Application Of Nanocellulose Research Articles

Engineered Cementitious Composite with Nanocellulose and High-Volume Fly Ash

This research develops a sustainable Engineered Cementitious Composites (ECC) with reduced cement usage by incorporating high volume fly ash (HVFA) and silica fume, along with the novel application of nanocellulose (NC), a plant-based nanomaterial, and hybrid fibres to achieve high strength and ductility simultaneously. 12 mixes were developed including three base ECC mixes with 1.5% polyethylene (PE) and 0.5% steel fibres with varying proportions of fly ash and silica fume (1.2:0-1:0.2) and nine NC reinforced ECC mixes with varying dosages of NC (0.15%, 0.2%, 0.25% by weight). The effect of fly ash/silica fume ratio and NC on mechanical properties was investigated through compressive and uniaxial tensile tests. Scanning electron microscope (SEM) and differential scanning calorimetry (DSC) techniques were utilized to gain insights into the HVFA and NC matrix systems and NC and hybrid fibre mechanism. Results showed that reducing the fly ash/ silica fume ratio increased strength but reduced tensile strain. Incorporating NC improved strength across all mixes, irrespective of fly ash/silica fume content, with the mix containing 0.2% NC showing the highest improvement. This novel ECC is anticipated to offer a sustainable and high-performance material solution for engineering structures.

Interfacial assembly of nanocellulose microgels enhances thermal insulation of Pickering foam

Nanocellulose has attracted extensive attention in the preparation of thermal insulation materials because of its high Young's modulus, high strength and low thermal expansion coefficient. In this study, nanocellulose microgels prepared by self-assembly of 2,2,6,6-Tetramethylpiperidoxyl oxidized nanocellulose (TOCNC) and Nisin were used as particle stabilizers, and acrylated epoxidized soybean oil (AESO) was used as oil phase to prepare Pickering emulsion, which was cured by heating to obtain biomass-based Pickering thermal insulation foam. Pickering foams prepared based on microgels with different Nisin contents have significant differences in thermal insulation performance. The results show that the addition of microgel particles can improve the thermal stability, increase the roughness of pore wall and reduce the thermal conductivity of AESO polymer foam. Among them, the Pickering foam prepared by microgel containing 0.06 wt% Nisin has the best thermal insulation performance and rougher pore wall surface, and its thermal conductivity is 0.040 W/(m·K), which is obviously lower than that of the foam prepared by TOCNC (0.083 W/(m·K)). Based on the structural design of nanocellulose microgel particles, this work innovatively realized the assembly of microgels at the oil-water interface and the regulation of thermal insulation performance through Pickering technology, and developed a biomass-based foam with improved thermal insulation effect, which provides a new idea for expanding the advanced application of nanocellulose in the field of thermal insulation materials.

Applications of Nanocellulose in Drug Release

Applications of Nanocellulose in Drug Release

Properties and Characterization of Nanocellulose

Abstract In the field of nanotechnology, nanocellulose plays crucial role. Some features of nanocellulose like high surface area, crystallinity, porosity and tensile stress makes remarkable changes in medical and Industrial area. It is known for its biocompatibility, renewability, high aspect ratio, infinitesimal toxicity and sustainability. Nanocellulose can be prepared by microcrystalline cellulose. For the synthesis of nanocellulose, Acid hydrolysis procedure was used. Various methods of characterizations were used for the prepared nanocellulose such as “Fourier transforms infrared spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and X-ray diffraction”. Nanocellulose drew the attention of scientists for their biochemical properties due to its physical and chemical structure. Various applications of nanocellulose in different field such as biochemical, waste water management, electronics, packaging, automotive etc.

Applications of nanocellulose and its derivatives in developing sustainable textiles

Applications of nanocellulose and its derivatives in developing sustainable textiles

Rheology control and shrinkage mitigation of 3D printed geopolymer concrete using nanocellulose and magnesium oxide

