Apparent Contact Angle Research Articles

Development of Laser Processing Algorithm for Hydrophobic Micro-texture

Functional textures with physical functions such as hydrophobicity are expected as a solution to improve the value of products. The purpose of this research was to achieve a femtosecond-pulsed laser processing method that can create hydrophobic micro-texture directly on a resin (polyethylene terephthalate) surface. A feedback control algorithm was proposed to achieve texture for improving the hydrophobicity. Pitch, tooth width, groove width, and depth were used as the geometric parameters of the micro-texture. Apparent contact angle of 144.9° was achieved with groove/tooth ratio of 9 when polyethylene terephthalate was processed with the hydrophobic micro-texture. We have achieved a processing speed that can process a 3 mm square area in 4 min. This laser processing technology will be realized as a low environmental impact, sustainable manufacturing that supports carbon neutrality and sustainability goals.

Flowrate effects on the lateral coalescence of two growing bubbles

AbstractThe coalescence of two growing bubbles presents unique characteristics compared to static bubble coalescence. The gas injection flowrate significantly affects the different stages of bubble evolution, which is poorly understood. In this study, we investigate the flowrate effects on the lateral coalescence of two growing bubbles experimentally. The synchronous bubbling from adjacent needles is achieved using water to push air. During the bubble growth process, we find that the initial nonlinear evolution of bubble volume is because the bubble emerges as a small spherical cap with a large curvature radius and apparent contact angle. As the neck expands after bubble coalescence, the injection flowrate accelerates the neck evolution compared to the case without air injection. We find the neck expansion time decreases linearly with increasing flowrate, while the expansion speed increases with flowrate, but only in the early stage. Moreover, we propose a new theoretical expression that predicts the neck radius well at all the flowrates. At the post‐coalescence oscillation stage, the average projection area of the coalesced bubble increases linearly with time, except for periodic oscillations. Besides, we find that the injected air primarily influences the coalesced bubble's height, which in turn affects the projection area.

Role of Surface Roughness in Surface Energy Calculation of Aggregate Minerals

Surface energy is a key material property and can work as a crucial parameter in various mechanical models to predict the moisture sensitivity and fatigue damage of asphalt mixtures. The calculated surface energy values of the aggregate minerals strongly depend on their surface roughness. Therefore, it is very relevant for accurate calculation of surface energy to study the relationship between roughness and surface energy. This study aims to investigate the relationship between surface roughness and surface energy of aggregate minerals. Two minerals—quartz and calcite—were used for this study. The surfaces of the mineral specimens were treated to achieve four levels of roughness. Their surface roughness was described by three roughness parameters. Based on the sessile drop method, an optical tensiometer with a 3D topography module was employed to measure the contact angle and the surface energy of the minerals with different roughness. The influences of surface roughness on the contact angle and the surface energy were then analyzed. The results showed that the contact angle for both quartz and calcite decreases with the increasing surface roughness when it is less than 90° and increases when it is greater than 90°. The Wenzel equation can remove the effect of surface roughness on the contact angles of the minerals. The surface energy of quartz and calcite in the presence of roughness at the microscale would be underestimated when using the measured (apparent) contact angle. The corrected surface energy based on the Wenzel equation must be applied to represent the real surface energy of the minerals.

Modification of Soil Hydroscopic and Chemical Properties Caused by Four Recent California, USA Megafires

While it is well known that wildfires can greatly contribute to soil water repellency by changing soil chemical composition, the mechanisms of these changes are still poorly understood. In the past decade, the number, size, and intensity of wildfires have greatly increased in the western USA. Recent megafires in California (i.e., the Dixie, Beckwourth Complex, Caldor, and Mosquito fires) provided us with an opportunity to characterize pre- and post-fire soils and to study the effects of fires on soil water repellency, soil organic constituents, and connections between the two. Water drop penetration time (WDPT) tests performed in the field showed a significant increase (from <1 s up to >600 s) in WDPT from pre- to post-fire soils. This increase in soil water repellency after fires was confirmed by increases in apparent contact angle (ACA) between 1.1 and 9 times from unburned to burned soils. The chemical characterization of burned soils with high resolution mass spectrometry showed the increased abundance of hydrophobic organics (e.g., PAH-like compounds and organic molecules with a low number of oxygen atoms) as well as the correlation of the average H/C ratio and aromaticity index (AI) with ACA. Most likely, these compounds contribute to post-fire soil water repellency that triggers hydrological effects such as landslides, flooding, and debris flows.

