Information Security Applications Research Articles

Dynamic color‐tunable ultra‐long room temperature phosphorescence polymers with photo‐chromism and water‐stimuli response for multilevel anti‐counterfeiting

AbstractDeveloping dynamic color‐tunable ultra‐long room temperature phosphorescence (URTP) polymers with afterglow of over 1 s, photo‐chromism, and multi‐stimuli response for practical anti‐counterfeiting and information security applications is attractive but very challenging. Herein, by doping multicolor phosphorescence pyridinium bromide L block or viologen‐based photo‐chromic V block into polyvinyl alcohol matrixes, the water‐stimuli‐responsive color‐tunable URTP polymer films with afterglow of up to 8 s and the reversible viologen‐based photochromic polymer films have been developed. More significantly, a series of dynamic color‐tunable URTP polymer films with ultra‐long afterglow of over 6 s, photo‐chromism, and water‐stimuli response have been successfully exploited by integrating L and V blocks into one polymer system. Mechanistic investigations have revealed that their photo‐chromism mainly comes from the photo‐generated viologen free radicals. Furthermore, their dynamic multilevel anti‐counterfeiting applications have been demonstrated. These results pave the way to develop smarter multifunctional URTP materials for anti‐counterfeiting and optical sensing.

Viologen‐based host–guest supramolecule with tunable intramolecular/intermolecular electron transfer chromism and dynamic fluorescence

AbstractViologen, as a type of strong electron acceptor, is prone to undergo electron transfer (ET) and change color under external stimuli. However, due to the easy aggregation of viologen molecules, they usually suffer from poor fluorescence emission in the condensed phase. Herein, a new viologen derivative of VioCl2·2Cl (12+·2Cl) was designed and synthesized, in which the fluorescence was enhanced by introducing Me‐β‐CD to weaken the interactions between viologen molecules. Then a viologen‐based host–guest supramolecule of 12+@Me‐β‐CD was obtained by electrostatic interactions. Photo‐/chemo‐responded guest 12+ supplies 12+@Me‐β‐CD, a green and dark purple caused by intramolecular and intermolecular ET. Furthermore, 12+@Me‐β‐CD displays an additional thermal responsive purple color. The triple chromic behaviors all exhibit excellent reversibility and cycling stability. As expected, 12+@Me‐β‐CD exhibits strong photoluminescence (PL) in solid–liquid dual states, presenting an improved quantum yield (Φ) from 12+ (Φs = 0.37%, Φl = 16.74%) to 12+@Me‐β‐CD (Φs = 10.45%, Φl = 25.86%), and the fluorescence intensity can be dynamically modulated by light, heat, and acid/base vapors. The multi‐responsive chromism and tunable fluorescence of 12+@Me‐β‐CD allow for potential applications in information security and smart windows.

Tailored Fabrication of Full-Color Ultrastable Room-Temperature Phosphorescence Carbon Dots Composites with Unexpected Thermally Activated Delayed Fluorescence.

The development of single-system materials that exhibit both multicolor room-temperature phosphorescence (RTP) and thermally activated delayed fluorescence (TADF) with tunable after glow colors and channels is challenging. In this study, four metal-free carbon dots (CDs) are developed through structural tailoring, and panchromatic high-brightness RTP is achieved via strong chemical encapsulation in urea. The maximum lifetime and quantum yield reaches 2141 ms and 56.55%, respectively. Moreover, CDs-IV@urea, prepared via coreshell interaction engineering, exhibits a dual afterglow of red RTP and green TADF. The degree of conjugation and functional groups of precursors affects the binding interactions of the nitrogen cladding on CDs, which in turn stabilizes triplet energy levels and affects the energy gap between S1 and T1 (ΔEST) to induce multicolor RTP. The enhanced wrapping interaction lowers the ΔEST, promoting reverse intersystem crossing, which leads to phosphorescence and TADF. This strong coreshell interaction fully stabilizes the triplet state, thus stabilizing the material in water, even in extreme environments such as strong acids and oxidants. These afterglow materials are tested in multicolor, time, and temperature multiencryption as well as in multicolor in vivo bioimaging. Hence, these materials have promising practical applications in information security as well as biomedical diagnosis and treatment.

