Alternative Process Research Articles

A spectrum-of-spectrum filtering method to extract direct and multipath arrivals from simulations and measurements

In measurements and numerical modelling of wave propagation, undesired interference between direct and multipath arrivals can be reduced using Fourier-based signal processing methods. Existing methods, such as cepstral analysis and time-signal gating, are not applicable to all cases. Here, an alternative Fourier-based signal processing method is presented, called spectrum-of-spectrum (SoS) filtering. Its main advantage over existing methods is its ability to extract single direct or multipath arrivals for relatively short propagation distances even when subsequent arrivals do not become successively weaker. The method is based on the following steps:•Apply a lowpass filter to the real and imaginary parts of an input frequency spectrum individually, using a digital finite impulse response (FIR) filter in the frequency domain.•Recombine the filtered real and imaginary parts of the frequency spectrum to get the frequency spectrum of the direct arrival.•For extraction of the first multipath arrival, subtract the filtered frequency spectrum from the input frequency spectrum and repeat the previous steps. Repeat multiple times to extract subsequent multipath arrivals.

‘English is our 2nd language, konglish is our mother tongue’: Recolonizing English Through Translingual Activism in a Social Movement

Abstract This paper probes alternative meanings and processes for decolonizing English that arise from the particular geopolitical histories and identities of Hong Kong and engagement with political and translingual activism. I illustrate the positioning and tension between English, ‘Kongish’ (a mix of English and localized linguistic resources in Hong Kong), and Chinese in 1,355 comments from four live-streamed videos of clashes between the police and protesters. Despite the default language of the news page being Chinese (standard written Chinese and written Cantonese), a vast majority of the comments are written in English and Kongish. I analyse the commenters’ metalinguistic discourse that represents their alignment and non-alignment stances towards the various linguistic practices in the comment threads. I draw on ‘translingual activism’ (Pennycook 2019) to understand the linguistic resourcefulness of the commenters who support the protests and the indexing of an us–them relationship between Hong Kong and mainland China. Rather than decolonizing English, I argue that the Hong Kong commenters recolonize English for new subversive purposes to maintain an ideological ‘separation’ between their Hong Kong and Chinese identities in times of political transformations.

The complexities of communication at hospital discharge of older patients: a qualitative study of healthcare professionals’ views

BackgroundHospital discharge of older patients is a high-risk situation in terms of patient safety. Due to the fragmentation of the healthcare system, communication and coordination between stakeholders are required at discharge. The aim of this study was to explore communication in general and medication information transfer in particular at hospital discharge of older patients from the perspective of healthcare professionals (HCPs) across different organisations within the healthcare system.MethodsWe conducted a qualitative study using focus group and individual or group interviews with HCPs (physicians, nurses and pharmacists) across different healthcare organisations in Sweden. Data were collected from September to October 2021. A semi-structured interview guide including questions on current medication communication practices, possible improvements and feedback on suggestions for alternative processes was used. The data were analysed thematically, guided by the systematic text condensation method.ResultsIn total, four focus group and three semi-structured interviews were conducted with 23 HCPs. Three main themes were identified: 1) Support systems that help and hinder describes the use of support systems in the discharge process to compensate for the fragmentation of the healthcare system and the impact of these systems on HCPs’ communication; 2) Communication between two separate worlds depicts the difficulties in communication experienced by HCPs in different healthcare organisations and how they cope with them; and 3) The large number of medically complex patients disrupts the communication reveals how the highly pressurised healthcare system impacts on HCPs’ communication at hospital discharge.ConclusionsCommunication at hospital discharge is hindered by the fragmented, highly pressurised healthcare system. HCPs are at risk of moral distress when coping with communication difficulties. Improved communication methods at hospital discharge are needed for the benefit of both patients and HCPs.

