Andesitic Composition Research Articles

Conditions for formation and preservation of andesite-hosted mafic enclaves during the 2018 Lower East Rift Zone eruption of Kīlauea

Andesites erupted at Kīlauea in 2018 in the Lower East Rift Zone for the first time in the known geological record. The evolved lavas erupted at Fissure 17 of the 2018 eruption, ranging from andesites to basaltic andesites, contain abundant mafic enclaves both in the lava flows and the ejecta, which are unusual at Kīlauea and in Hawai'i in general. Textural observations indicate that the enclaves originate from incomplete mixing of two magmas rather than the incorporation of cold basaltic wall rock. We suggest, on the basis of bulk and mineral compositions, that the source of the mafic enclaves is the early 2018 evolved basalt magma (phase 1b) that erupted concomitantly at adjacent fissures, which mixed with the andesite to produce the range of basaltic andesite compositions observed at Fissure 17. The coexistence of homogenized basaltic andesites and mafic enclaves within the same magma require a mixing mechanism resulting in both complete homogenization and preservation of enclaves. We propose that the range of mixing and mingling processes may be explained by spatial and temporal variability in the mixing percentages of the phase 1b basalt and the andesite within the andesite magma chamber. Field observations, chemical compositions, and 2D thermal conduction models suggest that enclaves are preserved where the basalt contribution to mixing is less than roughly 40 %, as a result of microlite crystallization leading to rigidification of the enclave magma. Above this threshold, the mixed magmas became largely homogenized. The scarcity of mafic enclaves at Kīlauea and in the Hawai'i igneous record is likely explained by mixing between magmas that lack sufficient compositional and rheological contrasts to preserve them.

Diverse magmatism along the northern margin of Tarim during the Ediacaran: Transition from Rodinian dispersing to Gondwana assemblage

The Ediacaran igneous rocks and sedimentary sequences play a key role for our understanding the transition from dispersing of the Rodinian continents to the assemblage of the Gondwana. On the other hand, some continental massifs at the marginal area of the Rodinia and Gondwana could preserve solid evidences for deciphering the geodynamic background from the break-up of Rodinia to the assemblage of Gondwana. In this contribution, we report field observations, petrography, ages and systematic geochemistry of the diverse Ediacaran igneous activities in the northern margin of the Tarim Block, which was favored as a marginal continental massif in the Rodinia configuration by most geologists. The Ediacaran igneous rocks along the northern margin of Tarim include the Baicheng and Yangxia granites, Tiemenguan syenite, Kurle mafic dykes and the basalt layers in the Zamoketi Formation (northeastern Tarim) and the Sugetbrak Formation (northwestern Tarim). Precise zircon UPb dating revealed that these distinct rocks were broadly coeval with crystallization/eruption ages of 630–600 Ma. Bulk-rock elemental and SrNd isotope compositions as well as zircon LuHf isotope compositions demonstrate that the Baicheng and Yangxia granites were derived from Neoarchean mafic lower crust and underwent intensive fractionation before their emplacements. The Tiemenguan syenites have potassic andesitic compositions, in combination with their pronounced enriched NdHf isotopes and extremely high Zr saturation temperatures (∼900 °C), we argue that their possible shoshonitic primary magmas were derived from previously metasomatized subcontinental lithospheric mantle source (amphibole-bearing) and then, coupling with assimilation and fractional crystallization (AFC) effects in magma chamber and/or en route to the emplacement space. This can account for their intriguing geochemical features. The ca. 615 Ma Zamoketi and Sugetbrak basalts and the slightly younger porphyrite dykes (ca. 580 Ma) cutting the Zamoketi basalt layer, show typical OIB-like geochemical signatures, they were most likely derived from a depleted asthenospheric mantle source with variable fractionation of olivine and pyroxene and negligible crustal contamination before eruption. On the whole, the geochemistry of the diverse Ediacaran igneous rocks unambiguously demonstrates that they were genetically related to an extensional environment. In combination with the significant passive continental features of the Ediacaran-Cambrian sedimentary sequences, we consider that these Ediacaran igneous rocks were the latest phase of igneous activity related to the dispersing of the Tarim at the margin of the Rodinia supercontinent.The dispersing of the Rodinian supra-continent was diachronic with the assemblage of the Gondwana. Late Tonian to Ediacaran dispersing of the Tarim from northern margin of Australia induced the opening of the Proto-Tethys Ocean. Then the initiation of the southward subduction of the Proto-Tethys Ocean at ca. 530 Ma (Fortunian) led to the Tarim assemblage to Gondwana at ca. 440 Ma.