Magnetic media synergistic carbon fiber@Ni/NiO composites for high-efficiency electromagnetic wave absorption

Electromagnetic wave (EMW) absorbing materials have garnered significant attention for their potential applications in information security and military stealth fields. However, the development of highly efficient EMW absorbing materials possessing characteristics such as being “thin, lightweight, broadband and strong” remains a considerable challenge. Addressing this challenge involves the construction of low-dimensional composite material systems, which proves to be an effective approach. Carbon fiber (CF) is highly regarded for its light weight. In this study, we developed a simple and innovative sol–gel strategy to fabricate CF@Ni/NiO composites. The results demonstrate that the incorporation of Ni/NiO particles into CF materials substantially enhances the ferromagnetic properties of CF@Ni/NiO composites. An optimum reflection loss (RL) of CF@Ni/NiO-3 is −55.58 dB at 15.4 GHz with a corresponding thickness of merely 1.7 mm. An effective absorption bandwidth (EAB) reaches a maximum of 6.0 GHz at a thickness of 1.8 mm. Meanwhile, the radar cross section (RCS) reduction value at 6 GHz reaches 29.92 dB m2. The uniform distribution of Ni/NiO nanoparticles not only establishes a magnetic coupling network but also creates abundant heterogeneous interfaces with CF, thereby enhancing interfacial polarization. The successful fabrication of CF@Ni/NiO composites will facilitate the development and broad application of advanced electromagnetic wave (EMW) absorption materials in the aviation and aerospace sectors.

Non-disjoint strong external difference families can have any number of sets

AbstractStrong external difference families (SEDFs) are much-studied combinatorial objects motivated by an information security application. A well-known conjecture states that only one abelian SEDF with more than 2 sets exists. We show that if the disjointness condition is replaced by non-disjointness, then abelian SEDFs can be constructed with more than 2 sets (indeed any number of sets). We demonstrate that the non-disjoint analogue has striking differences to, and connections with, the classical SEDF and arises naturally via another coding application.

Experimental estimation of sample entropy in a semiconductor laser with optical feedback for random number generation

Estimating the entropy rate of physical random number generators with uncertainty is crucial for information security applications. We evaluate the sample entropy of chaotic temporal waveforms generated experimentally by a semiconductor laser with time-delayed optical feedback. We demonstrate random number generation with uncertainty using a quantitative measurement of the entropy rate.

A new chaotic system and its practical applications in substitution box and random number generator

AbstractOne of the successful practical applications of chaos theory and nonlinear dynamics is chaos-based cryptology studies. In this study, a new chaotic system is proposed. The proposed chaotic system generator model has a simple algorithmic structure. In addition to, generated chaotic systems have rich dynamics. It has been examined whether this system has potential advantages, especially for information security applications. As a result of the analysis and experimental studies, it is seen that the study makes many contributions to the literature. The simple mathematical generator structure has the potential to reduce computational complexity, which is an important problem for cryptology applications. One of the most comprehensive studies has been realized for chaos-based substitution box designs. 70,000 different substitution box structures have been generated. It has been known that the highest nonlinearity value that can be achieved for designs that transform chaotic system outputs into substitution box structures is 106.75 today. It has been shown that this value may be higher. The new highest nonlinearity value is calculated as 107. Side channel analysis has been examined for substitution box structures with the highest nonlinearity value among the substitution boxes generated in the study. Analysis results show that the proposed new substitution box structures may have an advantage for application-oriented attacks. Among the generated substitution box structures, 289 substitution box structures with a nonlinearity value of 106 and above are presented as a public dataset for researchers to use. In addition, 3 different random sequences with a length of 1 million-bit were produced with the proposed map, and the NIST SP 800–22 test was applied. Test results for all datasets were successful. In this way, the proposed map can also be used as a random number generator.