3D printing concrete (3DPC) is an emerging technology that produces concrete using digital method and has revolutionized the traditional labor-intensive construction mode. However, the free formwork printing and layer-by-layer production of 3DPC induce severe shrinkage and plastic cracking during the early ages, especially for the geopolymer based materials. This research utilizes the nano-fibrillated cellulose (NFC) with the combination of magnesium oxides expansive agent (MEA) to mitigate the plastic and drying shrinkage of 3D printing geopolymer concrete (3DPGC), while optimizing its rheological behavior. The results show that after modification with proper dosages of NFC and MEA, 3DPGC showed reduced plastic and drying shrinkage at early ages, with improved printability, buildability, and mechanical strength. The underlying role of NFC and MEA on the performance of 3DPGC was thoroughly analyzed with rheometry, calorimetry, scanning electron microscopy, and internal humidity test. The water retention ability of nanocellulose can provide more moisture at early ages, thus mitigating cracking, while MEA can compromise the drying shrinkage at later ages. The contribution of the study shed light on the application of nanocellulose and MgO to increase the volume stability and mechanical performance of 3D printing geopolymer concrete.

Application of nanocellulose in food packaging - A SWOT analysis

Environmental concerns due to the wide use of plastic in food packaging have become one of the most significant challenges in the world. Consequently, the research in developing sustainable materials for food packaging has accelerated. Nanocellulose-based packaging is a biodegradable, renewable, and antimicrobial material with some competitive physicochemical characteristics when compared to plastic packaging. However, there has been insufficient research on a holistic discussion of the potentials and drawbacks of nanocellulose as well as its production, applications and disposal regarding sustainability. This study aims to evaluate the application of nanocellulose in food packaging. It gives an exhaustive overview of the essential aspects from the production to disposal of nanocellulose through a literature review. Then, a SWOT (Strengths, Weaknesses, Opportunities, Threats) analysis is used to evaluate the potential and drawbacks of applying nanocellulose in food packaging. It has been observed that the physicochemical properties of nanocellulose materials have the potential to be used in food packaging with fewer negative impacts on the environment. Furthermore, it supports the top tiers of the waste hierarchy and a circular economy. However, some challenges need to be addressed to ensure the safe and effective use of nanocellulose in food packaging, including high expenses, a lack of guidelines, and potential hazards to people and the environment. To eliminate these uncertainties, more studies need to be performed on applying nanocellulose in food packaging.

Nanocellulose as an Ecofriendly Source in Nanoscience: Synthesis, Characterization, Properties, and Applications—A Review

AbstractNanocellulose is a promising future material which has got attention due to its unique characteristics. Properties which make nanocellulose special are the eco‐friendliness, high strength, stiffness, renewability, abundance, tunable surface characteristics, and low weight. This review addresses major factors like processing of nanocellulose, modification, properties, preparation of nanocomposites from nanocellulose, and their application in different fields. This review facilitates the selection of biomass sources, processing techniques for NC synthesis, application, and challenges. This review also emphasizes on different applications of nanocellulose reinforced polymer composites in different areas such as biomedical, packaging, electronic and environmental remediation, etc. Recent developments in the processing of cellulose nanocomposites using solution casting and other complex methods have been highlighted. As an emerging functional polymeric material, nanocellulose has become a research hotspot. The importance of nanocellulose in future includes the design of nanocellulose as per the specific user requirements, reduction of the production cost, and making customized products using nanocellulose using green processing. Hence this review is intended to provide new insights into the field of eco‐friendly fundamental materials with in‐depth perspectives and current research trends in its future applications.

Highly efficient nanocellulose adsorbents

Adapting the use of nanocellulose as a sorbent is currently considered an extremely pressing problem, as synthetic analogues, although perform their functions well, are often toxic and incapable of biodegradation. In addition, the production of such synthetic sorbents is quite expensive. Therefore, today the production and modification of nanocellulose in order to increase their absorption capacity is especially important. Furthermore, a number of new applications of nanocellulose have been presented in nanocomposites, Pickering emulsions, wood adhesives, wastewater treatment, and emerging biomedical technologies. The problems and possibilities of new materials based on nanocellulose are being actively discussed. In the course of this work, a composite based on nanocrystalline cellulose from buckwheat, characterized by high sorption properties, environmental safety, and low cost of production, was obtained. Modification of cellulose was carried out with lactic acid. Nine groups of nanocrystalline cellulose samples with different acid soaking times were synthesized, and the optimal time required for the complete grafting of the acid into cellulose was determined. The specific surface area of the composite material was calculated using the Congo red dye adsorption method. It has been found that the specific surface area of the modified composite is not inferior to the specific surface area of many synthetic adsorbents, and even surpasses them in terms of environmental and economic indicators.

