Ammonium Nitrate Fuel Oil Research Articles

Study of continuous velocity probe method for the determination of the detonation pressure of commercial explosives

ABSTRACTA novel velocity probe, which permits recording the continuous velocities of detonations and shock waves, has been developed based on the transition of operation principle from ionization to pressure-conduction. Using the new probe and the impedance matching method, a series of measuring devices were set up to obtain the shock wave velocities in different inert materials, i.e., water, Plexiglas and paraffin wax. Two test types of powder ammonium nitrate/fuel oil (ANFO), exposed on the ground and tamped in the blast hole, were performed, from which we calculated their detonation pressures, with a density of approximately 0.86 g·cm−3, ranged from 3.52 GPa to 3.65 GPa, and the adiabatic exponents from 2.24 to 2.30. The results show that the present velocity probe-based method can be used to determine the detonation pressure of commercial explosives conveniently and reliably, which is an important supplement for the testing techniques of explosive performance.

The mechanism of the spontaneous detonation of ammonium nitrate in reactive grounds

The mechanism of the decomposition of ammonium nitrate fuel oil (ANFO) and of ammonium nitrate (AN) emulsions has been investigated. The formation of NO gas bubbles at the end of an induction period was observed, which led to the evolution of brown NO2 gas on contact with air. Inhibition of the decomposition reaction could be achieved by reducing the NO concentration in the gas phase, with inhibitors not in physical contact with the reaction mixture. NO adsorbing clay minerals (hydrotalcite) were effective inhibitors, indicating multiple mechanisms of inhibition. A central role is assigned to nitrous acid (HNO2): sequestering NO prevents its formation, base inhibitors keep it in the non-reactive form of the nitrite ion (pKa of HNO2∼3), and urea in acidic conditions decomposes it to harmless N2. Our results have implications in industries where NOx emissions can cause significant environmental problems for both aquatic and marine life as well as for human health.

Raman hyperspectral imaging in conjunction with independent component analysis as a forensic tool for explosive analysis: The case of an ATM explosion

In this work, Raman hyperspectral imaging, in conjunction with independent component analysis, was employed as an analytical methodology to detect an ammonium nitrate fuel oil (ANFO) explosive in banknotes after an ATM explosion experiment. The proposed methodology allows for the identification of the ANFO explosive without sample preparation or destroying the sample, at quantities as small as 70μgcm−2. The explosive was identified following ICA data decomposition by the characteristic nitrate band at 1044cm−1. The use of Raman hyperspectral imaging and independent component analysis shows great potential for identifying forensic samples by providing chemical and spatial information.

Leveraging multi-modal smartphone sensors for ranging and estimating the intensity of explosion events

Our society, unfortunately, is increasingly becoming exposed to explosion events that could have serious consequences. While explosion events like intentionally triggered bombs cause obvious harm to life and property, other explosions intended for benign purposes in quarries and construction zones may also cause unintended harm as a result of emanating seismic vibrations. As of today, detecting explosions, ranging them, and estimating their intensities are all accomplished only by seismometers that sense the associated ground vibrations and pressure changes as a result of their triggering. Unfortunately, seismometers are bulky, expensive and unsuitable for the ubiquitous use. In this paper, our broad motivation is to demonstrate the feasibility of leveraging the pervasive sensing and processing capabilities of modern smartphones to analyze explosion events. Within this context, we specifically address the problem of ranging and estimating the intensity of an explosion by leveraging the accelerometer and pressure sensors in the smartphone. To do so, we emplaced a number of smartphones in the vicinity of real explosion blasts conducted at a university mining laboratory, where the material blasted was Dynamite with Ammonium Nitrate Fuel Oil (ANFO). We then collected the corresponding accelerometer and pressure readings sensed by the phone. We extracted a number of novel features, and designed a machine learning based algorithmic framework for ranging and estimating the intensity of the explosion event. After an extensive validation, we find that the average-case error in ranging (i.e., estimating the distance to the source of the explosion event) and estimating the intensity of explosive material (in terms of its charge weight) are 8.24% and 7.37%, respectively. We also present perspectives on encoding our algorithm as a smartphone app, identify several critical challenges that will be encountered in real-time data processing of smartphone accelerometers and pressure sensors in the context of pervasive sensing of explosions, and also identify other practical issues like the diversity of smartphones. To the best of our knowledge, our work is pioneering in demonstrating the feasibility of using smartphones to analyze explosion events. We believe there are significant societal benefits emanating from our work.