Petrology and geochemistry of Mount Lurus lavas: evidence for alkaline to subalkaline transition in the rear arc of Java, Sunda Arc

Abstract Mount Lurus, a small Quaternary volcanic center in the rear of Java Island, Sunda arc, has erupted both alkaline and subalkaline lavas in a short span of active period. Furthermore, this small volcanic edifice, together with its neighboring alkaline volcanic center of Ringgit-Beser, corresponds to a shallower slab depth (∼160 km) than Muria in Central Java (270 km). We report the mineralogical and geochemical characteristics of Lurus lavas and compare them to the Ringgit-Beser lavas. All Lurus lavas show typical characteristics of island arcs with elevated Ba, Sr, Pb, and K and negative anomalies of Nb and Ti. The older Lurus edifice (Old Lurus) produces alkaline lavas with high alkalinity, which are trachyandesite and phonotephrite in composition. The younger Lurus (Young Lurus) generates calc-alkaline lavas with basaltic andesite composition. Both groups have plagioclase, clinopyroxene, olivine, and opaque minerals as phenocrysts phase. Leucite is found in one sample of Old Lurus with the lowest SiO2 content (48.92 wt%) and highest alkali content (5.38 wt%). Old Lurus lavas tend to show higher contents of incompatible elements (Pb, Ba, Nd, and Rb) than Young Lurus. The mineralogical and compositional differences between these lavas suggest that these magmas are sourced from at least three magma chambers of distinct composition: highly potassic magma chamber (comparable to the evolved-K series of Ringgit-Beser) and hydrous-potassic magma which fed Old Lurus edifice; and calc-alkaline magma chamber which fed Young Lurus edifice.

Proterozoic mafic dyke swarms of Bundelkhand Craton, North India: A connection to Columbia supercontinent

The present paper addresses petrography, geochemistry and Ar‐Ar geochronology of a significant number of mafic dykes from the Paleo‐ to Neoarchean Bundelkhand Craton in central India. The majority of the dykes are NW‐SE oriented (with a few NE‐SW and ENE‐WSW) with tholeiitic, sub‐alkaline and basalt to basaltic andesite composition. The trace element geochemistry of these dykes indicates an island arc setting during emplacement. The Ar‐Ar mineral dating (plagioclase) of three representative dykes reveals an emplacement age between 1.53 and 1.46 Ga. This finding and earlier reports (2.1–1.73 Ga) point to sustained mafic magmatism throughout the Bundelkhand Craton in a preferred structural orientation between 2.1 and 1.46 Ga. Mafic magmatism was episodic and can be linked to the perpetual subduction accretion processes between the central Indian Archean continents during the development of the Columbia supercontinent. The mafic dykes were emplaced at 45° to the maximum compression direction (E‐W), that is, along the line of no finite longitudinal strain. This time equivalent widespread NW‐SE and NE‐SW trending mafic dyke system is also relatable along the adjacent continents (Singhbhum, Bastar) and thus opened up a new paradigm for the dyke's emplacement across the Indian cratons.

Obsidian in the Caribbean islands? Mysterious Ceramic Age glass artefacts in the Lesser Antilles

AbstractThe Caribbean islands witnessed a population expansion of ceramic‐using horticulturalists during the Early Ceramic Age (ca. 500 BC to 750 AD) from the Orinoco Valley to Puerto Rico. We examined 18 lithic artefacts from Guadeloupe and Dominica initially thought to be obsidian, a material believed to be absent from those islands. We investigated the volcanic or meteoritic origin of this unique and yet unknown material through observation (binocular, SEM, microtomography) and geochemical analyses (PIXE, SEM‐EDS, ED‐XRF, EPMA, LA‐ICP‐MS). Elemental analyses rule out the hypothesis of an origin from a meteoritic impact (i.e. identification as tektites). Most of the artefacts have an andesitic composition (<63% SiO2), which appears to be unique among ‘massive’ glasses. The only artefact with a rhyolitic composition has been traced back to the Guadeloupe's Volcan du Tuf, where glassy fragments have been collected and analysed. The geological source of the other vitreous artefacts that exhibit an andesitic composition could be from a sublocal subduction‐arc volcanism (maybe from Martinique), although no volcanic vitreous material of this kind has ever been reported worldwide. These results once again highlight the regional mobility of Early Ceramic populations and the production of standard lithic products using a highly original, albeit low‐quality, local lithic resource, and provide valuable references for future identification of similar materials.

