Annual River Loads Research Articles

Four Years of Sediment and Phosphorus Monitoring in the Kraichbach River Using Large-Volume Samplers

Various sampling strategies come into operation to monitor water quality in rivers. Most frequently, grab samples are taken, but they are not suitable for recording the highly dynamic transport of solids and solid-bound pollutants. Composite samples reduce the influence of input and transport dynamics and are better suited to determine the annual river loads. Large-volume samplers (LVSs) produce both a composite sample over a long period of time and an amount of solids which allows for further analyses. In the small sub-catchment area of the Kraichbach river in Baden-Wuerttemberg (Germany) two LVSs have been installed to sample the river flow. The concentration of solids and phosphorus in the supernatant water and the settled sediment in the sampler have been determined and mean concentrations have been derived. Annual river loads were calculated in combination with discharge data from the nearby gauging station. Two sampling strategies of the LVS were tested and compared. For the first strategy, the LVS was used to collect quasi-continuous composite samples throughout the year, whereas, with the second strategy, samples were taken specifically for different flow conditions (low, mean and high flow). This study compares the advantages and constraints of both strategies. Results indicate that the first strategy is better suited to determine annual river loads. Quasi-continuous large-volume composite sampling is recommended for further monitoring campaigns.

Alkalinity and dissolved inorganic carbon exports from tropical and subtropical river catchments discharging to the Great Barrier Reef, Australia

AbstractDissolved inorganic carbon (DIC) transport by rivers is an important control on the pH and carbonate chemistry of the coastal ocean. Here, we combine DIC and total alkalinity (TAlk) concentrations from four tropical rivers of the Great Barrier Reef region in Australia with daily river discharge to quantify annual river loads and export rates. DIC in the four rivers ranged from 284 to 2,639 μmol kg−1 and TAlk ranged from 220 to 2,612 μmol kg−1. DIC:TAlk ratios were mostly greater than one suggesting elevated exports of free [CO2*]. This was pronounced in the Johnstone and Herbert rivers of the tropical wet north. The largest annual loads were transported in the two large river catchments of the southern Great Barrier Reef region, the Fitzroy and Burdekin rivers. The carbon stable isotopic composition of DIC suggests that carbonate weathering was the dominant source of DIC in the southern rivers, and silicate weathering was likely a source of DIC in the northern Wet Tropics rivers. Annual loads and export rates were strongly driven by precipitation and discharge patterns, the occurrence of tropical cyclones, and associated flooding events, as well as distinct seasonal dry and wet periods. As such, short‐lived hydrological events and long‐term (seasonal and inter‐annual) variation of DIC and TAlk that are pronounced in rivers of the tropical and subtropical wet and dry climate zone should be accounted for when assessing inorganic carbon loads to the coastal ocean and the potential to buffer against or accelerate ocean acidification.

Fertilizer, landscape features and climate regulate phosphorus retention and river export in diverse Midwestern watersheds

Non-point source pollution of phosphorus (P) is a primary cause of eutrophication of aquatic ecosystems, and poses a persistent management challenge due to the dynamic and poorly understood processes controlling the transport and transformation of P at the watershed scale. We examined phosphorus inputs, retention, and riverine losses in 62 diverse watersheds that included a wide range of land cover and use (minimally disturbed to human dominated) and human P inputs in Minnesota, USA. Fertilizer inputs from row crop cultivation were the dominant source of P to agricultural watersheds. A large majority of P inputs was retained in watershed soils or removed in agricultural products. However, fertilizer input was the most important factor associated with average annual river transport of total, dissolved, and particulate phosphorus (PP). Mean annual runoff increased total and dissolved P yields and decreased P retention. Dissolved P made up a significant portion of annual river loads at sites with high rates of P inputs and river TP export, with the ratio of dissolved to PP export increasing with crop cover and fertilizer inputs. PP export rose with larger extents of eroding bluffs near channels. Bluffs constitute only a small proportion of watershed area, but make a disproportionately high contribution to sediment loads due to their close proximity to river channels that are increasingly affected by human and climate-driven changes to river hydrology. Together, our results suggest that rising discharge and flow variability due to climate change and agricultural intensification coupled with high rates of P inputs will maintain elevated fluvial P export into the future. Without reductions in P inputs and reductions in both soluble P losses and stream bank erosion, reversal of water quality degradation will be difficult to achieve.

