In this paper, we utilize the potential offered by multidimensional separable states (MSS) for secure and simultaneous distributions of keys in a layered network. We present protocols for both quantum and semi-quantum key distribution and discuss their robustness against various eavesdropping strategies. We provide a procedure to identify the requisite resource states to generalize these protocols for arbitrary layered networks. Finally, we study the interrelation between the local dimensionalities of states and achievable key rates in a given layer. These proposals are realizable with current technology, thanks to the employment of MSS and many advances in the generation, manipulation, and measurement of higher-dimensional orbital angular momentum states of light.