Geochemical characteristics and mapping of Reşadiye (Tokat-Türkiye) bentonite deposits using machine learning and sub-pixel mixture algorithms

Reşadiye bentonite deposits, which play a significant role in Türkiye's bentonite production, are situated in Central Anatolia. Geochemical, mineralogical, and remote sensing data have been integrated to map the spatial distribution of clay minerals in the bentonite deposits and argillic areas. It is hypothesized that the bentonite samples occurred by the in-situ diagenetic alteration of rhyolite-dacite, trachyte, and andesite/basaltic andesitic composition pyroclastic rocks (ash-flow tuff). Biotite, clinoptilolite, calcite, dolomite, K-feldspar, opal-CT, quartz, and clay minerals are detected in most bentonite samples. The clay patterns determined in the bentonite samples in the X-ray diffraction (XRD) diagrams were 12.3–12.6 Å and were interpreted as being rich in Na-smectites. Mineral mapping in these deposits is essential for mining operations since the high-grade bentonite deposits can be affected by the other clay, gang, and ore minerals they contain in addition to the smectite. The sample spectra measurements matched montmorillonite and kaolin/smectite spectra. This study tests support vector machine (SVM) and artificial neural network (ANN) machine learning and MTMF subpixel algorithms in lithology and mineral mapping in Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) satellite data. It combines the power of subpixel unmixing algorithms to determine the distribution of clay and high-grade bentonites in argillic areas discriminated by machine learning. The results showed that the SVM algorithm can map better than ANN for argillic areas. Additionally, the distribution of high-grade bentonite and kaolin/smectite bearing sites in the study area is discriminated by the mixture-tuned matched filtered (MTMF) spectral classification method. As a result, this study shows that remote sensing studies can be utilized for the exploration and monitoring of high-grade bentonite sites during and/or post-mining operations.

Impact of ash fallout of the 2023 Shiveluch volcano eruption (Kamchatka) on forest vegetation

The ash fallout of Shiveluch volcano (April 11, 2023, Kamchatka) is the most intensive volcanic ash fallout of the last 60 years. We present the results of the reconnaissance fi eld investigations supplemented with analyses of satellite images of the area for estimations of deposits distribution and area aff ected by the ash fallout. We also estimated the properties of fi ne grained ash of andesitic composition and its infl uence on the forest vegetation composed by Picea yezoensis (Siebold et Zucc.) Carrière, Larix cajanderi Mayr и Betula ermanii Cham. As a result of moderate- scale ash fallout in the forest (thickness of freshly deposited ash is 5–8 cm), the negative impact on vegetation was minimal because the ash was fi ne-grained and was deposited on a thick snowpack, and the leaves were not formed yet. The forest vegetation on lower elevations was not damaged at all but strong changes occurred in grass and bush vegetation. We have observed the diminished density of plant coverage, decreased size of grass vegetation and a decreased number of plant species. Calamagrostis purpurea (Trin.) Link. s. l., a broadly represented dominant species among grass vegetation, became less common, but Chamerion angustifolium (L.) Holub became more widespread. The possibility of small plants to grow through the ash layer turned out to be strongly reduced. Mosses and lichens in the forest have been buried under the ash, the recovery could take several decades. We have found a notable impact on plants by ash remobilized by strong wind, this impact is the strongest in the open areas and on forest edges. This process can continue for many years due to the large volume of the deposited ash covering the open spaces of the volcano foot.

Первые сведения о редкоземельной минерализации в породах вулкана Эсмеральда (Марианская островная дуга)

The results of the study of rare earth mineralization in the rocks composing the Esmeralda underwater volcano located in the southern part of the Mariana island arc are presented. Despite the fact that the composition and structure of the Esmeralda volcano have been studied by various scientists for 75 years, information about the content of rare earth elements in its rocks is sporadic and is given in only six papers, and two of them present only average values. Our micro-level study of the mineral composition of the basaltic andesite, dissected by a crack, dredged during the 5th voyage of the research vessel «Vulcanologist» in 1978, made it possible for the first time for the Esmeralda volcano to establish the presence of rare earth minerals in its rocks, to determine their composition and formation conditions. The minerals were found to be localized in open crack zones and gas vacuoles.