Identification of ANFO: Use of luminescent taggants in post-blast residues

This work describes the incorporation of luminescent taggants in cartridges of ammonium nitrate-fuel oil (ANFO) to allow easy identification and collection of post-blast residues. Metal-Organic Frameworks taggants proved to be appropriate for explosive marking when ANFO proportions were above 3.0wt.%. Lanthanide-based light emission enabled in situ retrieval of explosive residues as well as chemical identification, allowing the creation of a coding system using Energy Dispersive Spectroscopy (EDS). The proposed method will accelerate laboratory analysis and support forensic investigations, connecting evidence to suspects and/or to the explosive origin.

Influence of homemade ammonium nitrate and fuel oil explosives charge shapes on blast wave propagation

The purpose of the paper is to investigate the influence of geometry of charges on the propagation of blast waves. Various shape charges (cylinder, sphere, irregular shape) were used in the field tests. The main type of explosive, homemade ANFO (Ammonium nitrate + fuel oil), was used as the most common used explosives in improvised explosive devices used in terrorist attacks. Characteristics of homemade and industrially made ANFO explosives are different. There were comparing charges of various types of industrially produced types of explosives and homemade explosive in the field tests. The blast wave propagation were investigated and compared.

Monitoring and assessment of pollutants resulting from bench-blasting operations

Nitrogen oxides and carbon monoxide gases together with dust are known as the major pollutants arising during the blasting operations using the ammonium nitrate-fuel oil (ANFO) explosive at the Sungun surface mine, located in the northwest of Iran. The pollutants were monitored during some blasting operations at the mine. It was concluded that the gases and dust clouds initially went up to the peak height, and were then released in the direction of wind flow. A large volume of the pollutants in the form of clouds, which fell at the mine and its surrounding environment, was usually discharged again to the atmosphere due to other mining activities. It was also found that all kinds of pollutants at the mine imposed high risks to the ecosystem of the mine. The maximum concentration of the pollutants belonged to the particles with a size more than 20 microns. The southern part of the mine had a more potential vulnerability than its northwestern part, according to the monthly wind rose diagrams of Sungun. The investigations carried out at the mine and its surrounding environment have indicated that the current traditional blasting operations have discharged a considerable amount of pollutants into the mine and the Arasbaran protected area. The current blasting pattern should be improved, especially through analyzing and changing the stemming materials and length, in order to provide a safe environment for the ecosystem of the mine and the Arasbaran area.

Analysis of ammonium nitrate headspace by on-fiber solid phase microextraction derivatization with gas chromatography mass spectrometry

A novel analytical method has been developed for the quantitation of trace levels of ammonia in the headspace of ammonium nitrate (AN) using derivatized solid phase microextraction (SPME) fibers with gas chromatography mass spectrometry (GC–MS). Ammonia is difficult to detect via direct injection into a GC–MS because of its low molecular weight and extreme polarity. To circumvent this issue, ammonia was derivatized directly onto a SPME fiber by the reaction of butyl chloroformate coated fibers with the ammonia to form butyl carbamate. A derivatized externally sampled internal standard (dESIS) method based upon the reactivity of diethylamine with unreacted butyl chloroformate on the SPME fiber to form butyl diethylcarbamate was established for the reproducible quantification of ammonia concentration. Both of these compounds are easily detectable and separable via GC–MS. The optimized method was then used to quantitate the vapor concentration of ammonia in the headspace of two commonly used improvised explosive device (IED) materials, ammonium nitrate fuel oil (ANFO) and ammonium nitrate aluminum powder (Ammonal), as well as identify the presence of additional fuel components within the headspace.

Different Approaches to Determine of the Explosion Effect, of a Homemade Explosive, on the Structure

With the increase in acts of terrorism, the effects of the explosion on structures has become highly topical. The aim of the paper is an analysis of various approaches to determine the response of blast loaded reinforced concrete pillar. Homemade ANFO (Ammonium nitrate + fuel oil) explosive will be a reference explosive. Such type of explosives is the most used one in terroristic attacks. The paper will be focused on the analysis of the blast wave, based on the experimental tests, and dynamic analysis of a structure under such load.

