Alumina Nanoparticles Research Articles

Solidification process modeling for energy storage by means of galerkin method utilizing nano-sized additives

In this study, a numerical method for modeling the freezing process inside a storage enclosure equipped with ψ-shaped fins has been scrutinized. The container features both square and sinusoidal walls, with ψ-shaped fins enhancing the thermal conduction within the system. Alumina nanoparticles, in both blade and cylindrical forms, have been dispersed in the water to investigate the effect of particle shape on the freezing process. The shape factor (m) is considered in the calculation of conductivity to capture the impact of different nanoparticle geometries. Additionally, a single-phase model is used for the nanomaterial formulation, with nanoparticle concentrations (φ) kept below 0.04 to ensure accurate representation. The results reveal that increasing (m) leads to a reduction in solidification time by approximately 7 %. When nanoparticles are dispersed in water, the time required for complete freezing decreases from 275.57 s to 201.95 s, representing a significant improvement. This demonstrates that the presence of nanoparticles can accelerate the freezing process by about 26.71 %. By incorporating ψ-shaped fins and optimizing nanoparticle characteristics, the study provides valuable insights into enhancing thermal conduction and reducing freezing times.

Repercussion of quadratic density variation on nonlinear mixed convective Darcy–Forchhimer Al2O3, Cu\\EG flow over an inclined plate with exponential heat source and Arrhenius equation

Generating and controlling energy at high temperatures is extremely challenging in solar energy applications with hybrid nanofluids (HNFs). This challenge is tackled with nonlinear changes in density with temperature and concentration. Hence, a nonlinear Boussinesq approximation is taken on Darcy – Forchhimer hybrid flow containing aluminium oxide ( A l 2 O 3 ) and copper ( Cu ) nanoparticles with base fluid Ethylene Glycol (EG) over an inclined plate at an angle of ξ = π 6 . The physical model is supported by a space-based exponential heat source (EHS) along with a temperature-based heat source (THS) in the energy equation and Arrhenius equation in diffusion relation with suction and blowing on the wall. The regulating equations are transformed into standard differential equations using the similarity conversions, and these equations are subsequently solved in MAPLE 2022. The thermal field is affected positively by EHS and THS parameters, which fulfil the purpose of including these parameters in the flow model. The rate of heat transport increment for Q E parameter by 1.04% for HNF whereas 1.06% for NF when Su > 0 . Also, Su < 0 heat transfer rate increases by 3.68% for HNF whereas 3.75% for NF. As A l 2 O 3 , Cu ∖EG HNF move from suction to injection, the Nusselt number reduces by more than 50%.

Impact of sol-gel synthesized α-aluminium oxide nanoparticles for the enhancement of transformer oil insulation properties

Transformers require advanced insulating materials that outperform mineral oil in terms of cooling, insulation effectiveness, eco-friendliness, and operational efficiency in extreme operational and weather conditions. As a result, emphasis has shifted to renewable and ecologically friendly materials. This change in emphasis is motivated by worries about the environment, fuel shortages, and the disposal of waste oil. Transformers have historically employed solid insulators like paper and pressboard as well as mineral or synthetic oil. However, the development of ecologically friendly insulating materials has been spurred by new environmental regulations as well as economic benefits. This research investigates the use of sol-gel synthesized aluminium oxide (Al2O3) nanoparticles to improve the insulation properties of host transformer oil. The synthesized aluminium nanoparticles were characterized with X-ray diffractometer (XRD) and found rhombohedral structure, whose chemical composition was studied by energy dispersive X-ray spectrum (EDAX). Investigation using Fourier transform infrared spectroscopy (FTIR) also revealed the production of AlOOH and hydroxyl vibrational bands at wavenumbers of 690 and 2976 cm−1, respectively. Studies using field emission scanning electron microscopy (FESEM) showed that the nanoparticles are spherical in form and have a diameter of around 38 nm. Additionally, the incorporation of α-aluminium oxide nanoparticles into the host oil showed an improvement in the breakdown voltage and suggested a possible use for better transformer oil insulation.