A review on alkaline sulfite anthraquinone methanol as an alternative pulping process for non-woody biomass

A review on alkaline sulfite anthraquinone methanol as an alternative pulping process for non-woody biomass

Development of cellulose films by means of the Ioncell® technology, as an alternative to commercial films

In recent years, the search for alternatives to petroleum derived products, such as plastic films, has become a priority due to the growing depletion of fossil reserves and the pollution of water resources by microplastics, microscopically small plastic particles which are harmful to ocean and aquatic life. Cellulose-based films, e.g., cellophane and cuprophane, have been on the market for almost a century. Despite being a more ecological option compared to plastic films, the manufacture of these cellulose films involves high production costs and the use of harmful chemicals. As an alternative, a sustainable and eco-friendly process based on the Lyocell-type Ioncell® technology is presented to produce cellulose films. Regenerated cellulose films are created by continuous extrusion via dry-jet wet spinning of an ionic liquid–cellulose solutions. The influence of the polymer concentration (8–13 wt%) and processing temperature (50–100 °C) on the properties of the films were studied by the determination of the thickness, mechanical properties, physical appearance, morphology, chemical composition, and hydrophobicity. The obtained films are thin (12–21 μm), transparent (transmittance = 91%) and of homogeneous structure. Moreover, they exhibit excellent mechanical properties: stress values up to 210 MPa and elongations up to 19% in machine (longitudinal) direction. These values clearly outperform commercial cellophane, which presents stress values of 125 MPa and elongations of 22%. The films presented herein hold great potential to become an eco-friendly and sustainable option to commercial films.

Unlocking the potential of ferrate(VI) in water treatment: Toward one-step multifunctional solutions

Ferrate(VI), though well-acknowledged for its multiple treatment functions, has traditionally found application in an auxiliary treatment of conventional water treatment trains, primarily targeting specific contaminants. However, the reactor configurations and system operations developed from this traditional approach are not optimally suited for harnessing its full multifunctionality. In contrast, an alternative process integration approach, such as process intensification, can allow for the tailored development of modular, multifunctional ferrate(VI) reactors capable of achieving various treatment objectives within a single unit. This perspective article critically analyzes and compares the two distinct development approaches for ferrate(VI) technology in water treatment. We argue that the process integration pathway represents a promising approach, given that it facilitates the reactor design to accommodate different ferrate(VI)-driven treatment processes and their interactions, while potentially accomplishing enhanced treatment efficiency, reduced costs and energy consumption, and a smaller physical footprint. The resulting system intensification and adaptability have the potential to drive technological innovation and revolution in water treatment for achieving water security.

Rice straw-based sustainable food packaging material with improved strength and barrier properties: Development and characterization

Sustainable food packaging paper with high barrier and strength properties was developed with rice straw nanocellulose materials. Pulping and bleaching of rice straw were performed using an organosolv pulping and DED (D: chlorine dioxide bleaching; E: sodium hydroxide extraction) bleaching sequence. Bleached rice straw pulp was refined to 90°SR using a laboratory Valley beater. The laboratory handsheets were prepared using pulp slurry at 40°SR and 90°SR. The handsheets of cellulose nanofibrils (CNFs) made of highly refined pulp (90°SR) were surface sized using alkyl ketene dimer (AKD) wax to increase the barrier properties of paper for selective food packaging applications. The paper samples were tested for mechanical, optical, surface, and barrier properties, including tensile index, burst index, tearing index, bending stiffness, elongation, porosity, apparent density, opacity, Cobb value, water vapor transmission rate (WVTR), oil and grease resistance, and contact angle. The refined pulp (90°SR) was analyzed using field-emission scanning electron microscopy (FE-SEM), and it was observed that the morphology of the developed fibers changes to the nanoscale (<100 nm) for at least one dimension. The particle size distribution of the refined pulp using DLS analyzer also confirmed the cellulose fibers to near nanoscale. It was concluded that nanofibers were formed by a high degree of the mechanical pulp refining process and found to be much more economical than alternative processes in this direction. The sample handsheets of CNFs showed good strength and barrier properties. The barrier properties further increased when surface sizing was done using low-cost, nontoxic, and biodegradable AKD wax.

