Applications Of Black Phosphorus Research Articles

Study on the modulation of luminescence peak position and luminescence mechanism of black phosphorus

The application of black phosphorus in optoelectronic devices is hindered because of its inherent band gap characteristics. In the paper, black phosphorus was prepared by high-energy ball milling, and its related structure and properties were characterized. At the same time, the luminescence mechanism of black phosphorus was explored, and the effect of ultrasonic time on the structure and optical properties of black phosphorus was studied. The luminescence peak of black phosphorus can be modulated to the visible light range after adding polyethylene glycol, and the luminescence of black phosphorus is closely related to the P (020) and P (021). It was found that the luminescence intensity of alcoholized black phosphorus decreases with the increase of ultrasonic time. When the ultrasonic time is 15min, the luminescence intensity of alcoholized black phosphorus decreases greatly, this is because that the content of P (020) in black phosphorus decreases with the increase of ultrasonic time, resulting in the decrease of luminescence intensity.

Research Progress on the Preparation Methods for and Flame Retardant Mechanism of Black Phosphorus and Black Phosphorus Nanosheets

Black phosphorus and black phosphorus nanosheets are widely used in the flame retardant field because of their excellent properties, but the immature preparation methods have resulted in extremely high preparation cost, which greatly limits their development and application. In this paper, various preparation methods of black phosphorus and black phosphorus nanosheets are described in detail, the advantages and disadvantages of each method are analyzed in depth, the flame-retardant mechanism and application of black phosphorus and black phosphorus nanosheets in flame retardants are discussed, and the subsequent development direction of black phosphorus and black phosphorus nanosheets is proposed.

Inspired electrocatalytic performance by unique amorphous PdCu nanoparticles on black phosphorus

The application of black phosphorus (BP) in electrocatalysis is due to its inherent susceptibility to oxidation in the presence of oxygen and water. Herein, we achieved for the first time the growth of amorphous palladium-copper alloy nanoparticles (PdCu NPs) on two-dimensional BP nanosheets by a one-step solvothermal method. PdCu NPs/BP overcomes the instability of BP and shows exceptional stability and catalytic performance for the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER). In particular, PdCu NPs/BP exhibits only 4.7% decay in current density after 36,000 s of chronoamperometric testing and 11 mV negative shift in half-wave potential after 10,000 cycles of accelerated durability test. This has resulted in PdCu NPs/BP being the most stable among the currently known Pd-based ORR catalysts. This work introduces a novel method for growing uniform amorphous alloy nanoparticles on BP as well as new ideas for improving BP's oxidation resistance for use in electrocatalysis.

Transcriptome Analysis Reveals the Growth Promotion Mechanism of Enteropathogenic Escherichia coli Induced by Black Phosphorus Nanosheets.

With the extensive production and application of black phosphorus (BP) nanosheets, release to the environment is inevitable, which raises concerns about the fate and effects of this two-dimensional (2D) material on sensitive receptors such as environmental microbes. Although the bacterial toxicity of BP nanosheets has been demonstrated, whether the biological response differs in pathogenic and nonpathogenic strains of a microorganism is unknown. Here, enteropathogenic Escherichia coli (EPEC) and nonpathogenic Escherichia coli DH5α (E. coli DH5α), Escherichia coli k12 (E. coli k12), and Bacillus tropicus (B.tropicus) are used to comparatively study the microbial toxicity of BP nanosheets. Upon exposure to BP nanosheets across a range of doses from 10 to 100 μg mL-1 for 12 h, EPEC experienced enhanced growth and E. coli DH5α and E. coli k12 were not affected, whereas B.tropicus exhibited clear toxicity. By combining transcriptome sequencing, proteome analysis, and other sensitive biological techniques, the mechanism of BP-induced growth promotion for EPEC was uncovered. Briefly, BP nanosheets activate the antioxidation system to resist oxidative stress, promote protein synthesis and secretion to attenuate membrane damage, enhance the energy supply, and activate growth-related pathways. None of these impacts were evident with nonpathogenic strains. By describing the mechanism of strain-dependent microbial effects, this study not only highlights the potential risks of BP nanosheets to the environment and to human health but also calls attention to the importance of model strain selection when evaluating the hazard and toxicity of emerging nanomaterials.

Synthesis, modification, and application of black phosphorus, few-layer black phosphorus (FLBP), and phosphorene: a detailed review

Synthesis, modification, and application of black phosphorus.

Electron Matters: Recent Advances in Passivation and Applications of Black Phosphorus.

2D materials have experienced rapid and explosive development in the past decades. Among them, black phosphorus (BP) is one of the most promising materials on account of its thickness-dependent bandgap, high charge-carrier mobility, in-plane anisotropic structure, and excellent biocompatibility, as well as the broad applications brought by the properties. In view of the electron configuration, the most unique feature of BP is the lone-pair electrons on each P atom. The lone-pair electrons inevitably cause high reactivity of BP, particularly toward water/oxygen, which greatly limits the practical application of BP under ambient conditions. The other side of the coin is that BP can serve as an electron donor to promote the construction of BP-based hybrid materials and/or to boost the performance of BP or BP-based hybrid materials in applications. Here, recent advances in passivation and application of BP by addressing the interaction between the lone-pair electrons of BP and the other materials are discussed, and prospects for future research on BP are also proposed.

