Ultrafast Photonic Applications Research Articles

Plasmonic gold-enhanced GaAs for femtosecond laser generation

Surface plasmon resonance (SPR) can significantly enhance the local electromagnetic fields, facilitating the interaction between light and matter at the nanoscale. However, its ultrafast photonics application in lasers remains unexplored, especially for femtosecond pulsed laser generation. In this work, we investigate the femtosecond pulse generation based on SPR-enhanced nonlinear absorption characteristics in GaAs for the first time, to the best of our knowledge. The gold nanoparticles (GNPs)+GaAs bilayer saturation absorber (SA) decorated on the tapered fiber generates a modulation depth of 2.02% and a saturable intensity of 3.13 MW/cm2. Stable mode-locked pulses can be obtained in an erbium-doped fiber cavity, as demonstrated here. The signal-to-noise ratio (SNR) of the pulses is 75 dB and the shortest pulse duration can reach 384 fs, highlighting the potential of the SPR effect in manufacturing ultrafast optical devices.

Generation of mode-locked pulses assisted by reduced graphene oxide/cerium oxide (rGO/CeO2) embedded in arc-shaped fiber

Abstract This study demonstrates the synthesis of a reduced graphene oxide/cerium oxide (rGO/CeO2) composite and its successful use as a saturable absorber (SA) in ultrafast photonics. The rGO/CeO2 composite was synthesized using a facile hydrothermal approach, and an arc-shaped fiber was fabricated using a polishing technique. The arc-shaped fiber employed indirect evanescent field coupling, allowing interaction between the composite material and the laser, which facilitated the generation of mode-locked pulses. An arc-shaped fiber drop-casted with rGO/CeO2 was connected to a 2.0 µm laser source, achieving a modulation depth of 50.16%. The emitted laser pulses have a duration of 1.776 ps, an operational wavelength of 1904 nm, and a spectral bandwidth (FWHM) of 2.76 nm. The pulse energy was 89.36 pJ with a high signal-to-noise ratio (SNR) of 63 dB. This study introduces rGO/CeO2 embedded in an arc-shaped fiber as an effective SA, exhibiting favorable nonlinear optical absorption in the near 2.0 µm wavelength region, making it suitable for applications in ultrafast photonics.

Nonlinear optical research on 2D NbSe2 nanosheets and their ultrafast photonics applications

Two-dimensional (2D) NbSe2 is a new material with a variety of excellent properties. In this article, 2D NbSe2 nanosheets are prepared using liquid phase exfoliation (LPE) and spin coating methods. At the same time, the properties of NbSe2 were calculated by using density functional theory (DFT), exploring the changes in the electronic band structure of NbSe2 with the number of layers, and studying the optical properties of NbSe2. The nonlinear optical properties caused by the Pauli blocking effect and the absorption spectra are studied through typical nonlinear testing techniques and an ultraviolet–visible-near-infrared (UV–VIS-IR) spectrophotometer. In addition, 2 µm solid-state pulse lasers have important applications in a variety of fields. For the first time, 2D NbSe2 nanosheets are prepared as saturable absorbers (SA) and applied them to solid-state lasers as nonlinear optical modulation devices, successfully achieving the generation of ultra-short pulse lasers with a pulse duration of 445.4 ps in 2 µm band. Our research results prove that 2D NbSe2 nanosheets is a promising nanomaterial, can be prepared into nonlinear optical modulation devices with excellent performance, and show great application potential as ultrafast photonic devices. It is beneficial to the miniaturization of solid-state pulse lasers in subsequent applications.

Power dependent tunable optical nonlinearity in Iron oxide/Borophene core-shell nanoparticles under ultrashort laser excitation

