The sufficient provision and sustenance of quality water have been of a fundamental consequence in the social and economic developmental activities of humans over the years, especially in Bayelsa state and Nigeria at large, where developmental activities are on the increase. Potable water is essential to humans and animals alike, for personal, communal, industrial and societal uses. This study seeks to investigate the concentration of dissolved minerals, using an integrated approach of VES data and physicochemical analysis of ground water samples in parts of Bayelsa state, south-south Nigeria. Vertical Electrical Sounding was implemented in ten stations and interpreted using IPI2WIN software. The results from the VES interpretation revealed that the area is constituted of four to five geoelectric layers. Four distinct sounding curve types (H, HK, K and KH) were identified; with the H and K type curves being dominant. The dominant curve types show that the area has two main hydrologic regimes (of low and high Iron (Fe) concentration). The results show that in VES stations with K-type curve, the stratigraphy consists of the three to four layers, with varying thickness and corresponding resistivities; with the third or fourth layers identified as the aquifer layer. At H-type curve locations, the stratigraphy consists of the top soil, the clay layer, and the sand layer, which was identified as the aquifer. The physicochemical characteristics of water samples, collected from drilled boreholes in the vicinity of the VES locations of the study area, were analyzed for prominent physical and chemical constituents, including EC, pH, TDS, Na, K, Ca, Mg, Fe, Cl, SO, NO, and HCO. Physicochemical analysis was achieved using the standard APHA methods and compared with WHO standard. The results showed that the concentration of the chemical constituents varied spatially in the study area. The analysis revealed that 90% of the mean concentration of measured parameters were within the WHO’s standard in all the samples, except for Mn (with a value of 0.532 mg/L) and Fe<sup>2+</sup> (with a value of 0.88 mg/L) which was seen to be high in five of the boreholes in locations with H-type curves, hence correlating areas of high groundwater contamination to VES stations of the H-Curve type. The high Mn and Fe concentrations in the groundwater of some of the locations, makes the water unsuitable for drinking and may require treatment. Further analysis of the ground water samples, indicated that, Chloride and Sulphate are the predominant anions while, Calcium and Magnesium are the predominant cations in groundwater within the study area.
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