Applied Machine Learning for Information Security

Information security has undoubtedly become a critical aspect of modern cybersecurity practices. Over the past half-decade, numerous academic and industry groups have sought to develop machine learning, deep learning, and other areas of artificial intelligence-enabled analytics into information security practices. The Conference on Applied Machine Learning (CAMLIS) is an emerging venue that seeks to gather researchers and practitioners to discuss applied and fundamental research on machine learning for information security applications. In 2021, CAMLIS partnered with ACM Digital Threats: Research and Practice (DTRAP) to provide opportunities for authors of accepted CAMLIS papers to submit their research for consideration into ACM DTRAP via a Special Issue on Applied Machine Learning for Information Security. This editorial summarizes the results of this Special Issue.

Continuous-Wave Pumped Monolayer WS2 Lasing for Photonic Barcoding.

Micro/nano photonic barcoding has emerged as a promising technology for information security and anti-counterfeiting applications owing to its high security and robust tamper resistance. However, the practical application of conventional micro/nano photonic barcodes is constrained by limitations in encoding capacity and identification verification (e.g., broad emission bandwidth and the expense of pulsed lasers). Herein, we propose high-capacity photonic barcode labels by leveraging continuous-wave (CW) pumped monolayer tungsten disulfide (WS2) lasing. Large-area, high-quality monolayer WS2 films were grown via a vapor deposition method and coupled with external cavities to construct optically pumped microlasers, thus achieving an excellent CW-pumped lasing with a narrow linewidth (~0.39 nm) and a low threshold (~400 W cm-2) at room temperature. Each pixel within the photonic barcode labels consists of closely packed WS2 microlasers of varying sizes, demonstrating high-density and nonuniform multiple-mode lasing signals that facilitate barcode encoding. Notably, CW operation and narrow-linewidth lasing emission could significantly simplify detection. As proof of concept, a 20-pixel label exhibits a high encoding capacity (2.35 × 10108). This work may promote the advancement of two-dimensional materials micro/nanolasers and offer a promising platform for information encoding and security applications.

Nucleic-acid-base photofunctional cocrystal for information security and antimicrobial applications

Cocrystal engineering is an efficient and simple strategy to construct functional materials, especially for the exploitation of novel and multifunctional materials. Herein, we report two kinds of nucleic-acid-base cocrystal systems that imitate the strong hydrogen bond interactions constructed in the form of complementary base pairing. The two cocrystals studied exhibit different colors of phosphorescence from their monomeric counterparts and show the feature of rare high-temperature phosphorescence. Mechanistic studies reveal that the strong hydrogen bond network stabilizes the triplet state and suppresses non-radiative transitions, resulting in phosphorescence even at 425 K. Moreover, the isolation effects of the hydrogen bond network regulate the interactions between the phosphor groups, realizing the manipulation from aggregation to single-molecule phosphorescence. Benefiting from the long-lived triplet state with a high quantum yield, the generation of reactive oxygen species by energy transfer is also available to utilize for some applications such as in photodynamic therapy and broad-spectrum microbicidal effects. In vitro experiments show that the cocrystals efficiently kill bacteria on a tooth surface and significantly help prevent dental caries. This work not only provides deep insight into the relationship of the structure-properties of cocrystal systems, but also facilitates the design of multifunctional cocrystal materials and enriches their potential applications.

Grayscale stereolithography 3D printing of shape memory polymers for dual information encryption based on reconfigurable geometry and tunable optics

