Anisotropy Of Susceptibility Research Articles

Emplacement of the Anta Granite from Rio de Janeiro State (SE, Brazil); determined by magnetic fabrics

Magnetic fabric and rock magnetism studies were performed on the three facies of the Anta granite (SE of Rio de Janeiro State, southern Brazil). This intrusion is roughly elliptical (∼ 14 km2), NE-SW oriented and composed of granodiorite, monzodiorite, quartz-diorite, syenogranite, and monzogranite. It shows solid-state deformation and tectonic foliation at its borders and is apparently isotropic in the central part where the internal fabrics are impossible or very difficult to measure through classical techniques. Magnetic fabrics were determined by applying both anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of anhysteretic remanent magnetization (AARM). The AMS and AARM fabrics are coaxial for all facies. The parallelism between AMS and AARM tensors excludes the presence of a single domain (SD) effect in the AMS fabric. Several rock-magnetism experiments performed on one specimen from each facies show that, for all units, magnetic susceptibility and fabrics are carried by magnetite grains. Most of the magnetic foliations are steeply dipping in all facies, and are roughly parallel or sub-parallel to the foliation measured in the field and in the country rocks. In contrast, the magnetic lineations present mostly low plunges for almost the whole pluton, except for one site where it is steep (> 60°). Thin section analysis show that rocks from the borders of the Anta pluton are solid-state deformed, indicating that the borders of the pluton were affected by the regional strain during its emplacement. On the other hand, the lack of solid-state deformation at outcrop scale and in thin sections precludes deformation in the central part of the pluton to be determined, where igneous textures are preserved. This evidence allows us to interpret the magnetic fabrics observed in this part of the pluton as primary in origin (magmatic) and acquired when the rocks were solidified as a result of magma flow, in which steeply plunging magnetic lineation suggests that a feeder zone could underlain this area. Our data suggest that the regional deformation partially affected the emplacement of the Anta granite.

Magnetic fabrics and microstructures of Paleoproterozoic intrusive bodies of Piedra Alta Terrane, Río de la Plata Craton, Uruguay: a reconnaissance study

Small to medium-sized intrusive bodies with ages between 2.1 and 2.0 Ga characterize Piedra Alta terrane and represent the final stabilization of Río de la Plata Craton. A reconnaissance study of petro- and magnetic fabrics based on microscopic observations, anisotropy of magnetic susceptibility and anhysteretic remanent magnetization, was carried out on 41 sites from 14 intrusive bodies, in order to obtain preliminary information on kinematics of their emplacement, degree of deformation, and regional stress regime during this magmatic event. The magnetic fabrics coupled with the microstructural analysis are interpreted as generally reflecting magma kinematics near solidus temperature, although few cases of tectonically modified fabrics at local levels have been interpreted. Field evidence and magnetic fabrics in most plutons show subvertical to high angle E-W to NE-SW trending foliations and subvertical lineations. These data suggest that plutons were probably intruded under a regional extensional to transtensional regime, which controlled the magma ascent and distribution of the intrusions. Lack of metamorphism and low to null deformation shown by the study plutons suggest a late-orogenic character for this magmatism, which has been associated with crustal stabilization after accretionary processes that led to the formation of Río de la Plata Craton in the Orosirian.

The Petrology of Gabbroids of the Anagram Islands (Wilhelm Archipelago, West Antarctica)

