In this paper the spectra of Gd3+ ions studied by electron spin resonance (ESR) in four types of tungstate crystals KY(WO4)2, CdWO4, CsLa(WO4)2 and La2(WO4)3 are discussed. The tungstate crystals were grown by the low-temperature gradient Czochralski technique with Gd2O3 addition in melt. The estimation of spin Hamiltonian (SH) parameters was realized using an original simulation program developed. The parameters of crystalline field in oxide crystals are comparable with Zeeman interaction so the solution of the Schrodinger equation was realized numerically. We have estimated 36 SH parameters from ESR angular diagrams of Gd3+, including gx, gy, gz, gi (where i = 1, …, 6), Bmn, Cmn (where m = 2, …, 6, n = 0 (or 1 for Cmn), …, m), and the Euler angles. The positions of Gd3+ ions in the crystal structures, the charge compensation and the influence of lattice parameters on the SH parameters B20 and B22 are discussed in this paper as well.
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