Electrowetting lattice Boltzmann method for micro- and nano-droplet manipulations.

Electrowetting has become a widely used tool for manipulating tiny amounts of liquids on surfaces. This paper proposes an electrowetting lattice Boltzmann method for manipulating micro-nano droplets. The hydrodynamics with the nonideal effect is modeled by the chemical-potential multiphase model, in which the phase transition and equilibrium are directly driven by chemical potential. For electrostatics, droplets in the micro-nano scale cannot be considered as equipotential as macroscopic droplets due to the Debye screening effect. Therefore, we linearly discretize the continuous Poisson-Boltzmann equationin a Cartesian coordinate system, and the electric potential distribution is stabilized by iterative computations. The electric potential distribution of droplets at different scales suggests that the electric field can still penetrate micro-nano droplets even with the screening effect. The accuracy of the numerical method is verified by simulating the static equilibrium of the droplet under the applied voltage, and the results show the apparent contact angles agree very well with the Lippmann-Young equation. The microscopic contact angles present some obvious deviations due to the sharp decrease of electric field strength near the three-phase contact point. These are consistent with previously reported experimental and theoretical analyses. Then, the droplet migrations on different electrode structures are simulated, and the results show that droplet speed can be stabilized more quickly due to the more uniform force on the droplet in the closed symmetric electrode structure. Finally, the electrowetting multiphase model is applied to study the lateral rebound of droplets impacting on the electrically heterogeneous surface. The electrostatic force prevents the droplets from contracting on the side which is applied voltage, resulting in the lateral rebound and transport toward the side.

Superhydrophilicity and Antifouling Behavior in Electrochemically Oxidized Nanocrystalline Pseudographite

Electrochemical oxidation of GUITAR (pseudoGraphite from the University of Idaho Thermolyzed Asphalt Reaction) produces a surface that exhibits superhydrophilic properties. This surface contains 20.7% relative oxygen abundance, giving it a heightened affinity for water relative to the pristine material. Scanning electron and atomic force micrographs reveal spherical, bubble-like structures on GUITAR, indicating a higher surface roughness (Rq = 300–400 nm) over the predominantly smooth titanium substrate (Rq = 94.5 nm). Combining an intrinsic affinity toward water with a heightened surface roughness produces a material with an apparent water contact angle of 0°. The synergistic effects of a superhydrophilic surface that can function as an electrode result in an electrocatalyst material that is highly resistant to fouling. When stored in water, oxidized GUITAR (Ox-GUITAR) completely resists fouling by volatile organic compounds for the duration of testing (72 h). When fouled directly with a drop of oil, the residue can be removed using a simple water rinse. The removal of oil residues from carbon surfaces is typically not possible without the use of solvents, surfactants, or mechanical exfoliation. This combination of properties opens Ox-GUITAR to a broad array of possible applications, such as implantable electrodes, field sensors, or water-quality monitoring.

Superhydrophobicity and compressive stability of Salvinia surface: Mechanical analysis and structural design

The surface of Salvinia had superhydrophobicity and kept good compressive stability, which was mainly attributed to the dense microscopic eggbeater structure villi on the surface. By means of force equilibrium, a theoretical model was established to analyze the interface mechanical behaviors when a droplet infiltrates the microstructures. Based on the minimum energy principle, a theoretical model was presented to analyze the process of a droplet spreading on the surface of Salvinia reaching a steady state. Combined with numerical simulations, it was found that the superhydrophobicity and compressive stability of the Salvinia were dependent on the morphological and geometric parameters of the microstructure (edge angle φ, number of branching n, width W and spacing D, etc.). By adjusting these geometrical parameters, the surface of the biomimetic structure can maintain a stable Cassie state at 0.63 kPa pressure, and the apparent contact angle is controllable in the range of 121°−169.8°. The research results provide a theoretical foundation for the structural design of superhydrophobic surfaces with high stability and tunable wettability.