The Anagram Islands are located near the Graham Coast of West Antarctica not far from the Ukrainian Antarctic Station "Akademik Vernadsky". Gabbroids that are probably Cretaceous in age predominate in the geological structure of the Anagram Islands. New data on the mode of occurrence of the Anagram gabbroids and their layering were obtained during the seasonal field works of the Ukrainian Antarctic Expeditions in 2017, 2019-2020 years. Samples of the gabbroids were examined by optical microscopy, electron microscopy and microprobe analysis as well as by measuring of anisotropy of magnetic susceptibility of rocks. The goal of the research was to clarify the geological position and petrographic features of the Anagram gabbroids, to determine the typomorphic features of rock-forming minerals, and to clarify the origin of the layering in gabbroids. It was determined that the bottom part of a large layered gabbroid intrusion is fragmentarily exposed on the Anagram Islands. The continuation of the intrusion is expected in the northeastern and southeastern directions. It was established that primary magmatic textures and mineral composition are preserved in the gabbroids despite the development of metamorphic amphibolization. The gabbroids show typical cumulative textures of magmatic origin. The main cumulative phases are plagioclase (An70-95), clinopyroxene (Wo41-49En34-47), orthopyroxene (Wo2-4En49-71), olivine (Fo67-69), Ti-magnetite and ilmenite. It is proved that the fine rhythmic-gradational layering in the gabbroids was formed by gravitational precipitation of the cumulative minerals on the bottom of the magma chamber and their further sorting by specific gravity due to convection currents. Cryptic layering is firstly discovered in the Anagram gabbroids and is explained by the processes of crystallization differentiation. The latter caused the accumulation of the most calcium plagioclases and the most magnesian mafic minerals in the layered gabbroids forming the bottom part of the intrusion. The present subvertical position of layering is explained by tectonic deformation that resulted in the tilting of the investigated section of the Anagram gabbroid intrusion. This confirmed by the studying of magnetic texture of the gabbroids (by the anisotropy of magnetic susceptibility data).

Spin-Hall effect of light and its enhancement in multilevel atomic system

Using the sensitivity of atomic transitions on the polarizations of pump fields in multi-Zeeman-sublevel atomic systems, we show the polarization-direction-dependent anisotropic susceptibility of atoms that yields the strong coupling between the spin and the transverse momentum of light, i.e., spin–orbit interaction (SOI). Moreover, we also show that the spin-Hall effect of light can be obtained due to SOI. It can be controlled via the orientation of the anisotropy and frequency of light, and substantially enhanced up to several micrometers, which could be easily observed in experiment.

Anisotropic damping and wave vector dependent susceptibility of the spin fluctuations in La2−xSrxCuO4 studied by resonant inelastic x-ray scattering

We report high-resolution resonant inelastic x-ray scattering (RIXS) measurements of the collective spin fluctuations in three compositions of the superconducting cuprate system La2-xSrxCuO4. We have mapped out the excitations throughout much of the 2-D (h,k) Brillouin zone. The spin fluctuations in La2-xSrxCuO4 are found to be fairly well-described by a damped harmonic oscillator model, thus our data allows us to determine the full wavevector dependence of the damping parameter. This parameter increases with doping and is largest along the (h, h) line, where it is peaked near (0.2,0.2). We have used a new procedure to determine the absolute wavevector-dependent susceptibility for the doped compositions La2-xSrxCuO4 (x=0.12,0.16) by normalising our data to La2CuO4 measurements made with inelastic neutron scattering (INS). We find that the evolution with doping of the intensity of high-energy excitations measured by RIXS and INS is consistent. For the doped compositions, the wavevector-dependent susceptibility is much larger at (1/4,1/4) than at (1/2,0). It increases rapidly along the (h,h) line towards the antiferromagnetic wavevector of the parent compound (1/2,1/2). Thus, the strongest magnetic excitations, and those predicted to favour superconductive pairing, occur towards the (1/2,1/2) position as observed by INS.

Torque property of titanium alloy cerebral aneurysm clips in a magnetic resonance scanner.

