Allyltrimethylsilane Research Articles

Effects of functional groups in glow discharge polymerization

Glow discharge polymerizations of allyltrimethylsilane (ATMS) and trimethylvinyloxysilane (TMVOS) were investigated by elemental analysis and infrared spectroscopy. The formed polymers were far different in elemental composition from the starting materials, and possessed high carbon and hydrogen contents. There was less difference in an infrared-spectral sense between the two polymers from ATMS and TMVOS. A polymer-forming process in a discharge state is discussed.

Regioselective Synthesis of Allyl Trimethylsilanes from Allylic Halides

Abstract Treatment of an allylic halide 1 with a trimethylsilyl metal reagent affords either trans allyl trimethylsilane 4 or the regioisomeric allyl trimethylsilane 3 with proper choice of reaction conditions.

Organometallic compounds in organic synthesis : electrophilic reactions of some tricarbonylcyclohexadienylium-iron complexes with allyltrimethyl silanes.

Allyltrimethylsilanes react with a range of tricarbonylcyclohexadienyl-iron complexes under mild conditions to form new carbon-carbon bonds in excellent yields.