Rainfall and Streamflow Effects on Estuarine Staphylococcus aureus and Fecal Indicator Bacteria Concentrations

Pathogenic bacteria in nearshore waters are a public health threat, and many have watershed sources. Hence, understanding direct and indirect causes of bacterial loading can improve awareness and watershed management. Rainfall‐driven runoff influences river discharge, affecting pathogen transport to the ocean. This study assessed pathogen loading to nearshore waters under varying weather conditions within Hilo Bay, Hawaii, from 2014 to 2017. Staphylococcus aureus, methicillin‐resistant S. aureus (MRSA), and fecal indicator bacteria (FIB) were quantified in the bay, rivers, and potential watershed sources using culture‐based methods. Relationships between their concentrations with rainfall, river discharge, and water quality data were examined. Staphylococcus aureus, MRSA, and FIB were present within Hilo Bay and its rivers, as well as road runoff, sewage, and soils; MRSA was less prevalent. Staphylococcus aureus and FIB concentrations increased with rainfall and river discharge. Turbidity and salinity were the best water quality parameters for predicting bacteria concentrations, with positive and negative relationships, respectively. Our results suggest that more intense storms, especially after longer dry periods between events, will increase S. aureus and FIB loads to nearshore waters, as storms comprise >80% of annual river loads. Our models can be used to assess recreational water users’ health risks and predict future water quality conditions with changing rainfall patterns.Core Ideas Staphylococcus aureus and FIB were present in the bay, rivers, road runoff, sewage, and soils. MRSA was less prevalent in the environment than S. aureus and FIB. S. aureus and FIB bay concentrations increased with rainfall and river discharge. S. aureus and FIB bay concentrations varied with bay salinity and turbidity. Bay bacteria concentrations can be modeled from hydrologic and water quality data.

Influence of sampling frequency and load calculation methods on quantification of annual river nutrient and suspended solids loads.

Better management of water quality in streams, rivers and lakes requires precise and accurate estimates of different contaminant loads. We assessed four sampling frequencies (2days, weekly, fortnightly and monthly) and five load calculation methods (global mean (GM), rating curve (RC), ratio estimator (RE), flow-stratified (FS) and flow-weighted (FW)) to quantify loads of nitrate-nitrogen (NO3--N), soluble inorganic nitrogen (SIN), total nitrogen (TN), dissolved reactive phosphorus (DRP), total phosphorus (TP) and total suspended solids (TSS), in the Manawatu River, New Zealand. The estimated annual river loads were compared to the reference 'true' loads, calculated using daily measurements of flow and water quality from May 2010 to April 2011, to quantify bias (i.e. accuracy) and root mean square error 'RMSE' (i.e. accuracy and precision). The GM method resulted into relatively higher RMSE values and a consistent negative bias (i.e. underestimation) in estimates of annual river loads across all sampling frequencies. The RC method resulted in the lowest RMSE for TN, TP and TSS at monthly sampling frequency. Yet, RC highly overestimated the loads for parameters that showed dilution effect such as NO3--N and SIN. The FW and RE methods gave similar results, and there was no essential improvement in using RE over FW. In general, FW and RE performed better than FS in terms of bias, but FS performed slightly better than FW and RE in terms of RMSE for most of the water quality parameters (DRP, TP, TN and TSS) using a monthly sampling frequency. We found no significant decrease in RMSE values for estimates of NO3-N, SIN, TN and DRP loads when the sampling frequency was increased from monthly to fortnightly. The bias and RMSE values in estimates of TP and TSS loads (estimated by FW, RE and FS), however, showed a significant decrease in the case of weekly or 2-day sampling. This suggests potential for a higher sampling frequency during flow peaks for more precise and accurate estimates of annual river loads for TP and TSS, in the study river and other similar conditions.

