The composite adsorbent of natural mesoporous powder of Wakkanai siliceous shale (WSS) impregnated with LiCl has been investigated. In this study, the slurry of WSS–LiCl with acryl resin as a binder was prepared for fabricating an adsorbent-filled heat exchanger (HEX). The optimal LiCl content for the impregnation with WSS was 20 wt%, which was chosen from the relation between water uptake and pore volume. The theoretical sorption amounts were estimated from various sorption isotherms, and the value was 0.34 g/g at the temperature conditions of 80 °C (regeneration), 30 °C (condensation and adsorption), and 15 °C (evaporation). From the analysis of sorption heat, it was found that water adsorption and desorption occurred repeatedly at the lower region of 45–50 kJ/mol at the driving conditions for the adsorption heat pump. To evaluate the coefficient of cooling performance (COP) and a specific cooling power (SCP), the adsorbent-filled HEX was prepared using a small-sized corrugated-fin-type aluminum HEX and the slurry. The COP and SCP were 0.41 and 498 W/kg at 80 °C of regeneration, respectively.
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