Titanium (Ti) alloys have been introduced in magnetic resonance (MR) safe implantable medical devices because the susceptibility of Ti is approximately 1/10 that of the Co-Cr-Ni alloy (Elgiloy), which was the previously preferred MR-safe material. The torque applied to metallic materials in an MR imaging (MRI) scanner is commonly believed to increase with the susceptibility of the material. However, a visual inspection showed that the torque applied to Ti alloy cerebral aneurysm clips is comparable with that in the case of those of Elgiloy. In this study, we measured the torque applied to the small test pieces of rods and aneurysm clips quantitatively in a 3-T MRI using an accurate self-developed torque measurement apparatus. The maximum torques of Ti alloy and Elgiloy rod test pieces were comparable as 1.1 and 1.2 µN·m, respectively. The values for Ti alloy aneurysm clips were distinctly higher than the values for those of Elgiloy. These contradictory results of a larger torque for smaller-susceptibility products could be explained by our new theory, which takes into account the crystal susceptibility anisotropy in addition to the conventional torque due to the shape anisotropy.

Anisotropy of Magnetic Susceptibility (AMS) of Sediments From Holes U1480E and U1480H, IODP Expedition 362: Sedimentary or Artificial Origin and Implications for Paleomagnetic Studies

AbstractRecognition of coring‐induced disturbance, which is essential for magnetic fabric and paleomagnetic studies of poorly lithified sediments, is generally not straightforward. Here, we report on anisotropy of magnetic susceptibility (AMS) and paleomagnetic data of the sediments from Holes U1480E and U1480H, IODP Expedition 362, west of the Sumatra subduction zone. AMS is characterized by steep minimum principal axes (Kmin) in undisturbed sediments. However, a considerable portion of the recovered sediments are affected by significant coring‐induced disturbance. In these cases, we observed three AMS patterns: (1) AMS principal axes are randomly distributed for sediments with mingling and distortion of beds, (2) Kmin axes of sediments with upward‐arching beds are deflected out of the splitting face of the working half, and (3) suck‐in sediments are characterized by vertical Kmax axes. These deformation‐dependent AMS patterns can be attributed to the realignment of mineral particles caused by the coring process and subsequent sampling procedures. Besides a low‐coercivity, vertical, drilling‐induced overprint, we observed a high‐coercivity component that is likely a composite of the primary magnetization with a demagnetization‐resistant portion of the drilling overprint. After accounting for the disturbed intervals, several polarity transitions can be identified in the undisturbed sediments which correlate well with the Pleistocene geomagnetic polarity timescale. These observations demonstrate that great caution is required when attributing geological significance to AMS and paleomagnetic data obtained from soft sediment cores, which are highly susceptible to coring‐induced disturbance. In addition, AMS measurements provide a potential tool for identifying core deformation for further paleomagnetic studies.

Mineralogical control on the magnetic anisotropy of lavas and ignimbrites: a case study in the Caviahue-Copahue field (Argentina)

SUMMARY Anisotropy of magnetic susceptibility is a petrofabric tool used to estimate the alignment of minerals at the site-scale, the imbrication between the magnetic foliation and the emplacement surface being an indicator of flow direction. However, despite numerous studies examining the flow direction in pyroclastic deposits and lava flows, the effect of magnetic mineralogy and the domain state of ferromagnetic phases on the magnetic fabric remains poorly understood. This paper describes the magnetic mineralogy and its influence on the magnetic fabric of Plio-Pleistocene lava flows and ignimbrites of the Caviahue-Copahue Volcanic Complex in the Andean Southern Volcanic Zone, Argentina. Rock magnetism, anisotropy of magnetic susceptibility and anhysteretic remanent magnetization and petrographic observations were performed on 30 sites of the volcanic complex. Results revealed the extrusive and pyroclastic rocks present varied magnetic mineralogy, formed in different stages of the magmatic evolution. Magnetic mineralogy variations strongly affect the anisotropy of magnetic susceptibility data in volcanic rocks and associated ignimbrites, providing ‘scattered’ fabrics when late Ti-rich titanomagnetite phases dominate the fabric, and ‘inverse’ or ‘intermediate’ fabrics when single-domain grains are present. ‘Normal’ fabrics are typically found when early crystallized pure magnetite is present. Our results highlight the complexity in the interpretation of magnetic anisotropy data in volcanic rocks and ignimbrites.

Imaging diamagnetic susceptibility of collagen in hepatic fibrosis using susceptibility tensor imaging.

