ABSTRACT Emulsified asphalt finds extensive application in pavement repair, addressing issues like road ruts and cracks. While the adsorption behaviour of emulsifiers on oxide surfaces (CaCO3 and SiO2) of aggregates is influenced by the presence of phenyl functional groups, the precise mechanism of this influence remains insufficiently understood. This study employs molecular dynamics models and macroscopic experiments to investigate the mechanism involving emulsifiers, sodium ions, and water at aggregate interfaces, quantifying the role of phenyl functional groups from a molecular perspective. The results reveal the following: strong electrostatic attraction between alkaline aggregates and Na+, leading to substantial Na+ adsorption. The phenyl functional groups reduce diffusion coefficient, adsorption energy, and amounts in alkaline aggregates (−34.6%, −16%, −12.5%), while increasing them in acidic aggregates (+15.9%, + 14.7%, + 27.7%). The phenyl functional groups impact hydrogen bond acceptors, TPSA, and emulsifier complexity, altering adsorption. They enhance emulsifier electrostatic potential, affecting adsorption on different surfaces. In summary, this ongoing research framework aims to fine-tune emulsifiers through the use of phenyl functional groups, enhancing adsorption strength, adsorption amount, and diffusion between emulsifiers and aggregates. This work holds great significance for optimizing emulsifier molecular structures.