An early Paleozoic accumulation-foundering cycle of ultramafic cumulates in the Harlik arc and its implications for continental crustal growth in the Altaids

Lower crustal ultramafic cumulates that are normally denser than the ambient mantle peridotites are prone to founder back into the convecting mantle, prompting the formation of continental Moho and andesitic crust at subduction zones. However, foundering events of ultramafic cumulates have not been widely reported in island arcs, including the Altaids, one of the largest accretionary orogens. The Altaids involved prominent continental crustal growth by the development of an archipelago in the Phanerozoic. But the scarcity of foundering events of ultramafic cumulates hinders a better understanding of the formation mechanism of andesitic crust in the Altaids. In this study, we report two dioritic plutons in the Harlik arc, southern Altaids, trying to identify the accumulation-foundering cycles of dense ultramafic cumulates. LA-ICP-MS dating revealed that the Miaoergou and Banfanggou plutons in the Harlik arc were intruded at ca. 445 ± 6 Ma and 423 ± 4 Ma, respectively. The homogeneous Miaoergou pluton is mainly composed of quartz diorites, they have a high- to medium-K calc-alkaline composition, and show enrichments in light rare earth elements (LREE) and large ion lithophile elements (LILE), but depletions in high field strength elements (HFSE, especially Nb and Ta) and heavy rare earth elements (HREE). They also have juvenile isotopic signatures (εNd(t) = +3.3 − +3.7, initial 87Sr/86Sr = 0.70399–0.70452), which together suggest that they were derived from fractional crystallization of the coeval hydrous basaltic magmas in an arc setting. The heterogenous Banfanggou pluton comprises a spectrum of lithologies from hornblende gabbro to diorite. The hornblende gabbros and diorites have a high- to medium-K calc-alkaline composition, and show enrichments in LREE and LILE, but depletions in HREE and HFSE. They all have juvenile isotopic compositions with εNd(t) ranging from +3.5 to +4.2, and (87Sr/86Sr)i from 0.70384 to 0.7047, respectively, indicating that their parental magmas were intruded in a subduction-related setting, and underwent fractional crystallization of clinopyroxene, plagioclase, amphibole and quartz. Both pulses of hydrous basaltic magmatism involved open-system conditions, with the development of mafic microgranular enclaves (MMEs) in the diorites and their mingling. In a synthesis of the published data, we found that the Harlik arc was continuously affected by subduction in the early Paleozoic, through extensive arc magmatism from ca. 452 to 440 Ma, the Harlik arc matured with the accumulation of thick ultramafic cumulates in its lower crust. The foundering of these ultramafic cumulates occurred later, which led to strong extension and related A-type granitic magmatism at ca. 436 Ma. This accumulation-foundering cycle of ultramafic cumulates facilitated the formation of andesitic composition and continental Moho in the Harlik arc, and contributed to the significant continental crustal growth in the Altaids.

Patterns of changes in the composition and physical-mechanical properties of andesites of the East Pauzhetsky thermal field under the influence of argillization (Southern Kamchatka)

The features of the transformation of andesites of the East-Pauzhetsky thermal field under the influence of the argillization process are studied on a number of samples of various degrees of alteration taken from boreholes and from outcrops near the object under study. The main patterns of changes in composition and physical-mechanical properties of andesites are revealed. A schematic diagram of the structure of the thermal field in the section has been compiled, according to which three horizons are distinguished from bottom to top, showing an increase in the degree of hydrothermal transformation — altered andesites, metasomatic breccias and hydrothermal clays.

Major, trace elements and Sr–Nd–Pb isotopes systematics of mafic dykes from the Figuil (northern Cameroon) and Léré (southwestern Chad) areas

