Emerging PbSnS2 pulse modulators for ultrafast and high repetition frequency photonic applications

Abstract

Two-dimensional ternary metal sulfides receive growing concern due to the diverse physicochemical properties and broad application potential. In this study, ultrafast nonlinear optical properties of two-dimensional lead tin sulfide (PbSnS2) nanosheets are demonstrated. PbSnS2 nanosheets with the thickness less than 3 nm were fabricated by liquid-phase exfoliation, and PbSnS2 nanosheets based saturable absorber (SA) was constructed by photodeposition. The nonlinear optical absorption properties such as modulation depth (21 %) and saturation intensity (14.2 MW/cm2) of PbSnS2-SA were investigated. Dispersion management was applied to Er3+-doped fiber laser (EDFL) coupled with PbSnS2-SA. The EDFL with net dispersion −0.36 ps2 outputs 928 fs mode-locked pulses. With a cavity dispersion of −0.58 ps2, tunable 1st to 9th order harmonic mode-locked (HML) is realized by tuning the pump power only. The EDFL (net dispersion −0.98 ps2) produces the highest repetition frequency at 362.59 MHz (corresponding to 80th order HML). The results indicate that two-dimensional PbSnS2 may be widely used as ultrafast photonics material for photonics and engineering applications research.