Significance of mixed convection and heat transfer flow past a vertical Riga plate in the presence of alumina nanoparticles: Analysis of streamlines for oblique stagnation point

AbstractThe aim of the current study to inspect the magnetic flow properties and heat transport features near an oblique stagnation point of a nanofluid with mixed convection through a vertical Riga plate are examined. The Riga plate is a familiar actuator made out of permanently fixed electrodes and magnets that moved away from the plate due to an exponential decline in the Lorentz force. Nanofluid is taken into consideration due to its peculiar properties, such as remarkable thermal conductivity is the significance of the study. These properties are important in heat exchangers, electronics, advanced nanotechnology, and material sciences. Using usual similarity transformations, the group of leading partial differential equations is distorted into a group of nonlinear ordinary differential equations. Then, a very proficient procedure namely bvp4c is utilized to discover the solution. For particular values of the different influential fluid parameters, the characteristics of the dimensionless temperature and velocity along with drag force and heat transfer are investigated graphically. In addition, the symmetrical results were initiated for both cases of the slip and without slip parameters. It is demonstrated that for greater influence of the volume fraction of nanoparticles, the normal and tangential velocity profile drops down for the instances of aiding and opposing flows due to fluctuations in the presence of slip factor, and absence of slip factor. In contrast, the temperature profile intensifies in both the cases of slip parameters and without the slip parameter owing to the phenomenon of assisting flow and opposing flow subject to superior impressions of the nanoparticle volume fractions. It is also observed that depending on the equilibrium between buoyancy effects, obliqueness, velocity slip parameters, and straining motion, the location of the point of zero shear stress (friction factor on the surface of the wall) is displaced to the right or the left of the origin.

Fluorocarbon-Capped Aluminum Nanoparticles: Synthesis, Characterization, Combustion, and Comparison to Hydrocarbon-Capped Aluminum Nanoparticles

ABSTRACT Aluminum nanoparticles (NPs) are attractive as fuel additives in propulsion or pyrotechnic applications, but their combustion is inhibited by native oxide layer formation, which also reduces the energy content. Capping Al NPs with fluorocarbon ligands may inhibit native oxide formation and create an intimate mixture of fuel with an oxidizer capable of reacting exothermically with both Al and the passivating oxide layer. We present an approach to producing Al NPs capped by perfluorotetradecanoic acid (PFTDA), based on rapid mechanical attrition of NPs followed by PFTDA capping under mild conditions. The materials were characterized by dynamic light scattering, electron microscopy with energy dispersive spectroscopy, elemental analysis, X-ray photoelectron spectroscopy, X-ray diffraction, and infrared spectroscopy. Ignition and combustion properties were studied using bomb calorimetry, thermogravimetric analysis with differential scanning calorimetry, and photographic analysis of both flame and laser ignition of particle samples. For comparison, Al NPs were produced identically but capped with a hydrocarbon (oleic acid). PFTDA-capped NPs were found to ignite at lower laser power and burn far more vigorously than oleic acid-capped NPs, despite the observation that oleic acid capping resulted in a thinner native oxide layer on the air-exposed NPs. PFTDA-capped NPs were also found to have shorter ignition delay and lower ignition energy compared to commercially available Al NPs. XPS and XRD were used to probe the combustion products for the PFTDA-capped NPs, confirming formation of AlF3 and other products. Density functional theory was used to calculate the heat of formation of PFTDA, which was then used to calculate reaction enthalpies for reactions in both inert and oxidizing environments.

Surgical dissection of ignition behavior of aluminum nanoparticles using molecular dynamics

Aluminum nanoparticles (ANPs) show great promise in energy technology, yet their atomic behavior during ignition remains a puzzle. This study provides insights into atomic migration processes within ANPs of different chemical layers during ignition and combustion, inspired by surgical peeling techniques. The research reveals that cavity formation in ANPs is inevitable due to disparities in atomic migration rates between core and surface areas, with core aluminum atoms experiencing sudden and significant stress alterations crucial for cavity formation. A linear trend in atom counts across radial layers correlates with particle geometry, influencing reactivity and morphological changes. The proposed Bond Environment Change (BEC) analysis reveals that oxygen atoms in the ANP shell undergo a three-phase evolution: intensive bonding, gradual relaxation, and stable configuration, reflecting the dynamic transformation of the oxide layer during the reaction process. While this research provides a deeper understanding of ANP ignition and combustion mechanisms, it may serve as a reference for refining ANP synthesis and guiding further inquiries in the field of nanoparticle-based energy technologies.

