Anisotropic Surface Research Articles

Instability analysis for MHD boundary layer flow of nanofluid over a rotating disk with anisotropic and isotropic roughness

The study focuses on the instability of local linear convective flow in an incompressible boundary layer caused by a rough rotating disk in a steady MHD flow of viscous nanofluid. Miklavčič and Wang's (Miklavčič and Wang, 2004) [9] MW roughness model are utilized in the presence of MHD of Cu-water nanofluid with enforcement of axial flows. This study will investigate the instability characteristics with the MHD boundary layer flow of nanofluid over a rotating disk and incorporate the effects of axial flow with anisotropic and isotropic surface roughness. The resulting ordinary differential equations (ODEs) are obtained by using von Kàrmàn (Kármán, 1921) [3] similarity transformation on partial differential equations (PDEs). Subsequently, numerical solutions are obtained using the shooting method, specifically the Runge-Kutta technique. Steady-flow profiles for MHD and volume fractions of nanoparticles are analyzed by the partial-slip conditions with surface roughness. Convective instability for stationary modes and neutral stability curves are also obtained and investigated by the formulation of linear stability equations with the MHD of nanofluid. Linear convective growth rates are utilized to analyze the stability of magnetic fields and nanoparticles and to confirm the outcomes of this analysis. Stationary disturbances are also considered in the energy analysis. The investigation indicates the correlation between instability modes Type I and Type II, in the presence of MHD, nanoparticles, and the growth rates of the critical Reynolds number. An integral energy equation enhances comprehension of the fundamental physical mechanisms. The factors contributing to convective instability in the system are clarified using this approach.

Роботизация в авиастроении

Some cses of robotized systems and complexes (RS and RC) in the aircraft industry are considered. A robotic cell for resistance spot welding is viewed, the main components of which are an industrial robot (IR), welding guns, a linear displacement module of IR, an inverting unit. Here the IR performs welding, it is equipped with welding guns as a hand. An inverting unit equipped with a stepper motor rotates the panel around the axis and sets the part to be welded within the whole welding process. The movement of the IR is also carried out due to the linear displacement module. The robotization of harnesses production is viewed, using automatic lofts and collaborative robots, which, moving along specialized lofts, with the help of a linear displacement module, install holders on the loft and ties wires into harnesses. After the operation is completed, made-up harness is put into a storage hopper. A robotized complex (RC) for manufacturing parts of the «rib» type is studied. It includes a machine equipped with a vacuum gripper, technological equipment, consisting of a cutting machine and a bending press. The technological process has two stages: cutting and bending. The cut blanks are blown out of the press onto the receiving tray. The IR performs feeding of blanks into the working area of the technological equipment and laying in the appropriate storage unit. 3D models of robotized sites are presented, their components are listed. In conclusion, the importance of analyzing the process operation is proved, when the feasibility of robotization is evident. An algorithm for analyzing the process operation is presented. It has been understood that the introduction of robotics in certain technological processes reduces the impact of hazardous production factors.

Structural and magnetic properties of Ni cluster embedded (111)NiO layers grown on (0001)GaN films

(111) NiO epitaxial layers embedded with crystallographically oriented Ni-clusters are grown on c-GaN/Sapphire templates using the pulsed laser deposition technique. Structural and magnetic properties of the films are examined by a variety of techniques including high-resolution x-ray diffraction, precession-electron diffraction, and superconducting quantum interference device magnetometry. It has been found that Ni-clusters are formed in the NiO matrix only at sufficiently low oxygen pressures during the growth. The study further reveals that the orientation, shape, size, density, and magnetic properties of these clusters depend strongly on the growth temperature (TG). Although most of the Ni-clusters are found to be obtained crystallographically aligned with the NiO matrix with Ni(111) ∥NiO(111), clusters with other orientations also exist, especially in samples grown at lower temperatures. The average size and density of the clusters increase with TG. The proportion of the Ni(111) ∥ NiO(111)-oriented clusters also improves as TG is increased. All cluster embedded films show ferromagnetic behavior even at room temperature. Easy-axis is found to be oriented in the layer plane in samples grown at relatively lower temperatures. However, it turns perpendicular to the layer plane for samples grown at sufficiently high temperatures. This reversal of easy-axis has been attributed to the size dependent competition between the shape and magnetoelastic and the surface anisotropies of the clusters. This composite material thus has great potential to serve as a spin-injector and spin-storage medium in GaN-based spintronics of the future.

