Angle-resolved Photoelectron Spectra Research Articles

Femtosecond laser-induced ultrafast electron dynamics and band gap renormalization in InSb

Femtosecond laser-induced ultrafast electron dynamics and band gap renormalization in InSb

Electronic Structures of Small Stoichiometric ZnxOx Clusters.

Stoichiometric ZnxOx clusters in the subnanometer size regime have been the topic of several computational and mass spectrometry studies that showed the particular stability of the stoichiometric species relative to nonstoichiometric species (ZnxOy, x ≠ y). In the current study, we present the angle-resolved anion photoelectron (PE) spectra of stoichiometric ZnxOx-clusters (2 ≤ x ≤ 5), which are interpreted with supporting computational studies that include natural orbital ionization calculations on detachment transition cross sections. All spectra show evidence of Dxh ring structures, which had been predicted to be the most stable structures in previous computational studies. However, a new lowest energy isomer is reported for the Zn2O2 anion and neutral, a bent chain, which is readily reconciled with the most intense feature in the Zn2O2- PE spectrum. The computed PE angular distributions (PADs) associated with the lowest energy cluster structures identified computationally agree with the experimental results, with the exception of Zn5O5-, the experimental PAD of which suggests that strong vibronic coupling may be introducing anomalies. While the lowest lying electronic state of the Zn2O2 chain structure is a triplet state, all neutral ring structures (including Zn2O2, the anion of which also populates the ion beam), favor a singlet electronic state. The computed singlet-triplet splitting of the Dxh structures increases monotonically with x. Overall, we find that the properties of the ring structures evolve smoothly, rather than in the punctuated manner typically seen in the small cluster size regime.

A robust superhydrophobic and oleophobic coating with short chain perfluoroalkyl group and flower-shaped SiO2 nanoparticles

Low-surface-energy fluorocarbon-based materials are widely used in superhydrophobic and oleophobic coatings. The fabrication of oil-repellant coatings, however, is particularly challenging due to the low surface tension of oils and the nondegradable of long-fluorocarbon compounds (CnF2n+1, n ≥ 8). In this work, superhydrophobic and oleophobic functional nanoparticles were prepared based on flower-shaped silica and environmentally friendly short chain perfluoroalkyl group. The experimental results show that a low-surface-energy coating surface (water contact angle of 152.5 ± 0.4°, oil contact angle of 142.2 ± 0.8°) can be obtained by using triethoxy(1H,1H,2H,2H-nonafluorohexyl)silane (CH3CH2O)3SiCH2CH2(CF2)3CF3 (C4FTES) and methyltriethoxysilane (MTES) to co-modified flower-shaped SiO2 nanoparticles (flower-shaped MF-SiO2). The analysis of morphology and chemical components of flower-shaped MF-SiO2 displayed a synergistic effect by providing a multi-scale rough structure of flower-shaped SiO2 which minimize contact at the liquid/solid interface, and promotes the distribution and accumulation of the outermost -CF3 groups of nanoparticles as evidenced by the angle-resolved X-ray photoelectron spectrum (AR-XPS) tests. Furthermore, flower-shaped MF-SiO2 nanoparticles have good mechanical stability under the action of adhesive, which means the flower-shaped MF-SiO2 nanoparticles as a promising candidate for superhydrophobic and oleophobic coating materials.

Symmetries and Selection Rules of the Spectra of Photoelectrons and High-Order Harmonics Generated by Field-Driven Atoms and Molecules

Using the strong-field approximation we systematically investigate the selection rules for high-order harmonic generation and the symmetry properties of the angle-resolved photoelectron spectra for various atomic and molecular targets exposed to one-component and two-component laser fields. These include bicircular fields and orthogonally polarized two-color fields. The selection rules are derived directly from the dynamical symmetries of the driving field. Alternatively, we demonstrate that they can be obtained using the conservation of the projection of the total angular momentum on the quantization axis. We discuss how the harmonic spectra of atomic targets depend on the type of the ground state or, for molecular targets, on the pertinent molecular orbital. In addition, we briefly discuss some properties of the high-order harmonic spectra generated by a few-cycle laser field. The symmetry properties of the angle-resolved photoelectron momentum distribution are also determined by the dynamical symmetry of the driving field. We consider the first two terms in a Born series expansion of the T matrix, which describe the direct and the rescattered electrons. Dynamical symmetries involving time translation generate rotational symmetries obeyed by both terms. However, those that involve time reversal generate reflection symmetries that are only observed by the direct electrons. Finally, we explain how the symmetry properties, imposed by the dynamical symmetry of the driving field, are altered for molecular targets.