Trend of herbicide loads in the river Rhine and its tributaries

Many policies have been established and actions have been taken to reduce pesticide pollution of surface waters. However, the effectiveness of these initiatives was rarely tested on an empirical basis. This study suggests that evidence on the policy effects can be evaluated by analyzing the temporal changes in the loads rather than the concentrations of active ingredients in rivers. It is shown that the long-term change of pesticide emissions into surface waters can be tested statistically by the number of upward versus downward trends in river load. To evaluate the situation in Germany, 57 concentration time series of 14 herbicide substances at 7 river monitoring stations with a minimum of 24 analyses per year were assembled and annual substance river loads were calculated. The longest time course was 17 years (1990-2006). The significance of trends of data rows was analyzed by an univariate Mann-Kendall test that evaluates 27 (47.4%) of the 57 time series as statistically significant downward trended. It took a period of 10 years and longer before the high annual atrazine and simazine loads measured in the years 1990-1991 had been diminished to a drastically lowered level after ban of the herbicides. Data are available on the yearly consumption of 8 substances used in German agriculture. A total of 36 time series for this subset were tested with a partial Mann-Kendall test with the consumption as covariance factor, which reduces the number of significant trends in river load noticeably. Based on this test, only 7 (19.4% of 36) declining time series remain. As a result, the intended effect of measures to reduce surface water contamination by the use of pesticides seems to be only partially successful, however, the database to justify this statement is small. For the water monitoring strategies in Germany, it is recommend to enhance the sampling frequency at river stations. A minimum of a semimonthly sampling interval would facilitate the calculation of valuable annual river loads and would therefore allow a pronounced validation of the long-term change of pesticide emission into rivers.

Development of a new indicator of pollutant loads and its application to the Chesapeake Bay watershed

AbstractPollutant load reductions are often required to restore aquatic ecosystems experiencing eutrophication. Loads can be estimated using watershed models or data from monitoring stations, however data availability can limit the timeliness or comprehensiveness of the load estimates. We developed an approach to address this challenge that used watershed model results to estimate the proportion of annual nonpoint source nitrogen (N), phosphorus (P) and sediment (Sed) loads derived from unmonitored catchments. This proportion was multiplied by the nonpoint portion of United States Geological Survey (USGS) estimated annual river loads to account for annual variation in hydrologic conditions. Total loads were calculated as the sum of measured river loads, reported point sources from unmonitored areas and the estimated nonpoint source loads from unmonitored catchments. We applied this approach to the Chesapeake Bay because of its socio‐economic and ecological importance. Median watershed loads for N, P and Sed were 140, 6.4 and 3030 Mg year−1, respectively (1990–2004). Nonpoint source loads from the monitored areas constituted the greatest source of N, P and Sed (55, 47 and 74% respectively) to the Bay. The high N, P and Sed yield rates (7.3, 0.38 and 99 kg ha−1 year−1, respectively) from nonpoint loads originating from unmonitored areas near the Bay resulted in 25, 32 and 26% (N, P and Sed, respectively) of the Bay's total loads (excluding direct atmospheric deposition, shoreline erosion and oceanic inputs). Disproportionately high loads of P and Seds were associated with years that experienced elevated discharge whereas N loads were directly related to discharge. Error estimates indicated that our methods were most reliable for N (±6%) but reasonable for P (±22%) and provide an effective technique for the timely estimation of pollutant loads from watersheds with unmonitored catchments. Management strategies that decrease N deposition and reduce runoff to control P and Sed transport will effectively reduce pollutant loads. Published in 2010 by John Wiley & Sons, Ltd.

