There is a growing need to apply geospatial artificial intelligence analysis to disparate environmental datasets to find solutions that benefit frontline communities. One such critically needed solution is the prediction of health-relevant ambient ground-level air pollution concentrations. However, many challenges exist surrounding the size and representativeness of limited ground reference stations for model development, reconciling multi-source data, and interpretability of deep learning models. This research addresses these challenges by leveraging a strategically deployed, extensive low-cost sensor (LCS) network that was rigorously calibrated through an optimized neural network. A set of raster predictors with varying data quality and spatial scales was retrieved and processed, including gap-filled satellite aerosol optical depth products and airborne LiDAR-derived 3D urban form. We developed a multi-scale, attention-enhanced convolutional neural network model to reconcile the LCS measurements and multi-source predictors for estimating daily PM2.5 concentration at 30-m resolution. This model employs an advanced approach by using the geostatistical kriging method to generate a baseline pollution pattern and a multi-scale residual method to identify both regional patterns and localized events for high-frequency feature retention. We further used permutation tests to quantify the feature importance, which has rarely been done in DL applications in environmental science. Finally, we demonstrated one application of the model by investigating the air pollution inequality issue across and within various urbanization levels at the block group scale. Overall, this research demonstrates the potential of geospatial AI analysis to provide actionable solutions for addressing critical environmental issues.