To characterize the magnetic susceptibility changes of liver fibrosis using susceptibility tensor imaging. Liver biopsy tissue samples of patients with liver fibrosis were obtained. Three-dimensional gradient-echo and diffusion-weighted images were acquired at 9.4 T. Susceptibility tensors of the samples were calculated using the gradient-echo phase signal acquired at 12 different orientations relative to the B0 field. Susceptibility anisotropy of the liver collagen fibers was quantified and compared with diffusion anisotropy, measured by DTI. For validation, a comparison was made to histology including hematoxylin and eosin staining, iron staining, and Masson's trichrome staining. Areas with strong diamagnetic susceptibility were observed in the tissue samples forming fibrous patterns. This diamagnetic susceptibility was highly anisotropic. Both the mean magnetic susceptibility and susceptibility anisotropy of collagen fibers exhibited a strong contrast against the surrounding nonfibrotic tissues. The same regions also showed an elevated diffusion anisotropy but with much lower tissue contrast. Masson's trichrome staining identified concentrated collagens in the fibrous regions with high susceptibility anisotropy, and a linear correlation was found between the susceptibility anisotropy and the histology-based staging. Diamagnetic susceptibility indicates the presence of collagen in the fibrotic liver tissues. Mapping magnetic susceptibility anisotropy may serve as a potential marker to quantify collagen fiber changes in patients with liver fibrosis.

Competing Electronic Phases near the Onset of Superconductivity in Hole-doped SrFe2As2

An intriguingly complex phase diagram of Na-doped SrFe2As2 is uncovered using high-resolution thermal-expansion, magnetization and heat-capacity measurements. The detailed temperature dependence of the orthorhombic distortion and the anisotropy of the uniform magnetic susceptibility provide evidence for nine distinct electronic phases near the transition region between stripe antiferromagnetism and unconventional superconductivity. In particular, we report the finding of a new magnetic phase which competes surprisingly strongly with superconductivity. From theoretical studies we propose that this phase is a double-Q phase consisting of a mixture of symmetry-distinct commensurate magnetic orders with a peculiar temperature-dependent magnetic moment reorientation.

Magnetic and electrical anisotropy with correlation and orbital effects in dimerized honeycomb ruthenate Li2RuO3

Li2RuO3 undergoes a structural transition at a relatively high temperature of 550 K with a distinct dimerization of Ru-Ru bonds on the otherwise isotropic honeycomb lattice. It exhibits a unique herringbone dimerization pattern with a largest ever reported value of the bond shrinkage of about ~ 0.5 \r{A}. Despite extensive studies, both theoretical and experimental, however, its origin and its effect on physical properties still remain to be understood. In this work, using high quality single crystals we investigated the anisotropy of resistivity ($\rho$) and magnetic susceptibility ($\chi$) to find a very clear anisotropy: $\rho$$_c*$ > $\rho$$_b$ > $\rho$$_a$ and $\chi$$_b$ > $\chi$$_a$ > $\chi$$_c*$. For possible theoretical interpretations, we carried out density functional calculations to conclude that these anisotropic behavior is due to the correlation effects combined with the unique orbital structure and the dimerization of Ru 4d bands.

In situ solid-state NMR of a magnetically oriented microcrystal suspension.

In situ solid-state NMR measurements of a magnetically oriented microcrystal suspension (MOMS) were demonstrated. Under modulated rotation of the static field, or equivalently, of the sample tube, randomly oriented microcrystals in a viscous liquid medium feel a torque arising from the anisotropic bulk susceptibility and eventually aligned in the same direction. In this way, a three-dimensional MOMS (3D-MOMS) was obtained. To apply an elliptically rotating magnetic field to microcrystals in suspension, a probe to rotate the sample tube around an axis perpendicular to the static magnetic field was developed. Single-crystal (SC) rotation patterns were obtained from the 3D-MOMS by solid-state CP measurements triggered in synchronous with the sample-tube rotation. Unlike the traditional SC method, the 3D-MOMS approach presented here does not require the elaborate adjustment of the direction of the reference frame. The process of three-dimensional magnetic alignment was also studied by monitoring the spectral changes during continuous application of the modulated sample rotation.

