Encryption Applications Research Articles

Highly Efficient Red/Near‐Infrared Phosphorescence from Doped Crystals

AbstractOrganic red/near‐infrared (NIR) room temperature phosphorescence (RTP) materials with low toxicity and facile synthesis are highly sought after, particularly for applications in biotechnology and encryption. However, achieving efficient red/NIR RTP emitters has been challenging due to the weak spin‐orbit coupling of organics and the rapid nonradiative decay imposed by the energy gap law. Here we demonstrate highly efficient red/NIR RTP with boosted quantum yields (Φps) of up to 32.96 % through doping the thionated derivatives of phthalimide (PAI) (MTPAI and DTPAI) into PAI crystals. The red‐shifted photoluminescence (PL) stems from a combination of the external heavy atom effect and the formation of emissive clusters centered around electron‐rich sulfur atoms. Furthermore, the dopants enhance exciton generation efficiency and facilitate energy transfer from smaller PAI units to larger aggregates, leading to dramatically increased Φp. This strategy proves universal, opening possibilities for acquiring long‐wavelength RTP with tunable photophysical properties. The doped crystals exhibit promising applications in optical waveguides and encryption paper/ink. This research provides a practical approach to obtaining long‐wavelength RTP materials and offers valuable insights into the mechanisms governing host‐guest systems.

Highly Efficient Red/Near-Infrared Phosphorescence from Doped Crystals.

Organic red/near-infrared (NIR) room temperature phosphorescence (RTP) materials with low toxicity and facile synthesis are highly sought after, particularly for applications in biotechnology and encryption. However, achieving efficient red/NIR RTP emitters has been challenging due to the weak spin-orbit coupling of organics and the rapid nonradiative decay imposed by the energy gap law. Here we demonstrate highly efficient red/NIR RTP with boosted quantum yields (Φps) of up to 32.96 % through doping the thionated derivatives of phthalimide (PAI) (MTPAI and DTPAI) into PAI crystals. The red-shifted photoluminescence (PL) stems from a combination of the external heavy atom effect and the formation of emissive clusters centered around electron-rich sulfur atoms. Furthermore, the dopants enhance exciton generation efficiency and facilitate energy transfer from smaller PAI units to larger aggregates, leading to dramatically increased Φp. This strategy proves universal, opening possibilities for acquiring long-wavelength RTP with tunable photophysical properties. The doped crystals exhibit promising applications in optical waveguides and encryption paper/ink. This research provides a practical approach to obtaining long-wavelength RTP materials and offers valuable insights into the mechanisms governing host-guest systems.

OFDM Transmission in Rayleigh Fading Channel for S-Box and 3D Chaotic Maps Based Encrypted Image

Data encryption is an important part of the communication system. The Chaos essential properties, make it a crucial candidate for encryption applications. There is a compromise between complexity and security in previous studies. In this study, high security was achieved with low complexity. This paper proposed a 3D chaotic map and S-Box has been cascaded to get a high efficiency as complex algorithms or multi-iteration schemes. The first stage is ciphering using 3D cat-map, the second stage is S-box based on 3D henon map, while the third stage is another ciphering stage using 3D henon map. In this study, various encryption techniques, including cipher algorithms and substitution box, are combined with the OFDM system to establish a secure image transmission over a Rayleigh fading channel. QPSK modulation is used to ensure the simplicity of the proposed system. Six gray images are used, Lena, the cameraman, Barbara, Baboon, pepper and Elaine for testing and comparing with previous works. Security analysis is performed to evaluate the quality and security of the encryption process, the entropy value reach 7.99, correlation coefficient is around zero and the histogram is uniform. In addition, the key size is 2630. For image transmission evaluation, the PSNR and BER are utilized and it reached 10-5 for BER. According to the statistical results, the proposed image encryption scheme is secure and efficient.

Full-Color Dynamic Afterglow in Carbon Dot-Based Materials Regulated by Dual-Phosphorescence Resonance Energy Transfer.

