Alluvial Aquifer Research Articles

Meteorological and hydrogeochemical control on the co-occurrence of geogenic contaminants in the alluvial aquifers of northwest India

Innumerable studies have emphasized elevated fluoride (Fˉ) and uranium (U) levels in shallow aquifers in the semi-arid region of Punjab, India, endangering the groundwater-dependent population's health. This study examines the factors and mechanisms contributing to Fˉ and U co-occurrence in the region's aquifers to enhance the understanding of the contaminants' behaviour. Fˉ and U concentrations were higher in shallow aquifers (<60 m) compared to deeper (>60 m), and both the contaminants surpassed their respective permissible limits under excess EC, TDS, Clˉ, NO3ˉ, SO42ˉ, Na+, and K+ levels. Elevated EC and TDS and their strong correlation with U and Fˉ suggest high salinity facilitated mobilization and co-contamination by increasing ionic strength and competitive behaviour through ion exchange mechanisms. Additionally, scanty precipitation, enhanced evapotranspiration, and aridity were significantly correlated to Fˉ and U, highlighting that these meteorological variables positively influence this co-contamination, particularly in the Malwa region. The mixed chemical composition of the groundwater emanated from rock-water interaction and evaporation, which further increased Fˉ and U and facilitated their co-occurrence. U existed predominantly as UO2(CO3)22ˉ and UO2(CO3)34ˉ (95%), which corroborated with a strong positive correlation with HCO3ˉ, whereas fluoride existed mainly as free Fˉ (90%). The findings of this work will help the scientific community to address similar issues in other arid and semi-arid regions globally and investigate the potential synergistic effect and health risks associated with the co-occurrence of Fˉ and U in the groundwater.

Groundwater Vulnerability Assessment—Case Study: Tirana–Ishmi Aquifer, Albania

This paper discusses the groundwater vulnerability to pollution assessment for the Tirana–Ishmi alluvium aquifer, Albania. Economic activities, municipal wastewater discharged into rivers and groundwater overexploitation threaten to pollute the groundwater. Based on the aquifer characteristics and the available data, SINTACS was selected as the most realistic assessment model. The SINTACS parameters’ rates assigned to the aquifer’s characteristics (water table depth, infiltration, unsaturated zone, soil media, aquifer media, hydraulic conductivity, topography) were adapted to the local features, followed by GIS vulnerability mapping. Statistical analysis indicates that the unsaturated zone, hydraulic conductivity and aquifer media have the highest influence on groundwater vulnerability, whereas topography has the lowest influence. Validation through sensitivity analysis and nitrates content confirms the rational selection of the SINTACS model and the reliability of the study’s outputs. The most vulnerable areas to pollution are the recharge zones, followed by the highly urbanized Tirana City area, characterized by high levels of groundwater extraction rate and wastewater discharged into the rivers. The paper, being the first completed groundwater vulnerability assessment of the study area, could serve as a basis for a scientific–based groundwater management that should be considered in local territory planning.

Grain Size Distribution and Provenance of Holocene Sand from the Sava River (Zagreb, Croatia)

This study involves an investigation into the grain size distribution and provenance of the sand deposited near Zagreb (Croatia) in the riverbed of the regionally important, almost 1000 km long Sava River, which connects several SE European countries. Recent research in the study area has mainly focused on the deposits forming the Zagreb alluvial aquifer system, rather on the Sava River sediment deposited in its riverbed, which is the focus of this study. The grain size distribution results obtained by dry sieving and laser granulometry showed a predominately fine and medium sand deposition at riverbanks and sand point bars. Medium sand increased downstream towards the east, within the artificially more channelized riverbed in the urban area. Fine sand prevailed 50 km further downstream in a more meandering low-relief area, near the city of Sisak and Lonjsko Polje Nature Park. Provenance analysis showed predominately carbonate sand in the western part of the city of Zagreb, originating from distant (Alpine) and local (Medvednica Mt. and Samobor Hills) sources. More siliciclastic sand was deposited in the Sava riverbed in the middle and eastern parts of Zagreb, originating mainly from the Medvednica Mt. The prevailing siliciclastic sand further downstream of the Sava River is probably sourced from the Kupa River tributary. Although various studies of the Zagreb alluvial aquifer system have been conducted so far, this study represents a novelty in its investigation into the grain size distribution of the Sava riverbed sand itself, setting the foundations for investigations in the future.