Forensic methodology for the thermochemical characterization of ANNM and ANFO homemade explosives

Measurements were carried out to obtain thermal signatures of the most commonly used homemade explosive (HME) materials, i.e., ammonium nitrate/nitromethane and ammonium nitrate/No. 2 diesel fuel oil, using a novel laser-heating technique referred to as the laser-driven thermal reactor (LDTR). Experiments were performed for different compositions, initial masses, and steady-state temperatures, along with the effects associated with HME aging. For ammonium nitrate/nitromethane (ANNM), the NM/ANNM mass fractions investigated were 29% (stoichiometric value) and 14%; these experiments were with fresh mixtures. The 29% NM/ANNM mass fraction mixture was also aged to 3%. For ammonium nitrate/fuel oil (ANFO), a fresh stoichiometric FO/ANFO mass fraction of 6% was used initially, and aged mixtures were then investigated for mass fractions of 5.4%, 4.7%, 4.4%, and 3.7%. The results indicated that the LDTR thermograms (i.e., sample temperature change with time) for the mixed ANNM were different than the individual isolated components, and that the technique was sensitive to varying HME composition. In addition, changes in the thermograms as ANFO aged were attributed to the varying volatility of the fuel hydrocarbon fractions, and thus provide important information for forensics analysis as to the HME reactivity.

A 3D Smoothed Particle Hydrodynamics Method with Reactive Flow Model for the Simulation of ANFO

AbstractANFO (ammonium nitrate/fuel oil) is a widely used bulk industrial explosive mixture that is considered to be highly “non‐ideal” with long reaction zones, low detonation energies, and large failure diameters. Thus, its detonation poses great challenge for accurate numerical modeling. Herein, we present a numerical model to simulate ANFO based on improved smoothed particle hydrodynamics (SPH) method, which is a mesh‐free Lagrangian method performing well in simulating situations consist of moving interface and large deformation, as happened in high‐velocity impact and explosion. The improved three‐dimensional SPH method incorporated with JWL++ model is used to simulate the detonation of ANFO. Good agreement is observed between simulation and experiment, which indicates that the proposed method performs well in prediction of behavior of ANFO.

Characterization of ANFO explosive by high accuracy ESI(±)–FTMS with forensic identification on real samples by EASI(−)–MS

Ammonium nitrate fuel oil (ANFO) is an explosive used in many civil applications. In Brazil, ANFO has unfortunately also been used in criminal attacks, mainly in automated teller machine (ATM) explosions. In this paper, we describe a detailed characterization of the ANFO composition and its two main constituents (diesel and a nitrate explosive) using high resolution and accuracy mass spectrometry performed on an FT-ICR-mass spectrometer with electrospray ionization (ESI(±)–FTMS) in both the positive and negative ion modes. Via ESI(−)–MS, an ion marker for ANFO was characterized. Using a direct and simple ambient desorption/ionization technique, i.e., easy ambient sonic-spray ionization mass spectrometry (EASI–MS), in a simpler, lower accuracy but robust single quadrupole mass spectrometer, the ANFO ion marker was directly detected from the surface of banknotes collected from ATM explosion theft.

