This paper is aimed to address the issue of decreased accuracy in the ship block docking caused by the structural errors of posture adjustment mechanism. First, inverse kinematic analysis is performed to investigate the sources of static errors in the mechanism. Subsequently, based on the closed-loop vector method, a pose error model for the moving platform is established, which includes eight categories of error terms. The impact of various structural errors on the pose accuracy of the moving platform is then compared and analyzed under both single-limb and multi-limb configurations. Therefore, a compensation method based on the whale optimization algorithm optimized radial basis function neural network is proposed. By transforming pose errors into actuator length errors, it establishes a predictive model between the theoretical pose of the dynamic platform and actuator length errors. After optimizing the network parameters, it yields the actuator length compensation to correct the actual pose of the dynamic platform. Simulation and experimental results validate the effectiveness of this method in enhancing the motion accuracy of the parallel mechanism. The mean pose accuracy of the moving platform is improved by 85.07%, demonstrating a significant compensation effect.