Apparent Flux Research Articles

Fundamental effective temperature measurements for eclipsing binary stars – V. The circumbinary planet system EBLM J0608–59

ABSTRACT EBLM J0608$-$59/TOI-1338/BEBOP-1 is a 12$^{\rm th}$-magnitude, F9 V star in an eclipsing binary with a much fainter M dwarf companion on a wide, eccentric orbit (P = 14.6 d). The binary is orbited by two circumbinary planets: one transiting on a 95-d orbit and one non-transiting on a 215-d orbit. We have used high-precision photometry from the TESS mission combined with direct mass measurements for the two stars published recently to measure the following model-independent radii: $R_1 = 1.32 \pm 0.02 {\rm R}_{\odot }$, $R_2 = 0.309 \pm 0.004 {\rm R}_{\odot }$. Using $R_1$ and the parallax from Gaia EDR3, we find that this star’s angular diameter is $\theta = 0.0309 \pm 0.0005$ mas. The apparent bolometric flux of the primary star corrected for both extinction and the contribution from the M dwarf ($\lt 0.4$ per cent) is ${\mathcal {F}}_{{\oplus },0} = (0.417\pm 0.005)\times 10^{-9}$ erg cm$^{-2}$ s$^{-1}$. Hence, this F9 V star has an effective temperature $T_{\rm eff,1} = 6031{\rm \, K} \pm 46{\rm \, K\, (rnd.)} \pm 10 {\rm \, K\, (sys.)}$. EBLM J0608$-$59 is an ideal benchmark star that can be added to the sample of such systems we are establishing for ‘end-to-end’ tests of the stellar parameters measured by large-scale spectroscopic surveys.

Integrating diffusion dialysis for sustainable acid recovery from ion exchange regeneration stages: Characterization of metal and non-metal ions migration

Seawater mining presents a potential option for recovering the European Union’s Critical Raw Materials (CRMs), but direct extraction from seawater is challenging due to their low concentrations, as most of them are Trace Elements (TEs) (at levels of mg/L or µg/L). Saltworks bitterns (ultraconcentrated brines resulting from the sea salt production process) offer an alternative solution, naturally concentrated up to 40 times more than seawater. These bitterns can be further processed with chelating Ion Exchange (IX) sorbents to selectively extract TEs. However, this process requires an acidic elution stage with strong acids, followed by neutralization, to recover TEs through precipitation, demanding extensive chemicals consumption. Diffusion Dialysis (DD) could be used to recover the excess acid without external reagents, using an acid-resistant Anion Exchange Membrane (AEM). This study evaluates DD through batch and once-through tests for acid recovery from simulated IX eluate generated in the elution stage of TEs (B, Ga, Ge, Co, Sr) recovery from saltworks bitterns.Batch tests achieved high recoveries for HCl (45–50 %) and H2SO4 (30–37 %), being the theoretical maximum attainable recovery equal to 50 %. B and Ge only partially permeated through the membrane (82 % rejection) by a diffusion mechanism in their neutral form (H3BO3(aq), H4GeO4(aq)). Ga, Co and Sr, in cationic form, were highly rejected (>96 %). Permeability followed the order Ga < Sr < Co ≪ Ge < B, due to the relevant charge and size. HCl permeability correlated linearly with concentration, while H2SO4 was inversely proportional. Once-through tests showed higher acid (74 % HCl, 62 % H2SO4) and oxoacid (66 % H3BO3(aq), 52 % H4GeO4(aq)) recovery at a low specific flow rate, or apparent flux, (0.38 L/(m2membrane·h)) due to increased residence time. Water to acid flow rate ratios did not affect species transport when an excess of water was guaranteed. Conversely, an influence was observed when the ratio was below 1, with a minimum at 0.18, where a very low passage of species was observed due to the reduced dilution volume of the dialysate solution (water). A 1D transport model, incorporating the solutes permeabilities determined experimentally, effectively described the system performance, especially for HCl and B, albeit slightly overestimating the other TEs’ transport.