Dual information encryption such as geometry and transparency switching is highly desirable for preventing the leakage of confidential information and constructing a secure environment which has wide range of applications in privacy protection, anti-counterfeiting, and information security. However, it is still a challenge to develop a novel encrypted strategy and smart material to achieve credible protective capacity for stored information by a facile and programmed manner. Herein, integrating with arbitrary grayscale stereolithography, the hydrophilic ultraviolet (UV) curable shape memory polymers (HU-SMPs) with superior mechanical properties (the tensile strength of 29.39 MPa, elongation of 46.32 %, and the toughness of 1021.98 kJ.m−3) were prepared, which can be used for multifunctional information encryption. During the encrypted process, the HU-SMPs with the performances of high deformable and excellent shape memory behaviors can provide the preprogrammed morphological information and inevitable encryption, while the humidity-responsive of HU-SMPs capable of generating revisable transparency switching that can be encoded as the secondary information encryption. In this way, the dual encrypted information in the HU-SMPs is readable only after sequential shape recovery and fast hydration under heat-stimuli and humidity-stimuli. In addition, with the aid of digitally grayscale drawing, the secondary encrypted information is cyclically displayed and erasable due to the reversible hydration and dehydration process of HU-SMPs. Finally, the encrypted information is also can be permanently storage or decryption by the versatile post-processing methods of UV irradiation after and before decryption, respectively. In short, the design of HU-SMPs that compatible with grayscale digital light process (g-DLP)-based 3D printing, will motivates the future development of smart materials and provides a new insight into the information encrypt fields.

Intelligent management process analysis and security performance evaluation of sports equipment based on information security

This paper discusses the application and analysis of information security in the intelligent management of sports equipment. With the rapid development of information security, the intelligent management of sports equipment has become more and more convenient, fast and safe. Through the information security situation assessment algorithm and Petri net model of natural language processing, the intelligent management of sports body is realized, personalized service and recommendation are provided, user participation and interaction are enhanced, marketing strategies are optimized, and user experience and user loyalty are enhanced. In the design of sports equipment management, SVM model, attack and defense tree model and SVM-Bayesian model are used in the classification of sports equipment. In the experimental comparison of the three models, it is found that the number of attack and defense SVM-Bayesian alarms is 11, the false alarm rate is 0.55%, the number of missed alarms is 57, the false alarm rate is 2.85%, and the accuracy rate is 96.6%. SVM-Bayesia has obvious advantages in attack success rate and risk defense probability. By constantly comparing the path data and the number of nodes, the algorithm in this paper also has a good application effect.

Broadband Generation of Fractional Perfect Optical Vortices via Plasmonic Metasurface

AbstractA fractional perfect optical vortex (FPOV) represents a class of structured light characterized by phase singularities carrying fractional orbital angular momentum (OAM). It manifests a notched annular intensity distribution, and notably, the size of this distribution remains independent of the topological charge. Conventional methods for generating FPOVs involve a series of cascaded bulk components, leading to optical aberrations due to alignment errors and impeding their integration into highly integrated devices. In this work, an experimental demonstration is presented of the broadband generation of FPOVs in the visible spectrum utilizing a monolithic plasmonic metasurface with phase‐only modulation. The metasurface allows for flexible control of various parameters of the FPOVs, including their topological charge, beam radius, ellipticity factor, orientation, and the number of opening gaps. Furthermore, as a proof‐of‐concept, an FPOV pair is utilized to encode a double‐digit hexadecimal number, showcasing the potential of a metasurface array for optical information encryption. This research establishes a highly integrated platform for FPOV generation, with implications for advancing their applications in optical information security.

Photocleavable DNA Nanotube-Based Dual-Amplified Resonance Rayleigh Scattering System for MicroRNA Detection Incorporating Molecular Computing-Cascaded Keypad Lock Functionality.

Cascade molecular events in complex systems are of vital importance for enhancing molecular diagnosis and information processing. However, the conversion of a cascaded biosensing system into a multilayer encrypted molecular keypad lock remains a significant challenge in the development of molecular logic devices. In this study, we present a photocleavable DNA nanotube-based dual-amplified resonance Rayleigh scattering (RRS) system for detecting microRNA-126 (miR-126). The cascading dual-amplification biosensing system provides a multilayer-encrypted prototype with the functionality of a molecular computing cascade keypad lock. RRS signals were greatly amplified by using photocleavable DNA nanotubes and enzyme-assisted strand displacement amplification (SDA). In the presence of miR-126, enzyme-assisted SDA produced numerous identical nucleotide fragments as the target, which were then specifically attached to magnetic beads through the DNA nanotube by using a Y-shaped DNA scaffold. Upon ultraviolet irradiation, the DNA nanotube was released into the solution, resulting in an increase in the intensity of the RRS signal. This strategy demonstrated a low limit of detection (0.16 fM) and a wide dynamic range (1 fM to 1 nM) for miR-126. Impressively, the enzyme-assisted SDA offers a molecular computing model for generating the target pool, which serves as the input element for unlocking the system. By cascading the molecular computing process, we successfully constructed a molecular keypad lock with a multilevel authentication technique. The proposed system holds great potential for applications in molecular diagnosis and information security, indicating significant value in integrating molecular circuits for intelligent sensing.