In this study, field descriptions of the dolerite dykes cross‐cutting the Pan‐African basement (DPB) and the dolerite and gabbroic dykes cross‐cutting the Cretaceous sedimentary basin (DGCSB) are used together with petrographic, bulk‐rock geochemistry, as well as Sr–Nd–Pb isotopic data to constrain the geodynamic setting and origin of these mafic (basanite, basalt and basaltic andesite in composition) rocks that outcrop in the Figuil–Léré area. The DPB dykes are alkaline with SiO2 of 46.63–49.03 wt% and MgO of 3.93–7.11 wt%. In contrast, the DGCSB dykes are subalkaline with SiO2 ranging between 50.24 and 53.16 wt% and MgO fluctuating between 5.22 and 7.90 wt%, comparable to dykes described in other regions of the Cameroon Line (CL). The rocks studied belong to the tholeiitic series and were emplaced in within‐plate basalts (WPB) and mid‐ocean ridge basalts (MORBs) setting. The variations in major and trace elements from the basanite to basaltic andesite compositions are dependable with fractional crystallization (FC) of different mineral phases such as opaque minerals, olivine, clinopyroxene, amphibole and alkali feldspar. Most samples exhibit negative Nb–Ta and positive Sr anomalies, which together with the negative correlation between MgO and 87Sr/86Sr, and isotopic ratio of 206Pb/204Pb <19.5 (18.27–19.49) suggests interactions of crustal components. Nevertheless, this contamination seems limited because there is a positive correlation between SiO2 and 143Nd/144Nd plot and low Ba contents (72–210 ppm) of the samples compared to the mid‐continental crust (259–628 ppm). Trace element modelling proposes a derivation of the Figuil–Léré dykes from parental melts generated by 4%–15% partial melting of a source containing garnet peridotite in the mixed lithospheric–asthenospheric mantle. The isotopic data of the dykes studied with hybrid magma composition are characterized by more radiogenic 87Sr/86Sr, 143Nd/144Nd and 206Pb/204Pb isotopic ratios with a dominant mixing of depleted MORB mantle (DMM)–enriched mantle 1 (EM1)–enriched mantle 2 (EM2), like those of other mafic dykes of the CL.

Amphibole recycling and polybaric crystallization in rhyolitic lava domes from melt inclusion geochemistry at Cerro La Torta, Altiplano-Puna Volcanic Complex

La Torta is a rhyolitic lava dome located in the El Tatio volcanic complex, Región de Antofagasta (northern Chile), to the west of the Cerros de Tocorpuri volcanoes. La Torta is considered to be an important part of the central zone of the Altiplano Puna Magma Body (APMB) based on chemical and petrological signatures that distinguish it from other highly silicic volcanic systems in the area (i.e., Chao dacite). The petrological and geochemical characteristics, along with parental composition and magma evolution, were determined by analyzing amphibole and plagioclase-hosted melt inclusions using electron microprobe (EMP) and laser ablation ICP-MS (LA-ICP-MS). Our results show that La Torta dome was formed from a rhyolitic Ca- and K-rich, calc-alkaline magma, with an average SiO2 content of 76.8 wt % and H2O content of about 5.4 wt %, which was emplaced in the upper continental crust between 3.9 and 7.6 km below the paleosurface. The parental source of La Torta dome was a highly hydrous mush of andesitic composition, with plagioclase + amphibole ± quartz ± pyroxene crystal assemblage.Heating by an influx of magmas ascending from deeper sources to upper crustal depths (i.e., Altiplano-Puna Magma Body) caused the partial melting of amphibole and pyroxene in the source, evidenced by amphibole dissolution textures, enriching the melt in Cr, Ni, HFSE and HREE. As the system starts to cool and ascend, new amphibole crystallized from this mush, trapping the enriched residual melt as enriched melt inclusions in its cores, along with crystallization of biotite and plagioclase. We refer to this process as amphibole recycling. At the same time, the new melt drags the plagioclase and quartz inherited from the parental mush, forming the magma that emplaced at shallower levels in the crust to eventually erupt as La Torta.

Lithology, Geochemistry of the Middle Devonian Sediments and the Influence of Volcanism on Sedimentation in the Southeast of West Siberia

Abstract —Dataset on the Middle Devonian volcanic-carbonate–terrigenous sediments of Salair and the Kuznetsk trough, submerged northward under the Mesozoic–Cenozoic West Siberian geosyneclise (WSG) cover, have been presented. Mainly deep water sediments composed of thin- and fine-grained clastic material (with predominance of tephroids) and thin-, fine-clastic biodetrital limestones with slope slide breccia, as well as turbidites and peculiar “conglomerate-like” limestones (paleoseismites) were found. Sedimentary and geodynamic environments have been reconstructed for the Middle Devonian strata. Predominantly andesitic composition of pyroclastic ashes with fewer values of felsic and basic volcanic components have been determined. The structures related to the continental margin environments of the Siberian continent, the continental slope and its basement have been found. According to sedimentary and geochemical data, the paleogeodynamic environment within the studied region was relatively stable and generally corresponded to the island arc conditions. The paleoclimate of the source area changed from semi-humid in the late Emsian–early Eifelian (Malaya Salairka age) to aridic in the middle Givetian (Kerlegesh age). Basin sediments formed in the deep water oxic environments with good water aeration, excepting euxinic environments found in the lowermost part of studied succession.