Entropy analysis of MHD hybrid nanofluid in a rotating channel filled with porous material

This study investigates entropy generation of MHD hybrid nanofluid in a rotating channel filled with porous material. The hybrid nanofluid, which uses Cu and alumina nanoparticles along with water as the base fluid, has been used. The hybrid model equations were solved numerically using MATLAB’s ode15s which employs Runge-Kutta–Fehlberg scheme. Effects of entropy generation and other system variables were investigated. Parametric analysis reveals that, hybrid nanofluids show better heat transport capacities with a higher Nusselt number than Cu–water and alumina-water nanofluids. Thus, because of its improved thermal characteristics, the hybrid nanofluid transfers more heat, which makes it a better option for applications that need effective heat dissipation. The results show that, increasing the Biot number reduces temperature, while hybrid nanofluids yield a higher Bejan number, indicating more efficient heat transfer with minimized entropy generation. The study identifies increased friction between fluid and porous media as the cause of temperature rise with higher porous media resistance and shape factor parameters. It is also depicted that, the rate of entropy generation decreases as the Biot number Bi rises, this happens as a result of the channel’s temperature gradient being less pronounced at higher Bi, which reduces thermal irreversibility and, in turn, entropy generation. The findings also demonstrate that the presence of a magnetic field reduces axial velocity while increasing transverse velocity. Consequently, skin friction increases in the axial direction and decreases in the transverse direction. In addition, the increase of rotational parameter has been found to reduce skin friction to the greatest extent. These findings underscore the potential of hybrid nanofluids in optimizing thermal systems by reducing entropy generation and enhancing heat transfer efficiency.

In vitro cytotoxicity evaluation of green synthesized alumina nanoscales on different mammalian cell lines

Nanoscale research is gaining interest in the biomedical, engineering, and environmental fields. Current expensive traditional chemical methods for synthesizing nanoparticles (NPs) inevitably lead to the synthesis of NPs with potentially less or no toxic effects on living cells. To overcome these challenges, in this study, we use a simple, inexpensive, and less toxic one-pot green chemistry approach instead of a chemical method to synthesize alumina nanoparticles (AlNPs) from Carica papaya extract. Nano-alumina has been widely studied due to its remarkable biological and physiochemical properties at nanoscale. However, to date, its biomedical application is limited due to the lack of sufficient data on cytotoxicity in living cells. The physicochemical properties of nano-alumina were determined by FT-IR, DLS, SEM and HRTEM. The cytotoxic effects of the synthesized nano-alumina were studied in cell lines LT and VERO at concentrations of 10–480 µg/mL in vitro. The cell viability of nano-alumina was evaluated using the MTT assay and the AO /EB double staining technique. Our results based on DLS and HRTEM analyzes confirmed spherical AlNPs with a zeta potential and average particle size of − 25 to 5 mV and 52 nm, respectively. The nano-alumina tested showed low toxicity to both cell lines after 28- and 48-h exposure. Furthermore, cell viability statistically decreased with increasing incubation time and concentration of AlNPs up to 480 μg/mL (p < 0.001). However, a minimal increase in cytotoxicity was observed at threshold levels in the range of 120–480 µg/mL. The half-maximal inhibitory concentration (IC50) of AlNPs in the VERO and LT cell lines were 153.3, 252.0 µg/mL and 186.6, 395.3 µg/mL, respectively, after 24- and 48-h exposure to AlNPs. Thus, we conclude that the cytotoxic effect of AlNPs depends on the concentration, exposure time and cell type. The result suggests that the concentration used in this study may be useful for biomedical applications.

Recycling spent battery components into highly efficient hydrogen and oxygen evolution electro-nano-catalysts

Inspired by the 'waste-to-resource' strategic theme for environmental recovery, here we present the recycling of spent dry cells and spent Lithium-ion batteries aiming to achieve the preparation of cheap and efficient electrocatalysts for Proton Exchange membrane electrolyzers instead of the precious-based electrocatalysts. Graphite doped with manganese (IV) oxide nanoparticles, graphite doped with manganese (IV) oxide and aluminum oxide nanoparticles, lithium cobalt oxide doped with copper oxide nanoparticles, and lithium cobalt oxide doped with copper oxide and zinc oxide nanoparticles synthesis procedures are done via hydrothermal method at a pressure of 4.5 Mpa at 180 ○C. Electrochemical characterization is done to determine overpotential, tafel slope, and electrocatalytic stability via a three-electrode system. The optimum results are observed by the graphite doped with manganese (IV) oxide nanoparticles, which show -55.06 mV and -41.33 mV/dec as overpotential and tafel slope at -10 mA/cm2 for hydrogen evolution reaction with surface area of 40.87 m2/g and 21.05 nm as crystal size and Graphite doped with manganese oxide and aluminum oxide nanoparticles, which show 321.58 mV and 174.14 mV/dec as overpotential and Tafel slope for oxygen evolution reaction at 10 mA/cm2 with surface area of 7.64 m2/g and 44.43 nm as crystal size.