Laser-assisted photoionization: Streaking, sideband, and pulse-train cases

We present a theoretical study of atomic laser-assisted photoionization emission (LAPE). We consider an atom driven by a linearly polarized XUV laser in two different scenarios: i) a single attosecond pulse (in both the streaking and sideband regimes) and ii) an attosecond pulse train. The process takes place assisted by a linearly polarized infrared (IR) laser field. In all these cases the energy and angle-resolved photoelectron spectrum (PES) is determined by a leading contribution, related to the intracycle factor [Gramajo et al., J. Phys. B 51, 055603 (2018)], complemented by other ones, derived from the periodicity and symmetry properties of the dipole transition matrix with respect to the IR field. Each of these terms imprint particular features in the PES that can be straightforwardly understood in terms of generalized energy conservation laws. We investigate in detail these PES structures, in particular, for the case of argon initially in the 3s quantum state. Our theoretical scheme, based on the strong-field approximation (SFA), can be applied, however, to other atomic species and field configurations as well.

Evolution of a Molecular Shape Resonance along a Stretching Chemical Bond.

We report experiments on laser-assisted electron recollisions that result from strong-field ionization of photoexcited I_{2} molecules in the regime of low-energy electron scattering (<25 eV impact energy). By comparing differential scattering cross sections extracted from the angle-resolved photoelectron spectra to differential scattering cross sections from quantum-scattering calculations, we demonstrate that the electron-scattering dynamics is dominated by a shape resonance. When the molecular bond stretches during the evolution of a vibrational wave packet this shape resonance shifts to lower energies, both in experiment and theory. We explain this behavior by the nature of the resonance wave function, which closely resembles an antibonding molecular orbital of I_{2}.

Propensity rules and interference effects in laser-assisted photoionization of helium and neon

We investigate the angle-resolved photoelectron spectra from laser-assisted photoionization for helium and neon atoms using an ab initio method based on time-dependent surface flux and configuration interaction singles. We find that the shape of the distributions can be interpreted using a propensity rule, an intrinsic difference in the absorption and the emission processes, as well as interference effects between multiple paths to the final angular momentum state. The difference between absorption and emission is hidden in the first sideband in neon due to the multiple competing m channels, while in the second sideband a qualitative difference between absorption and emission is observed. In the m-resolved case, a clear difference is observed already in the first sideband, as exemplified in helium and m-resolved neon.

Bi ultra-thin crystalline films on InAs(1 1 1)A and B substrates: a combined core-level and valence-band angle-resolved and dichroic photoemission study

The growth of Bi on both the In-terminated (A) face and the As-terminated (B) face of InAs(1 1 1) has been investigated by low-energy electron diffraction, scanning tunnelling microscopy, and photoelectron spectroscopy using synchrotron radiation. The changes upon Bi deposition of the In 4d and Bi 5d5/2 photoelectron signals allow to get a comprehensive picture of the Bi/InAs(1 1 1) interface. From the early stage the Bi growth on the A face is epitaxial, contrary to that on the B face that proceeds via the formation of islands. Angle-resolved photoelectron spectra show that the electronic structure of a Bi deposit of ≈10 bi-layers on the A face is identical to that of bulk Bi, while more than ≈30 bi-layers are needed for the B face. Both bulk and surface electronic states observed are well accounted for by fully relativistic ab initio calculations performed using the one-step model of photoemission. These calculations are used to analyse the dichroic photoemission data recorded in the vicinity of the Fermi level around the point of the Brillouin zone.

Anisotropy control in photoelectron spectra: A coherent two-pulse interference strategy

Coherence among rotational ion channels during photoionization is exploited to control the anisotropy of the resulting photoelectron angular distributions at specific photoelectron energies. The strategy refers to a robust and single parameter control using two ultra-short light pulses delayed in time. The first pulse prepares a superposition of a few ion rotational states, whereas the second pulse serves as a probe that gives access to a control of the molecular asymmetry parameter $\beta$ for individual rotational channels. This is achieved by tuning the time delay between the pulses leading to channel interferences that can be turned from constructive to destructive. The illustrative example is the ionization of the $E(1\Sigma_{g}^{+})$ state of Li$_{2}$. Quantum wave packet evolutions are conducted including both electronic and nuclear degrees of freedom to reach angle-resolved photoelectron spectra. A simple interference model based on coherent phase accumulation during the field-free dynamics between the two pulses is precisely exploited to control the photoelectron angular distributions from almost isotropic, to marked anisotropic.