Modeling decompression paths in a basaltic andesite magma using the nucleation and growth of plagioclase microlites

Plagioclase microlites in a magma nucleate and grow in response to melt supersaturation (Δϕplag). The resultant frozen plagioclase crystal size distribution (CSD) preserves the history of decompression pathways (dP/dt). SNGPlag is a numerical model that calculates the equilibrium composition of a decompressing magma and nucleates and grows plagioclase in response to an imposed Δϕplag. Here, we test a new version of SNGPlag calibrated for use with basaltic andesite magmas and model dP/dt for the ca. 12.6 ka Curacautín eruption of Llaima volcano, Chile. Instantaneous nucleation (Nplag) and growth (Gplag) rates of plagioclase were computed using the experimental results of Shea and Hammer (J Volcanol Geotherm Res 260:127–145, 10.1016/j.jvolgeores.2013.04.018, 2013) and used for SNGPlag modeling of basaltic andesite composition. Maximum Nplag of 6.1 × 105 cm h−1 is achieved at a Δϕplag of 44% and the maximum Gplag of 27.4 μm h−1 is achieved at a Δϕplag of 29%. Our modeled log dP/dtavg range from 2.69 ± 0.09 to 6.89 ± 0.96 MPa h−1 (1σ) with an average duration of decompression from 0.87 ± 0.25 to 16.13 ± 0.29 h assuming a starting pressure Pi of 110–150 MPa. These rates are similar to those derived from mafic decompression experiments for other explosive eruptions. Using assumptions for lithostatic pressure gradients (dP/dz), we calculate ascent rates of < 1–6 m s−1. We conducted a second set of Monte Carlo simulations using Pi of 15–30 MPa to investigate the influence of shallower decompression, resulting in log dP/dtavg from 2.86 ± 0.49 to 6.00 ± 0.86 MPa h−1. The dP/dt modeled here is two orders of magnitude lower than those calculated by Valdivia et al. (Bull Volcanol, 10.1007/s00445-021-01514-8, 2022) for the same eruption using a bubble number density meter, and suggests homogeneous nucleation raises dP/dt by orders of magnitude in the shallow conduit. Our modeling further supports the rapid-ascent hypothesis for driving highly explosive mafic eruptions.

Petrogenesis of metavolcanics and detrital zircon geochronology of the Mesoarchean western Iron Ore Group supracrustals, Singhbhum Craton (India): Evidence for an intracontinental extension setting

The Singhbhum Craton of eastern India, consisting of well-preserved Paleo- to Mesoarchean granitoids, volcanic and sedimentary rocks, is an excellent archive of early earth processes. In this contribution, we investigated the geological evolution of the Noamundi-Jamda-Koira IOG Basin (WIOG) using detrital zircon U-Pb ages, whole rock geochemical and Nd isotopic data on metavolcanic rocks from this belt including the Jagannathpur volcanics. The metavolcanics of the WIOG and Jagannathpur are compositionally basaltic andesites with enriched LREE and negative anomalies of Nb-Ta and Ti. The ratios of crustal contamination sensitive elements such as La/Sm, Sm/Nd, Nb/La, Th/Yb and Nb/Yb are close to that of bulk continental crust. The Nd isotopic composition of these basaltic andesites are broadly chondritic (εNdt = +0.93 to −1.20). The geochemical and isotopic signatures are consistent with significant assimilation of Paleoarchean granitoids of the Singhbhum Craton. The overlapping geochemical and isotopic compositions support the view that Jagannathpur volcanics is an eastward extension of the ∼3.04 Ga WIOG metavolcanics and shouldn’t be considered as a separate stratigraphic unit. The presence of pillowed structures, vesicularity, absence of volcanic breccia, and their association with clastic sediments clearly indicate a subaqueous and shallow marine eruption for the WIOG basaltic andesites. The deposition of clastic sediments before basaltic magmatism points towards lithospheric thinning and basin opening. The detrital zircon ages from the WIOG ranges from 3.51 to 2.96 Ga and the detritus was mainly sourced from the adjacent Singhbhum granite and Bonai granite. The petrogenesis of the WIOG metavolcanics can be attributed to assimilation-fractional crystallisation of a depleted mantle derived tholeiitic mafic-ultramafic magma in an intracontinental extension setting.