Sub-acute Inhalation Exposure to Aluminum Oxide Nanoparticles and its Effects on Wistar Rats as Opposed to the Micro-sized Chemical Analog.

Aluminum oxide nanoparticles (Al2O3 NPs) are widely used in various productions. Simultaneously, many research works report the toxic effects of this nanomaterial. Given that, there is a growing risk of negative effects produced by Al2O3 NPs on public health. This study aims to investigate the toxic effects of Al2O3 NPs as opposed to the micro-sized chemical analogue under sub-acute inhalation exposure. We identified the physical properties of Al2O3 NPs as opposed to the micro- sized chemical analogue, including size, specific surface area, and total pore volume. Inhalation exposure to Al2O3 NPs was simulated on Wistar rats in a chamber for whole-body. The animals were exposed for 4 hours each day for 28 days. NPs and MPs concentrations in the chamber were kept at ~ 1/4000 from LC50. Rats' behavior was examined prior to the exposure period and after it; after the last daily exposure, we examined biochemical and hematological blood indicators, NPs and MPs bioaccumulation, and pathomorphological changes in organ tissues. The tested Al2O3 sample is a nanomaterial according to its analyzed physical properties. Rats' behavior changed more apparently under exposure to NPs compared to MPs. Aluminum levels, which were 1.62-55.20 times higher than the control, were identified in the lungs, liver, brain, and blood under exposure to NPs. These levels were also 1.55-7.65 times higher than the control under exposure to MPs. Biochemical indicators of rats' blood also changed under exposure to NPs against the control. We identified more active ALT, AST, ALP, and LDH, elevated levels of GABA, MDA, and conjugated bilirubin, and a lower level of Glu. As opposed to exposure to MPs, ALT, AST, and ALP were more active; GABA and MDA levels were higher; Glu level was lower. Under exposure to NPs, the number of platelets grew, whereas no similar effect occurred under exposure to MPs. We established pathomorphological changes in tissues of the lungs, brain, heart, and liver under exposure to Al2O3 NPs; similar changes occurred only in the lungs under exposure to MPs. Exposure to NPs induced changes in tissue structures in a wider range of various organs, and these changes were more apparent than under exposure to MPs. Greater toxicity of Al2O3 NPs as opposed to MPs is evidenced by a wider range of organs where their bioaccumulation occurs, more apparent pathomorphological and pathological functional changes. Established peculiarities of toxic effects produced by the analyzed nanomaterial should be considered when developing hygienic recommendations aimed at preventing and mitigating adverse impacts of Al2O3 NPs on human health under inhalation exposure.

A comparative analysis on the dynamics of solid-liquid interfacial layer and nanoparticle diameter of magnetohydrodynamic nanofluid flow containing spherical and cylindrical-shaped alumina nanoparticles over a stretching curved surface

In this work, a comparative analysis on magnetohydrodynamic nanofluid flow containing spherical and cylindrical-shaped alumina nanoparticles over a stretching curved surface is mainly focused. The effects of Brownian motion, Joule heating, thermophoresis, chemical reaction and activation energy are taken into consideration in this work. It is important to mention that this analysis considers a 4 % volume fraction of the alumina nanoparticles. A thermal convective and zero-mass flux conditions are imposed to scrutinize the heat transfer analysis. The leading equations are transformed into dimensionless form by using suitable similarity variables. A numerical solution is obtained using the shooting technique. The acquired outcomes depict that greater magnetic factor enhances the skin friction coefficient. The greater magnetic factor, thermal Biot number, Eckert number, and interfacial layer thickness augment the heat transfer rate, while a greater nanoparticle diameter diminishes the thermal transfer rate. A higher magnetic factor has an increasing impact on thermal distribution and a reducing impact on velocity distribution. A greater curvature factor enhances both the velocity and thermal distributions. The concentration distribution is enhanced by the higher interfacial layer thickness and activation energy factor, while it is reduced by a higher nanoparticle diameter, Brownian motion factor, and chemical reaction factor. From the comparative analysis, it is found that the velocity, thermal, and concentration distributions are higher for the cylindrical-shaped nanoparticles compared to spherical-shaped nanoparticles.