Seasonal hypoxia enhances sediment iron-bound phosphorus release in a subtropical river reservoir

Dams worldwide commonly accelerate the eutrophication of reservoirs. While the seasonal hypoxia in deep reservoirs is widely acknowledged, there is limited research on its impact on benthic phosphorus (P) cycling and P fraction release from the reservoir sediments. Here we show that seasonal hypoxia enhances sediment P release and P fluxes at the sediment-water interface (SWI) which might alter P dynamics in deep reservoirs. We conducted a detailed measurement of sediment P fractions through the SEDEX approach, combined with a labile P gradient analysis using the diffusive gradients in thin films (DGT) technique to understand P cycling patterns in sediments during the transition period from spring (oxic) to late summer (hypoxic) conditions. The sediment P pool was predominantly composed of iron-bound phosphorus (Fe−P, 76–80 %), primarily due to the widespread occurrence of lateritic red soil (rich in Fe2O3/MnO2) in subtropical areas. More organic-P was observed in summer compared to spring. A significant increase in labile P occurred at the depth of 0–4 cm and 0–1 cm in spring and summer, respectively, where sediment P release was primarily governed by the reduction of Fe−P and the generation of S2−. A higher apparent fluxes of phosphate across the SWI were observed in summer characterized by higher temperature and lower oxygen levels. The current results suggest that seasonal hypoxia was a crucial factor affecting P cycling and diffusion in deep reservoirs. These findings present important implications for the ecology and management of the watershed-coast ecosystem.

Process intensification of the electrodialysis metathesis for calcium bromide preparation: Effects of key influencing factors and phenomena of water migration

Calcium bromide, a high-value bromine resource, is widely used in the industrial synthesis processes and mercury removal from flue gas. However, there are some problems in traditional preparation methods for calcium bromide, such as long processing time, environmentally unfriendly and so on. To address these challenges, an electrodialysis metathesis (EDM) process was developed in this study to prepare high value-added calcium bromide using sodium bromide and calcium chloride as the raw materials. In order to obtain calcium bromide with high purity and improve the economic efficiency of the EDM process, the key influencing factors were investigated. Furthermore, the water migration during EDM was analyzed, and potential prospects of reducing apparent water flux volume by lowering temperature, current density, and the concentration difference between the dilute chamber and the concentrated chamber within an appropriate range. As a result, a calcium bromide product with a purity higher than 99 % was obtained with no Cl− detected. Mass fraction of Na+ was found to be 0.016 %, meeting the standards required by the industry. This method provides a new perspective and a good guide for the efficient preparation of highly valued bromine resources.

Direct Numerical Simulation of single bubble dynamics in nucleate pool boiling with micro-region modeling and thermal coupling to a solid wall

In this study, we conduct two-dimensional, axisymmetric simulations to investigate the growth and departure of a single bubble, with a particular focus on the conjugate heat transfer between the fluid and the heating wall. A multiscale modeling approach is employed to account for nanoscale effects near the liquid-vapor-solid triple contact line (CL). At the macro (bubble size) scale, the interface dynamics is captured with the front-tracking method by using the open-source code TRUST/TrioCFD. The macro scale algorithm is coupled with a sub-grid micro-region model. It is driven by the wall superheating at the CL as input, and predicts the macroscopic apparent contact angle and heat fluxes. To validate our modeling approach, we first conduct quantitative comparisons using the data on the bubble growth experiment RUBI and its simulations. Next, an investigation of the case of water under atmospheric pressure and gravity is performed. Notably, we observe a significant spatial variation in temperature near the nucleation site during the expansion and contraction of the bubble base. This variation greatly affects the thermal boundary layers in the fluid and solid domains and the bubble growth, demonstrating the need to resolve the conjugate heat transfer in the considered cases.