Two-dimensional (2D) nanomaterials find immense applications in ultrafast photonics and optical switching systems due to their fascinating nonlinear optical (NLO) characteristics. This work presents a systematic investigation of laser power-dependent nonlinear optical characteristics of borophene nanosheets in a core-shell nanostructure. For this purpose, we have synthesized Borophene encapsulated Iron oxide (Fe3O4) core-shell nanoparticles (Fe3O4/Borophene CSNPs). The CSNPs were synthesized by mixing and annealing sodium borohydride (NaBH4) as a boron precursor with iron oxide nanoparticles (Fe3O4 NPs) in a controlled environment using chemical vapor deposition technique (CVD) followed by characterization using XRD, FTIR Spectroscopy, UV–vis absorption spectroscopy, TEM, SEM, and EDX techniques. Magnetic properties were analyzed by a vibrating sample magnetometer (VSM) which shows that the saturation magnetization of Fe3O4 NPs increases after being encapsulated in borophene nanosheets. The role of borophene in modifying the NLO characteristics of Fe3O4/Borophene CSNPs was studied using a power-dependent Z-scan technique utilizing ultrashort (femtosecond) laser pulses at a wavelength of 800 nm in both open and close aperture configuration. It was found that borophene-coated Fe3O4 NPs reveal tunable NLO properties that resemble the NLO characteristics of borophene nanosheets with enhanced features. This provides insights into an interaction between materials in NLO phenomena and illustrates the distinctive performance of the core-shell nanostructure. The tunable NLO properties of Fe3O4/Borophene CSNPs offer an innovative approach for developing optoelectronics and ultrafast nonlinear photonic devices.

Generation of h-shaped pulse rains in Er3+-doped fiber lasers utilizing TaTe2 as saturable absorber

This paper presents a study on generating h-shaped pulse rains phenomena in Er3+-doped fiber laser employing TaTe2 as saturable absorber. The spectrum of the h-shaped pulse rains has a central wavelength of 1561.63 nm and a repetition frequency of 3.353 MHz. The h-shaped pulse rains comprise a leading peak, a flat-top, and drifting pulses. The leading peak is attributed to incomplete saturation caused by significant gain losses and the incomplete effect of peak power clamping. The flattop is produced by the effect of peak power clamping, while the mechanism underlying the drifting pulses necessitates further exploration. During the investigation of the h-shaped pulse rains, it was discovered that adjusting the pump power allows control over the number of drifting pulses and the length of the flat-top. A distinctive drifting pulse is observed at pump power of 210 mW. Our experimental results show that TaTe2 saturable absorber have great potential for application in ultrafast photonics.

Copper Functionalized SnSe Nanoflakes Enabling Nonlinear Optical Features for Ultrafast Photonics.

This study enhances the ultrafast photonics application of tin selenide (SnSe) nanoflakes via copper (Cu) functionalization to overcome challenges such as low conductivity and weak near-infrared (NIR) absorption. Cu functionalization enhances concentration, induces strain, and reduces the bandgap through Sn substitution and Sn vacancy filling with Cu ions. Demonstrated by density functional theory calculations and experimental analyses, Cu-functionalized SnSe exhibits improved NIR optical absorption and superior third-order nonlinear optical properties. Z-scan measurements and femtosecond transient absorption spectroscopy reveal better performance of Cu-functionalized SnSe in terms of nonlinear optical properties and shorter carrier relaxation times compared to pristine SnSe. Furthermore, saturable absorbers based on both SnSe types, when integrated into an erbium-doped fiber laser, show that Cu functionalization leads to a decrease in pulse duration to 798 fs and an increase in 3dB spectral bandwidth to 3.44nm. Additionally, it enables stable harmonic mode-locking of bound-state solitons. This work suggests a new direction for improving wide bandgap 2D materials by highlighting the enhanced nonlinear optical propertiesand potential of Cu-functionalized SnSe in ultrafast photonics.

Surface plasmonic Au nanoparticles assisted CuO nanorods for broadband diverse ultrafast pulse generation

In virtue of the local surface plasmon resonance (LSPR) properties of metal nanoparticles to enhance the nonlinear optical response of the material, we successfully embed small-size Au nanoparticles into CuO nanorods. Then, theoretical and experimental methods verify that the assistance of ultrafast plasma response enhances the light-matter interaction. The LSPR characteristics and evanescent field distribution of the Au-CuO saturable absorber on the tapered fiber are studied by the finite element simulation method (FEM). By utilizing the Z-scan technology and twin-balanced detector system, excellent nonlinear optical (NLO) properties of the Au-CuO nanorods are demonstrated. Subsequently, depending on the remarkable nonlinear saturable absorption effect of Au-CuO, multiple operating states such as Q-switched, conventional soliton, double-subpulse soliton cluster, and noise-like pulse mode-locking are achieved in the erbium-doped fiber ring cavity at 1.5 μm. In addition, dual-wavelength mode-locking pulses with the center wavelengths of 1031 nm and 1035 nm are realized in the ytterbium-doped fiber ring cavity. This work describes an effective strategy to improve the NLO properties of CuO nanorods and indicates the great potential of Au-CuO in pulsed fiber lasers, opening a path for its application in ultrafast photonics and optoelectronics.