SEG Summer Field Camp: Multigeophysical imaging of an aquifer in the Astara region of Azerbaijan

Groundwater faces growing pressure due to human activities and the impacts of global climate change. Therefore, it is imperative to characterize near-surface aquifers, especially those that are unconfined because they are particularly vulnerable to these challenges. In Azerbaijan, alluvial plain aquifers represent a critical facet of the nation's water resources, yet they remain largely understudied. The objective of our study is to employ a multigeophysical survey (including electrical resistivity, seismic refraction, and ground-penetrating radar) to describe the subsurface attributes of an unconfined alluvial aquifer situated within an agricultural field in Astara, Azerbaijan. These data were acquired during the 2023 SEG Summer Field Camp by global students and specialists. Based on our general knowledge of the area, we interpret our findings as a subsurface with four distinct layers. The first is an initial 1 m thick soil layer covering the second layer, which is a more permeable unconfined aquifer likely consisting of a mixture of sand, pebbles, and gravel with a silty matrix (3 m thick). The third is a potential confining layer that is possibly clayey. The fourth layer is a presumed confined aquifer at a depth of 10 m. These results shed light on previously unstudied alluvial plain aquifers and contribute to comprehension of the hydrogeologic conditions at the local scale. To provide a broader understanding at the regional scale, the survey area should be extended and linked to borehole data to improve the interpretation of the geophysical results.

Untapped Potential of Groundwater Resources of Bihar

"Bihar is endowed with rich water resources due to the high precipitation, extensive river basin network, and alluvial aquifer with significant storage space for groundwater. Majority of its population is dependent on agriculture and related activities for their sustenance. However, there is uneven distribution of groundwater potentials due to variability of rainfall. Although evidence at the aggregate level indicates the under-utilization of groundwater resources in Bihar, there are few areas with depleting groundwater levels as well. This is indicated by the increase in the over-exploited and critical blocks from zero per cent to 1.5 and 2.2 per cent respectively. Irrigation being the predominant consumer of groundwater bears the prime responsibility of using this resource sustainably. Presently, groundwater irrigates 63% of the net irrigated area and its share has been rising. Various studies on water quality and quantity indicate that Bihar may experience severe scarcity of water in the nearby future. Water shortages will become chronic in this water surplus condition, necessitating quick remedial measures to conserve and protect this vital water supply. As groundwater is largely underutilized, there exists a huge scope to accelerate sustainable use of groundwater for harnessing a positive groundwater-agricultural development linkage. The untapped groundwater resource should be utilized by private and government agencies for irrigation."

Understanding arsenic and manganese enrichment in the aquifers of the Ghaghara river basin, Middle Gangetic Plain (MGP), India: A multivariate statistical, compositional data analysis (CoDA), and receptor model approach

The focus of this study was to comprehend the spatial distribution, source apportionment, evaluation of natural background level (NBL), and mobilization mechanisms of arsenic (As) and manganese (Mn) in the Ghaghara river basin, located in the middle Gangetic plain (MGP) of India. A combination of analytical tools was employed, including multivariate statistical analysis (MSA), correlation analysis, and receptor models such as positive matrix factorization (PMF) and principal component analysis-multi linear regression (PCA-MLR). Taking into consideration the compositional constraints of the geochemical data, compositional data analysis (CoDA) methods were applied on the raw data prior to the correlation analysis and MSA. The results of MSA, correlation analysis and receptor models showed that major ion chemistry and As, Mn enrichment in groundwater were largely controlled by carbonate weathering, Fe and Mn oxyhydroxides dissolution. Anthropogenic activities, such as the infiltration of dissolved organic matter-rich water from local surface water bodies used as dumping sites and the infiltration of fertilizer-rich water from agricultural lands, were found to notably impact the groundwater geochemistry and release of As in the research area. The lower NBL of As (5.92 μg/L) compared to its mean concentrations (17.9 μg/L) in the study area also indicated that the rate of As release in groundwater through natural processes was comparatively low but various anthropogenic activities operating in the study region possibly acted as a trigger for the mobility of As from the mineral phases of the subsurface sediments. This study also highlighted the significance of applying CoDA techniques on geochemical data prior to statistical analysis, and the importance of receptor models, to better understand the nature and contribution of various natural and anthropogenic processes governing the hydrochemistry of groundwater in the alluvial aquifers.