Ammonium perchlorate catalyzed with novel n-Al modified on ZIF-67 with silane coupling agent: Superior catalytic activity, advanced decomposition kinetics and mechanisms

Ammonium perchlorate (AP) is commonly utilized as an oxidizer in composite solid propellants (CSPs), and the thermal decomposition of AP has a significant impact on the combustion behaviour of CSPs. Aluminum nanoparticles (n-Al) as a prospective metal fuel have received a lot of interest, however properly extracting energy from n-Al remains a great challenge. Native oxide layer limits the energetic performance of n-Al by impeding sufficient combustion and slowing down mass/heat transport. Development of the high energy storage based on metastable intermolecular composite (MIC) is always a desirable way. This group of hybrid materials uses zeolitic imidazole framework (ZIF) as the precursors of the metal oxides as the oxidizers in conventional nanothermite. Coating n-Al on the surface of ZIF-67 with a silane coupling agent to erase or disturb the oxide layer on the n-Al surface improves n-Al combustion. n-Al@ZIF-67 was synthesized and integrated into AP matrix. The catalytic activity of n-Al@ZIF-67 on AP decomposition was assessed via DSC and TGA/DTG. Whereas n-Al@ZIF-67/AP nanocomposite demonstrated decomposition enthalpy of 2350 J/g; pure AP demonstrated 836 J/g, ZIF-67/AP demonstrated 1680 J/g, and n-Al/AP demonstrated 1170 J/g. While Al@ZIF-67/AP nanocomposite demonstrated one decomposition temperature at 327 oC; pure AP decompose at two decomposition stages at 298 oC, and 453 oC. n-Al@ZIF-67/AP showed a violent reaction with high intensity of flame, and micro-explosion occurred due to rapidly disrupted oxide layer that covered Al core. Decomposition kinetics was investigated. n-Al@ZIF-67/AP demonstrated apparent activation energy of 125.3 ± 1.23 kJ/mol compared with 173.16 ± 1.95 kJ/mol for pure AP. Co3O4 NPs as the combustion product from ZIF-67 can expose active surface sites; the ability of adsorption of released NH3 gas, which inhibition AP from decomposition, offering efficient combustion. This work provides a new strategy for advanced CSPs by introducing ZIF-67 to construct bifunctional properties for AP decomposition, and n-Al combustion.

Influence of different introduction methods of graphene on the mechanical properties and cutting performance of Al2O3/TiB2 ceramic tool materials

This study investigated the effects of incorporating graphene-coated alumina (Al2O3@G) nanoparticles and graphene oxide (GO) on the microstructure, mechanical properties, and cutting performance of Al2O3/TiB2 matrix ceramic tool materials. Compared to the addition of GO, the inclusion of Al2O3@G enhanced the dispersion of graphene in the ceramic tool materials and alleviated defects such as pores caused by graphene agglomeration. Additionally, during sintering, uniformly distributed graphene interwove to form a three-dimensional grid structure owing to grain growth and pore disappearance, increasing the contact area and interface bonding strength between the graphene and the matrix. Based on the results of the microstructure observation and analysis, the favorable interfacial strength not only facilitated load transfer from the ceramic matrix to graphene but also triggered the fracture mechanism of graphene, consuming more fracture energy than the traditional toughening mechanism. The hardness, flexural strength, and fracture toughness of the obtained ATB-G@3.0 ceramic tool material with 3.0 vol% Al2O3@G were measured at 19.52 GPa, 1063.52 MPa, and 9.16 MPa m1/2, respectively, which were 16.82 %, 27.92 %, and 26.87 % higher than those of the ATB-G3.0 ceramic tool material with 3.0 vol% GO. Compared with the ATB-G3.0 ceramic tool, the ATB-G@3.0 ceramic tool displayed superior cutting performance and longer service life when machining hardened steel 40Cr. Furthermore, the addition of Al2O3@G effectively reduced the cutting force, friction coefficient, and cutting temperature of the ceramic tools and enabled the workpiece to achieve better surface processing quality after cutting.