Water advancing and receding process as a liquid–vapor interface geometrical question

Existing wetting theories have difficulty accurately describing advancing/receding processes on micro-structured surfaces. A strategy is proposed to solve this problem by recognizing it as a liquid–vapor interface geometrical question. The wetting chip method is proposed to realize the microscopic observation of liquid–vapor interface variations. A wetting model based on the liquid–vapor interface shape (LVIS model) is established to describe the analytical relationships between the apparent contact angles, liquid–vapor interface radius, substrate geometry, and chemical nature of liquid. The LVIS model is divided into four typical time points and three transition stages, and its predictions agree with the experimental measurements. In contrast to traditional theories, the apparent contact angles in a quasi-equilibrium state should be separated into advancing and receding processes, and in this state, apparent contact angles vary with changes in the parameters of micro-pillar width and spacing. This strategy has the potential to accurately describe the wetting process on micro-structure surfaces.

Integrating Fly Ash-Controlled Surface Morphology and Candle Grease Coating: Access to Highly Hydrophobic Poly (L-lactic Acid) Composite for Anti-Icing Application

New ways of recycling fly ash are of great significance for reducing the environmental pollution. In this work, biodegradable hydrophobic poly (L-lactic acid)/fly ash composites for anti-icing application were successfully fabricated via a facile solvent-volatilization-induced phase separation approach. A silane coupling agent of 3-(Trimethoxysilyl) propyl methacrylate was used to decorate a fly ash surface (FA@KH570) for strengthening the interface bonding between fly ash and poly (L-lactic acid). Moreover, FA@KH570 could obviously enhance the crystallinity of poly (L-lactic acid) (PLLA)/FA@KH570 composites, which accelerated the conversion from the liquid-liquid to the liquid-solid phase separation principle. Correspondingly, the controllable surface morphology from smooth to petal-like microspheres was attained simply by adjusting the FA@KH570 content. After coating nontoxic candle grease, the apparent contact angle of 5 wt% PLLA/FA@KH570 composite was significantly increased to an astonishing 151.2°, which endowed the composite with excellent anti-icing property. This strategy paves the way for recycling waste fly ash and manufacturing hydrophobic poly (L-lactic acid) composite for potential application as an anti-icing material for refrigerator interior walls.

Multiscale Analysis for Dynamic Contact Angle Hysteresis on Rough Surfaces

Dynamic contact angle hysteresis is of critical importance for many two-phase flow problems with moving contact lines. It is induced by inhomogeneity or roughness of the substrates. In this paper, we present theoretical studies on the time averaging of a reduced model for wetting on rough surfaces and also the analysis on the effect of stochastic thermal forces. We derive equations for the averaged dynamics and show that the apparent contact angle depends on the harmonic averaging of the geometric and chemical properties of the substrates as well as the contact line velocity. The contact angle hysteresis can be determined quantitatively by the equations. The averaging results are proved rigorously by multi-scale analysis and verified by some numerical examples.

Anti-Icing Property of Superhydrophobic Nanostructured Brass via Deposition of Silica Nanoparticles and Nanolaser Treatment.