Process design for acidic and alcohol based deep eutectic solvent pretreatment and high pressure homogenization of palm bunches for nanocellulose production

This research aimed to study on nanocellulose production from palm bunch using process design and cost analysis. Choline chloride based deep eutectic solvent pretreatment was selected for high-purity cellulose separation at mild condition, followed by nano-fibrillation using mechanical treatment. Three types of choline chloride-based deep eutectic solvents employing different hydrogen-bond donors (HBDs) namely lactic acid, 1,3-butanediol and oxalic acid were studied. The optimal cellulose extraction condition was choline chloride/lactic acid (ChLa80C) pretreatment of palm empty bunch at 80 °C followed by bleaching yielding 94.96%w/w cellulose content in product. Size reduction using ultrasonication and high-pressure homogenization produced nanocellulose at 67.12%w/w based on cellulose in raw material. Different morphologies of nanocellulose were tunable in the forms of nanocrystals, nano-rods and nanofibers by using dissimilar deep eutectic solvents. This work offered a sustainable and environmentally friendly process as well as provided analysis of DES pretreatment and overview operating cost for nanocellulose production. Application of nanocellulose for the fabrication of highly functional and biodegradable material for nanomedicine, electronic, optical, and micromechanical devices is achievable in the near future.

The influence of reed nanocellulose on the quality indicators of paper-basis for wallpapers

Improving the production technology of products with improved quality indicators and with less impact on the environment remains an urgent scientific and practical problem of paper industry enterprises. This refers to the technology for the production of paper-bases for wallpaper using environmentally safe chemical additives, in particular nanocellulose (NC), which was obtained by acid hydrolysis from reed cellulose. The production of cellulose was carried out in two stages - extraction from reed stalks with a solution of alkali and an organosolvent method of cooking in a solution of peracetic acid. The obtained organosolvent cellulose contained the remains of lignin and mineral substances, which allows it to be used for the preparation of NC. As a result of the hydrolysis of organosolvent cellulose, a time-stable NC suspension was extracted, the properties of which were investigated by scanning electron microscopy (morphological changes in the structure of reed cellulose-containing materials), atomic force microscopy (determination of topographic characteristics of NC), analysis of electronic absorption spectra (transparency of NC films). It was established that reed NC films had nanoparticles with a cross-sectional size of 5-25 nm, density up to 1.52 g/cm3, transparency up to 81.6 %, tensile strength up to 65 MPa. For the production of castings of paper-bases for wallpaper samples, sulfated pine bleached cellulose and polyester synthetic fiber were used, to the fibrous mass of which were added the following chemical additives: alkyl ketene dimer, reed NC, binder, and optical brightener. It has been shown that the use of nanocellulose at a rate of 0.35 % to 1.0 % of the paper mass leads to a significant improvement in the physical and mechanical quality indicators of the paper base for wallpaper. It was established that the replacement of 50 % of the synthetic chemical auxiliary substance alkyl ketene dimer with nanocellulose or additional application of nanocellulose at a rate of 0.5 g/m2 on the surface of the casting with 0.7 % alkyl ketene dimer allows to obtain paper that meets the requirements of the standard. The obtained results indicate the prospects of using reed nanocellulose for the production of other mass types of paper and cardboard.

Valorization of agro-industry wastes for nanocellulose fabrication and its multifunctional applications

Nanocellulose (NC) isolation from different types of agroindustrial wastes is emerging as ital. Field of research, because of its multifunctional applications. This work uses the VOS viewer software for extracting the agroindustry based nanocellulose production. This review specifically grasps the attention of scientists towards on valorization of agricultural wastes as sources for nanocellulose production. It also explores the variety of sources including vegetables, fruits, cereals and nuts. The ecological system is negatively influenced by the chemicals and its derived products; these products have caused the ecological imbalance. The demand for functional materials and fine chemicals made from natural resources is enormous. NC is considered as one of the promising green material and next generation renewable resource. Further, this work describes about the pre-treatment, characterization and synthesis of nanocellulose from agro-industrial waste using mechanical, chemical and enzymatic methods. It also elaborate the management of agricultural wastes for the purpose of reducing environmental impact, use of fossil based fuel resources, assuring the sustainable economic growth and close the circle of green economy and its resource use. In addition, the potential and versatile applications of nanocellulose from diverse industrial and agricultural sources were discussed.

