In the last decade, unmanned aerial vehicles (UAVs) for plant protection have rapidly developed worldwide as a new method for pesticide application, especially in China and other Asian countries. To improve the deposition quality in UAV applications, adding appropriate types of spray adjuvants into pesticide solutions is one of the most effective ways to facilitate droplet deposition and control efficacy. At present, research on spray adjuvants for UAVs are mainly based on droplet drift and laboratory tests. Few studies have been conducted on the physicochemical properties of spray adjuvants and the effects of droplet deposition characteristics. To explore the properties of four different kinds of spray adjuvants (Mai Fei, Bei Datong, G-2801, and Agrospred 910) and the deposition characteristics of spray adjuvants on litchi leaves, an automatic surface tension meter, a contact angle measuring device, an ultraviolet visible spectrophotometer, and a DJI AGRAS T30 plant protection UAV was used to measure the surface tension, contact angle, and droplet deposition characteristics on litchi under UAV spraying operations. The results showed that the addition of spray adjuvants could significantly reduce the surface tension of the solution. The surface tension value of the solution after adding the spray additives was reduced by 53.1–68.9% compared with the control solution. Among them, the Agrospred 910 spray adjuvant had the best effect on reducing the surface tension of the solution. The contact angle of the control solution on the litchi leaves varied from 80.15° to 72.76°. With the increase in time, the contact angle of the spray adjuvant solution gradually decreased, the Agrospred 910 spray adjuvant had the best effect, and the contact angle decreased from 40.44° to 20.23° after the droplets fell on the litchi leaves for 60 s. The adjuvant solutions increased the droplet size, but the uniformity of the droplet size decreased. The Dv0.5 of different spray solutions ranged from 97.3 to 117.8 μm, which belonged to the fine or very fine droplets, and the Dv0.5 of adjuvants solutions were significantly greater than that of the control solution. The RSs of adjuvant solutions were very similar and ranged from 0.92 to 0.96, all of which were significantly greater than the result of the control solution (0.57). Compared with the deposition of the control solution, the Mai Fei, Bei Datong, and G-2801 solutions clearly increased spray deposition, with total depositions of 0.776, 0.705, and 0.721 μL/cm2, which are all greater than the total deposition of the control solution of 0.645 μL/cm2. The addition of tank-mixed adjuvants could effectively increase the uniformity of the spray deposition, and all the average CVs of adjuvant solutions were lower than 96.86%. On the whole, Mai Fei performed best in increasing the spray deposition and promoting penetration, followed by Bei Datong and G-2801. Meanwhile, the test can also provide a reference for improving the utilization rate of UAV pesticide applications.
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