Irreversible Ca2B2O5‐Based Multicolor Mechanoluminescence for Security Labels

AbstractAs the Internet of Things (IoT) continues its pervasive influence and digital technologies increasingly weave into the fabric of daily lives, the imperative for robust security measures becomes paramount to mitigate the escalating risks to the digital landscape. Traditional anti‐counterfeiting technologies, while capable to some extent, are constrained by factors such as material toxicity, low‐security efficacy, and intricate fabrication process. Mechanoluminescent materials have shown great potential in the areas of anti‐counterfeiting and security. Here, a multicolor mechanoluminescent (ML) material (lanthanide doped Ca2B2O5) synthesized by solid‐phase reaction is reported for the first time at a relatively lower temperature of 750 °C. The ML devices are obtained by embedding ML materials into polydimethylsiloxane elastomer, allowing for stress visualization with colors ranging from blue and green to orange and red. Through elaborate co‐doping, successive and accurate stress visualizations are realized. Finally, security labels based on the lanthanide ions doped Ca2B2O5 are prepared and also demonstrated to safeguard valuable packages. This work provides a novel multicolor ML material and pioneers its use in security labels, offering a universal solution for multicolor display, information security, dynamic anti‐counterfeiting, and other potential applications within the realm of IoT.

New constructions for disjoint partial difference families and external partial difference families

AbstractRecently, new combinatorial structures called disjoint partial difference families (DPDFs) and external partial difference families (EPDFs) were introduced, which simultaneously generalize partial difference sets, disjoint difference families and external difference families, and have applications in information security. So far, all known construction methods have used cyclotomy in finite fields. We present the first noncyclotomic infinite families of DPDFs which are also EPDFs, in structures other than finite fields (in particular cyclic groups and nonabelian groups). As well as direct constructions, we present an approach to constructing DPDFs/EPDFs using relative difference sets (RDSs); as part of this, we demonstrate how the well‐known RDS result of Bose extends to a very natural construction for DPDFs and EPDFs.

Dual-Stimuli-Responsive Modulation Organic Afterglow Based on N─H Proton Migration Mechanism.

Organic afterglow materials have significant applications in information security and flexible electronic devices with unique optical properties. It is vital but challenging to develop organic afterglow materials possessing controlled output with multi-stimuli-responsive capacity. Herein, dimethyl terephthalate (DTT) is introduced as a strong proton acceptor. The migration direction of N─H protons on two compounds Hs can be regulated by altering the excitation wavelength (Ex) or amine stimulation, thereby achieving dual-stimuli-responsive afterglow emission. When the Ex is below 300nm, protons migrate to S1-2 DTT , where strong interactions induce phosphorescent emission of Hs, resulting in afterglow behavior. Conversely, when the Ex is above 300nm, protons interact with the S0 DTT weakly and the afterglow disappears. In view of amine-based compounds with higher proton accepting capabilities, it can snatch proton from S1-2 DTT and redirect the proton flow toward amine, effectively suppressing the afterglow but obtaining a new redshifted fluorescence emission with Δλ over 200nm due to the high polarity of amine. Moreover, it is successfully demonstrated that the applications of dual-stimuli-responsive organic afterglow materials in information encryption based on the systematic excitation-wavelength-dependent (Ex-De) behavior and amine selectivity detection.