Unified modeling for clay and sand with a hybrid-driven fabric evolution law

This paper presents a novel critical state model for both clay and sand considering the inherent and induced anisotropy, named as CASM-h. The CASM-h model is developed based on the well-calibrated CASM model and incorporates the concepts of subloading surface and fabric anisotropy. To describe the induced anisotropy, a hybrid-driven fabric evolution law is proposed, defining fabric evolution as driven jointly by stress and strain rates. Subsequently, the fabric tensor together with its evolution law is appropriately incorporated into constitutive relation by employing the anisotropic transformed stress approach, without introducing additional mechanical mechanisms. The CASM-h model is validated under a series of stress paths, including triaxial tests, simple shear tests, shear tests with fixed principal stress direction as well as principal stress rotation (PSR) tests. The simulation results show that CASM-h model can satisfactorily capture the anisotropic behaviours of both clay and sand, such as the loading direction dependency of strength, non-coaxial behaviour, PSR effects and so on.

Describing inherently anisotropic behaviours of natural clay by a hypoplastic model

The purpose of this paper is to model the loading direction‐dependent behaviours of inherently anisotropic intact clay by means of the hypoplastic framework. The basic hypoplastic model for clays proposed by Mašín (2013) is enhanced by incorporating a predefined anisotropic asymptotic state boundary surface formulation which is based on an anisotropic variable by projecting the microstructure tensor onto the normal of the spatially mobilized plane. The capability of the proposed hypoplastic model is first illustrated by simulations of intact Wenzhou soft clay under drained torsional shear tests using the hollow cylinder apparatus. The model is then used to predict undrained shear results on San Francisco Bay mud. Comparisons between the predicted and measured results demonstrate that the proposed hypoplastic model is capable of modelling the combined effect of the principal stress direction and intermediate principal stress on the stress‐strain behaviour of natural soft clay with inherent anisotropy.

Solution of planar elastic stress problems using stress basis functions

The use of global displacement basis functions to solve boundary-value problems in linear elasticity is well established. No prior work uses a global stress tensor basis for such solutions. We present two such methods for solving stress problems in linear elasticity. In both methods, we split the sought stress σ into two parts, where neither part is required to satisfy strain compatibility. The first part, σ p , is any stress in equilibrium with the loading. The second part, σ h is a self-equilibrated stress field on the unloaded body. In both methods, σ h is expanded using tensor-valued global stress basis functions developed elsewhere. In the first method, the coefficients in the expansion are found by minimizing the strain energy based on the well-known complementary energy principle. For the second method, which is restricted to planar homogeneous isotropic bodies, we show that we merely need to minimize the squared L2 norm of the trace of stress. For demonstration, we solve nine stress problems involving sharp corners, multiple-connectedness, non-zero net force and/or moment on an internal hole, body force, discontinuous surface traction, material inhomogeneity, and anisotropy. The first method presents a new application of a known principle. The second method presents a hitherto unreported principle, to the best of our knowledge.

Crystal Facet Engineering on SrTiO3 Enhances Photocatalytic Overall Water Splitting.

Single-crystal semiconductor-based photocatalysts exposing unique crystallographic facets show promising applications in energy and environmental technologies; however, crystal facet engineering through solid-state synthesis for photocatalytic overall water splitting is still challenging. Herein, we develop a novel crystal facet engineering strategy through solid-state recrystallization to synthesize uniform SrTiO3 single crystals exposing tailored {111} facets. The presynthesized low-crystalline SrTiO3 precursors enable the formation of well-defined single crystals through kinetically improved crystal structure transformation during solid-state recrystallization process. By employing subtle Al3+ ions as surface morphology modulators, the crystal surface orientation can be precisely tuned to a controlled percentage of {111} facets. The photocatalytic overall water splitting activity increases with the exposure percentage of {111} facets. Owing to the outstanding crystallinity and favorable anisotropic surface structure, the SrTiO3 single crystals with 36.6% of {111} facets lead to a 3-fold enhancement of photocatalytic hydrogen evolution rates up to 1.55 mmol·h-1 in a stoichiometric ratio of 2:1 than thermodynamically stable SrTiO3 enclosed with isotropic {100} facets.

