Satellite communication (SATCOM) systems have attracted great attention from academic and industrial communities in recent years, and huge amount of data delivery over satellite downlinks is considered as a promising service in emerging 5G networks, such as multimedia broadcasting. Nevertheless, due to intermittent connections from LEO or MEO satellite to earth station, and high dynamic channel conditions over downlinks, satellites may not be able to transmit the large data files to the ground station on time. In this paper, we propose a new rateless coding transmission for multi-state dying erasure channels (MDEC) with random channel life span and time-varying packet error rates, to improve the transmitting capability over SATCOM downlinks. Firstly, a heuristic approach for suboptimal degree distributions based on AND-OR tree technique is presented to achieve higher intermediate performance and lower symbol error rate of our proposed rateless codes. Furthermore, the appropriate code length of the connective window is derived and analyzed for enhanced average throughput on MDEC that is also optimized by maximum problem solving. Simulations have been conducted to evaluate the effectiveness of our rateless coding transmission for large file delivery on dynamic channel conditions. The results demonstrate that our proposed transmission scheme outperforms existing conventional rateless codes with significantly better intermediate performance and throughput performance over unreliable SATCOM downlinks, under time-varying packet error rates and unpredictable occurrences of exhausted energy or cosmic ray attacks.