Numerical simulation of a 100-ton ANFO detonation

This work describes the results from a US government-owned hydrocode (SHAMRC, Second-Order Hydrodynamic Automatic Mesh Refinement Code) that simulated an explosive detonation experiment with 100,000 kg of Ammonium Nitrate–Fuel Oil (ANFO) and 2,080 kg of Composition B (CompB). The explosive surface charge was nearly hemispherical and detonated in desert terrain. Two-dimensional axisymmetric (2D) and three-dimensional (3D) simulations were conducted, with the 3D model providing a more accurate representation of the experimental setup geometry. Both 2D and 3D simulations yielded overpressure and impulse waveforms that agreed qualitatively with experiment, including the capture of the secondary shock observed in the experiment. The 2D simulation predicted the primary shock arrival time correctly but secondary shock arrival time was early. The 2D-predicted impulse waveforms agreed very well with the experiment, especially at later calculation times, and prediction of the early part of the impulse waveform (associated with the initial peak) was better quantitatively for 2D compared to 3D. The 3D simulation also predicted the primary shock arrival time correctly, and secondary shock arrival times in 3D were closer to the experiment than in the 2D results. The 3D-predicted impulse waveform had better quantitative agreement than 2D for the later part of the impulse waveform. The results of this numerical study show that SHAMRC may be used reliably to predict phenomena associated with the 100-ton detonation. The ultimate fidelity of the simulations was limited by both computer time and memory. The results obtained provide good accuracy and indicate that the code is well suited to predicting the outcomes of explosive detonations.

Microbial degradation of expired slurry explosives in mines: a review

Minerals are mostly produced from opencast and underground mines and blasting is an essential operation in India. Mining explosives and initiating accessories are used for removing overburden rocks and to produce minerals. Ammonium nitrate fuel oil (ANFO), emulsion (Water-in-Oil) and water gel slurry explosives are used in the blasting operations. In India, the quantity of cartridge slurry and bulk slurry explosives used in mining is approximately 30% of the total mining explosives consumed in the country. Huge amounts of slurry explosives deteriorate in storage, as their properties become impaired, and they should be discarded safely. The only method for disposal of slurry explosives is open burning, which creates air pollution. This paper reviews the characteristics of uni-molecular and slurry explosives and their available disposal methods.

Fast Switching of CO3–(H2O)n and O2–(H2O)n Reactant Ions in Dopant-Assisted Negative Photoionization Ion Mobility Spectrometry for Explosives Detection

Ion mobility spectrometry (IMS) has become the most deployed technique for on-site detection of trace explosives, and the reactant ions generated in the ionization source are tightly related to the performances of IMS. Combination of multiform reactant ions would provide more information and is in favor of correct identification of explosives. Fast switchable CO3(-)(H2O)n and O2(-)(H2O)n reactant ions were realized in a dopant-assisted negative photoionization ion mobility spectrometer (DANP-IMS). The switching could be achieved in less than 2 s by simply changing the gas flow direction. Up to 88% of the total reactant ions were CO3(-)(H2O)n in the bidirectional mode, and 89% of that were O2(-)(H2O)n in the unidirectional mode. The characteristics of combination of CO3(-)(H2O)n and O2(-)(H2O)n were demonstrated by the detection of explosives, including 2,4,6-trinitrotoluene (TNT), cyclo-1,3,5-trimethylene-2,4,6-trinitramine (RDX), ammonium nitrate fuel oil (ANFO), and black powder (BP). For TNT, RDX, and BP, product ions with different reduced mobility values (K0) were observed with CO3(-)(H2O)n and O2(-)(H2O)n, respectively, which is a benefit for the accurate identification. For ANFO, the same product ions with K0 of 2.07 cm(2) V(-1) s(-1) were generated, but improved peak-to-peak resolution as well as sensitivity were achieved with CO3(-)(H2O)n. Moreover, an improved peak-to-peak resolution was also obtained for BP with CO3(-)(H2O)n, while the better sensitivity was obtained with O2(-)(H2O)n.

Sensitive detection of black powder by stand-alone ion mobility spectrometer with chlorinated hydrocarbon modifiers in drift gas

This paper introduces a simple method for selective and sensitive detection of black powder by adding chlorinated hydrocarbons in the drift gas instead of changing the structure of conventional ion mobility spectrometer (IMS). The function of chloride modifiers was to substitute Cl(-)(H₂O)n for [O₂⁻ (H₂O)(n)] in the drift region so as to avoid the overlap between O₂⁻ (H₂O)(n) and sulfur ion peaks. Among CH₂Cl₂, CHCl₃ and CCl₄, CCl₄ was chosen as the modifier due to the best peak-to-peak resolution and stability towards the fluctuation of modifier concentration. With 1.4 ppm CCl₄ as the modifier, the minimum detectable quantity of 0.1 ng for sulfur was achieved. Moreover, this method showed the ability for detection of common explosives at sub-nanogram level, such as black powder (BP), ammonium nitrate fuel oil (ANFO), 2,4,6-trinitrotoluene (TNT), and pentaerythritol tetranitrate (PETN). In summary, this method requiring no configuration modification has high sensitivity and selectivity, and consumes trace amount of modifier. And these characteristics make it easy to be adopted in current deployed IMS to detect black powder explosives.