SternheimerGW: A program for calculating [formula omitted] quasiparticle band structures and spectral functions without unoccupied states

Abstract The SternheimerGW software uses time-dependent density-functional perturbation theory to evaluate G W quasiparticle band structures and spectral functions for solids. Both the Green’s function G and the screened Coulomb interaction W are obtained by solving linear Sternheimer equations, thus overcoming the need for a summation over unoccupied states. The code targets the calculation of accurate spectral properties by convoluting G and W using a full frequency integration. The linear response approach allows users to evaluate the spectral function at arbitrary electron wavevectors, which is particularly useful for indirect band gap semiconductors and for simulations of angle-resolved photoelectron spectra. The software is parallelized efficiently, integrates with version 6.3 of Quantum Espresso, and is continuously monitored for stability using a test farm. Program summary Program Title: SternheimerGW Program Files doi: http://dx.doi.org/10.17632/7ywzjng9t5.1 Licensing provisions: GNU General Public License v3.0 Programming language: Fortran 2003 Nature of problem: The lack of the exchange–correlation discontinuity in density-functional theory (DFT) leads to a systematic underestimation of the band gap between conduction and valence states. Many-body perturbation theory in the G W approximation provides an effective solution to this problem, as well as other limitations faced by DFT in the description of electronic excitations. However, the G W method comes with its own set of limitations: (i) The perturbation of the system is typically expressed in terms of the unoccupied states, and achieving numerical convergence with respect to these states is often cumbersome. Since the underlying DFT codes rely only on the occupied states, their default behavior is often ill-suited to provide a sufficient amount of empty states. Combined with the large number of parameters that need to be converged, this limits the use of G W codes by non-expert users and automatic scripts. (ii) Currently, G W codes require that a homogeneous k -point mesh is used in the calculation. Hence, features close to the band edges are often only accessible via prohibitively expensive dense k -point meshes or interpolation techniques. (iii) To evaluate the frequency convolution of the Green’s function G and the screened Coulomb interaction W , many current G W calculations rely on approximations such as the plasmon-pole approximation, the analytic continuation, or the contour deformation. The relative merits and accuracy of the various approximations are not fully understood. Solution method: In SternheimerGW , we address (i) by replacing the summation over unoccupied states with a linear response equation. The solution depends on the occupied states only, and it employs linear response algorithms already provided by the Quantum ESPRESSO suite to compute phonons and related properties. As an additional benefit, transforming the problem in a linear response equation removes the restriction to homogeneous k -point meshes (ii), so that the G W self-energy for any arbitrary point can be evaluated. Finally (iii), we provide the possibility to perform a full frequency convolution along the real frequency axis. This feature can serve as a benchmark for approximate integrations using models or analytic continuation.

The photoionization dynamics based on molecular pre-orientation.

We study theoretically the photoionization dynamics of pre-oriented NaK molecule. Firstly, a THz laser pulse is utilized to orient the ground state molecule. And then the pump and probe laser pulses are used to excite and ionize the molecule, respectively. We study the influence of molecular orientation duration and degree on the ionization probability, angle-resolved photoelectron spectrum and photoelectron angular distribution (PAD). It is shown that we could obtain more stable ionization signal and PAD when the molecules are ionized in molecular orientation duration. We could increase the ionization probability and obtain more concentrated ionization signal and photoelectron distribution by increasing the orientation degree in the ground state. Moreover, we discuss the splitting pattern in the angle-resolved photoelectron spectrum.

Asymmetry flip in angle-resolved photoelectron spectra of rare gas atoms by intense circularly polarized few-cycle pulses

We examine the phenomenon of the flip in the asymmetry in the emission direction of photoelectrons from rare gas atoms upon the ionization by a circularly polarized few-cycle laser field, and derive an analytical formula representing the photoelectron kinetic energy at which the asymmetry flip occurs based on the semiclassical tunnel ionization theory. We show that the energy at which the asymmetry flip occurs varies sensitively to the duration of few-cycle laser pulses and propose that the pulse duration can be determined experimentally using this analytical formula for the asymmetry flip energy.

Effects of W Addition on the Electrochemical Behaviour and Passive Film Properties of Fe-Based Amorphous Alloys in Acetic Acid Solution

The electrochemical behaviour and passive film properties of Fe–Cr–Mo–W–C–B–Y amorphous alloys in acetic acid solution were investigated. The potentiodynamic polarisation and Nyquist curves demonstrated that W addition significantly enhanced the corrosion resistance. Mott–Schottky plots and angle-resolved X-ray photoelectron spectra indicated that passive films with different W contents exhibited dipolar (p–n) semiconducting characteristics separated by flat-band potentials. The outer and inner oxide layers of the passive films were modified by reducing the acceptor and donor densities. Moreover, W addition favoured the formation of a thicker and more stable passive film to inhibit the dissolution of alloy elements.