Distinguishing the Mélange-Forming Processes in Subduction-Accretion Complexes: Constraints from the Anisotropy of Magnetic Susceptibility (AMS)

The strong morphological similitude of the block-in-matrix fabric of chaotic rock units (mélanges and broken formations) makes problematic the recognition of their primary forming-processes. We present results of the comparison between magnetic fabric and mesoscale structural investigations of non-metamorphic tectonic, sedimentary, and polygenetic mélanges in the exhumed Late Cretaceous to early Eocene Ligurian accretionary complex and overlying wedge-top basin succession in the Northern Apennines (northwest Italy). Our findings show that the magnetic fabric reveals diagnostic configurations of principal anisotropy of magnetic susceptibility (AMS) axes orientation that are well comparable with the mesoscale block-in-matrix fabric of mélanges formed by different processes. Broken formations and tectonic mélanges show prolate and neutral-to-oblate ellipsoids, respectively, with magnetic fabric elements being consistent with those of the mesoscale anisotropic “structurally ordered” block-in-matrix fabric. Sedimentary mélanges show an oblate ellipsoid with a clear sedimentary magnetic fabric related to downslope gravitational emplacement. Polygenetic mélanges show the occurrence of a cumulative depositional and tectonic magnetic fabric. The comparison of field and laboratory investigations validate the analysis of magnetic features as a diagnostic tool suitable to analytically distinguish the contribution of different mélange forming-processes and their mutual superposition, and to better understand the geodynamic evolution of subduction-accretion complexes.

Quantitative Susceptibility Mapping of Magnetic Quadrupole Moments

We modeled the magnetic field up to the quadrupole term to investigate not only the average susceptibility (dipole), but also the susceptibility distribution (quadrupole) contribution. Expanding the magnetic field up to the 2nd order provides the quadrupole (0th: monopole, 1st: dipole). Numerical simulations were performed to investigate the quadrupole contribution with subvoxel nonuniformity. Conventional dipole and our dipole + quadrupole models were compared in the simulation, the phantom and human brain. Furthermore, the quadrupole field was compared with the anisotropic susceptibility field in the dipole tensor model. In a nonuniformity case, numerical simulations showed a nonnegligible quadrupole field contribution. Our study showed a difference between the two methods in the susceptibility map at the edges; both the phantom and human studies showed sharper structural edges with the dipole + quadrupole model. Quadrupole moments showed contrast mainly at the structural boundaries. The quadrupole moment field contribution was smaller but nonnegligible compared to the anisotropic susceptibility contribution. Nonuniform and uniform source distributions can be separately considered by quadrupole expansion, which were mixed together in the dipole model. In the presence of nonuniformity, the susceptibility maps may be different between the two models. For a comprehensive field model, the quadrupole might need to be considered along with susceptibility anisotropy and microstructure effects.

Measurements Combination of Elastic Anisotropy and Anisotropy of Magnetic Susceptibility on Case Study in Igneous Rock of Lava Flow Type from Ijen Volcanic Complex, East Java