Sulfur oxidation state and solubility in silicate melts

We have determined the solubility of sulfur (S) as sulfide (S2–) for 13 different natural melt compositions at temperatures of 1473–1773 K under controlled conditions of oxygen and sulfur fugacities (fO2 and fS2, respectively). The S and major element contents of the quenched glasses were determined by electron microprobe. The sulfide capacity parameter (CS2–) was used to express S2– solubility as a function of the oxygen and sulfur fugacities according to the equation: log C_{{S^{2 - } }} = log S_{melt} left( {wt% } right) + 0.5log left( {frac{{fO_{2} }}{{fS_{2} }}} right). Sulfide capacities of silicate melts were found to increase with temperature and the FeO content of the melt. We combined our sulfide data at 1473–1773 K with (O’Neill and Mavrogenes, J Petrol 43:1049–1087, 2002) results at 1673 K, and obtained by stepwise linear regression the following equation for sulfide capacity log C_{{S^{2 - } }} = 0.225 + left( {25237X_{FeO} + 5214X_{CaO} + 12705X_{MnO} + 19829X_{{K_{2} O}} - 1109X_{{Si_{0.5} O}} - 8879} right)/T{ }. XMO is the mole fraction of the oxide of M on a single-oxygen basis, and T is in Kelvin. The sulfide capacity equation was combined with sulfate capacity (CS6+) data for similar compositions and at the same temperatures (Boulliung and Wood, Geochim Cosmochim Acta 336:150–164, 2022), to estimate the S redox state (S6+/S2– ratio) as a function of melt composition, temperature and oxygen fugacity. Results obtained are in good agreement with earlier measurements of S6+/S2– for basaltic and andesitic compositions. We observe a significant increase, however, relative to FMQ of the oxygen fugacity of the S2– to S6+ transition as temperature is lowered from 1773 to 1473 K. We used our results to simulate sulfur-degassing paths for basaltic compositions under various redox conditions (FMQ –2 log fO2 units to FMQ + 2). The calculations indicate that, given an initial concentration of 0.12 wt% S in an ascending melt at 250 MPa, most of the S (> 80%) will be degassed before the magma reaches 100 MPa pressure.

Geochemistry, petrogenesis, and tectonic setting of the Cúcamo mafic and intermediate volcanic rocks from the Ahualulco Volcanic Complex, San Luis Potosí, Mexico

The Ahualulco Volcanic Complex (AVC) is situated in the north-central part of the San Luis Potosí Volcanic Field (SLPVF) that is found in the southern portion of the Mesa Central (MC). The Cúcamo, AVC is mainly composed of mafic and intermediate volcanic rocks. The present study focuses on understanding the evolution, origin, and magmatic processes and petrogenesis of mafic and intermediate rocks in the Cúcamo, AVC. The Quaternary mafic rocks have porphyritic textures with the mineral assemblage of olivine, and clinopyroxene. These volcanic rocks display high K calc-alkaline basaltic compositions with enrichment in light rare earth elements (LREEs) and incompatible elements. Geochemical modeling reveals that mafic magmas were derived through a partial melting process of a spinel lherzolite source at low degrees of melting (~2 to 15 %) in an extensional regime. The intermediate volcanic rocks show porphyritic and glomeroporphyritic textures with matrix formed by randomly oriented microlites. The main mineral assemblage consists of plagioclase, K-feldspar, and clinopyroxene. These volcanic rocks are characterized by calc-alkaline basaltic andesitic and andesite compositions with enrichment in light rare earth elements and incompatible elements. Geochemical modeling suggests that intermediate rocks were derived from high ratios of assimilation and fractional crystallization processes between mafic melts and continental crust in an extensional environment.

Genesis and interaction of magmas at Nishinoshima volcano in the Ogasawara arc, western Pacific: new insights from submarine deposits of the 2020 explosive eruptions

Sudden changes of eruption styles and magma compositions at arc volcanoes are enigmatic processes. Nishinoshima volcano, western Pacific, has had historical eruptions in 1973–1974 and from 2013 on and off to the present day. These eruptions were characterized by effusive Strombolian eruptions of andesite magmas until mid-June 2020, when they suddenly transitioned to violent explosive Strombolian eruptions that produced tephra fallout over a wide area. To understand this transition, we conducted marine surveys and sampling of the extensive submarine deposits of the tephra fallout. Our new data demonstrate that the full compositional range of the 2020 eruptions spans from basalt to dacite. We present evidence for magma mixing of newly injected basalt with andesite magmas. Nishinoshima consists of an andesitic main edifice surrounded by basaltic knolls: previous studies have shown that Nishinoshima andesite compositions can be generated by olivine fractionation of primary andesitic magmas that result from partial melting of hydrous mantle at relatively low pressures under the thin crust of the Ogasawara arc; knoll basalt compositions can be generated by partial melting of mantle at greater depths and were interpreted as older events of the volcano. We show that basalt magmas could have been generated throughout the entire history of Nishinoshima. In addition, we show that andesites from Nishinoshima and nearby Nishinoshima-Minami Knoll, which are only ∼8 km apart, have distinct subduction components. Together, these data improve our understanding of the diverse primary magmas responsible for the construction and continuing eruptive activity of an active island arc volcano.