Developing afterglow materials with wide-range and time-dependent colors is highly desirable but challenging. Herein, by calcinating the mixture of Rhodamine B and NH4Al(OH)2CO3, carbon dots (CDs) are generated and in situ embedded in the porous Al2O3, forming the CDs@Al2O3 composite, which exhibits time-dependent phosphorescence colors (TDPCs) from blue to green after excited by a UV lamp. Photophysical studies reveal that the blue phosphorescence with a short lifetime of 214ms originates from the carbon core state, while the green phosphorescence with a long lifetime of 915ms is associated with the surface state of CDs. Simultaneous activation of the blue and green phosphorescence with different lifetimes induces the TDPC performance. Using CDs@Al2O3 as the donor, a series of long-wavelength fluorescent dyes including Rhodamine 123, Rhodamine 6G, and Rhodamine B as the acceptors, and epoxy resin (ER) as the matrix, a dual-phosphorescence resonance energy transfer system (CDs@Al2O3-dye-ER) is constructed to rationally regulate the afterglow emission, conferring the full-color dynamic afterglow from blue to red at different decay times with high afterglow quantum yields of up to 48.2%. The fascinating afterglow properties of the CDs@Al2O3-dye-ER composites enable their successful applications in multidimensional information encryption and polychrome 3D artworks.

Ionic Hydrogen-Bonded Organic Frameworks with a Two-Photon Synergistic Color Change and Their Information Encryption Applications.

Photochromic hydrogen-bonded organic frameworks (HOFs) can introduce different luminescent functional groups to achieve synergistic controlled multiple color change properties, which are in great demand for diverse information encryption applications. We report in this paper switchable photochromic and photoluminescent dual luminescent functional group HOFs constructed with synergistic effects by N,N'-bis(2-phenylalanine)-1,4,5,8-naphthalenediimine (H2PheNDI) and benzenecarboximidamide 4,4'-azobis(hydrochloride) (AZBH). The crystal powder of iHOF-41 is orange-red in color, which can be changed to black under the irradiation of a 365 nm ultraviolet (UV) light source for 15 min. The photoisomerization rate of the crystal solution under continuous UV irradiation for 5 h was close to 99%. The composite membranes can achieve the properties of photochromism and photoluminescence when they are discolored under 365 nm UV irradiation and, at the same time, excite red bright fluorescence. This work achieves the construction of HOFs based on switching biluminescent functional groups and explores the synergistic mechanism of the photoisomerization process and photochromism as well as its practical application in information encryption.

Multi-wing chaotic system based on meminductor and its application in image encryption

Meminductor is a novel type of nonlinear device following the memristor, characterized by its memory properties. Currently, research on meminductors is still in its infancy, with their physical devices yet to be formally realized. Therefore, conducting fundamental research on their nonlinear circuit properties and applications is of great significance. In this paper, a new multi-wing chaotic system is proposed based on the mathematical model of a magnetically controlled meminductor. By varying the values of its parameters, the system can generate two-wing, three-wing, and four-wing chaotic attractors. Various analytical methods are employed to study the dynamical behaviours of the proposed chaotic system. The results demonstrate that the system is highly sensitive to its initial conditions and control parameters, which makes it suitable for image encryption. Based on the new system, we propose a new algorithm for image encryption that combines the newly established four-dimensional multi-wing chaotic system with bit plane decomposition technique, firstly, the high four-bit planes containing 94% image information are disordered by S-type permutation, then the disordered bit planes perform operation of XOR with the random matrix generated by chaotic sequences, and finally, the encrypted image is obtained by merging the bit planes.

A chiral supramolecular liquid crystal based on pillararene and its application in information encryption.

A chiral supramolecular liquid crystal based on a pillararene mesogen was constructed. The regulation of liquid crystal behavior was achieved through the host-guest interactions between the pillararene-based mesogen and a tetraphenylethylene-containing guest. In addition, this supramolecular liquid crystal system, showing pH-responsive fluorescence emission character, was applied as an information encryption material capable of storing multiple levels of distinct information, thereby enriching the application of liquid crystal materials in the field of information security.

Flexible and transparent leaf-vein electrodes fabricated by liquid film rupture self-assembly AgNWs for application of heaters and pressure sensors

The leaf veins with hierarchically interconnected network structures have great potential as self-assembly templates for transparent and flexible electrodes. In this paper, a liquid membrane ruptured assisted AgNWs self-assembly method was adopted to obtain conductive veins, which show a low sheet resistance of 3.6Ω/□ and a high transparency of 79 % at a minimal materials waste. The figure of merit of conductive veins was as high as 433Ω-1 and can be further increased by increasing the number of soaking because the light transmittance is nearly immune to the AgNWs layer number. The veins maintained a good electrical conductivity even after bending 10,000 times at a 2 mm radius of curvature and exhibited a good corrosion resistance under harsh conditions. Heaters based on the conductive veins are shown as application examples. A high temperature of 104 °C was achieved at a low voltage of 2 V, which is enough to heat cold water. They still have good heating properties even in the bending state or tensile state. Furthermore, pressure sensors based on the conductive veins were fabricated as examples of wearable devices. The sensor exhibits a high sensitivity of 3.8 kPa−1 in the low-pressure range (0–15 kPa) and 17.4 kPa−1 in the high pressure range (15–50.96 kPa). It can monitor human actions such as finger bending, finger taping, throat swallowing and wrist pulse in real-time, which has promising potential for motion monitoring and information encryption applications.