Influence of chloride salt erosion on the adhesion of asphalt-aggregate interfaces considering mineral anisotropy: insights from molecular dynamics.

Asphalt, a polymer mixture composed of various hydrocarbons, is extensively utilized due to its excellent performance. To evaluate the sensitivity of asphalt concrete to chloride salt damage at the nanoscale, considering the anisotropy of aggregate mineral crystal orientation, molecular dynamic simulations were employed to model the interface interactions between asphalt and aggregate mineral components (silica and calcite) under chloride salt exposure. The wetting processes of water droplets and chloride salt droplets on different crystal surfaces of silica and calcite were analyzed. Furthermore, the adhesive energy, decohesion energy, degradation ratio, and energy ratio of the interaction model between asphalt and aggregate mineral interfaces were analyzed to reveal the variations in the interfaces between the two components. The results demonstrated that the anisotropy of the minerals significantly affects the adhesion energy of asphalt and aggregate. Moreover, the surface hydrophilicity of calcite was larger than that of silica. The interfacial adhesion energy of asphalt-calcite was larger than that of asphalt-silica under dry condition and chloride salt attack, and the interfacial adhesion energy of both asphalt and mineral decreased with the increase of chloride salt concentration. The degradation ratio and energy ratio values of asphalt and calcite were larger than those of asphalt and silica, and the anisotropy of the mineral surface affected the degradation ratio and energy ratio values. This study provides a new method and theoretical basis for further research on the damage mechanism and strengthening measures of asphalt-aggregate under chloride salt attack. To investigate the interaction between asphalt and mineral aggregates under chloride salt erosion, models of asphalt, aggregate, and asphalt/aggregate composite systems were constructed using the Amorphous Cell module in Materials Studio 2020 software. Molecular dynamic simulations of the asphalt/aggregate composite system were then conducted using the Forcite module, employing the COMPASS II force field to describe atomic and molecular interactions. Initially, considering the crystal orientation and surface configuration of the aggregate minerals, the impact of mineral anisotropy on the asphalt-aggregate interface model was analyzed. Subsequently, by simulating the contact states of nano water droplets and chloride salt droplets with different mineral surfaces, the wetting characteristics of nano water droplets on silica and calcite surfaces were determined. Lastly, considering the corrosion effect of chloride solution at different concentrations, the adhesion energy, debonding energy, degradation ratio, and energy ratio of the asphalt-aggregate interface interaction model were analyzed.

Anisotropic yielding model of lattice material and influencing factors

Experiments and numerical simulations were used to study and analyze the anisotropy of lattice materials, and the elastic-plastic properties of lattice materials were obtained. The equivalent continuum hypothesis was used to approximate the lattice material as a homogeneous continuous orthotropic material. The relevant equivalent yield parameters and plastic yield surfaces of the lattice materials were calculated using the Hill yield criterion. Comparisons of numerical simulations and experimental data show that they match very well. The effect of strut radius on anisotropic yield property and yield surface of lattice material was investigated.

Influence of Fe3+ substitution by Al3+ on the structural, microstructural, and magnetic properties of Co0.2Ni0.3Zn0.5Fe2O4 nanoparticles

A series of aluminum-substituted ferrite nanoparticles, Co0.2Ni0.3Zn0.5Fe2-xAlxO4 (0 ≤ x ≤ 1) was synthesized using the polyol method. The structural analysis confirmed the formation of pure cubic ferrispinels. The unit cell parameter decreased monotonically with increasing Al3+ content obeying Vegard's law. Besides, it was found that Al3+ ions prefer to enter octahedral sites. The produced particles consisted of roughly spherical ultrasmall nanocrystals with an average particle size of ∼3-6 nm. The nanoparticles are superparamagnetic with magnetic features (blocking temperature, saturation magnetization and Curie temperature) showing a decrease with the increase in Al3+ content. The magnetic tendency correlates with the weakening of the superexchange interactions in the spinel sublattices caused by substituting the non-magnetic Al3+ ions for Fe3+ ones. While, the coercivity and effective magnetic anisotropy increased with the increase of Al3+ concentration, suggesting the development of high surface anisotropy that largely compensates for the decrease of intrinsic magnetic anisotropy caused by the magnetic dilution.