Upper limits of 44Ti decay emission in four nearby thermonuclear supernova remnants

ABSTRACT To identify progenitors and investigate evidence of He burning, we searched for decay radiation of freshly synthesized 44Ti in four young nearby thermonuclear supernova remnants: Kepler, SN 1885, G1.9+0.3, and SN 1006, by analysing the up-to-date NuSTAR archival data. No apparent flux excess from the 68 and 78 keV line emissions accompanying decay was detected above the power-law continuum applied for the remnants and the absorbed stray light. By comparing the inferred upper limits of the line flux and the initial 44Ti masses with a wide variety of supernova nucleosynthesis models, we placed constraints on the supernova progenitors. We derived the first NuSTAR line flux upper limit for Kepler and ruled out most of the double-detonation scenarios with a thick He layer under low density. We estimated, for the first time, the upper limit for SN 1885, which is high because of the large distance, yet still remains consistent with the He shell detonation. The new flux and mass limit of G1.9+0.3 derived from a longer total exposure is lower than the results from previous studies and evidently excludes explosive burning of He-rich matter. The relatively advanced age and the large spatial extent of SN 1006 have prevented meaningful constraints.

Exogenous methyl jasmonate regulates endogenous hormone synthesis of soilless cultivated Chinese chive to promote growth physiology and photosynthesis

Methyl jasmonate (MeJA) is involved in regulating various growth and development processes of plants, yet the underlying mechanisms remain unclear. Therefore, the objective of this study was to investigate the effects of exogenous MeJA on physiological growth, photosynthesis, and endogenous hormones in soilless cultivated Chinese chives. Four concentrations of MeJA (0, 300, 500, and 800 μM) were applied to the leaves of substrate-grown and hydroponics Chinese chives. The results showed that MeJA increased the leaf tissues water content and SPAD values of hydroponically Chinese chives, and 500 μM MeJA significantly enhanced the root activity and leaf carotenoids content of soilless cultivated Chinese chive, and promoted the activities of key enzymes of chlorophyll synthesis (ChlM and POR), thereby increasing chlorophyll a, chlorophyll b and total chlorophyll contents. Meanwhile, MeJA (500 μM) enhanced the activity of key enzymes in the Calvin cycle (Rubisco, FBA, FBPase, GAPDH, and TK), promoted CO2 fixation, improved photosynthetic carbon assimilation efficiency, and promoted Gs, Tr, and Pn, thereby enhancing photosynthesis. Moreover, MeJA (500 μM) significantly enhanced the instantaneous distribution (I-P) of the OJIP curve, enhanced the ability of the plastoquinone pool (PQ) to accept electrons, increased the quantum yield, promoted the apparent quantum flux per unit leaf area and energy flux ratio per unit PSII active reaction center, improved the electron transfer efficiency while reducing the heat dissipation energy flux per unit PSII active reaction center, and thus enhanced PSII activity. Additionally, exogenous MeJA (500 μM) promoted the accumulation of endogenous ZT, GA3, IAA, and ABA, but inhibited the upstream substrates for OPDA synthesis (MGDG and DGDG) in the JA synthesis pathway, and decreased the activities of JA synthases (LOX, AOC, and OPR), which in turn inhibited the synthesis of JA and MeJA. Changes in the relative content of MGDG/DGDG altered the membrane lipid composition of the photosynthetic membrane, which in turn altered the energy balance of the light reaction and improved the efficiency of electron transfer within the photosynthetic membrane, thereby enhancing the photosynthetic capacity. In conclusion, our study demonstrates that exogenous MeJA improves root activity and chlorophyll accumulation in soilless cultured Chinese chives, and adjusting the composition of photosynthetic membrane lipids by regulating the levels of endogenous hormones and JA-synthesizing substrates, promoting the efficiency of electron transfer, enhancing PSII activity, and promoting photosynthetic carbon fixation, thereby enhancing photosynthesis and promoting growth.

Dasatinib loaded mucoadhesive lecithin-chitosan hybrid nanoparticles for its augmented oral delivery, in-vitro efficacy and safety