The Nano-Revolution in Rubber Bushings: Boosting Mechanical Performance

Abstract A new method for manufacturing rubber bushings with unique properties has been introduced. The method involves adding alumina nanoparticles at different ratios (0.2, 0.4, 0.6, 1, 1.5, 2, 2.5, and 3) Phr to a rubber recipe consisting of 30% natural rubber, 70% styrene-butadiene rubber. The recipe also contains a constant percentage of carbon black (51 Phr). The materials were mixed for (specific time) to ensure even distribution. Extensive testing has been conducted to ensure the cured rubber meets performance standards, including evaluations of tensile strength, tear propagation, wear resistance, hardness, elasticity, and resistance to fatigue. The bush material excelled in friction resistance and long-term fatigue performance. Adding 0.6 phr Nano-Alumina further enhanced its elasticity, strength, tear resistance, and resilience. At 3 phr of Al2O3 increased Elongation, Hardness, and Fatigue resistance value.

Mixed toxic effects of aluminium oxide nanoparticles with hexavalent chromium, tetracycline, and humic acid towards marine crustacean Artemia salina

ABSTRACT Aluminium oxide nanoparticles (Al2O3 NPs) are prevalent in natural water bodies due to their commercial applications, necessitating an evaluation of their toxicity to aquatic life. This study assessed the toxicity of Al2O3 NPs both alone and in combination with pollutants like chromium (Cr VI) and tetracycline (TC), as well as with organic matter such as humic acid (HA) on brine shrimp (Artemia salina). The addition of Cr (VI) enhanced the aggregation of Al2O3 NPs. Acute toxicity tests showed a concentration-dependent increase in A. salina mortality, primarily due to the early absorption of Al2O3 NPs. The presence of TC and HA reduced toxicity by binding to the nanoparticles. Additionally, HA influenced Al2O3 aggregation, while reactive oxygen species (ROS) production, protein concentration, and lipid peroxidation supported the toxicity findings. This research ultimately highlights the ecological implications of Al2O3 NPs on aquatic ecosystems.

Unraveling the Nanosheet Zeolite-Catalyzed Combustion of Aluminum Nanoparticles-Doped exo-Tetrahydrodicyclopentadiene (JP-10) Energetic Fuel.

Nanosheet MFI zeolites (Zeolite Socony Mobil, five) have grown in popularity in cracking catalysis considering their tunability in porous topologies, acidic sites, and sheet thickness, thus allowing them to selectively adsorb molecules of specific sizes, shapes, and polarities, resulting in improved cracking performance for a specific fuel. Five different MFI zeolites in the form of a mesoporous nanosheet structure with a controlled concentration of acidic sites denoted as NSMFI(y), where y is Si/Al ratio, have been synthesized. The effects of the relative acidity content of these NSMFI(y) samples on the zeolite-catalyzed combustion of aluminum nanoparticles (AlNPs)-aided exo-tetrahydrodicyclopentadiene (JP-10) mixed energetic fuel droplets levitated in an oxygen-argon atmosphere were investigated using time-resolved imaging (optical and thermal infrared) and spectroscopic techniques (UV-vis and FTIR). The addition of 1.0 wt % of NSMFI(y) zeolites to AlNPs-JP-10 fluid fuel results in critically reduced ignition delays (9 ± 2 ms), elevated ignition temperatures (2800 ± 170 K), and prolonged burning times (60 ± 10 ms) with an enhanced combustion efficiency. The NSMFI(y) zeolites, which possess high acidity and significant mesoporosity, play a crucial role in improving the combustion efficiency by effectively catalyzing the chemical activation of JP-10 and prolonging the burning of the igniting droplet. The NSMFI (60) variant with the highest acidic site content achieved a maximum combustion efficiency of 80 ± 6%. A comprehensive catalytic combustion mechanism has been elucidated based on the detected reactive intermediates such as hydroxyl radical (OH) and aluminum monoxide (AlO). These findings will help to critically advance the development of next-generation, sustainable, and innovative mixed nanofluid fuels.