The effects of sodium chloride on the explosive performance of ammonium nitrate

Sodium chloride (NaCl) was added to the ammonium nitrate (AN) by different mixing methods. The heat sensitivity performance and the explosive performance of AN and ammonium nitrate fuel oil (ANFO) were studied by using differential scanning calorimeter (DSC), the UN gap test and Koenen test. The results show that: When AN contained 15 % (solution mixing) and 35 % (mechanical mixing) additive, AN maximum exothermic peak increased from 286.75 to 300.63 and 307.83 °C, respectively. For the mechanical mixing, the critical values of the UN gap test and Koenen test AN were 35 and 40 %. The ANFO both were 50 %; for the solution mixing, AN were 15 and 40 %, the critical value of the UN gap test, ANFO was 25 %. AN and ANFO contain more than the critical value of additive, the AN and ANFO would not be detonated.

Dynamic Response of Steel Columns Subjected to Blast Loading

AbstractIn this study, 13 typical wide-flange steel columns, each carrying an axial load equal to 25% of its axial capacity, are field tested using live explosives, involving charge size of 50 to 250 kg of ammonium nitrate/fuel oil (ANFO) and ground stand-off distance of 7.0 to 10.3 m. The reflected pressure time histories, time-dependent displacements, accelerations, and strains of the columns are measured, and their postblast damages and failure modes are reported. Maximum deformations, vibration periods, strain-rate, and contributing modes in the dynamic response of the columns are compared to those of companion steel beams (without axial load) tested in the same setup. Results show that columns that exhibit elastic response, due to the elongation of the column vibration period caused by the axial load, the lateral deformation caused by blast load is reduced rather than magnified by the axial load. The axial-bending interaction, or P-δ effect, may be neglected for steel columns with axial load up to 25...

Effect of explosive characteristics on the explosive welding of stainless steel to carbon steel in cylindrical configuration

The aim of this research is to study the influence of explosive characteristics on the weld interfaces of stainless steel AISI 304L to low alloy steel 51CrV4 in a cylindrical configuration. The effect of ammonium nitrate-based emulsion, sensitized with different quantities and types of sensitizing agents (hollow glass microballoons or expanded polystyrene spheres) and Ammonium Nitrate Fuel Oil (ANFO) explosives on the interface characteristics is analyzed. Research showed that the type of explosive and the type and proportion of explosive sensitizers affect the main welding parameters, particularly collision point velocity. The morphology of the wavy weld interfaces, chiefly the amplitude and length of the waves, is affected both by the impact velocity and the type and particle size of the explosive sensitizers, and increases with particle size. All the weld interfaces, except welds done with ANFO, displayed localized melted and solidified regions, whose chemical composition resulted from the contribution of both flyer and base metal.

MCNP Simulation Benchmarks for a Portable Inspection System for Narcotics, Explosives, and Nuclear Material Detection

MCNPX simulations have been used to guide the development of a portable inspection system for narcotics, explosives, and special nuclear material (SNM) detection. The system seeks to address these threats to national security by utilizing a high-yield, compact neutron source to actively interrogate the threats and produce characteristic signatures that can then be detected by radiation detectors. The portability of the system enables rapid deployment and proximity to threats concealed in small spaces. Both dD and dT electronic neutron generators (ENG) were used to interrogate ammonium nitrate fuel oil (ANFO) and cocaine hydrochloride, and the detector response of NaI, CsI, and LaBr3 were compared. The effect of tungsten shielding on the neutron flux in the gamma ray detectors was investigated, while carbon, beryllium, and polyethylene ENG moderator materials were optimized by determining the reaction rate density in the threats. In order to benchmark the modeling results, experimental measurements are compared with MCNPX simulations. In addition, the efficiency and die-away time of a portable differential die-away analysis (DDAA) detector using 3He proportional counters for SNM detection has been determined.