Ternary ReS2(1-x)Se2xalloys of different composition for Q-switched and mode-locked all-fiber laser.

This paper systematically studied the composition-controlled nonlinear optical properties and pulse modulation of ternary ReS2(1-x)Se2xalloys for the first time. The compositionally modulated characteristics of ReS2(1-x)Se2xon the band gap were simulated based on the first principles. We investigated the effect of the band gap on the saturable absorption properties. In addition, we demonstrated the modulation characteristics of different components ReS2(1-x)Se2xon 1.5μm Q-switched pulse performance. The Q-switched threshold, repetition rate, and pulse duration increase as the S(sulfur)-element composition rise. And pulse energy also was affected by the S(sulfur)-element composition. The ReS0.8Se1.2SA was selected to realize a conventional soliton with high energy in the all-fiber mode-locked laser. The pulse was centered at 1562.9 nm with a pulse duration of 2.26 ps, a repetition rate of 3.88 MHz, and maximum pulse energy of 1.95 nJ. This work suggests that ReS2(1-x)Se2xhas great potential in laser technology and nonlinear optics, and widely extends the material applications in ultrafast photonics.

Integrated graphene-based semimetal/metallic-like MSe2 (M = Pt, Re) heterostructures for mid-infrared ultrafast photonics

Mid-infrared (MIR) ultrafast photonics has received significant interest due to the development of compact and robust MIR laser sources capable of emitting wavelengths beyond 2 μm. Transition metal selenides (TMSes), with the properties of feasibly tunable bandgaps, desirable photocarrier transmission property, and broadband nonlinear optical response, have become a research focus on ultrafast photonic applications. However, the relatively large bandgap (around 1 eV) of the TMSes greatly restricts their applications in the MIR region. Here, the synergetic interaction between multilayer graphene (Gr) and semimetal or metallic-like (PtSe2 and ReSe2) is employed to tune the optical properties and to further optimize the optical performance of TMSes in the MIR region. Benefiting from the ultrafast photocarrier relaxation time, appropriate modulation depth, and almost zero non-saturated loss of Gr-PtSe2 and Gr-ReSe2 heterostructures, stable Q-switched laser operation at 1.9 μm has been achieved in an integrated design based on waveguide laser platform. The results demonstrate that combining the semimetal or metallic-like TMSes with van der Waals (vdW) heterostructures is a promising strategy to extend the photonic applications of TMSes into the MIR region, indicating the potential applications of graphene-based TMSes vdW heterostructures for MIR integrated photonics.

Stable Q-switched and femtosecond mode-locked erbium-doped fiber laser based on a CuSe nanosheets saturable absorber.

Stable Q-switched and femtosecond mode-locked erbium-doped fiber laser (EDFL) have been achieved using CuSe nanosheets as novel saturable absorber (SA), where the CuSe nanosheets were prepared by a hydrothermal method. The nonlinear optical properties of CuSe nanosheets were measured using an Z-scan setup, revealing nonlinear absorption coefficients of -3.67 ± 0.22 cm GW-1 at 1560 nm. The prepared CuSe nanosheets were mixed with polyvinyl alcohol (PVA) to obtain a CuSe-PVA SA with a modulation depth of 3.8 ± 0.13%, and it was utilized to realize a Q-switched EDFL, obtaining the narrowest pulse duration of 1.29 µs and the maximum output power of 5.96 mW, which corresponds to a pulse energy of up to 103.7 nJ. In addition, CuSe nanosheets were deposited on a D-shaped fiber (DSF) to fabricate a CuSe-DSF SA with a modulation depth of 5.6 ± 0.17%, and it was utilized to realize a mode-locked EDFL. The mode-locked EDFL demonstrated a low threshold of only 42 mW, a pulse duration of 740 fs, and a maximum output power of 9.7 mW. Meanwhile, it exhibited a high signal-to-noise ratio of 72 dB. To the best of our knowledge, this is the first time of CuSe nanosheets as SA in EDFL. The results demonstrate that CuSe nanosheets are a highly promising nonlinear optical material with great potential for applications in ultrafast photonics.