History of anthropogenic nitrogen input to the German Bight/SE North Sea as reflected by nitrogen isotopes in surface sediments, sediment cores and hindcast models

The German Bight/SE North Sea is considered a hot-spot of river-induced eutrophication, but the scarce observational data of river nitrate loads prior to the 1970s complicate the assessment of target conditions for environmental management and legislation. Stable nitrogen isotope ratios (δ 15N) in sediment records can be used to decipher historical river nitrate contributions. To better constrain pre-1970s conditions, we determined δ 15N in archive sediment samples (1950–1969) and dated cores from the Helgoland depositional area. We also modeled the δ 15N in past situations (1960 and 1860) using an N-isotope-tracking ecosystem model. The modeled spatial distribution of δ 15N in sediments for 1960 conditions and the observed spatial pattern of δ 15N in archive sediment samples (1950–1969) represent a period of moderate eutrophication. The modeled spatial distribution of δ 15N in sediments for 1860 conditions (pre-industrial) showed a moderate δ 15N gradient from the Elbe river mouth (δ 15N<4‰) to the open sea (δ 15N∼5‰). This pattern contrasts with the δ 15N pattern in modern surface sediments, which exhibits a steep and inverted δ 15N gradient from the Elbe river mouth (δ 15N>9‰) to the open sea (δ 15N<7‰). Modeled δ 15N for 1860 conditions are consistent with δ 15N values observed in dated sediment cores that span the last 900 years. Value of δ 15N in sediment cores increased from approximately 1860 to 2000 by 2.5‰. The increasing trend reflects changes in the abundance and isotopic composition of riverine nitrate loads caused by anthropogenic activities. Sensitivity tests suggest that loads and isotopic ratios of nitrogen forms other than nitrate (ammonium and organic nitrogen) have minor impact on the modeled surface sediments, despite their higher abundance in the riverborne loads in the past. Our results suggest that eutrophication of the German Bight predates the 1960 period of documented rapidly increasing river loads. Pre-industrial levels of δ 15N modeled with 28% of the modern annual (1990–1999) atmospheric loads and 10% of the modern annual river loads agree best with levels of δ 15N (∼6‰) observed in sediments of the cores dated to 1860.

Dramatic beach and nearshore morphological changes due to extreme flooding at a wave-dominated river mouth

Record flooding on the Santa Clara River of California (USA) during January 2005 injected ∼ 5 million m 3 of littoral-grade sediment into the Santa Barbara Littoral Cell, approximately an order of magnitude more than both the average annual river loads and the average annual alongshore littoral transport in this portion of the cell. This event appears to be the largest sediment transport event on record for a Southern California river. Over 170 m of local shoreline (mean high water (MHW)) progradation was observed as a result of the flood, followed by 3 years of rapid local shoreline recession. During this post-flood stage, linear regression-determined shoreline change rates are up to −45 m a − 1 on the subaerial beach (MHW) and − 114 m a − 1 on the submarine delta (6 m isobath). Starting approximately 1 km downdrift of the river mouth, shoreline progradation persisted throughout the 3-year post-flood monitoring period, with rates up to + 19 m a − 1 . Post-flood bathymetric surveys show nearshore (0 to 12 m depth) erosion on the delta exceeding 400 m 3/m a − 1 , more than an order of magnitude higher than mean seasonal cross-shore sediment transport rates in the region. Changes were not constant with depth, however; sediment accumulation and subsequent erosion on the delta were greatest at − 5 to − 8 m, and accretion in downdrift areas was greatest above –2 m. Thus, this research shows that the topographic bulge (or “wave”) of sediment exhibited both advective and diffusive changes with time, although there were significant variations in the rates of change with depth. The advection and diffusion of the shoreline position was adequately reproduced with a simple “one line” model, although these modeling techniques miss the important cross-shore variations observed in this area. This study illustrates the importance of understanding low-frequency, high volume coastal discharge events for understanding short- and long-term sediment supply, littoral transport, and beach and nearshore evolution in coastal systems adjacent to river mouths.