Dasatinib (DAS) is an oral tyrosine kinase inhibitor; however, its efficacy is significantly subsided by its low oral bioavailability. The present research aimed to improve DAS’s oral delivery and efficacy in triple-negative breast cancer by fabricating its mucoadhesive lecithin-chitosan hybrid nanoparticles (DAS-L/CS-NPs). DAS-L/CS-NPs were optimized using Box-Behnken design which showed mean particle size and percent entrapment efficiency of 179.7 ± 5.42 nm and 64.65 ± 0.06 %, respectively. DAS-L/CS-NPs demonstrated sustained release profile in different release media up to 48 h and showed 10 times higher apparent permeability coefficient and flux than free DAS suspension. The binding of DAS-L/CS-NPs to the mucus layer was demonstrated via ex-vivo mucoadhesion study and change in absorbance using turbidimetry. In cell culture studies, DAS-L/CS-NPs revealed a 4.14-fold decrease in IC50, significantly higher cellular uptake and mitochondrial membrane depolarization, 3.82-fold increased reactive oxygen species generation and 2.10-fold enhanced apoptosis in MDA-MB-231 cells than free DAS. In in-vivo pharmacokinetic assessment, DAS-L/CS-NPs showed a 5.08-fold and 3.74-fold rise in AUC (0-t) and Cmax than free DAS suspension, respectively. An acute toxicity study revealed a good safety profile of DAS-L/CS-NPs. In a nutshell, proposed hybrid nanoparticles are promising carriers for improved oral delivery of poorly water-soluble drugs.

An Algorithm to Mitigate Charge Migration Effects in Data from the Near Infrared Imager and Slitless Spectrograph on the James Webb Space Telescope* *This work is based on observations made with the NASA/ESA/CSA James Webb Space Telescope. The data were obtained from the Mikulski Archive for Space Telescopes at the Space Telescope Science Institute, which is operated by the Association

We present an algorithm that mitigates the effects of charge migration due to the “brighter-fatter effect” (BFE) that occurs for highly illuminated stars in the Teledyne HAWAII-2RG detectors used in the NIRCam, NIRISS, and NIRSpec science instruments aboard the James Webb Space Telescope (JWST). The impact of this effect is most significant for photometry and spectrophotometry of bright stars in data for which the point-spread function (PSF) is undersampled, which is the case for several observing modes of the NIRISS instrument. The main impact of BFE to NIRISS data is incorrect count rate determinations for pixels in the central regions of PSFs of bright stars due to jump detections that are caused by charge migration from peak pixels to surrounding pixels. The effect is especially significant for bright compact sources in resampled, distortion-free images produced by the drizzle algorithm: quantitatively, apparent flux losses of >50% can occur in such images due to BFE. We describe the algorithm of the “charge_migration” mitigation step that has been implemented in version 10.0 of the operational JWST calibration pipeline as of 2023 December 5. We illustrate the impact of this step in terms of the resulting improvements of the precision of imaging photometry of point sources. The algorithm renders the effects of BFE on photometry and surface brightness measurements to stay within 1%.

Energy Spectra of Nonlocal Internal Gravity Wave Turbulence.

Starting from the classical formulation of the weak turbulence theory in a density stratified fluid, we derive a simplified version of the kinetic equation of internal gravity wave turbulence. This equation allows us to uncover scaling laws for the spatial and temporal energy spectra of internal wave turbulence which are consistent with typical scaling exponents observed in the oceans. The keystone of our description is the assumption that the energy transfers are dominated by a class of nonlocal resonant interactions, known as the "induced diffusion" triads, which conserve the ratio between the wave frequency and vertical wave number. Our analysis remarkably shows that the internal wave turbulence cascade is associated to an apparent constant flux of wave action.

Rumen fermentation of meal-fed sheep in response to diets formulated to vary in fiber and protein degradability.