Generation of stable femtosecond pulses using MoS2−xSex as the saturable absorber in Er-doped fiber laser

A new transition-metal dichalcogenide (Janus TMDs), molybdenum selenide sulfide (MoS[Formula: see text]Se[Formula: see text]), has attracted wide attention due to its unique and highly stable alloy structure, high carrier mobility and the ability to modulate the band gap based on composition. In this work, MoS[Formula: see text]Se[Formula: see text] nanosheets were prepared through liquid phase exfoliation and further prepared as a saturable absorber (SA). The nonlinear optical response was investigated by the homemade balanced twin-detector measurement system, revealing the potential of MoS[Formula: see text]Se[Formula: see text]-SA in ultrafast photonics. The SA devices exhibited good saturation absorption characteristics. By applying it to the Er-doped fiber laser, a stable mode-locked fiber laser based on MoS[Formula: see text]Se[Formula: see text]-SA was successfully achieved. The pulse width was measured to be 509 fs, with a spectral width of 6.33 nm and a maximum output power of 7.44 mW in the mode-locked state. This is the first reported instance of achieving mode-locking operation in the Er-doped fiber laser using MoS[Formula: see text]Se[Formula: see text]-SA, indicating its great potential for applications in ultrafast photonics.

Preparation of amorphous silicon-doped Y2O3 aerogel enabling nonlinear optical features for ultrafast photonics

Abstract Amorphous aerogels with the microscopic nanoscale three-dimensional meshes provide superb platforms for investigating unique physicochemical properties. In order to enhance the physical, thermal and mechanical performances, one efficient and common approach is integrating diverse functional materials. Herein, we report a simple strategy to fabricate the amorphous silicon doped Y2O3 aerogels with the post-gelation method under the N2/EtOH supercritical atmosphere. The impact of Si concentration on the nonlinear optical properties is investigated for the first time. The maximum modulation depth is 1.65 % with a saturation intensity of 0.78 MW cm−2 with the 1-ps laser excitation at 1590 nm. Finally, we incorporated the silicon-doped Y2O3 aerogel based saturable absorber (SA) into an erbium-doped fiber laser (EDFL) and achieved various mode-locking operations at different wavelengths in the super C band, in terms of the conventional soliton, harmonic soliton molecules pulses, and dual-wavelength soliton mode-locking. Overall, this work confirms that amorphous silicon-doped Y2O3 aerogels are good nonlinear optical materials and pave a way for the ultrafast photonic and nonlinear optical applications with amorphous materials in near future.

Saturable absorption properties and ultrafast photonics applications of HfS3.

In this Letter, we focus on investigating the ultrafast photonics applications of two-layer HfS3 nanosheets. We prepared two-layer HfS3 nanosheets and carried out experiments to study their nonlinear saturable absorption properties. The results showed that the two-layer HfS3-based saturable absorber exhibited a modulation depth of 16.8%. Additionally, we conducted theoretical calculations using first principles to estimate the structural and electronic band properties of the two-layer HfS3 material. Furthermore, we utilized the two-layer HfS3 materials as SAs in an erbium-doped fiber cavity to generate mode-locked laser pulses. We measured a repetition frequency of 8.74 MHz, a pulse duration of 540 fs, and a signal-to-noise ratio of 77 dB. Overall, our findings demonstrate that the two-layer HfS3 material can serve as a reliable saturable absorber, possessing properties comparable to currently used two-dimensional materials. This expands the application fields of HfS3 materials and highlights their potential for advanced optoelectronic devices.