Nanocellulose as Sustainable Bio-Nanomaterial for Packaging and Biomedical Applications

Fibrous substrates made of cellulose like paper and paperboard are widely used in packaging. Furthermore, cellulose materials are biodegradable and completely safe for the environment. The water vapor barrier properties of paper and paperboard are limited due to the hydrophilic nature of cellulose fibrils. Paper is frequently combined with other materials, such as plastics, wax, and aluminum to improve its water barrier properties. Unfortunately, these materials lead to significant environmental problems and are difficult to recycle. Nanocellulose has shown the potential of being a substitute natural nanomaterial for creating environmentally friendly and sustainable barrier materials for a range of uses, including food packaging materials and substrates for the development of functional materials. Numerous cellulose sources can be used to create nanocellulose, which offers benefits like a high aspect ratio and tensile strength, making it useful for a variety of applications. The production of nanocellulose is done through a variety of processes. Potential biomedical applications of nanocellulose are tissue engineering, drug delivery, wound dressings, biosensors, implants and prosthetics, and nerve regeneration. Its application in these fields will result in the advancement of medical technology and the improvement of healthcare outcomes. Furthermore, biodegradable materials, barrier coatings, antimicrobial packaging, sustainable packaging solutions, smart packaging, and lightweight, high-strength packaging can all be made with nanocellulose. Nanocellulose-based packaging will improve the sustainability and efficiency of the packaging supply chain while providing environmentally friendly substitutes for conventional packaging materials.

Upcycling Food By-products: Characteristics and Applications of Nanocellulose.

Rising global food prices and the increasing prevalence of food insecurity highlight the imprudence of food waste and the inefficiencies of the current food system. Upcycling food by-products holds significant potential for mitigating food loss and waste within the food supply chain. Food by-products can be utilized to extract nanocellulose, a material that has obtained substantial attention recently due to its renewability, biocompatibility, bioavailability, and a multitude of remarkable properties. Cellulose nanomaterials have been the subject of extensive research and have shown promise across a wide array of applications, including the food industry. Notably, nanocellulose possesses unique attributes such as a surface area, aspect ratio, rheological behavior, water absorption capabilities, crystallinity, surface modification, as well as low possibilities of cytotoxicity and genotoxicity. These qualities make nanocellulose suitable for diverse applications spanning the realms of food production, biomedicine, packaging, and beyond. This review aims to provide an overview of the outcomes and potential applications of cellulose nanomaterials derived from food by-products. Nanocellulose can be produced through both top-down and bottom-up approaches, yielding various types of nanocellulose. Each of these variants possesses distinctive characteristics that have the potential to significantly enhance multiple sectors within the commercial market.

Research Progress on the Application of Nanocellulose in Glucose Sensing.

Nanocellulose is not only a biocompatible and environmentally friendly material but also has excellent mechanical properties, biodegradability, and a large number of hydroxyl groups that have a strong affinity for water. These characteristics have attracted significant attention from researchers in the field of glucose sensing. This review provides a brief overview of the current research status of traditional materials used in glucose sensors. The sensing performance, chemical stability, and environ-mental properties of nanocellulose-based glucose sensors are compared and summarized based on the three sensing methods: electrochemical sensing, colorimetric sensing, and fluo-rescence sensing. The article focuses on recent strategies for glucose sensing using nanocel-lulose as a matrix. The development prospects of nanocellulose-based glucose sensors are also discussed. Nanocellulose has outstanding structural characteristics that contribute signifi-cantly to the sensing performance of glucose sensors in different detection modes. However, the preparation process for high-quality nanocellulose is complicated and has a low yield. Furthermore, the sensitivity and selectivity of nanocellulose-based glucose sensors require further improvement.

Nanocellulose, the Green Biopolymer Trending in Pharmaceuticals: A Patent Review.