The concentration of volatile fatty acid (VFA) provides an imprecise view of VFA dynamics due to the confounding effects of fluid pool size and dynamics. Determination of VFA flux using isotope is expensive and a complex methodology. Therefore, a rapid and affordable approach to explore VFA dynamics may allow comprehensive characterization of VFA availability. The objective of this study was to explore the use of VFA dynamics generated by meal feeding to derive time-series rates of VFA apparent appearance and disappearance driven by different protein and fiber sources. Six ruminally cannulated wethers were fed diets containing timothy hay or beet pulp (TH and BP) and soybean meal (SBM) or heated soybean meal (HSBM). Diets were, TH + HSBM; TH + SBM; BP + HSBM; and BP + SBM and the experimental design was a partially replicated 4 × 4 Latin Square. Concentrations of VFA and polyethylene glycol (PEG) in rumen fluid samples were estimated. Concentrations of PEG were used to estimate fluid passage and volume to calculate VFA mass, and fluid-mediated exit. Maximum apparent appearance rate (mmol/h), the rate of apparent appearance decline (mmol/mmol/h), mean apparent appearance flux (mmol/h), mean apparent disappearance (mmol/h), and apparent disappearance rate (mmol/mmol/h) were estimated by deriving a 1 pool model for each VFA on a mass basis where appearance was assumed to follow an exponential decay pattern and disappearance followed mass-action kinetics. Statistical analyses were conducted using a linear mixed effect regression with fixed effects for fiber source, protein source, and their interaction, as well as random effects for animal and period. Rumen fluid volume (L) was greater in HSBM diets (P = 0.033) and fluid passage (%/h) was greater in SBM diets (P = 0.048). Concentrations (higher acetate and butyrate, P = 0.002 and 0.004, respectively) and molar proportions (higher valerate, P = 0.035) of VFA were affected only by fiber source; however, protein source and fiber source interacted to significantly influence apparent appearance rates and absorption rates of many major VFA. On a flux basis, HSBM supported significantly elevated mean disappearance of propionate (P = 0.033). This data demonstrates that time-series evaluation of fermentation dynamics, including fluid dynamics and VFA concentrations can be used to estimate apparent appearance and disappearance of VFA. Although further work is needed to confirm the alignment of these estimates with measurements of VFA supplies to the animal, this modeling approach may provide a simpler way to better understand the kinetics of rumen.

Temporal variability of explosive activity at Tajogaite volcano, Cumbre Vieja (Canary Islands), 2021 eruption from ground-based infrared photography and videography

The 2021 eruption at Tajogaite (Cumbre Vieja) volcano (La Palma, Spain) was characterized by Strombolian eruptions, Hawaiian fountaining, white gas-dominated and grey ash-rich plumes, and lava effusion from multiple vents. The variety of eruptive styles displayed simultaneously and throughout the eruption presents an opportunity to explore controls on explosivity and the relationship between explosive and effusive activity. Explosive eruption dynamics were recorded using ground-based thermal photography and videography. We show results from the analysis of short (&lt;5 min) near-daily thermal videos taken throughout the eruption from multiple ground-based locations and continuous time-lapse thermal photos over the period November 16 to November 26. We measure the apparent radius, velocity, and volume flux of the high-temperature gas-and-ash jet and lava fountaining behaviors to investigate the evolution of the explosive activity over multiple time scales (seconds-minutes, hours, and days-weeks). We find fluctuations in volume flux of explosive material that correlate with changes in volcanic tremor and hours-long increases in explosive flux that are immediately preceded by increases in lava effusion rate. Correlated behavior at multiple vents suggests dynamic magma ascent pathways connected in the shallow (tens to hundreds of meters) sub-surface. We interpret the changes in explosivity and the relative amounts of effusive and explosivity to be the result of changes in gas flux and the degree of gas coupling.

FEASIBILITY OF ZEBRAFISH LARVA MODEL AS A VIABLE SUBSTITUTE TO RAT NON-EVERTED SAC MODEL FOR PERMEATION EVALUATION OF BCS III DRUGS

The oral route is the most convenient route of drug administration. Many drugs exhibit poor oral bioavailability. BCS III drugs exhibit high solubility and present a massive challenge due to poor permeability. Different permeation enhancers viz., nonionic Cremophor® RH 40, Tween® 80 and Lutrol® F68, anionic docusate sodium with sodium cholate, and anionic polymer sodium carboxymethyl cellulose were evaluated using rat non-everted sac method and zebrafish larva model. Maximum permeation enhancement was seen with docusate sodium for both drugs. The permeation enhancement ratio for netilmicin sulphate was 4.07±0.657, while for deferoxamine mesylate it was 1.482±0.378. Cremophor® RH 40 enabled augmented flux of netilmicin sulphate, and Tween® 80 showed enhanced permeation of deferoxamine mesylate. An excellent correlation was observed between apparent permeability and flux with drug absorbed per zebrafish larva (µg) (R2 = 0.938) for netilmicin sulphate and for deferoxamine mesylate (R2 = 0.9397). An important outcome of the study is the demonstration of the feasibility of the zebrafish larvae model as a viable substitute to the non-everted sac method, which could also enable screening of potential permeation enhancers for the development of orally bioavailable formulations of BCS III.