Revisiting the Slot-to-Coefficient Transformation for BGV and BFV

Numerous applications in homomorphic encryption require an operation that moves the slots of a ciphertext to the coefficients of a different ciphertext. For the BGV and BFV schemes, the only efficient algorithms to implement this slot-to-coefficient transformation were proposed in the setting of non-power-of-two cyclotomic rings. In this paper, we devise an FFT-like method to decompose the slot-to-coefficient transformation (and its inverse) for power-of-two cyclotomic rings. The proposed method can handle both fully and sparsely packed slots. Our algorithm brings down the computational complexity of the slot-to-coefficient transformation from a linear to a logarithmic number of FHE operations, which is shown via a detailed complexity analysis. The new procedures are implemented in Microsoft SEAL for BFV. The experiments report a speedup of up to 44 times when packing 2^12 elements from GF(8191^8). We also study a fully packed bootstrapping operation that refreshes 2^15 elements from GF(65537) and obtain an amortized speedup of 12 times.

Upconversion/Downshifting Circularly Polarized Luminescence over 1200 nm in a Single Nanoparticle for Optical Anticounterfeiting and Information Encryption.

Multimodal upconversion and downshifting circularly polarized luminescent materials hold significant potential for optical anticounterfeiting applications due to their exceptional chiroptical properties. However, constructing these materials within a single emitter remains challenging. In this study, a conceptual model of multimodal up-conversion/downshifting circularly polarized luminescence (CPL) is realized within a single nanoparticle. A new type of nanoparticles with multilayer core-shell architecture is fabricated, capable of delivering upconversion/downshifting luminescence, when excited by a 980 nm laser. Utilizing a co-assembly strategy, multimodal upconversion/downshifting CPL emission, covering a broad emission range from ultraviolet (UV) to the second near-infrared (NIR-II) region, can be realized at the supramolecular level. These chiroptical properties closely follow the chirality of host matrix and are strongly dependent on the distribution mode of nanoparticles within the matrix films. The multimodal upconversion/downshifting CPL behavior enabled cutting-edge encryption applications including optical anticounterfeiting and information encryption. This work introduces a novel approach to designing multimodal upconversion/downshifting CPL materials and opens new avenues for the development of chiroptical functional materials.

Upconversion/Downshifting Circularly Polarized Luminescence over 1200 nm in a Single Nanoparticle for Optical Anticounterfeiting and Information Encryption

Multimodal upconversion and downshifting circularly polarized luminescent materials hold significant potential for optical anticounterfeiting applications due to their exceptional chiroptical properties. However, constructing these materials within a single emitter remains challenging. In this study, a conceptual model of multimodal up‐conversion/downshifting circularly polarized luminescence (CPL) is realized within a single nanoparticle. A new type of nanoparticles with multilayer core‐shell architecture is fabricated, capable of delivering upconversion/downshifting luminescence, when excited by a 980 nm laser. Utilizing a co‐assembly strategy, multimodal upconversion/downshifting CPL emission, covering a broad emission range from ultraviolet (UV) to the second near‐infrared (NIR‐II) region, can be realized at the supramolecular level. These chiroptical properties closely follow the chirality of host matrix and are strongly dependent on the distribution mode of nanoparticles within the matrix films. The multimodal upconversion/downshifting CPL behavior enabled cutting‐edge encryption applications including optical anticounterfeiting and information encryption. This work introduces a novel approach to designing multimodal upconversion/downshifting CPL materials and opens new avenues for the development of chiroptical functional materials.

Synthesis of ZnO nanoparticles-based fluorescent ink for information encryption and security applications

Synthesis of ZnO nanoparticles-based fluorescent ink for information encryption and security applications

A Novel Parameter-Variabled and Coupled Chaotic System and Its Application in Image Encryption with Plaintext-Related Key Concealment.

