Various forms of machine learning (ML) methods have historically played a valuable role in environmental remote sensing research. With an increasing amount of “big data” from earth observation and rapid advances in ML, increasing opportunities for novel methods have emerged to aid in earth environmental monitoring. Over the last decade, a typical and state-of-the-art ML framework named deep learning (DL), which is developed from the traditional neural network (NN), has outperformed traditional models with considerable improvement in performance. Substantial progress in developing a DL methodology for a variety of earth science applications has been observed. Therefore, this review will concentrate on the use of the traditional NN and DL methods to advance the environmental remote sensing process. First, the potential of DL in environmental remote sensing, including land cover mapping, environmental parameter retrieval, data fusion and downscaling, and information reconstruction and prediction, will be analyzed. A typical network structure will then be introduced. Afterward, the applications of DL environmental monitoring in the atmosphere, vegetation, hydrology, air and land surface temperature, evapotranspiration, solar radiation, and ocean color are specifically reviewed. Finally, challenges and future perspectives will be comprehensively analyzed and discussed.