Passively mode-locked fiber lasers with broadband FeOOH saturable absorber

In this contribution, we synthesized iron oxide hydroxide (FeOOH) nanomaterials and successfully demonstrated the application of FeOOH-based saturable absorbers in ultrafast photonics at 1 μm and 1.5 μm. Various characterizations were conducted to analyze the morphological and structural features of FeOOH nanomaterials. Subsequently, a tapered fiber coated with FeOOH was integrated into the resonator as a saturable absorber, exhibiting the significant saturable absorption effect with modulation depths of 1.26 % at 1 μm and 2.61 % at 1.5 μm, respectively. In an Yb-doped fiber laser, stable noise-like mode-locking pulses were achieved with a pulse duration of 519 fs at the operating wavelength of 1037.2 nm with a full-width at half-maximum (FWHM) spectral bandwidth of 4.7 nm, yielding a maximum single pulse energy of 1.23 nJ with a high signal-to-noise ratio (SNR) of 47.8 dB. Meanwhile, the conventional soliton pulses were produced in the passively mode-locked Er-doped fiber laser, featuring a pulse duration of 1.02 ps, and an SNR of 42.5 dB at a peak wavelength of 1559.25 nm with a FWHM bandwidth of 2.8 nm. This work demonstrates the considerable nonlinear optical properties of FeOOH nanomaterials in the near-infrared range, proposing a promising saturable absorber for ultrafast photonics applications.

Organic frame metal structure materials UIO-66 for picosecond ultrafast pulsed fiber lasers

The UIO-66 studied in this paper exhibits unprecedented thermal stability with a very high surface area and mechanical strength. This unique combination of properties opens up a wide range of promising applications. Here, we investigate the saturable absorption effects and ultrafast photonic applications of UIO-66. It shows that UIO-66 could emerge as a novel nonlinear material for ultrafast optics. By fabricating a real saturable absorber and incorporating it into a passively mode-locked Er-doped fiber laser, traditional solitons with a pulse duration of 0.96 ps at a repetition rate of 4.12 MHz have been obtained. The mode-locked spectrum centered at 1562.4 nm features a full width at half maximum of 3.5 nm. Our results may trigger follow-up investigations on the optical properties of UIO-66 and pave potential avenues for photonic and optoelectronic applications.

Emerging PbSnS2 pulse modulators for ultrafast and high repetition frequency photonic applications

Two-dimensional ternary metal sulfides receive growing concern due to the diverse physicochemical properties and broad application potential. In this study, ultrafast nonlinear optical properties of two-dimensional lead tin sulfide (PbSnS2) nanosheets are demonstrated. PbSnS2 nanosheets with the thickness less than 3 nm were fabricated by liquid-phase exfoliation, and PbSnS2 nanosheets based saturable absorber (SA) was constructed by photodeposition. The nonlinear optical absorption properties such as modulation depth (21 %) and saturation intensity (14.2 MW/cm2) of PbSnS2-SA were investigated. Dispersion management was applied to Er3+-doped fiber laser (EDFL) coupled with PbSnS2-SA. The EDFL with net dispersion −0.36 ps2 outputs 928 fs mode-locked pulses. With a cavity dispersion of −0.58 ps2, tunable 1st to 9th order harmonic mode-locked (HML) is realized by tuning the pump power only. The EDFL (net dispersion −0.98 ps2) produces the highest repetition frequency at 362.59 MHz (corresponding to 80th order HML). The results indicate that two-dimensional PbSnS2 may be widely used as ultrafast photonics material for photonics and engineering applications research.

Broadband nonlinear optical response and sub-picosecond carrier dynamics in graphene-SnSe2 van der Waals heterostructures.

The van der Waals (vdWs) heterostructures, with vertical layer stacking structure of various two-dimensional (2D) materials, maintain the reliable photonic characteristics while compensating the shortcomings of the participating individual components. In this work, we combine the less-studied multilayer tin selenide (SnSe2) thin film with one of the traditional 2D materials, graphene, to fabricate the graphene-based vdWs optical switching element (Gr-SnSe2) with superior broadband nonlinear optical response. The transient absorption spectroscopy (TAS) measurement results verify that graphene acts as the recombination channel for the photogenerated carrier in the Gr-SnSe2 sample, and the fast recovery time can be reduced to hundreds of femtoseconds which is beneficial for the optical modulation process. The optical switching properties are characterized by the I-scan measurements, exhibiting a saturable energy intensity of 2.82 mJ·cm-2 (0.425 µJ·cm-2) and a modulation depth of 15.6% (22.5%) at the wavelength of 1030 nm (1980nm). Through integrating Gr-SnSe2 with a cladding waveguide, high-performance picosecond Q-switched operation in the near-infrared (NIR) and mid-infrared (MIR) spectral regions are both achieved. This work experimentally demonstrates the great potential of graphene-based vdWs heterostructures for applications in broadband ultrafast photonics.