Robust Zwitterionic Poly(imidazolium)-Coated PVDF Membrane for Oily Water Treatment with Antibacterial and Anti-Biofouling Performances

Membrane fouling remains a major challenge during oily wastewater purification, resulting in reduced water flux and separation efficiency. Zwitterionic polymers have been introduced to the PVDF membrane and shown their fouling resistance ability. However, most current zwitterions lack bactericidal effects and tend to be fouled by the attachment of bacteria and biofilm formation in long-term service. Herein, a synthetic zwitterionic poly(imidazolium), poly(ZIM-co-VTS), was introduced onto the PVDF membrane by co-assembly with polydopamine (PDA) and tetraethyl orthosilicate (TEOS) as a silica source. The in situ covalent bond can be formed between the catechol from PDA and silanol groups from both TEOS and imidazole-based polymers. Further, Fe3+ cross-linking contributes to the robust chemical stability of modified PVDF. The as-prepared coating exhibits superhydrophilicity and underwater superoleophobicity under harsh conditions (pH = 1 and 13), remaining high separation efficiency (>99%) toward various surfactant-stabilized oil-in-water emulsions without an apparent water flux (>1013 L m–2 h–1 bar–1) decline. More importantly, the cationic imidazolium in poly(ZIM-co-VTS) endues the excellent bacterial killing efficiency toward Staphylococcus aureus (4.5 log10 reduction) and Escherichia coli (4.7 log10 reduction). The zwitterionic poly(imidazolium)-modified PVDF exhibited long-term durability with anti-biofouling properties and was a promising candidate for practical oily wastewater remediation.

GaiaData Release 3

Context.The astrophysical characterisation of sources is among the major new data products in the thirdGaiaData Release (DR3). In particular, there are stellar parameters for 471 million sources estimated from low-resolution BP/RP spectra.Aims.We present the General Stellar Parameterizer from Photometry (GSP-Phot), which is part of the astrophysical parameters inference system (Apsis). GSP-Phot is designed to produce a homogeneous catalogue of parameters for hundreds of millions of single non-variable stars based on their astrometry, photometry, and low-resolution BP/RP spectra. These parameters are effective temperature, surface gravity, metallicity, absoluteMGmagnitude, radius, distance, and extinction for each star.Methods.GSP-Phot uses a Bayesian forward-modelling approach to simultaneously fit the BP/RP spectrum, parallax, and apparentGmagnitude. A major design feature of GSP-Phot is the use of the apparent flux levels of BP/RP spectra to derive, in combination with isochrone models, tight observational constraints on radii and distances. We carefully validate the uncertainty estimates by exploiting repeatGaiaobservations of the same source.Results.The data release includes GSP-Phot results for 471 million sources withG &lt; 19. Typical differences to literature values are 110 K forTeffand 0.2–0.25 for log g, but these depend strongly on data quality. In particular, GSP-Phot results are significantly better for stars with good parallax measurements (ϖ/σϖ &gt; 20), mostly within 2 kpc. Metallicity estimates exhibit substantial biases compared to literature values and are only useful at a qualitative level. However, we provide an empirical calibration of our metallicity estimates that largely removes these biases. ExtinctionsA0andABPshow typical differences from reference values of 0.07–0.09 mag. MCMC samples of the parameters are also available for 95% of the sources.Conclusions.GSP-Phot provides a homogeneous catalogue of stellar parameters, distances, and extinctions that can be used for various purposes, such as sample selections (OB stars, red giants, solar analogues etc.). In the context of asteroseismology or ground-based interferometry, where targets are usually bright and have good parallax measurements, GSP-Phot results should be particularly useful for combined analysis or target selection.