Controlling the Energy Release Behavior of Aluminum Nanoparticles as Metal Fuels by Atomic Layer Deposited Copper Oxide Nanocoatings

Controlling the Energy Release Behavior of Aluminum Nanoparticles as Metal Fuels by Atomic Layer Deposited Copper Oxide Nanocoatings

Flat plate solar collector activated with alumina-silicon dioxide-copper oxide hybrid nanofluid: Thermal performance study

Flat plate collectors (FPC) play a crucial role in solar-powered desalination by harnessing sunlight to purify water. They are acclaimed for their simple yet efficient design, as their dark, flat surfaces effectively transfer heat to the desalination system, making them a preferred choice for sustainable water treatment. Nevertheless, the performance of FPC systems is hindered by the working fluid, which reduces the productivity of distilled water, particularly without the use of nanotechnology to enhance the fluid’s thermal properties. This study aims to enhance the performance of FPCs in desalination processes by integrating them with conventional still systems and employing hybrid nanofluids. These nanofluids, composed of alumina (Al2O3), silicon dioxide (SiO2), and copper oxide (CuO) nanoparticles at concentrations of 0.3 % in 50:50 combinations, namely Al2O3/SiO2, SiO2/CuO, and Al2O3/CuO, are introduced into the working fluid (water). The integration of these hybrid nanofluids is evaluated in terms of thermal behaviour, including thermal conductivity, outlet temperature, energy gain, water productivity, and thermal and exergy efficiency of FPC. Among the different combinations, the Al2O3/CuO hybrid nanofluid demonstrates the highest thermal conductivity, outlet temperature, energy gain, water productivity, as well as thermal and exergy efficiencies, reaching approximately 0.631 W/mK, 87.5 °C, 568.7 W, 124.3 ml/m2, 61.4 %, and 6.7 %, respectively. The Al2O3/CuO featured flat plate solar collector system has the potential for an optimum system of addressing the pressing global issue of water scarcity.

Computational simulation of Casson hybrid nanofluid flow with Rosseland approximation and uneven heat source/sink

This article candidly presents the magnetohydrodynamics Casson hybrid nanofluid flow over a stretching surface. In the present study, we added a nonuniform heat source or sink and non-linear thermal radiation. We considered Al2O3 and copper nanoparticles to have antibacterial and antiviral properties without any harmful impacts and used water as the host fluid. We simplified the governing flow equations by using suitable self-similarity variables, which are used to convert PDEs to ODEs. The mathematical equations are numerically solved by using the bvp5c technique in the MATLAB software. Additionally, with higher values of the magnetic field and Casson fluid parameters the velocity profile decreased. The temperature profile is enhanced by increasing the magnetic field and thermal radiation parameters. Increasing the Casson fluid and radiation parameters enhances the skin friction and Nusselt number profiles. Alumina nanoparticles find applications in cosmetic fillers, polishing materials, catalyst carriers, analytical reagents. Copper nanoparticles have high electrical conductivity, which has many uses in electrical circuits and biosensors.

Effective utilization of waste plastics and ammonia as biodiesel to assess performance and emission

Purpose This study aims to examine the environmental effects of plastic waste on the atmosphere and its implications for disaster waste management. It focuses on using ammonia, pyrolyzed plastic oil and the effectiveness of alumina nanoparticles as a catalyst. Design/methodology/approach The research explores different combinations of conventional diesel and nano Al2O3 derived from pyrolyzed plastic oil (ranging from P10 to P40). Critical performance metrics evaluated include brake mean effective pressure (BMEP), brake specific fuel consumption, brake thermal efficiency and emissions of CO2, CO and NOx. The study specifically investigates the impact of adding 50 ppm of Al2O3 nanoparticles to these blends. Findings The findings indicate that using blended fuels with nanoadditives significantly lowers pollution. Specifically, the P30 blend with 50 ppm of Al2O3 nanoparticles greatly reduced CO emissions. Additionally, the same blend reduced NOx emissions and CO2 emissions. The P30 mix showed improved BMEP and brake thermal efficiency due to its density, calorific value and viscosity (6.3 bar). The P30 blend exhibited higher thermal efficiency due to decreased heat loss, whereas conventional diesel demonstrated the best mechanical efficiency due to its longer ignition delay. Originality/value This study highlights the potential of using Al2O3 nanoparticles and pyrolyzed plastic oil to reduce emissions and enhance the performance of internal combustion engines. It underscores the environmental benefits and implications for disaster waste management by converting plastic waste into useful resources and reducing air pollution.