The use of nanocellulose in pharmaceutics is a trend that has emerged in recent years. Its inherently good mechanical properties, compared to different materials, such as its high tensile strength, high elastic modulus and high porosity, as well as its renewability and biodegradability are driving nanocellulose's industrial use and innovations. In this sense, this study aims to conduct a search of patents from 2011 to 2023, involving applications of nanocellulose in pharmaceuticals. A patent search was carried out, employing three different patent databases: Patentscope from World Intellectual Property Organization (WIPO); Espacenet; and LENS.ORG. Patents were separated into two main groups, (i) nanocellulose (NC) comprising all its variations and (ii) bacterial nanocellulose (BNC), and classified into five major areas, according to their application. A total of 215 documents was retrieved, of which 179 were referred to the NC group and 36 to the BNC group. The NC group depicted 49.7%, 15.6%, 16.2%, 8.9% and 9.5% of patents as belonging to design and manufacturing, cell culture systems, drug delivery, wound healing and tissue engineering clusters, respectively. The BNC group classified 44.5% of patents as design and manufacturing and 30.6% as drug delivery, as well as 5.6% and 19.4% of patents as wound healing and tissue engineering, respectively. In conclusion, this work compiled and classified patents addressing exclusively the use of nanocellulose in pharmaceuticals, providing information on its current status and trending advancements, considering environmental responsibility and sustainability in materials and products development for a greener upcoming future.

Progress in Achieving Fire-Retarding Cellulose-Derived Nano/Micromaterial-Based Thin Films/Coatings and Aerogels: A Review

The enormous potential of renewable bioresources is expected to play a key role in the development of the EU’s sustainable circular economy. In this context, inexhaustible, biodegradable, non-toxic, and carbon-neutral forest-origin resources are very attractive for the development of novel sustainable products. The main structural component of wood is cellulose, which, in turn, is the feedstock of nanocellulose, one of the most explored nanomaterials. Different applications of nanocellulose have been proposed, including packaging, functional coatings, insulating materials, nanocomposites and nanohybrids manufacturing, among others. However, the intrinsic flammability of nanocellulose restricts its use in some areas where fire risk is a concern. This paper overviews the most recent studies of the fire resistance of nanocellulose-based materials, focusing on thin films, coatings, and aerogels. Along with effectiveness, increased attention to sustainable approaches is considered in developing novel fire-resistant coatings. The great potential of bio-based fire-resistant materials, combined with conventional non-halogenated fire retardants (FRs), has been established. The formulation methods, types of FRs and their action modes, and methods used for analysing fireproof are discussed in the frame of this overview.

Degraded Paper: Stabilization and Strengthening Through Nanocellulose Application

ABSTRACT Cellulose nanomaterials are a promising material for the stabilization of degraded paper, since their characteristics in composition, structure and physical properties are close to those of cellulose. Two types of nanocellulose were tested regarding their performance in stabilizing fragile papers: cellulose nanofibrils (CNF) and cellulose nanocrystals (CNC). The suspensions were applied to a pure cellulose paper and historical newspaper. The study included optical and microscopic characterization, determination of pH, conductivity, and rheology as well as measurement of changes in tensile strength after treatment. The results showed that the pH, as well as the optical and haptic properties, were not altered after treatment. A 50% increase in paper’s tensile strength is achieved with 3% CNC applied on the paper. In addition, fluorescence microscopy demonstrated that, due to their nanoscale dimension, the suspensions can reinforce the surface but also fully penetrate the paper matrix achieving therefore an overall stabilization.

Transforming textile waste into nanocellulose for a circular future.

The expansion of the textile industry and improvements in living standards have led to increased cotton textile production, resulting in a rise in textile waste, with cotton accounting for 24% of total textile waste. Effective waste management through recycling and reuse is crucial to reducing global waste production. Nanocellulose has diverse applications in environmental, geotechnical, food packaging, and biomedical engineering areas. As interest in nanocellulose's unique properties grows, cotton-based textile waste emerges as a promising source for nanocellulose development. However, there is a notable lack of comprehensive reviews on the extraction of nanocellulose from textile waste as a sustainable biomaterial. This paper aims to address this gap by exploring current extraction processes, properties, and recent applications of nanocellulose derived from textile waste. We discussed (1) the potential of nanocellulose resources from different textile wastes, (2) a comparison of the various extraction methods, (3) the functionalization technology and the potential application of such nanocellulose in the textile industry, and (4) the life cycle assessment (LCA) and potential gap of the current technology. It also emphasizes the potential reintegration of extracted nanocellulose into the textile industry to manufacture high-value products, thus completing the loop and strengthening the circular economy.

Environmental safety of nanocellulose: an acute in vivo study with marine mussels Mytilus galloprovincialis

The growing application of nanocellulose in various industrial sectors with potential release into the natural environment demands a safety assessment and thus ecotoxicity.