Nutrient fluxes across reaches and impoundments in two southeastern Michigan watersheds

River systems with impoundments are expected to experience greater nutrient removal as a consequence of enhanced nitrogen (N) loss by denitrification, settling and burial of phosphorus (P), and longer residence times of water relative to a free-flowing river. We evaluated the magnitude of N and P removal across stream reaches and impoundments, including annual and seasonal trends, in two southeastern Michigan rivers that differ in their degree of impoundment and watershed land use patterns. All nutrient fraction concentrations remained statistically unchanged across stream reaches of 2–3 km in length, but dissolved oxygen and pH increased. Impoundment outlets exhibited increases in water temperature and decreases in conductivity, TP, TN, TDP, SRP, TDN, and NO3-N relative to inflowing water. A nutrient load mass balance showed that two connected impoundments removed 18 and 32% of the annual river loads of TN and TP, respectively. Removal rates were seasonably variable, with TP removal most pronounced during winter months when the impoundment received episodic high P loads. Conversely, TN removal was greatest during summer and autumn months when impoundments were stratified and water temperatures were elevated. Strong seasonal differences in N and P transport through the impoundments demonstrated the capacity of impoundments to dramatically alter the timing and stoichiometry of downstream nutrient export. These seasonal differences also highlight the need to consider the entire annual cycle when estimating surface water nutrient dynamics or designing management plans for nutrient abatement.

Modeling the physical and biogeochemical response of a marine shelf system to a tropical cyclone

[1] We describe the first use of a fully integrated biogeochemical model to explore the response of a marine shelf system to a tropical cyclone. Ocean currents, nutrients, sediments and plankton dynamics were simulated under conditions representative of Tropical Cyclone Bobby, which traversed the Australian North West Shelf in February 1995. Results show strong upwelling of nutrients and a phytoplankton bloom. While chlorophyll changes were similar to those estimated from satellite data in other coastal systems exposed to cyclonic conditions, the overall phytoplankton response was limited by cyclone induced sediment resuspension and the net contribution to annual primary production on the shelf was relatively small. In contrast, sediment loads exported off the shelf during Bobby were found to be more than 50 times modeled annual loads in years with little cyclone exposure and equivalent to at least 20 years of annual river-loads to the North West Shelf.

Retention of Riverine Sediment and Nutrient Loads by Coastal Plain Floodplains

Despite the frequent citation of wetlands as effective regulators of water quality, few quantitative estimates exist for their cumulative retention of the annual river loads of nutrients or sediments. Here we report measurements of sediment accretion and associated carbon, nitrogen, and phosphorus accumulation as sedimentation over feldspar marker horizons placed on floodplains of the non-tidal, freshwater Coastal Plain reaches of seven rivers in the Chesapeake Bay watershed, USA. We then scale these accumulation rates to the entire extent of non-tidal floodplain in the Coastal Plain of each river, defined as riparian area extending from the Fall Line to the upper limit of tidal influence, and compare them to annual river loads. Floodplains accumulated a very large amount of material compared to their annual river loads of sediment (median among rivers = 119%), nitrogen (24%), and phosphorus (59%). Systems with larger floodplain areas and longer floodplain inundation retained greater proportions of riverine loads of nitrogen and phosphorus, but systems with larger riverine loads retained a smaller proportion of that load on floodplains. Although the source and long-term fate of deposited sediment and associated nutrients are uncertain, these fluxes represent the interception of large amounts of material that otherwise could have been exported downstream. Coastal Plain floodplain ecosystems are important regulators of sediment, carbon, and nutrient transport in watersheds of the Chesapeake Bay.

Migratory salmonids as vectors of carbon, nitrogen and phosphorus between marine and freshwater environments in north-east England

This study provides estimates of fluxes between freshwater and marine environments of organic carbon (C), nitrogen (N) and phosphorus (P) transported by migrating Atlantic salmon and sea trout. Mean annual values were assessed for a group of seven rivers in north-east England over a 7-year period (1989–1995). The total annual import to the rivers via adults of both species ranged between 48.5 and 156.8 t C, 10.5–34.1 t N and 1.7–5.3 t P. Total annual export by smolts and kelts ranged between 20.3 and 71.5 t C, 4.5–15.9 t N and 0.75–2.6 t P. The net flux of each of C, N and P by these fish represented only 0.09–0.24% of the total annual river loads. The net marine import of each element represented approximately 75% of the gross adult import. Migratory fish provide the only direct source of such materials to the upper reaches of rivers.