Framework for Lean Implementation Through Fuzzy AHP-COPRAS Integrated Approach

Manufacturing industries strive hard to improve their productivity to meet the highly demanding business market. Productivity can be improved by effective use of resources, elimination of wastes, process flow enhancement, and continuous improvement. There are strategies and tools to improve productivity but industries face the problem of selecting appropriate strategies. Lean manufacturing philosophy helps the manufacturing industries to enhance their productivity aspects by identifying and eliminating the wastes using specific tools/techniques. This article presents an integrated framework for the lean implementation process in the steel processing industry. The value stream mapping (VSM) tool is used to identify the wastes at each stage of the production process. Lean tools are identified from literature based on the wastes identified from the current state. For prioritizing the lean tools based on the positive correlation on one another, fuzzy integrated analytic hierarchy process and complex proportional assessment of alternatives are used. A future state value stream map is developed to illustrate the improvements achieved due to the implementation of selected lean tools. Comparison of present and future state VSM shows a great reduction of wastes, such as scale waste (50%), miss roll defects (72.7%), size variation defect (62%), corrosion defect, and improvements in talk time and cleanliness.

Feasibility of electrodeionization for phosphate removal.

In this study, electrodeionization (EDI) in bath mode was tested regarding its capability to remove phosphate (PO4 3- ) ions from aqueous solutions. Various parameters affecting the phosphate removal rate via EDI were determined. The results showed that the phosphate removal rate depends on the applied voltage and that the optimum potential was 15 V, corresponding to a phosphate removal rate of 97%. Changing the stream rate of the phosphate-containing solution also affected the phosphate removal rate. Changing the pH of the phosphate-containing solution from 2 to 6 enhanced the phosphate removal rate from 80% to 97%. The presence of Cl- , NO3 - , and SO4 2- ions did not affect the phosphate removal rate. The highest mass transfer coefficient (k) of phosphate was calculated to be 7.85 × 10-4 m/s, and the flux was calculated to be 3.72 × 10-4 mol/m2 s1 at a flow velocity of 3L/h. Thus, the study results showed the feasibility of EDI as an alternative membrane process for removing phosphate from aqueous solutions. PRACTITIONER POINTS: Electrodeionization was employed for the removal of phosphate. The removal of phosphate exhibited dependence on applied potential. EDI demonstrated a remarkable 97% efficiency in phosphate removal. The pH of the solution was found to influence the removal rate.

On the influence of joining processes on the vibration of structures

The joining of new and dissimilar materials in the transportation sector, to meet the demands for lighter structures, requires the use of alternative joining processes. However, it is not clear how different types of structural joints compare in terms of their contribution to the vibration and damping of structures. The present work aims to provide a comprehensive experimental and numerical analysis on the contribution of three structural joints – butt friction stir welding, single lap adhesive joint and hole hemmed joint – to the vibration and damping of two joined aluminium sheets. For this purpose, experimental analysis is performed to study the free-free vibration of the three structural joints. In addition, finite element models are developed to better understand the behaviour of these joints and discuss the challenges of the numerical modelling procedure. The first four natural frequencies, experimentally obtained for each structure, suggest that the adhesive joint has significantly higher natural frequencies, due to the thickness increase at overlap, while the hole hemmed joint presents the most significant contribution to damping, owing to sliding at the overlap region. The numerical models show a very good agreement with the experimental results in terms of the natural frequencies and mode shapes, with simple modelling providing accurate results. In conclusion, the main findings are that the adhesive joints allow for a stiffer structure, with the natural frequencies increasing with the overlap dimension, while hole hemming enhances damping. The butt-butt friction stir welding has a small effect on the structural behaviour, showing a similar dynamic stiffness and damping when compared to a solid sheet of the same dimension.