A multi-method approach for assessing groundwater vulnerability of shallow aquifers in the Marchfeld region (Austria)

Study regionMarchfeld region (Austria) Study focusA multi-method and multi-scale assessment of the intrinsic groundwater vulnerability to generic pollutants was carried out. At the regional scale, a parametric method, to assess the intrinsic groundwater vulnerability, and a transfer function model, to assess the travel time of a generic and non-reactive pollutant through the unsaturated zone, were applied. At the site-specific scale, the travel time of the peak concentration was evaluated by using a physically-based hydrological model. The comparison of results of different approaches allowed mutual validation and advanced the knowledge about the assessment of groundwater vulnerability. New hydrogeological insights for the regionTo assess the groundwater vulnerability, a detailed hydrogeological map of the study area was reconstructed. A large variability of hydrogeological, morphological and anthropic conditions was recognized. Alluvial aquifers formed by high-permeability deposits hosting shallow groundwater circulation are characterized by the highest groundwater vulnerability. Contrarily, lower groundwater vulnerability was recognized for aquifers formed by low-permeability deposits, favoring a reduction of infiltration processes and a major attenuation of pollutants’ potential effects. The presented multi-method approach revealed how comparing the results of a DRASTIC-like method and two process-based models can deliver hints regarding their suitability, different spatial densities and quality of required inputs, and effectiveness. Finally, the potential strong impact of some agricultural practices was confirmed.

Unravelling the signatures of submarine groundwater discharge and seawater intrusion along the coastal plains of Odisha, India: a multi-proxy approach.

Submarine Groundwater Discharge (SGD) and Seawater Intrusion (SWI) are two contrary hydrological processes that occur across the land-sea continuum and understanding their nature is essential for management and development of coastal groundwater resource. Present study has attempted to demarcate probable zones of SGD and SWI along highly populated Odisha coastal plains which is water stressed due to indiscriminate-exploitation of groundwater leading to salinization and fresh groundwater loss from the alluvial aquifers. A multi-proxy investigation approach including decadal groundwater leveldynamics, LANDSAT derived sea surface temperature (SST) anomalies and in-situ physicochemical analysis (pH, EC, TDS, salinity and temperature) of porewater, groundwater and seawater were used to locate the SGD and SWI sites. A total of 340 samples for four seasons (85 samples i.e., 30 porewater, 30 seawater and 25 groundwater in each season) were collected and their in-situ parameters were measured at every 1-2km gap along ~ 145km coastline of central Odisha (excluding the estuarine region). Considering high groundwater EC values (> 3000 μS/cm), three probable SWI and low porewater salinities (< 32 ppt in pre- and < 25 ppt in post-monsoons), four probable SGD zones were identified. The identified zones were validated with observed high positive hydraulic gradient (> 10m) at SGD and negative hydraulic gradient (< 0m) at SWI sites along with anomalous SST (colder in pre- and warmer in post-monsoon) near probable SGD locations. This study is first of its kind along the Odisha coast and may act as initial basis for subsequent investigations on fresh-saline interaction along the coastal plains where environmental integrity supports the livelihood of coastal communities and the ecosystem.