Melt Inclusions in Arclogitic Xenoliths Constrain the Genesis of the Lower Continental Arc Crust beneath the Northern Volcanic Zone, Colombia

ABSTRACT Volcanic arcs above subduction zones are thought to be the principal locations where juvenile magmatic crust forms and is refined to become continental crust with an andesitic composition. During this refinement mechanism, the formation of dense garnet pyroxenites (arclogites), represented by high-pressure cumulates and restites after partial melting, leads to the delamination of the lower arc crust. The Mercaderes-Río Mayo area in southern Colombia is the only known locality in an active volcanic arc where arclogitic xenoliths have been recovered. These xenoliths are entrained in the Granatifera Tuff, a late Cenozoic volcanic vent, and they mainly consist of garnet, clinopyroxene, amphibole, plagioclase, rarely scapolite, and accessory mineral inclusions of rutile, apatite, zircons, and quartz. Moreover, the arclogites are also characterized by the presence of melt inclusions (MI), which are mainly found within garnet, but can be also observed in amphibole, plagioclase, clinopyroxene, and scapolite. The glasses measured for the MI in garnet and scapolite typically have SiO2 contents &amp;gt;57 wt.%, ranging from andesite to rhyolite in composition. Petrographic and geochemical investigations allowed to discriminate between cumulitic and restitic arclogites, with the latter showing the concomitant presence of primary MI and quartz inclusions within the peritectic garnets. Therefore, our study provides for the first time a strong evidence, at the microscale, for the anatectic origin of some arclogitic xenoliths. Pressure and temperature conditions for the studied arclogites were estimated by intracrystalline geothermometry, elastic geothermobarometry, phase equilibria modelling and classical Fe–Mg exchange between garnet and clinopyroxene. Results fall within the range of 960°C to 1150°C and 1.6 to 1.9 GPa for most samples. We suggest that the investigated arclogites derive from the root of the active Colombian volcanic arc, where differentiation processes from mantle-derived melts and lower crust anatexis occur in close association.

Precise Pb-Pb baddeleyite geochronology, geochemistry, and Sr-Nd isotopic constraints on the 2.36 & 1.88 Ga mafic dykes from the Bastar craton, India: Implications for their petrogenesis in conjunction with the Dharwar mafic dykes

This research focuses on the geochronology and geochemistry of WNW-NW-NNW trending Paleoproterozoic mafic dykes from the Bastar craton in India. The weighted mean 207Pb/206Pb ages of baddeleyite grains obtained from the Tuskal, Pakhanjore, and Gariaband regions were 2365.25 ± 0.54 Ma, 2365.70 ± 0.48 Ma, and 2363.85 ± 0.79 Ma, respectively. Baddeleyite grains from a mafic dyke near Narayanpur-Kondagaon yielded a weighted mean 207Pb/206Pb age of 1886.5 ± 1.8 Ma. In the TAS (Total Alkali Silica) diagram, the 2.36 Ga and 1.88 Ga mafic dykes have basalt to basaltic andesite composition. Dykes from both age groups are represented by the tholeiitic magma series in the AFM diagram. In the spidergrams, the dykes show LREE and LILE enrichment, with the 2.36 Ga dykes showing flat HREE and the 1.88 Ga dykes showing slightly inclined HREE patterns. The REE non-modal batch melting model indicates derivation of the 2.36 Ga mafic dykes from a shallower spinel lherzolitic source, whereas the 1.88 Ga mafic dykes were derived from a deeper spinel-garnet lherzolitic mantle source. The 2.36 Ga dykes have near chondritic to slight super chondritic initial Nd isotopic values (εNd(2.36 Ga) = −0.95 to 2.36), whereas the 1.88 Ga dykes have sub chondritic initial Nd isotopic values (εNd(1.88 Ga) = −2.37 to −9.67). Present-day orientations and similar precise ages of the mafic dykes reported from the Bastar and Dharwar cratons indicate the counter-clockwise rotation of the Bastar craton during the Paleoproterozoic.