive adsorption (PSA) of Nd3+ cation without the formation of rare earth hydroxides. Hence, the selective PSA of Nd3+ was verified in an electrolyte solution with equimolar concentrations of Nd3+, Mg2+, Li+, Na+ and K+, achieving separation factors of 8.6, 1.1, and 10.9 for Nd3+/Li+, Nd3+/Na+, and Nd3+/Mg2+, respectively. Analysis of the potential-time curves for the various cations suggests that storage of ions in the electrode involved pore-spacings rather than interlayer spacings and was corroborated by XRD analysis. Specific capacitance as high as >640 F.g−1 for Nd3+ was also observed for the carbon electrode, with Faradaic efficiencies (FE) of >20 % for Nd3+ and Mg2+, and >9 % for Na+. Furthermore, adsorption capacity of >125 mg g−1 after 4hrs of electrosorption was observed for Nd3+. In the presence of the Nd3+ electrolyte, the electrode achieved increasing storage of Nd3+ with >94 % retention of Nd3+ with a FE > 20 % over 6 cycles between loading and releases in 1 M KCl solution. These preliminary results provide information and some guidance on the selective recovery of rare earth elements, such as Nd, in aqueous streams in the presence of competitive cations employing the use of carbon-based materials.