Material Influence on the Micropitting and Wear Resistance of Nitrided External and Internal Gears

Abstract Due to increasing performance requirements and sometimes tribologically challenging operating conditions in gears (such as those found in wind turbines), alternative heat treatment processes to quenching and tempering or case hardening are becoming more and more important. Nitriding can significantly increase the load-carrying capacity of gears compared to the quenched and tempered initial state. The nitrided surface layer is characterized by a hard compound layer on the surface that is just a few micrometers thick and a diffusion zone that extends deeper into the material. The structure of the compound layer of iron and alloy element nitrides is primarily decisive for the wear behavior of nitrided components. Previous studies on nitrided gears with regard to micropitting and wear focus primarily on a systematic variation of the compound layer on gears made of nitriding steel 31CrMoV9. Results on the influence of the base material on the micropitting and wear resistance of nitrided gears are not yet available. In systematic load and speed stage tests, nitrided gears made from a quenched and tempered steel (42CrMo4) and a material with an alternative alloy composition (34CrNiMo6) were examined in addition to the reference (nitriding steel 31CrMoV9). Both external and internal gear pairings were tested, with the alternative materials showing more favorable tribological behavior in some cases. The results are presented and categorized according to the current state of the art. Finally, recommendations for the practical use of nitrided gears are derived.

HIV-1 Tat commandeers nuclear export of Rev-viral RNA complex by controlling hnRNPA2-mediated splicing.

HIV-infected host cells impose varied degrees of regulation on viral replication, from very high to abortive. Proliferation of HIV in astrocytes is limited when compared to immune cells, such as CD4+ T lymphocytes. Understanding such differential regulation is one of the key questions in the field as these cells permit HIV persistence and rebound viremia, challenging HIV treatment and clinical cure. This study focuses on understanding the molecular mechanism behind such cell-specific disparities. We show that one of the key mechanisms is the regulation of heterogenous nuclear ribonucleoprotein A2, a host factor involved in alternative splicing and RNA processing, by HIV-1 Tat in CD4+ T lymphocytes, not observed in astrocytes. This regulation causes an increase in the levels of unspliced/partially spliced viral RNA and nuclear export of Rev-RNA complexes which results in high viral propagation in CD4+ T lymphocytes. The study reveals a new mechanism imposed by HIV on host cells that determines the fate of infection.

Comparative Analysis of Diffusion Metallization Coatings Applied on Steel Parts

In this paper the positive and negative aspects of diffusion metallization of steels were reviewed. It was shown that at high heating temperatures and prolonged exposure under these temperatures, steels show a tendency to enlarge austenitic grain. Overheating can occur at high exposure temperatures (T>1000ᵒC), which can be rectified by repeated heating however if burning of the steel microstructure occurs, it cannot be corrected. Given these circumstances, when assigning diffusion metallization modes, it is necessary to consider the factor of overheating or burning of steel in the process of exposure to high temperatures. To avoid this phenomenon, it is recommended to use alternative low-temperature processes of diffusion saturation of steels. Nitriding, nitro-cementation, gas-thermal spraying of the surface of steels are shown as such examples. It was suggested that these processes in comparison with diffusion metallization are more promising and acceptable for the restoration of worn surfaces of steels in the manufacture of parts of specialized equipment. Given that the parts of specialized equipment work in extreme conditions, repeated high-temperature heating of these steels is not recommended.To overcome the shortcomings of the diffusion metallization, the most frequently used coatings are applied by CVD, thermal spray, and cloth cladding techniques. As an alternative promising solution, the development of innovative methods of diffusion saturation, like an ion plantation of atoms on a relatively cold surface of the part could also be considered. It is shown that diffusion metallization is most acceptable for saturation of the surface of non-ferrous metals and alloys with the hardest and wear-resistant compounds.