Research about the anisotropy parameters of rock is important for geophysical investigations. This research was a preliminary study which aims to find the relationship between elastic anisotropy and anisotropy of magnetic susceptibility in igneous rock of lava flow type with MR1 code and to interpret preferred orientation in MR1 sample based on the integration of anisotropy measurement results with the supported results from micro-computed tomography (μCT) analysis, petrography analysis and geological data analysis. This research has never been done before. This study was divided into several main stages consist of elastic anisotropy measurements on a cube-shaped specimen to determine the direction of maximum velocity and elastic anisotropy parameter values, anisotropy of magnetic susceptibility measurements on six cylindrical specimens to determine the direction of maximum susceptibility (magnetic mineral orientation) and AMS parameter values, petrography analysis on the all sides of the cube in order to observe preferred orientation in mineral and μCT analysis in a cylindrical specimen to determine the pore trend of rock. This study showed the relationship between AMS and elastic anisotropy in MR1 sample which indicated by positive correlation between the direction of maximum susceptibility and maximum velocity. Based on the results, MR1 sample has elastic anisotropy degree ranges from 2,6 % - 6,6 % for P waves and 2,2 % - 4 % for S waves and anisotropy of magnetic susceptibility degree around 2,6 % - 5,4 %. The integration of all measurement results including the direction of maximum velocity, direction of maximum susceptibility, preferred orientation in mineral, pore trend, and dip direction of sheeting joint indicate preferred orientation in MR1 sample towards NE-SW. One possible cause of such preferred orientation is the direction of the lava flow. Further studies in this topic are needed to support this hypothesis.

Progressive Growth of the Cerro Bayo Cryptodome, Chachahuén Volcano, Argentina—Implications for Viscous Magma Emplacement

AbstractCryptodome and dome collapse is associated with volcanic hazards, such as explosive eruptions, pyroclastic density currents, and volcanic edifice collapse. The study of the growth and evolution of volcanic domes provides vital information on the link between dome growth and the development of weakness zones that may cause collapse. The Cerro Bayo cryptodome is superbly exposed in the eroded Miocene Chachahuén volcano in the Neuquén basin, Argentina. Cerro Bayo is a >0.3‐km3 trachyandesitic cryptodome that intruded within the uppermost kilometer of the Chachahuén volcano. Here we investigate the emplacement of the Cerro Bayo cryptodome using structural mapping, photogrammetry and measurement of magma flow indicators, brittle deformation features, and magnetic fabrics with anisotropy of magnetic susceptibility. Magma flow fabrics near the margin are concentric and indicate contact‐parallel flow and internal inflation of the body. Magmatic and magnetic fabrics and fracture patterns in the interior of the cryptodome are more complex and outline several structural domains. These domains are separated by magmatic shear zones that accommodated intrusion growth. The shear zones locally overprint the earlier formed concentric fabric. The nature of the structural domains shows that the emplacement of Cerro Bayo occurred in three stages that resemble the endogenous to exogenous growth of volcanic domes. The formation of magmatic shear zones during cryptodome formation may have a profound effect on cryptodome stability by creating weakness zones that increase the risk of collapse.

Diagonal nematicity in the pseudogap phase of HgBa2CuO4+\u03b4

The pseudogap phenomenon in the cuprates is arguably the most mysterious puzzle in the field of high-temperature superconductivity. The tetragonal cuprate HgBa2CuO4+δ, with only one CuO2 layer per primitive cell, is an ideal system to tackle this puzzle. Here, we measure the magnetic susceptibility anisotropy within the CuO2 plane with exceptionally high-precision magnetic torque experiments. Our key finding is that a distinct two-fold in-plane anisotropy sets in below the pseudogap temperature T*, which provides thermodynamic evidence for a nematic phase transition with broken four-fold symmetry. Surprisingly, the nematic director orients along the diagonal direction of the CuO2 square lattice, in sharp contrast to the bond nematicity along the Cu-O-Cu direction. Another remarkable feature is that the enhancement of the diagonal nematicity with decreasing temperature is suppressed around the temperature at which short-range charge-density-wave formation occurs. Our result suggests a competing relationship between diagonal nematic and charge-density-wave order in HgBa2CuO4+δ.