Optoelectronic characteristics and application of black phosphorus and its analogs

The tunable bandgap from 0.3 eV to 2 eV of black phosphorus (BP) makes it to fill the gap in graphene. When studying the properties of BP more comprehensive, scientists have discovered that many two-dimensional materials, such as tellurene, antimonene, bismuthene, indium selenide and tin sulfide, have similar structures and properties to black phosphorus thus called black phosphorus analogs. In this review, we briefly introduce preparation methods of black phosphorus and its analogs, with emphasis on the method of mechanical exfoliation (ME), liquid phase exfoliation (LPE) and chemical vapor deposition (CVD). And their characterization and properties according to their classification of single-element materials and multi-element materials are described. We focus on the performance of passively mode-locked fiber lasers using BP and its analogs as saturable absorbers (SA) and demonstrated this part through classification of working wavelength. Finally, we introduce the application of BP and its analogs, and discuss their future research prospects.

Phosphorene Nanosheets Exfoliated from Low-Cost and High-Quality Black Phosphorus for Hydrogen Evolution

Black phosphorus (BP) has recently attracted intense research interest due to its unique thickness-dependent and anisotropic electronic and photonic properties, and has shown promising potential in nanophotonic, nanoelectronics and energy storage applications. However, the application of BP in practical devices is hindered by its high commercial cost. To further reduce the cost and accelerate the development of BP, a highly efficient preparation strategy for low-cost BP must be found. Herein, we report such a method via a modified chemical vapor transport (CVT) method by replacing high-purity red phosphorus (RP) with a low-purity precursor counterpart. We show that this method can drastically reduce the cost of manufacturing by several orders of magnitude. Furthermore, the BP produced using low-cost RP shows nearly the same crystal quality, high purity, local chemical structure, and electronic properties, compared with those of the high-cost BP prepared by the traditional CVT method. Most importantly, exfoliated phosphorene nanosheets prepared from the low-cost BP exhibit promising hydrogen evolution reaction (HER) activity. Owing to the high quality and high conversion efficiency, the low-cost BP holds promising potential in future scientific research and industrial applications.

An overview of the optical properties and applications of black phosphorus.

Since the year 2014, when scientists first obtained black phosphorus using a sticky tape to peel the layers off, it has attracted tremendous interest as a novel two-dimensional material. After it was successfully produced, its outstanding optical properties have been unveiled. Various applications based on these properties have been reported. This study mainly reviews the unique optical properties and potential applications of black phosphorus. The optical performances of black phosphorus mainly include linear optical properties and nonlinear optical properties. Some examples include the anisotropic optical response, saturable absorption effect and Kerr effect. The researchers found that the nonlinear saturable absorption coefficients of black phosphorus are better than that of MoS2 and WS2 from the visible region to the near-infrared region. Compared with graphene, black phosphorus has a better nonlinear saturable absorption performance. After passivation or surface modification, black phosphorus is stable when exposed to oxygen and water. Herein, black phosphorus has the potential to be used in detector/sensors, solar energy harvesting, photocatalysts, optical saturable absorbers in ultrafast lasers, all optical switches, optical modulation, nanomedicine and some others in the near future.

Review on Applications of Black Phosphorus in Catalysis.

As emerging non-metallic semiconductors, black phosphorus (BP) and few-layered BP (phosphorene) have exhibited unique physicochemical properties and promising application prospect for catalysis related fields. In this review, we first introduced the intriguing properties of BP, including high carrier mobility, a wide optical absorption range and tunable direct band gap. We then summarized the recent research progress about the applications of BP as catalysts, mainly focus on photocatalytic water splitting, photocatalytic degradation of organic pollutants and electrocatalytic H₂ and O₂ evolution. The recent works about other catalytic applications were also introduced.

Revisiting the Growth of Black Phosphorus in Sn-I Assisted Reactions

Black phosphorus, an emerging layered material, exhibits promising applications in diverse fields, ranging from electronics to optics. However, controlled synthesis of black phosphorus, particularly its few-layered counterparts, is still challenging, which should be due to the unclear growth mechanism of black phosphorus. Here, taking the most commonly used Sn-I assisted synthesis of black phosphorus as an example, we propose a growth mechanism of black phosphorus crystals by monitoring the reactions and analyzing the as-synthesized products. In the proposed mechanism, Sn24P19.3I8 is the active site for the growth of black phosphorus, and the black phosphorus crystals are formed with the assistance of SnI2, following a polymerization-like process. In addition, we suggest that all Sn-I assisted synthesis of black phosphorus should share the same reaction mechanism despite the differences among Sn-I containing additives. Our results shown here should shed light on the controlled synthesis of black phosphorus and facilitate further applications of black phosphorus.