High-order photoelectron holography in the midinfrared-wavelength regime

We study the dynamical photoelectron holography of an excited hydrogen atom with a strong midinfrared laser field using numerical solutions of the three-dimensional time-dependent Schrodinguer equation. A clear holographic interference pattern of first and high order (hologram) is recorded in the two-dimensional (2D) momentum distribution of the photoelectron. The patterns are well reproduced by additional quantitative calculations based on the Lippmann-Schwinger equation. Here, the high-order interference effect is linked to the multsicattering of low-momentum electrons driven by the midinfrared laser field prior to ejection. The phenomenon manifests by low-momentum structures in 2D momentum distributions and is found to be sensitive to the change of the optical carrier-envelope phase (CEP). By analyzing the temporal evolution of the buildup of the hologram, we show that this sensitivity results from the birth time of the continuum wave packet with an offset in time during the subcycle dynamics, thus encoding information about the ionization mechanism which is mapped into the CEP-resolved 2D momentum distributions and angle-resolved photoelectron spectra. It is indeed an indicator that the ejected electrons exhibit a memory of their birth-time. These findings suggest that the CEP-resolved photoelectron holography serves as a tool for a direct measurement of attosecond dynamics. Furthermore, the effects due to such multiple scattering electron paths can be used to design new atom interferometers to highlight mechanisms that require higher accuracy.

An experimental and theoretical study of the valence shell photoelectron spectra of 2-chloropyridine and 3-chloropyridine.

The valence shell photoelectron spectra of 2-chloropyridine and 3-chloropyridine have been studied both experimentally and theoretically. Synchrotron radiation has been employed to record angle resolved photoelectron spectra in the photon energy range 20-100 eV, and these have enabled anisotropy parameters and branching ratios to be derived. The experimental results have been compared with theoretical predictions obtained using the continuum multiple scattering Xα approach. This comparison shows that the anisotropy parameter associated with the nominally chlorine lone-pair orbital lying in the molecular plane is strongly affected by the atomic Cooper minimum. In contrast, the photoionization dynamics of the second lone-pair orbital, orientated perpendicular to the molecular plane, seem relatively unaffected by this atomic phenomenon. The outer valence ionization has been studied theoretically using the third-order algebraic-diagrammatic construction (ADC(3)) approximation scheme for the one-particle Green's function, the outer valence Green's function method, and the equation-of-motion (EOM) coupled cluster (CC) theory at the level of the EOM-IP-CCSD and EOM-EE-CC3 models. The convergence of the results to the complete basis set limit has been investigated. The ADC(3) method has been employed to compute the complete valence shell ionization spectra of 2-chloropyridine and 3-chloropyridine. The relaxation mechanism for ionization of the nitrogen σ-type lone-pair orbital (σN LP) has been found to be different to that for the corresponding chlorine lone-pair (σCl LP). For the σN LP orbital, π-π* excitations play the main role in the screening of the lone-pair hole. In contrast, excitations localized at the chlorine site involving the chlorine πCl LP lone-pair and the Cl 4p Rydberg orbital are the most important for the σCl LP orbital. The calculated photoelectron spectra have allowed assignments to be proposed for most of the structure observed in the experimental spectra. The theoretical work also highlights the formation of satellite states, due to the breakdown of the single particle model of ionization, in the inner valence region.

Extracting spectroscopic molecular parameters from short pulse photo-electron angular distributions.

Using a quantum wave packet simulation including the nuclear and electronic degrees of freedom, we investigate the femtosecond and picosecond energy- and angle-resolved photoelectron spectra of the E(Σg+1) electronic state of Li2. We find that the angular distributions of the emitted photoelectrons depend strongly on the pulse duration in the regime of ultrashort laser pulses. This effect is illustrated by the extraction of a time-dependent asymmetry parameter whose variation with pulse duration can be explained by an incoherent average over different ion rotational quantum numbers. We then derive for the variation of the asymmetry parameter a simple analytical formula, which can be used to extract the asymptotic CW asymmetry parameters of individual transitions from measurements performed with ultra-short pulses.

Ionization of pyridine: Interplay of orbital relaxation and electron correlation.