Microsoft Excel Learning Application Design with Android Based using Gamification Method

Microsoft excel is software can support performance in data processing, microsoft excel provides formulas and function that can be used to facilitate perfomance in data processing. Utilization of microsoft excel can be used in every day life in business and educational activities. Microsoft excel can perform arithmetic calculation, so can simplifying the assessment results and as an alternative that can provide maximum results. The purpose of this research is design and build a microsoft excel learning application with the gamification method to increase behavioral intention to use and immersion in the learning process to provide an alternative learning process in learning formulas and functions in microsoft excel. The method used in this study was designed and built with the gamification method using the six steps to gamification framework developed by Kevin Werbach in 2016. The results of this learning application have been evaluated by 32 respondents by filling out a survey based on the Hedonic Motivation System Adoption Model. From the survey, 77.5% were obtained for the behavioral intention to use aspect and 64.53% were obtained for the immersion aspect. The conclusion of this study in implementing gamification using the six steps to gamification framework states that they agree with evidence of 77.5% for the behavioral intention to use aspect and 64.53% for the immersion aspect.

Cyclic Voltammetry of C.I. Disperse Orange 62 in an Aqueous Electrolyte.

Disperse dyes are an important group of colorants for dyeing polyester fibers. Approximately 30.000 tons of disperse dyes are released into the waste water annually from spent dyebaths. Therefore, methods for decolorizing such dyes are of general interest. The reductive after-treatment of disperse dyes using reducing agents, such as Na2S2O4, is a widely used process to improve rub fastness through dye reduction. Electrochemical dye reduction could be an alternative process for reductive dye treatment. In this work C.I. Disperse Orange 62 was used as a representative dye to study the direct cathodic reduction of a disperse dye with cyclic voltammetry. As anticipated for dispersed organic matter, relatively low current densities were observed, which strongly depend on the state of dispersion of the dye. The current density was increased by using dispersions prepared through dye precipitation from DMF solution and by the use of N-cetyl-N,N,N,-trimethyl-ammonium bromide as a cationic surfactant. The results demonstrate the successful cathodic reduction of a dispersed organic dye; however, the low solubility of the reaction products in the aqueous electrolyte hinders an efficient cathodic dye reduction.

Psych verbs: the behavior of ObjExp verbs in Brazilian Portuguese

AbstractPsychological verbs, especially Object Experiencer verbs, are widely discussed in the linguistic literature because of their peculiar syntactic and semantic properties. Two main issues regarding Object-Experiencer verbs are often raised: their aspectual nature and an alternation process (with the experiencer in subject position). This article analyzes Brazilian Portuguese Object Experiencer verbs, focusing on these issues. Based on a study of 170 verbs, we claim that Object Experiencer verbs constitute a verb class whose members describe a complex stage-level state in which a stimulus state activates (in a causative relation) a mental state in an experiencer. In addition, we argue that Object-Experiencer verbs appear in an inverse form: the experiencer as subject, and the stimulus as oblique. We claim that such an inverse form does not result from the causative alternation. In the inverse structure, different from an inchoative form of a change-of-state verb, both arguments are strongly preferable, and the verbs still denote a stative situation. We also provide a representation for the event structure of those verbs, using predicate decomposition, that is associated with their syntactic properties.

AI-powered decision-making in facilitating insurance claim dispute resolution

AbstractLeveraging Artificial Intelligence (AI) techniques to empower decision-making can promote social welfare by generating significant cost savings and promoting efficient utilization of public resources, besides revolutionizing commercial operations. This study investigates how AI can expedite dispute resolution in road traffic accident (RTA) insurance claims, benefiting all parties involved. Specifically, we devise and implement a disciplined AI-driven approach to derive the cost estimates and inform negotiation decision-making, compared to conventional practices that draw upon official guidance and lawyer experience. We build the investigation on 88 real-life RTA cases and detect an asymptotic relationship between the final judicial cost and the duration of the most severe injury, marked by a notable predicted $${R}^{2}$$ R 2 value of 0.527. Further, we illustrate how various AI-powered toolkits can facilitate information processing and outcome prediction: (1) how regular expression (RegEx) collates precise injury information for subsequent predictive analysis; (2) how alternative natural language processing (NLP) techniques construct predictions directly from narratives. Our proposed RegEx framework enables automated information extraction that accommodates diverse report formats; different NLP methods deliver comparable plausible performance. This research unleashes AI’s untapped potential for social good to reinvent legal-related decision-making processes, support litigation efforts, and aid in the optimization of legal resource consumption.