Fundamental effective temperature measurements for eclipsing binary stars – IV. Selection of new benchmark stars and first results for HD 22064

ABSTRACT I describe the selection and initial characterization of 20 eclipsing binary stars that are suitable for calibration and testing of stellar models and data analysis algorithms used by the PLATO mission and spectroscopic surveys. The binary stars selected are F-/G-type dwarf stars with M-type dwarf companions that contribute less than 2 per cent of the flux at optical wavelengths. The light curves typically show well-defined total eclipses with very little variability between the eclipses. I have used near-infrared spectra obtained by the APOGEE survey to measure the spectroscopic orbit for both stars in HD 22064. Combined with an analysis of the TESS light curve, I derive the following masses and radii: M1 = 1.35 ± 0.03M⊙, M2 = 0.58 ± 0.01M⊙, R1 = 1.554 ± 0.014R⊙, R2 = 0.595 ± 0.008R⊙. Using R1 and the parallax from Gaia EDR3, I find that the primary star’s angular diameter is θ = 0.1035 ± 0.0009 mas. The apparent bolometric flux of the primary star is ${\mathcal {F}}_{{\oplus },0} = (7.51\pm 0.09)\times 10^{-9}$ erg cm−2 s−1. Hence, this F2V star has an effective temperature $T_{\rm eff,1} = 6763{\rm \, K} \pm 39{\rm \, K}$. HD 22064 is an ideal benchmark star that can be used for ‘end-to-end’ tests of the stellar parameters measured by large-scale spectroscopic surveys or stellar parameters derived from asteroseismology with PLATO. The techniques described here for HD 22064 can be applied to the other eclipsing binaries in the sample in order to create an all-sky network of such benchmark stars.

Evaluation of Different Reverse Osmosis Membranes for Textile Dyeing and Finishing Wastewater Reuse

Different commercial reverse osmosis (RO) membranes from Vontron and DuPont Filmtec were evaluated for textile dyeing and finishing wastewater (TDFW) reuse in China. All six tested RO membranes produced qualified permeate meeting TDFW reuse standards at a water recovery ratio (WRR) of 70% in single batch tests. The rapid decline of apparent specific flux at WRR over 50% was mainly ascribed to feed osmotic pressure increase caused by concentrating effects. Multiple batch tests using Vontron HOR and DuPont Filmtec BW RO membranes with comparable permeability and selectivity demonstrated the reproducibility and showed low fouling development. The occurrence of carbonate scaling on both RO membranes was identified by scanning electron microscopy and energy disperse spectroscopy. No obvious organic fouling was detected on both RO membranes by attenuated total reflectance Fourier transform infrared spectrometry. From the orthogonal tests, with an integrated RO membrane performance index (i.e., 25% rejection ratio of total organic carbon + 25% rejection ratio of conductivity + 50% flux ratio of final to initial) as a target, the optimal parameters were determined as WRR of 60%, cross-flow velocity (CFV) of 1.0 m/s, temperature (T) of 20 °C for both RO membranes, while trans-membrane pressures (TMP) of 2 and 4 MPa were optimal for Vontron HOR RO membrane and DuPont Filmtec BW RO membrane, respectively. Both RO membranes with the optimal parameters produced good permeate quality for TDFW reuse and kept a high flux ratio of final to initial, demonstrating the effectiveness of the orthogonal tests.

Coastal aquaculture regulates phosphorus cycling in estuarine wetlands: Mobilization, kinetic resupply, and source-sink process

