A sliding gusset plate braced frame (SGBF) is proposed to enhance the seismic resilience of steel concentrically braced frames (CBFs). The symmetric friction connection (SFC) is used at the brace-to-gusset plate connection to create a sliding gusset plate brace. The sliding gusset plate brace offers high initial stiffness to withstand wind and service level earthquake loads. It also absorbs energy through friction beyond service level earthquakes, which mitigates performance degradation caused by brace buckling. Besides, replaceable links are added to the beam ends where plastic hinges are anticipated to form, creating a dual system that allows for damage control and rapid repair. The paper first presents the design concepts and performance objectives of SGBFs. Subsequently, a thermodynamic model is established to reveal the energy–temperature–coefficient of friction (CoF) (E-T-μ) relationship based on quasi-static tests of SFCs. The model partially tackles and addresses the challenge of temperature-dependent variations in CoF during sliding. By incorporating the model into performance-based seismic design, the overstrength ratio of SFC due to temperature-induced hardening can be quantified, according to the energy absorption demand of a specific SGBF during an earthquake. In this manner, unexpected damage and failure of members adjacent to the SFC and sliding gusset plate braces can be avoided. To demonstrate the application of the thermodynamic model and verify the seismic performance of SGBF, a prototype is designed based on a practical four-story hospital and validated through an excessive array of nonlinear dynamic analyses. The results show that the proposed SGBF can achieve the targeted performance objectives under different seismic shaking intensities. In addition, the SGBF has a sufficient margin of safety against collapse. Hence, the proposed SGBF can be used as an efficient and resilient structural system in high seismic zones.