Continuum contact model for friction between graphene sheets that accounts for surface anisotropy and curvature

Continuum contact model for friction between graphene sheets that accounts for surface anisotropy and curvature

Signature of surface anisotropy in the spin-flip neutron scattering cross section of spherical nanoparticles: Atomistic simulations and analytical theory

Signature of surface anisotropy in the spin-flip neutron scattering cross section of spherical nanoparticles: Atomistic simulations and analytical theory

A Multiscale Method to Develop Three-Dimensional Anisotropic Constitutive Model for Soils

A multiscale method is presented to develop a constitutive model for anisotropic soils in a three-dimensional (3D) stress state. A fabric tensor and its evolution, which quantify the particle arrangement at the microscale, are adopted to describe the effects of the inherent and induced anisotropy on the mechanical behaviors at the macroscale. Using two steps of stress mapping, the deformation and failure of anisotropic soil under the 3D stress state are equivalent to those of isotropic soil under the triaxial compression stress state. A series of discrete element method (DEM) simulations are conducted to preliminarily verify this equivalence. Based on the above method, the obtained anisotropic yield surface is continuous and smooth. Then, a fabric evolution law is established according to the DEM simulation results. Compared with the rotational hardening law, the fabric evolution law can also make the yield surface rotate during the loading process, and it can grasp the microscopic mechanism of soil deformation. As an example, an anisotropic modified Cam-clay model is developed, and its performance validates the ability of the proposed method to account for the effect of soil anisotropy.

Investigation on the atomic level removal mechanism of diamond with intrinsically anisotropic surface

Herein, the atomic level material removal mechanisms of single-crystal diamond (SCD) (001), (1-10), and (111) planes were investigated through a combination of atomic force microscopy (AFM) scratching experiments and molecular dynamics (MD) simulations. The results showed that the "soft" directions on the planes of (001) was <100>, the (1-10) was <001>, and the (111) were [11-2], [1-21], and [-211]. These directions exhibited the highest scratching force/depth and the largest quantity of amorphous atoms. We found that the scratching force would lead to the amorphization of the diamond surface atoms during the scratching process, which would facilitate the removal of the surface material. These intriguing findings would provide a theoretical basis for further improving the surface quality of superhard materials.

An anisotropic PRS for squinting the radiation pattern with gain improvement of MIMO system

This work presents the design and analysis of a new anisotropic Partial Reflective Surface (PRS) to address beam squinting as well as gain improvement, using the phase gradient property of periodic structure in a 3-port Multiple Input Multiple Output (MIMO) system. An angular tilt of 30° is obtained relative to the boresight direction by manipulating the transmission properties. Additionally, the gain is improved by utilizing a homogenous PRS. Gradation constant is realized by changing the radius of adjacent unit cells in a dielectric host structure, ensuring a continuous variation in PRS properties. The formation of a Fabry-Perot antenna reduces the overlap between the adjacent beams, improving field correlation and isolation performance, in addition to gain enhancement. Furthermore, two 1 × 5 absorbers are strategically placed between the radiating elements to minimize the surface currents and achieve high port isolation. This combination of PRS and absorber leads to reduced field-to-field coupling and port-to-port coupling, thus achieving high signal isolation and beam squinting accuracy. The effectiveness of the proposed approach is validated through simulations, which are further supported by an equivalent circuit model. Experimental validation is also conducted to verify the results obtained.