Effect of Film Density on MgSiO3-Based Resistive Random-Access Memory

Different film density MgSiO3 based resistive random-access memorys (RRAMs) are fabricated to investigate the resistive switching behaviors. The X-ray diffraction results, set voltage, reset voltage, cycling endurance, and retention time are drawn for comparison. With the increasing oxygen ratio gas flow, the resistive switching characteristics of MgSiO3 RRAM are drastically elevated by changing the fabrication conditions of the RS layer. Moreover, we portray a filament model to explain the most likely mechanism associated with the generation and rupture of conductive filaments composed of oxygen vacancies. The high randomness among switching cycles for memory application should be prevented, but it is suitable for the physical unclonable function. The relationship between HRS and the next time set voltage shows a strong correlation, and the conduction mechanisms of the low-resistance state (LRS) and HRS correspond to ohmic conduction and space charge-limited conduction, respectively. Meanwhile, the RRAM undergoes 10,000 s retention tests, and the two resistance states can be distinguished without obvious alternation or degradation. A favorable cycling endurance and retention time achieved by optimizing the fabrication parameters of Cu/MgSiO3/Pt RRAM have the potential for nonvolatile memristors and information security applications.

Modification of Intertwining Logistic Map and a Novel Pseudo Random Number Generator

Chaotic maps have been widely studied in the field of cryptography for their complex dynamics. However, chaos-based cryptosystems have not been widely used in practice. One important reason is that the following requirements of practical engineering applications are not taken into account: computational complexity and difficulty of hardware implementation. In this paper, based on the demand for information security applications, we modify the local structure of the three-dimensional Intertwining Logistic chaotic map to improve the efficiency of software calculation and reduce the cost of hardware implementation while maintaining the complex dynamic behavior of the original map. To achieve the goal by reducing the number of floating point operations, we design a mechanism that can be decomposed into two processes. One process is that the input parameters value of the original system is fixed to 2k by Scale index analysis. The other process is that the transcendental function of the original system is replaced by a nonlinear polynomial. We named the new map as “Simple intertwining logistic”. The basic chaotic dynamic behavior of the new system for controlling parameter is qualitatively analyzed by bifurcation diagram and Lyapunov exponent; the non-periodicity of the sequence generated by the new system is quantitatively evaluated by using Scale index technique based on continuous wavelet change. Fuzzy entropy (FuzzyEn) is used to evaluate the randomness of the new system in different finite precision digital systems. The analysis and evaluation results show that the optimized map could achieve the designed target. Then, a novel scheme for generating pseudo-random numbers is proposed based on new map. To ensure its usability in cryptographic applications, a series of analysis are carried out. They mainly include key space analysis, recurrence plots analysis, correlation analysis, information entropy, statistical complexity measure, and performance speed. The statistical properties of the proposed pseudo random number generator (PRNG) are tested with NIST SP800-22 and DIEHARD. The obtained results of analyzing and statistical software testing shows that, the proposed PRNG passed all these tests and have good randomness. In particular, the speed of generating random numbers is extremely rapid compared with existing chaotic PRNGs. Compared to the original chaotic map (using the same scheme of random number generation), the speed is increased by 1.5 times. Thus, the proposed PRNG can be used in the information security.

Smart-Responsive HOF Heterostructures with Multiple Spatial-Resolved Emission Modes toward Photonic Security Platform.

Luminescent hydrogen-bonded organic frameworks (HOFs) with the unique dynamics and versatile functional sites hold great potential application in information security, yet most of responsive HOFs focus on the single-component framework with restrained emission control, limiting further applications in advanced confidential information protection. Herein, the first smart-responsive HOF heterostructure with multiple spatial-resolved emission modes for covert photonic security platform is reported. The HOF heterostructures are prepared by integrating different HOFs into a single microwire based on a hydrogen-bond-assisted epitaxial growth method. The distinct responsive behaviors of HOFs permit the heterostructure to simultaneously display the thermochromism via the framework transformation and the acidichromism via the protonation effect, thus generating multiple emission modes. The dual stimuli-controlled spatial-resolved emission modes constitute the fingerprint of a heterostructure, and enable the establishment of the smart-responsive photonic barcode with multiple convert states, which further demonstrate the dynamic coding capability and enhanced security in anticounterfeiting label applications. These results offer a promising route to design function-oriented smart responsive HOF microdevices toward advanced anticounterfeiting applications.