Ice accumulation on brass surfaces can lead to heat transfer inefficiency, equipment degradation, and potential accidents. To address this issue, superhydrophobic surface technology is utilized. This work aims to develop superhydrophobic nanostructured brass surfaces using the combination of nanolaser ablation and the deposition of silica nanoparticles to achieve the anti-icing property. Four distinct types of brass surfaces namely, the bare surface (BS), the lasered surface (LS), the coated surface (CS), and the coated-lasered surface (CLS) were prepared. The anti-icing performances of the fabricated samples including the effects of the surface structure, the droplet size, and the surface temperature were investigated and evaluated. The results showed that the delayed icing time increased with the increases in the apparent contact angle, the droplet size, and the surface temperature. When the apparent contact angle increased, the contact area between the droplet and the cooling substrate reduced, leading to the longer delayed icing time. With the deposition of silica nanoparticles and nanolaser treatment, CLS achieved the greatest apparent contact angle of 164.5°, resulting in the longest delayed icing time under all experimental conditions. The longest delayed icing time on CLS recorded in this study was 2584 s, which was 575%, 356%, and 27% greater than those on BS, LS, and CS, respectively. The study also revealed that the surface structure played a more crucial role in achieving the anti-icing property when compared to the surface temperature or the droplet size. The shortest delayed icing time on CLS at the lowest surface temperature and at the smallest droplet size was longer than those on BS and LS at all conditions. The results were also discussed in relation to a heat transfer model. The findings of this research can serve as an avenue for advancing knowledge on heat transfer enhancement and energy efficiency.

Electrowetting modulated enhancement of critical heat flux in pool boiling

Critical heat flux (CHF) represents the upper limit for nucleate boiling, beyond which heat transfer deteriorates due to the boiling regime transition to film boiling. This paper reports a new strategy for CHF enhancement by employing electrowetting (EW) to tailor the far-field and near-field effects of CHF. With electrowetting, the instability of liquid-vapor interface is amplified due to the reduction in the hydrodynamic wavelength, apparent contact angle is reduced and the bubble's lateral expansion over the heating surface is refrained by a resistive electric force, all contributing to CHF improvement. A comprehensive theoretical model is developed to understand the effects of the electric field on various aspects of CHF. Experiments are conducted to demonstrate the feasibility of this CHF enhancement strategy and to validate the theoretical model.

Theoretical analysis of contact angle hysteresis of suspended drops on micropillared superhydrophobic surfaces

The contact angle hysteresis of superhydrophobic surfaces is very important for many industrial applications, but related mechanisms of the motion of the contact line induced by varying drop volumes are not fully understood. In this work, a thermodynamic model was established to analyze contact angle hysteresis, and a relationship between the varying drop volume and free energy barriers is presented. The calculation results showed the advancing/receding free energy barriers changing markedly with addition of liquid to a drop as well as its removal from the drop, ultimately leading to pinning/depinning of three-phase contact lines and varying apparent contact angles. The advancing contact line tends to pin to the upper surface of micropillars, and the receding contact line shows a stick−slip motion on this surface. Regarding contact angle hysteresis, the theoretical value of the advancing contact angle was indicated to be independent of geometric parameters of micropillars, and to reach a value of 180°. In contrast, the receding contact angle was strongly affected by micropillar structures, and specifically decreased with the increasing pillar width and decreasing pillar spacing. Moreover, the efficacy of the model was verified by a comparison with experimental observations for superhydrophobic surfaces with different geometric parameters. This work has offered insights into the stickiness of a suspended drop on a micropillared superhydrophobic surface.

Electrospun Multilayered Films Based on Poly(3-hydroxybutyrate-co-3-hydroxyvalerate), Copolyamide 1010/1014, and Electrosprayed Nanostructured Silica

In this research, bio-based electrospun multilayered films for food packaging applications with good barrier properties and close to superhydrophobic behavior were developed. For this purpose, two different biopolymers, a low-melting point and fully bio-based synthetic aliphatic copolyamide 1010/1014 (PA1010/1014) and the microbially synthesized poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and food-contact-complying organomodified silica (SiO2) nanostructured microparticles, were processed by electrospinning. The production of the multilayer structure was finally obtained by means of a thermal post-treatment, with the aim to laminate all of the components by virtue of the so-called interfiber coalescence process. The so developed fully electrospun films were characterized according to their morphology, their permeance to water vapor and oxygen, the mechanical properties, and their water contact angle properties. Interestingly, the annealed electrospun copolyamide did not show the expected improved barrier behavior as a monolayer. However, when it was built into a multilayer form, the whole assembly exhibited a good barrier, an improved mechanical performance compared to pure PHBV, an apparent water contact angle of ca. 146°, and a sliding angle of 8°. Consequently, these new biopolymer-based multilayer films could be a bio-based alternative to be potentially considered in more environmentally friendly food packaging strategies.