Carbon nanodots derived from organo-templated zeolites for femtosecond mode-locked fiber laser

Carbon nanodots (CNDs) have been widely investigated due to their physicochemical and optical properties. However, the nonlinear saturable absorption property and its application in laser technology is rarely reported. Here, we report the CNDs as an ideal saturable absorber (SA) for ultra-stable femtosecond mode-locked fiber laser at a wavelength of 1.5 μm. The mono-sized CNDs of 2 nm are fabricated from a dipropylamine-templated zeolite precursor calcination with a temperature of 380 °C. The nonlinear saturable absorption property of the as-synthesized CNDs is investigated by using a balanced twin-detector measurement system. The modulation depth and saturable intensity are measured to be 33 % and 3.1 MW/cm2, respectively. By inputting the CNDs SA into the erbium-doped fiber laser (EDFL) ring cavity, a highly stable mode-locked EDFL with pulse width of 388 fs and single-to-noise ratio (SNR) of 84.4 dB can be obtained. In addition, stable soliton pairs with single-pulse width of 422 fs and SNR of 84.1 dB can also be achieved. These findings demonstrate that the carbon dots can be used as an ideal SA and has promising applications in ultrafast photonics.

Research on near-infrared ultrafast excited carrier dynamics of a pyrene-based derivative and its application in femtosecond laser

Femtosecond laser, compared to continuous wave (c.w.) or nanosecond laser, has shown great promise in diversities of frontier applications because of its extremely short pulse width, high peak power and low thermal effect. In order to obtain femtosecond laser output, the design of suitable saturable absorber (SA) materials as a nonlinear modulation device is a key issue for a given laser system. However, the previous SA materials are limited in inorganic semiconductors, which have some constraints such as narrow working wavelength ranges, complex preparation process and high cost. By contrast, organic semiconductors have high molecular design freedom, good flexibility, simple preparation process, and low cost, and would act as an ideal SA material. Here, we report a novel strategy to tune and realize the femtosecond laser out by employing an organic small molecule SA of (Z)-2-(4-(pyrene-1-yl) phenyl)-3-(4-(1,2,2-triphenylvinyl) phenyl) acrylonitrile (Py-TPE). We show that Py-TPE has an ultrafast excited carrier relaxation time less than 20 ps, shorter than most of inorganic semiconductor materials. More importantly, by depositing such Py-TPE on the surface of tapered fiber as an SA device in Er-doped fiber laser system, an ultrafast fiber laser output with a pulse width as narrow as 447 fs and good stability was realized. This is the first report, to the best of our knowledge, to achieve femtosecond laser by taking advantage of the Py-TPE with ultrafast excited carrier relaxation time. These results demonstrate that Py-TPE is a novel organic saturable absorption material with great potential application in ultrafast laser and photonics.

Emerging 2D Materials with Nonparabolic Bands for Ultrafast Photonics

In recent years, 2D materials have been widely used in optical and photonic applications such as mode lockers, optical switches, polarizers, and optical modulators. As is known, many 2D optical materials are parabolic semiconductors. The electronic states determines the material's optical characteristics. The energy band structure with a bandgap dominates the electron dynamics process associated with intrinsic light absorption. Particularly, the Dirac cone and flat band (FB) are special nonparabolic energy band structures in materials. Dirac materials are characterized by a zero bandgap, and FB materials have a completely flat dispersionless band in the Brillouin zone. These materials are used as emergent and promising 2D materials for saturable absorbers (SAs) due to their excellent nonlinear optical response, and they become potential candidates for ultrafast photonics applications. Herein, the focus is on the characteristics of the energy band structure; the carrier dynamics are reviewed, and application in ultrafast photonics are summarized.