The valence shell ionization spectrum of pyridine was studied using the third-order algebraic-diagrammatic construction approximation scheme for the one-particle Green's function and the outer-valence Green's function method. The results were used to interpret angle resolved photoelectron spectra recorded with synchrotron radiation in the photon energy range of 17-120 eV. The lowest four states of the pyridine radical cation, namely, 2A2(1a2-1), 2A1(7a1-1), 2B1(2b1-1), and 2B2(5b2-1), were studied in detail using various high-level electronic structure calculation methods. The vertical ionization energies were established using the equation-of-motion coupled-cluster approach with single, double, and triple excitations (EOM-IP-CCSDT) and the complete basis set extrapolation technique. Further interpretation of the electronic structure results was accomplished using Dyson orbitals, electron density difference plots, and a second-order perturbation theory treatment for the relaxation energy. Strong orbital relaxation and electron correlation effects were shown to accompany ionization of the 7a1 orbital, which formally represents the nonbonding σ-type nitrogen lone-pair (nσ) orbital. The theoretical work establishes the important roles of the π-system (π-π* excitations) in the screening of the nσ-hole and of the relaxation of the molecular orbitals in the formation of the 7a1(nσ)-1 state. Equilibrium geometric parameters were computed using the MP2 (second-order Møller-Plesset perturbation theory) and CCSD methods, and the harmonic vibrational frequencies were obtained at the MP2 level of theory for the lowest three cation states. The results were used to estimate the adiabatic 0-0 ionization energies, which were then compared to the available experimental and theoretical data. Photoelectron anisotropy parameters and photoionization partial cross sections, derived from the experimental spectra, were compared to predictions obtained with the continuum multiple scattering approach.

Determination of the absolute carrier-envelope phase by angle-resolved photoelectron spectra of Ar by intense circularly polarized few-cycle pulses

The angle-resolved photoelectron spectra of Ar are recorded using intense circularly polarized near-infrared few-cycle laser pulses, and the effect of the depletion of Ar atoms by the ionization and the effect of the Coulombic potential are examined by the classical trajectory Monte Carlo simulations. On the basis of the comparison between the experimental and theoretical photoelectron spectra, a procedure for estimating the absolute carrier-envelope phase (CEP) of the few-cycle laser pulses interacting with atoms and molecules is proposed. It is confirmed that the absolute CEP can securely be estimated without any numerical calculations once the angular distribution of the yield of photoelectrons having the kinetic energy larger than 30 eV is measured with the peak laser intensity in the range between $1\ifmmode\times\else\texttimes\fi{}{10}^{14}$ and $5\ifmmode\times\else\texttimes\fi{}{10}^{14}\phantom{\rule{0.16em}{0ex}}\mathrm{W}/\mathrm{c}{\mathrm{m}}^{2}$.

Forward-backward asymmetry of photoemission inC60excited by few-cycle laser pulses

We theoretically analyze angle-resolved photo-electron spectra (ARPES) generated by the interaction of C$_{60}$ with intense, short laser pulses. In particular, we focus on the impact of the carrier-envelope phase (CEP) onto the angular distribution. The electronic dynamics is described by time-dependent density functional theory, and the ionic background of $\csixty$ is approximated by a particularly designed jellium model. Our results show a clear dependence of the angular distributions onto the CEP for very short pulses covering only very few laser cycles, which disappears for longer pulses. For the specific laser parameters used in a recent experiments, a very good agreement is obtained. Furthermore, the asymmetry is found to depend on the energy of the emitted photoelectrons. The strong influence of the angular asymmetry of electron emission onto the CEP and pulse duration suggests to use this sensitivity as a means to analyze the structure of few-cycle laser pulses.

Electron-phonon interactions from first principles

This article reviews the theory of electron-phonon interactions in solids from the point of view of ab-initio calculations. While the electron-phonon interaction has been studied for almost a century, predictive non-empirical calculations have become feasible only during the past two decades. Today it is possible to calculate from first principles many materials properties related to the electron-phonon interaction, including the critical temperature of conventional superconductors, the carrier mobility in semiconductors, the temperature dependence of optical spectra in direct and indirect-gap semiconductors, the relaxation rates of photoexcited carriers, the electron mass renormalization in angle-resolved photoelectron spectra, and the non-adiabatic corrections to phonon dispersion relations. Here we review the theoretical and computational framework underlying modern electron-phonon calculations from first principles, as well as landmark investigations of the electron-phonon interaction in real materials. In the first part of the article we summarize the elementary theory of electron-phonon interactions and their calculations based on density-functional theory. In the second part we discuss a general field-theoretic formulation of the electron-phonon problem, and establish the connection with practical first-principles calculations. In the third part we review a number of recent investigations of electron-phonon interactions in the areas of vibrational spectroscopy, photoelectron spectroscopy, optical spectroscopy, transport, and superconductivity.