Estuarine mangrove wetlands have gradually declined owing to the growing construction of aquaculture ponds. How the speciation, transition, and migration of phosphorus (P) adaptively change in the sediments of this pond-wetland ecosystem remains unclear. In this study, we used high-resolution devices to explore the contrasting P behaviors associated with the redox cycles of Fe-Mn-S-As in estuarine and pond sediments. The results showed that the construction of aquaculture ponds increased the content or percentage of the silt, organic carbon, and P fractions in sediments. Dissolved organic P (DOP) concentrations in pore water were fluctuant with depths, accounting for only 18±15% and 20±11% of total dissolved P (TDP) in estuarine and pond sediment, respectively. Furthermore, DOP was less strongly correlated with other P species, including Fe, Mn, and sulfide. The coupling of dissolved reactive P (DRP) and TDP with Fe and sulfide confirmed that P mobility is regulated by Fe redox cycling in estuarine sediments, whereas Fe(III) reduction and sulfate reduction co-regulate P remobilization in pond sediments. The apparent diffusion flux revealed all sediments acting as sources for TDP (0.04–0.1 mg m−2 d−1) to the overlying water, while mangrove sediments were sources of DOP, and pond sediments were major sources of DRP. The DIFS model overestimated the P kinetic resupply ability, which was evaluated using DRP rather than TDP. This study improves our understanding of P cycling and budget in aquaculture pond-mangrove ecosystems and has important implications for understanding water eutrophication more effectively.

Evaluation of the distribution and mobility of labile phosphorus in sediment profiles of Lake Nansi, the largest eutrophic freshwater lake in northern China

Understanding various biogeochemical processes, especially in eutrophic sediments, necessitates fine-scale phosphorus (P) measurements in pore waters. To the best of our knowledge, the fine-scale distributions of P across the sediment profiles of Lake Nansi have rarely been investigated. Herein we evaluated the dynamic distributions of labile P and Fe across the sediment-water interface (SWI) of Lake Nansi at two-dimensional (2D) and sub-millimeter resolution, using well-established colorimetric diffusive gradients in thin films (DGT) methodology. The concentrations of labile P in all investigated sediment profiles exhibited strong spatial variations, ranging from 0 to 1.50 mg/L with a considerable number of hotspots. Lake Nanyang (0.55 ± 0.21 mg/L) had the highest mean concentration of labile P, followed by Lake Dushan (0.38 ± 0.19 mg/L), Lake Weishan (0.28 ± 0.21 mg/L), and Lake Zhaoyang (0.18 ± 0.09 mg/L). The highest concentrations of labile P were always detected in Lake Dushan, which had been subjected to excessive exogenous P pollution. The co-distributions of labile P and Fe in the majority of the sediment of Lake Nansi confirmed highly positive correlations (P < 0.01), suggesting that the mobility of labile P throughout the SWI was likely governed by iron redox processes. The apparent diffusion fluxes of P across the SWI ranged from −7.7 to 33.6 μg/m2·d, with a mean value of 5.26 ± 7.80 μg/m2·d. Positive apparent fluxes for labile P were recorded in most sediment cores, demonstrating the strong upward mobility of P from the sediment to the overlying water. Our results provided accurate and extensive information regarding the micro-distribution and dynamic exchange of labile P across the SWI. This allows for a better understanding of eutrophication processes and the implementation of P management strategies in Lake Nansi.

In Situ Simultaneous Analysis of Nitrogen and Phosphorus Migration in Urban Black Odorous Runoff.

The extremely serious urban runoff eutrophication and black odorous phenomenon pose a significant threat to the lake aquatic ecosystem, resulting in a significantly increased frequency, magnitude, and duration of algal blooms in lakes. However, few investigations focus on small tributaries of the lakes, despite the ubiquity and potential local importance of these runoffs. Thus, the labile sediments NH4+-N, NO3−-N, PO43−, Fe2+, and S2− in black odorous runoff at Wuxi were overall analyzed at high resolution using diffusive gradients in thin films (DGT). The variations in labile N, P, Fe, and S distribution profiles at different sampling sites indicated high heterogeneity in sediments. The concentrations of labile P, Fe, and S showed synchronous variation from the sediment-water interface (SWI) up to −20 mm along sediment profiles. Moreover, there existed a significant positive correlation among labile P, Fe, and S concentrations (p < 0.05), which might represent typical odor compounds’ FeS and H2S synchronous release process in urban runoff. Furthermore, the apparent diffusion fluxes of labile P, Fe, and S across the SWI were all released upward, while fluxes of NH4+-N and NO3−-N release downward, indicating the sediments act as source and sink of P and N, respectively. Sediments’ potential for endogenous P and N fractions release results in the black−odorous water, and sediment finally abouchement the Taihu, which intensifies further lake eutrophication phenomenon.