Superhydrophobic Epoxy/Fluorosilicone/PTFE Coatings Prepared by One-Step Spraying for Enhanced Anti-Icing Performance

The icing of glass insulators is likely to cause faults such as insulator flashover, which poses a serious threat to the power system. Traditional deicing techniques have the disadvantage of being costly and inefficient. Herein, polytetrafluoroethylenes (PTFEs) as nanoparticles and epoxy and fluorosilicone resins as binders were blended to construct an anti-icing coating. The superhydrophobic (SHP) epoxy/fluorosilicone/PTFE coatings for anti-icing were successfully prepared on glass slides through one-step spraying. The effect of PTFE mass fraction on the microstructure, on the wettability and on the anti-icing properties of the coatings was investigated. The results showed that the coatings with different PTFE mass fractions had different microstructures. When the PTFE mass fraction was 47.2%, the SHP coating exhibited a uniform rough structure with an apparent contact angle as high as 164.7° and a sliding angle as low as 3.2°. Moreover, the water droplets can bounce back five times with a contact time of only 9.5 ms and a rebound height of 4.58 mm. In the low-temperature environment (−10 °C), the SHP coating displayed good anti-frosting, anti-icing and icephobic properties. The delayed frosting time (1499 s) and delayed freezing time (1295.3 s) of the SHP coating were three and five times longer than those of the glass, respectively. The SHP coating presented an ice-adhesion strength (39.8 kPa) that was six times lower than that of glass. The prepared SHP coating demonstrated potential applications for the anti-icing of glass insulators.

Effect of Al Content in Steel on Interfacial Interaction between Molten Steel and MgO Substrate

The apparent contact angles between the molten steel with different [Al] contents (w[Al]) from 0.002% to 0.831% (mass fraction) and the microporous MgO (MM) substrates are measured at 1823 K using the sessile drop method. In particular, the contact angles of No. 1 (w[Al] = 0.002%) and No. 5 (w[Al] = 0.831%) molten steels gradually increase with time at the initial stage. As w[Al] increases from 0.002% to 0.831%, the transformation route of interfacial products between molten steel and the MM substrate is MgO–FeO → MgO·Al2O3 → CaO·2Al2O3 + MgO·Al2O3. The w[Al] of No. 1 molten steel is small, and the dissolution of CaO·ZrO2(s) in the substrate is mainly affected by FeO. As w[Al] increases gradually, [Al] consumes the (MgO) contained in CaO·MgO·SiO2 (CMS), and turns the CMS into (CaO·SiO2) slag layer, which promotes the CaO·ZrO2(s) dissolving and thus increasing the interaction area percentage. When w[Al] is 0.831%, [Al] can react with (CaO·SiO2) slag layer or CaO·ZrO2(s) to form CaO·2Al2O3(s).

Wetting of porous thin films exhibiting large contact angles.

Porous solid films that promote large apparent contact angles are interesting systems since their wetting properties are dependent on both the surface structure and water penetration into the film. In this study, a parahydrophobic coating is made by sequential dip coating of titanium dioxide nanoparticles and stearic acid on polished copper substrates. The apparent contact angles are determined using the tilted plate method, and it is found that the liquid-vapor interaction decreases and water droplets are more likely to move off the film when the number of coated layers increases. Interestingly, it is found that under some conditions, the front contact angle can be smaller than the back contact angle. Scanning electron microscopy observations demonstrate that the coating process led to the formation of hydrophilic TiO2 nanoparticle domains and hydrophobic stearic acid flakes that allows heterogeneous wetting. By monitoring the electrical current through the water droplet to the copper substrate, it is found that the water drops penetrate the coating layer to make direct contact with the copper surface with a time delay and magnitude that depends on the coating thickness. This additional penetration of water into the porous film enhances the adhesion of the droplet to the film and provides a clue to understand the contact angle hysteresis.

Contact angle hysteresis on random self-affine rough surfaces in Wenzel's wetting regime: Numerical study.