The design of a chaotic system and pseudo-random sequence generation method with excellent performance and its application in image encryption have always been attractive and challenging research fields. In this paper, a new model of parameter-variabled coupled chaotic system (PVCCS) is established by interaction coupling between parameters and states of multiple low-dimensional chaotic systems, and a new way to construct more complex hyperchaotic systems from simple low-dimensional systems is obtained. At the same time, based on this model and dynamical DNA codings and operations, a new pseudo-random sequence generation method (PSGM-3DPVCCS/DNA) is proposed, and it is verified that the generated pseudo-random sequence of PSGM-3DPVCCS/DNA has excellent random characteristics. Furthermore, this paper designs a novel pixel chain diffusion image encryption algorithm based on the proposed parameter-variabled coupled chaotic system (PVCCS) in which the hash value of plaintext image is associated with the initial key to participate in the encryption process so that the encryption key is closely associated with plaintext, which improves the security of the algorithm and effectively resists the differential cryptanalysis risk. In addition, an information hiding method is designed to hide the hash value of plaintext image in ciphertext image so that the hash value does not need to be transmitted in each encryption, and the initial key can be reused, which solves the key management problem in application and improves the application efficiency of the encryption algorithm. The experimental analysis shows that the chaotic system constructed in this paper is creative and universal and has more excellent chaotic characteristics than the original low-dimensional system. The sequence generated by the pseudo-random sequence generation method has excellent pseudo-random characteristics and security, and the image encryption algorithm can effectively resist differential cryptanalysis risk, showing advanced encryption performance.

Fabrication of Color-Tunable Gold Nanoclusters and Their Application for Information Encryption

Fabrication of Color-Tunable Gold Nanoclusters and Their Application for Information Encryption

Development of Hill Cipher Method For Encryption And Decryption of Drug Prescriptions to Improve Data Security

A prescription is a written request from a doctor to a pharmacist, as not everyone can know the dosage or type of a particular drug, especially patients who need a prescription for the drug must be kept secret. Rapid technological advances can have an impact on all sectors, both private and government, including the medical field. One of the medical services that utilizes IT is to send prescription messages electronically to pharmacists in response to doctors' requests. The many misuse of prescription drugs by irresponsible people and misreading prescription drugs by pharmacists can be fatal for patients, so a solution is needed to overcome these problems. The purpose of this study is to create an encrypted electronic recipe application using the Hill Cipher method. This research method generally starts from data collection, data analysis and encryption model development. Applications designed with the Hill Cipher Algorithm are developed with modified algorithm keys using postal code patterns as the matrix keys, this aims to achieve the maximum level of security. The results of the system functionality test using the black box method obtained normal results for all system test scenarios. Validity testing yields valid results. The final test, through questionnaire testing, obtained a good level of system feasibility, namely an average level of Service of 83%, Features of 78% and Performance of 81%. Overall, the system has given a good performance score as the accuracy of the system is above 70%.

Facile synthesis and tunable fluorescent properties of a new D-π-A isocoumarin: Applications in encryption and OLED technology

A facile synthesis of a new D-π-A isocoumarin (ICP-NH2) with only two steps under mild conditions through O-acylation/Wittig/reduction reaction has been established. The readily accessible phosphonium salt precursor 1 and 4-nitrobenzoyl chloride 2 produced intermediate ICP-NO2 in the presence of triethylamine. Subsequently, ICP-NO2 underwent conversion to ICP-NH2 through the reduction of stannous dichloride. ICP-NH2 exhibits enhanced fluorescence overcoming the photo-induced electron transfer (PET) process in ICP-NO2. ICP-NH2 demonstrates a significant change in fluorescence from blue to green in various polar solvents, and DFT analysis confirmed that its solvatochromism is attributed to intramolecular charge transfer (ICT) effect. ICP-NH2 undergoes noticeable acidochromism based on reversible protonation and deprotonation reactions with TFA and TEA, leading to periodic changes in fluorescence from green to dark blue. This phenomenon can be utilized in designing reusable encryption technology. Additionally, ICP-NH2 can be employed in the fabrication of a cyan green OLED device.

Memristor-coupled cubic hyperchaotic system, feedback synchronization and its application in image encryption

Discrete memristive chaotic systems play a crucial role in information security, and chaotic synchronization form the bedrock of secure and confidential communication. To enhance the chaotic complexity of the Cubic map, we introduce a memristor-coupled Cubic hyperchaotic system by integrating a discrete absolute memristor model with the Cubic map. The dynamics are thoroughly investigated through attractor phase diagrams, bifurcation diagrams, SE complexity analysis, and diagrams illustrating the distribution of dynamic behaviors. Furthermore, we establish methods for chaos control and nonlinear feedback synchronization for the memristive Cubic map. Leveraging this feedback synchronization, we achieve encrypted transmission of digital images. Simulation results validate the feasibility and robust security of the proposed encrypted transmission scheme.