Anisotropy of magnetic susceptibility in salt rocks from the German Zechstein Basin, Sondershausen mine

SUMMARY The anisotropy of magnetic susceptibility (AMS) of rocks reflects the alignment of certain minerals, and therefore it can be used to investigate the deformation history of rocks. However, for salt rocks, very few studies on the AMS of salt rocks and the influence of accessory minerals exist. In this study, we analysed the potential to use the AMS of salt rocks with low impurity content for fabric characterization. Samples of rock salt, sylvinite and carnallitite from a salt mine in Sondershausen (Germany) from the Late Permian (Zechstein 2, Stassfurt series) are investigated. The results of low-field AMS (LF-AMS) measurements show a very weak but significant magnetic anisotropy for sylvinite, carnallitite, and rock salt with an elevated content of accessory minerals. The AMS results are consistent in individual layers of the same rock type. In order to identify the magnetic minerals, which cause the magnetic anisotropy, the high-field AMS (HF-AMS) was measured using a torque magnetometer in order to separate ferrimagnetic and paramagnetic contributions to the AMS. A significant paramagnetic subfabrics exists, which reflects the alignment of phyllosilicates. The magnitude of the LF-AMS is considerably greater than that of the paramagnetic subfabric. This indicates the existence of a ferrimagnetic subfabric due to magnetite, which can have a different orientation than the paramagnetic subfabric. Differences in the orientation of the AMS in samples from two sites suggest a relationship of deformation history and AMS. At a site with dipping layers, the AMS orientation is independent of the bedding and shows large differences between individual lithological layers. In a tight fold, the AMS of all rock types has similar shape and orientation. We conclude that AMS in salt rocks can give meaningful information on the mineral fabric, which could be used in the analysis of the deformation history.

Anisotropy of Magnetic Susceptibility and Preferred Pore Orientation in Lava Flow from the Ijen Volcanic Complex, East Java, Indonesia

Anisotropy of magnetic susceptibility (AMS) has been used in various studies related to interpreting the direction of lava flow, some of which have shown ambiguity with regard to the data generated. In this study, we explored an alternative option to support the aforementioned application, using lava flow type igneous rock samples from the Ijen Volcanic Complex, East Java, Indonesia. We have investigated the preferred rock pore orientations from micro-computed tomography (μCT) images and quantified their directions. We then calculated their correlation with AMS data by calculating the angle between preferred pore orientation. The axis with the smallest gap to the preferred pore orientation of each sample was assumed to imply lava flow direction. Different lava flow direction preferences were obtained from different magnetic ellipsoids. Another important factor for consideration is the relative vertical position of the sampling site within a single lava flow unit. Only one out of five samples (ANY2) show good quantitative conformity between AMS data, preferred pore orientation, and topographical slope, despite these limitations. Our results point to a direction that seems to be correct and coherent on a physical basis. Additional research would likely clarify the issues involved. This encourages us to explore and work further in this field of research.

A New Class of Lanthanide Complexes with Three Ligand Centered Radicals: NMR Evaluation of Ligand Field Energy Splitting and Magnetic Coupling.

Combination of three radical anionic Ph-BIAN ligands (Ph-BIAN=bis-(phenylimino)-acenaphthenequinone) with lanthanoid ions leads to a series of homoleptic, six-coordinate complexes of the type Ln(Ph-BIAN)3 . Magnetic coupling data were measured by paramagnetic solution NMR spectroscopy. Combining 1 H NMR with 2 H NMR of partially deuterated compounds allowed a detailed study of the magnetic susceptibility anisotropies over a large temperature range. The observed chemical shifts were separated into ligand- and metal-centered contributions by comparison with the Y analogue (diamagnetic at the metal). The metal-centered contributions of the complexes with the paramagnetic ions could then be separated into pseudocontact and Fermi contact shifts. The latter is large within the Ph-BIAN scaffold, which shows that magnetic coupling is significant between the lanthanide ion and the radical ligand. Pseudocontact shifts were further correlated to structural data obtained from X-ray diffraction experiments. Ligand-field parameters were determined by fitting the temperature dependence of the observed magnetic susceptibility anisotropies. The electronic structure determined by this approach shows, that the Er and Tm analogues are candidates for single molecule magnets (SMM). These results demonstrate the possibilities for the application of NMR spectroscopy in investigations of paramagnetic systems in general and single molecule magnets in particular.