Why do metals become superhydrophilic during nanosecond laser processing? Design of superhydrophilic, anisotropic and biphilic surfaces

This research investigates the impact of the surrounding environment on the characteristics of copper, nickel and tin during nanosecond laser processing. By comparing the results of processes conducted in vacuum and air, we conclude that changes in wetting properties cannot be solely attributed to development of surface microstructure. To elucidate this phenomenon, we conducted model experiments using a tin target. Laser processing parameters for the tin target were established, involving deep cavity melting without ablation, resulting in highly evolved material morphology. Under these conditions, laser processing in air did not lead to metal hydrophilization. Therefore, our study demonstrates that the primary cause of changes in material wetting properties during nanosecond laser processing is the re-deposition of ablation products onto the material surface. These products form a nanoporous layer that enhances wicking capabilities and subsequently serves as a sorbent for various impurities, gradually leading to the hydrophobization of most commonly used materials. The proposed mechanism opens the possibility for the development of new methods to create materials with biphilic and anisotropic wetting properties. The key insight lies in the control of the thickness of the nanoporous layer, as it emerges as a pivotal factor dictating wettability properties and wicking capability.

Anisotropic 3D rough surface reconstruction model based on fractal method and its application in contact characteristics

Anisotropic 3D rough surface reconstruction model based on fractal method and its application in contact characteristics

Electromagnetic guided waves in composite liquid crystal-based interfaces

We study an air–crown glass planar interface that includes a thin layer of a cholesteric liquid crystal doped with silver spheres of nanometer size. We propose a new theoretical model for the propagation of electromagnetic waves through the liquid crystal part and use the Marcuvitz–Schwinger form of the Maxwell equations to compute guided surface wave profiles. The results suggest the presence of anisotropic surface modes with negligible attenuation. The dependence of the surface wave parameters on the liquid crystal layer parameters can be used in liquid crystal-based sensors.

An Anisotropic Side Contact Model Based on the Peak Description Method of Surface Profile

Abstract In contact models, traditional profile description methods are based on all sampling points of the profile. The methods can only describe the features in the height direction of profile, but are difficult to describe the profile features perpendicular to the height direction, which is the main obstacle to side contact modeling. In this paper, a profile description method based on peaks is proposed, which enables the profile features perpendicular to the height direction of the profile to be expressed. The statistical distribution law of the horizontal distances perpendicular to the height direction of the profile between adjacent asperities on anisotropic contact surfaces is investigated for the first time, and it is found that the distribution of the horizontal distances is very close to the normal distribution, but the values are different in different texture directions. The distribution law of the height differences between adjacent asperities is also investigated and is found to be close to a normal distribution, but the numerical values are different from the normal distribution of profile heights. Based on the results, the distribution function of the contact angle widely used in side contact model is replaced, and a new side contact model is proposed. By the model, the effects of the statistical parameters of surface profile and the material parameters of surfaces on the surface contact characteristics are investigated. The results of investigation show that the effect of the standard deviations of the horizontal distances between asperities in different texture directions on the normal contact stiffness between surfaces is obvious, and the normal contact stiffness will decrease with the increase of the standard deviation of the horizontal distances in any direction.

Angular Engineering Strategy for Enhanced Surface Nonlinear Frequency Conversion in Centrosymmetric Topological Semimetal HfGe0.92Te.

Surface nonlinear optics are essential for developments in integrated photonics and micro/nano optoelectronics. However, the nonlinear optical conversion efficiency on a surface is restricted by the finite nonlinear susceptibility of matter and the intrinsic atomic-layered interaction length between light and matter. In this work, based on an angular engineering strategy, it is demonstrated that the centrosymmetric topological semimetal HfGe0.92Te crystal has a giant and anisotropic surface second-order nonlinear susceptibility up to 5535 ± 308pm V-1 and exhibits efficient and unprecedented second-harmonic generation (SHG). The maximum optical conversion efficiency is found to be up to 3.75‰, which is 104 times higher than that obtained from a silicon surface. Because of the linear dispersion over a wide range of energies around the Dirac points, this high conversion efficiency can be maintained with SHG wavelengths ranging from the visible region (779nm) to the deep-UV region (257.5nm). This study can facilitate the development of topological photonics and integrated nonlinear photonics based on topological semimetals.