Enhancing Fertilizer Effect of Bioprocessed Brewers’ Spent Grain by Microbial Consortium Addition

Brewers’ spent grain (BSG) is primarily recycled as livestock feed due to its high fiber content, undegradable protein, and water-soluble vitamins. However, BSG composting represents a possible alternative to organic waste management. Adding a microbial consortium further enhances the agronomical properties of the compost intended for fertilizing applications. Microbial-based fertilizers (plant growth-promoting microorganisms, PGPM) are a means to mitigate the adverse environmental impacts of excessive or improper chemical fertilizer use, enhance the direct or indirect uptake of nutrients by plants, and add value to food waste. In a short-term pot experiment on iceberg lettuce (Lactuca sativa L.), this study assessed the effects of compost and pelletized compost from brewers’ spent grain, both enriched with a microbial consortium. In a randomized block experiment, this study compared four organic BSG fertilizers to chemical fertilizer (NPK) and an unfertilized control treatment. The investigation indicates that BSG compost and BSG pelleted compost, with and without bio-inoculum, in general, are comparable to mineral fertilizer treatment; lettuce fresh weight was higher in pots amended with bioprocessed BSG, associated with more significant growth of soil LAB, fungi, and actinomycetes. The investigation outcomes support composting as an alternative recycling process for producing PGM for agricultural applications.

Comparative analysis of isopropyl alcohol dehydration using ionic liquids and deep eutectic solvent

The current article deals with the separation of the azeotropic mixture of isopropyl alcohol (IPA) and water using an ionic liquid, 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM][BF4]) and Deep Eutectic Solvents (DESs), Choline Chloride/glycerol (Glyceline) and Choline Chloride/Ethylene Glycol (Ethaline). Conventional dimethyl sulfoxide (DMSO) solvents are used to compare the results for IPA dehydration. Process modelling and simulation were carried out in the Aspen Plus simulator (v.8.6). The NRTL model was used to calculate the thermodynamic properties as well as the vapour-liquid equilibria of the ternary systems. The process parameters such as entrainer flow rate, binary feed stage, entrainer feed stage, column stages, reflux ratio, reboiler and condenser duties were evaluated using sensitivity analysis and design spec tools of the simulator. The industrial process for both systems, containing a separation column and a recovery column, was simulated at a steady state. Both processes were optimised using the optimisation tool of the simulator and compared based on the energy requirement. Further, based on the simulation results, we proposed an alternate process design for solvent recovery using a flash drum. The results show that more than 99.9 mol% IPA purity can be achieved using both ILs as well as DESs. The overall energy requirement for the separation of IPA-water mixture using [EMIM][BF4] entrainer in a conventional process was found to be lower than DMSO. The proposed alternate process further reduces the energy requirement compared to the conventional process for both IL and DESs systems.

Connecting friends

We study how people form networks through introductions. We consider a model where players with different ability levels are connected in a network. The players seek to match with someone they are linked to in the network (i.e., their neighbors), and they prefer high-ability neighbors over low-ability ones. We investigate whether a player will strategically introduce two unacquainted neighbors to each other to improve her own matching outcome. We find that this is possible if (i) the player making the introduction is less capable than both of the neighbors she considers introducing, and (ii) there exists an even-length alternating path—a sequence of linked players that alternate between matching and not matching with the next player on the sequence—from one of the neighbors to the introducer. The characterization based on alternating paths arises because an introduction can trigger a chain of rematches along these paths. Then, we characterize stable networks and efficient networks, and we show that stability and efficiency do not imply each other. Finally, we consider several extensions, such as alternative matching processes and incomplete information.