Dual-emission rare-earth fluorescent nanomaterials for ratiometric and visual detection of N-acetylneuraminic acid and applications in information encryption and anti-counterfeiting

N-acetylneuraminic acid (NANA) can be used as a biomarker for many types of cancers. Currently, there are various methods for detecting NANA but showing some shortcomings that limit the real-time diagnosis of cancer. In contrast, fluorescence analysis has obvious advantages such as low cost, fast response time, and easy operation, and it also enables visual detection for real-time cancer monitoring. Therefore, the establishment of an efficient and rapid detection method is essential for the early prevention and treatment of the disease. Based on the properties of layered rare-earth hydroxide (LRH), we synthesized a dual-emission fluorescent material (NDC/SDS-LEuH), and further fabricated a fluorescent nanoprobe (ANP) for the detection of NANA. The probe has the advantages of high sensitivity (LOD = 32.9 μM) and high selectivity with fast response. During the sensing process, the dual emission of the probe shows opposite changes due to the photoinduced electron transfer (PET) effect and the interaction between NANA and the probe. The color changes of the system can be observed under UV irradiation. Therefore, a visual platform was developed to detect NANA with a LOD of 0.09 mM. In addition, a probe hydrogel was prepared, which can be applied in the anti-counterfeiting to improve the difficulty of counterfeiting and the security of anti-counterfeiting. The probe achieves ratiometric fluorescence detection of NANA, which reduces background interference and improves the accuracy of detection. A visual detection platform was fabricated to realize the real-time detection. In addition, the prepared probe hydrogel showed the potential applications in anti-counterfeiting, which provided new ideas for the design and application of anti-counterfeiting materials.

Photo-induced fluorescence discoloration and photo-responsive room temperature phosphorescence carbon dot-based composites with excellent reversibility and water resistance

Photo-stimulation responsive room temperature phosphorescence (RTP) carbon dots (CDs) have potential applications in advanced dynamic information encryption and anti-counterfeiting. However, the development of photo-responsive long-wavelength RTP CD materials with excellent reversibility and water resistance, as well as CD materials with both photo-induced fluorescence discoloration and photo-responsive reversible RTP properties, remains a challenge. Here, pyrene, which has a large conjugated structure, and 4-(1,2,2-triphenylvinyl)benzaldehyde, which has a tetraphenylethylene structure, were selected as the main raw materials to synthesize two CDs. Then, by introducing a PMMA matrix, reversible photo-responsive long-wavelength red RTP emission with a lifetime of 257 ms from a CD-based composite is realized for the first time, and the combination of photo-induced fluorescence discoloration and photo-responsive reversible yellow RTP with a lifetime of 287 ms is realized. Importantly, photo-responsive reversible RTP has excellent water resistance. The fluorescence discoloration was caused by photocyclization under long-term UV irradiation due to the presence of the tetraphenylethylene structure. The rigid environment provided by the PMMA matrix and the hydrogen bonds formed between the PMMA and CDs promote the generation of RTP. The photo-responsiveness of RTP is caused by the conversion of molecular oxygen (3O2) to singlet oxygen (1O2) under continuous UV irradiation. It is filled with 3O2 again after being placed in air to inactivate the RTP, thus achieving reversible RTP behavior. Owing to their excellent photo-responsive properties and water resistance, these materials have the potential to achieve repeatable dynamic information encryption and multilevel pattern anti-counterfeiting while also broadening the range of applications in water environments.

Sign Inversion of Circularly Polarized Luminescence in Cholesteric Liquid Crystals Induced by Mercury Ions through Binaphthyl Dopants' Conjugation Control.

Stimuli-responsive circularly polarized luminescence (CPL) materials based on cholesteric liquid crystal (CLC) platforms show great promise for applications in information encryption and anticounterfeiting. In this study, we constructed a mercury ion-responsive CPL system in CLCs by controlling the conjugation degree of axially chiral binaphthyl derivatives. Two chiral binaphthyl derivatives (R/S-1 and R/S-2) were initially used as chiral dopants to demonstrate that CPL inversion (glum values from 0.5/-0.44 to -0.53/0.48) in CLCs could be achieved by modulating the conjugation degree of the chiral binaphthyls. Based on this concept, the thioacetal binaphthyl R-2S was developed and used as a mercury-responsive chiral dopant in CLCs. Under Hg ion treatment, the CPL sign inverted (glum value changed from 0.22 to -0.29) due to the transformation of the thioacetal into an aldehyde group. Additionally, the mercury ion-responsive CPL material was applied in information encryption.