We present a numerical study of the advancing and receding apparent contact angles for a liquid meniscus in contact with random self-affine rough surfaces in Wenzel's wetting regime. Within the framework of the Wilhelmy plate geometry, we use the full capillary model to obtain these global angles for a wide range of local equilibrium contact angles and for different parameters that determine the self-affine solid surfaces: Hurst exponent, wave vector domain, and root-mean-square roughness. We find that the advancing and receding contact angles are single-valued functions that depend only on the roughness factor determined by the set of values of the parameters of the self-affine solid surface. Moreover, the cosines of these angles are found to depend linearly on the surface roughness factor. The relations between the advancing, the receding, and Wenzel's equilibrium contact angles are investigated. It is shown that for materials with self-affine surface structure, the hysteresis force is the same for different liquids and it depends only on the surface roughness factor. A comparison with existing numerical and experimental results is carried out.

Predictions of the Wettable Parameters of an Axisymmetric Large-Volume Droplet on a Microstructured Surface in Gravity

In this study, a numerical model was developed to predict the wettable parameters of an axisymmetric large-volume droplet on a microstructured surface in gravity. We defined a droplet with the Bond number Bo>0.1 as a large-volume droplet. Bo was calculated by using the equation Bo=ρlgγlv3V4π23 where ρl is the density of liquid, γlv is the liquid-vapor interfacial tension, g is the gravity acceleration and V is the droplet volume. The volume of a large-volume water droplet was larger than 2.7 μL. By using the total energy minimization and the arc differential method of the Bashforth-Adams equation, we got the profile, the apparent contact angle and the contact circle diameter of an axisymmetric large-volume droplet in gravity on a microstructured horizontal plane and the external spherical surface. The predictions of our model have a less than 3% error rate when compared to experiments. Our model is much more accurate than previous ellipsoidal models. In addition, our model calculates much more quickly than previous models because of the use of the arc differential method of the Bashforth-Adams equation. It shows promise for use in the design and fabrication of microfluidic devices.

Assessment of the Effects of the 2021 Caldor Megafire on Soil Physical Properties, Eastern Sierra Nevada, USA

The Caldor fire burned ~222,000 acres of the Eastern Sierra Nevada during summer–fall 2021. We evaluated the effects of this “megafire” on the physical properties of a sandy soil developed from glacial tills to document fire-induced soil modifications in this region. We measured soil water retention and hydraulic conductivity functions as well as the thermal properties of five core samples from control (unburned) areas and eight core samples from burned soil of the same soil unit. Soil water repellency was measured in terms of water drop penetration time (WDPT) in the field and apparent contact angle in the laboratory on control and burned soil as well as ash samples. Soil organic matter (SOM) and particle and aggregate size distributions were determined on control and burned soil samples. Additionally, scanning electron microscopy (SEM) was used to image microaggregates of control and burned soil samples. We found a significant difference in SOM content and sand and silt aggregate size distribution between control and burned samples, which we associated with the disintegration of microaggregates due to the fire. We found no significant difference between soil water retention and hydraulic conductivity functions of control and burned soil but observed greater variation in saturated hydraulic conductivity and systematic shifts in thermal conductivity functions of burned compared to control samples. WDPT and apparent contact angle values were significantly higher for burned soils, indicating the occurrence of fire-induced soil hydrophobicity (FISH). Interestingly, the average apparent contact angle of the control soil was >90°, indicating that even the unburned soil was hydrophobic. However, the ash on top of the burned soil was found to be hydrophilic, having apparent contact angles <10°. Our results indicate that SOM and microaggregates were readily affected by the Caldor fire, even for sandy soil with a weakly developed structure. The fire seemed to have moderated thermal properties, significantly and soil wettability but had only minimal effects on water retention and hydraulic conductivity functions. Our findings demonstrate the complex nature of fire-soil interactions in a natural environment and highlight the need for additional investigation into the causes and processes associated with FISH and structure alterations due to fire to improve our ability to rapidly determine potential problem areas in terms of hazards commonly associated with fire-affected soils.