GIS-based multi-criteria decision analysis for groundwater dam site selection in an arid and semi-arid region of Algeria

Securing reliable water resources in arid and semi-arid regions poses a significant challenge for decision-makers, especially under recent droughts and projected climate change. This need is particularly acute in the M'zi Wadi basin, located in the north-central part of Algeria, where its surface water projects are challenged by low and erratic rainfall coupled with high water evaporation, adversely impacting its water resources sustainability. Implementing water harvesting techniques in such arid regions, specifically groundwater dams, can be regarded as an effective water scarcity adaptation strategy, and their effectiveness is dependent on the optimal site selection which must consider many complex criteria. The paper aims to identify potential sites for groundwater dams in the M'zi Wadi basin using a multi-criteria decision-making approach in a GIS environment based on seven socio-economic and natural factors such as rainfall, stream order, land use/land cover (LULC), geology, Topographic wetness index (TWI), and distances from faults and villages. The results showed that approximately 1.27% of the M'zi Wadi basin area is highly suitable for groundwater dam siting. Four candidate sites were identified as having favourable conditions for installing new groundwater dams based on field and geophysical survey data conducted along the alluvial aquifer of the M'zi Wadi basin, and the remaining areas were deemed unsuitable due to specific constraints. The suitability of the selected sites was validated through a comparative analysis with existing groundwater dams. The results of the present study could offer valuable insights for decision-makers at all levels, facilitating informed judgments during the initial planning of groundwater dam construction. Furthermore, the methodology can be replicated in other data-scarce regions under similar arid climate conditions.

Integration of ground geophysical methods to characterize near‐surface aquifer zones within an active mine

AbstractUnderstanding near‐surface groundwater storage, flow patterns, surface and groundwater interactions in mining areas can assist in making mining more efficient and profitable. This is especially important in opencast mines affected by water inflows that may negatively affect production and increase mining costs. We map and characterize the near‐surface aquifer zones at the opencast site of Tharisa Minerals, located in the southwestern region of the Bushveld Complex (South Africa). The main goal is to infer pit water inflow at the mine site and determine how it may be better controlled. The Bushveld Complex hosts partially connected and unconfined alluvial, shallow‐weathered and crystalline bedrock aquifers, which are often connected by small‐scale permeable zones. Seismic refraction tomography, multichannel analysis of surface waves, electrical resistivity tomography and borehole data are used to map and understand the different aquifer zones in the vicinity of the mine, as well as infer their relation to water inflow in the mine pits. The geophysical surveys map the overburden, weathered bedrock aquifer zone, and the top of the crystalline aquifer rock zone reasonably well. They reveal extensive and deep weathering, and possible high hydraulic conductivity in the vicinity of the mine. The results provide a better understanding of the mine's near‐surface environment, which could be used to implement effective and targeted dewatering techniques, thus enabling better pit inflow water control to improve mine working conditions and production.

Economic Evaluation of Water Management Alternatives in the Upper Green River Basin of Wyoming

Water use efficiency measures are generally recommended to reduce water use. Yet, flood irrigation practices in high-elevation mountain valleys of the Colorado River Basin headwaters generate return flows, which support late-season streamflow and groundwater recharge. Return flows support the ecosystem and provide recreational benefits. This study provides a framework for quantifying how land-use changes and associated return flow patterns affect the economic value of water across uses in a hydrologically connected, shallow alluvial aquifer system. This study first investigates how return flow patterns could change under three alternatives to flood irrigation: an increased use of center pivots, increased residential development, and conversion to pasture. The brown trout was used as an indicator species to track eco-hydrology, return flow, and capacity for recreational activities under each alternative. Estimates from the non-market valuation literature coupled with predicted changes in brown trout productivity approximate associated changes to recreational angler value. Recreational angler values are highest under the flood irrigation alternative. The inclusion of recreational angler values with agricultural values alters the magnitude of returns but not the rankings. These results highlight the potential heterogeneity of conclusions to be drawn regarding water use efficiency, depending on the economic value of water in different uses and the degree of hydrologic connectivity. This study also highlights data gaps and modeling needs for conducting similar future analyses.

Evaluating trends in groundwater quality of coastal alluvial aquifers of Eastern India for sustainable groundwater management.

Groundwater is a precious natural element which ensures global water, food, and environmental security in the twenty-first century. Systematic monitoring, sustainable utilization, preservation and remediation are critical aspects of efficient groundwater resource management. This study deals with the analysis of spatial variability and trend in groundwater chemistry as well as identification of possible contamination sources in a coastal alluvial basin of eastern India. Pre-monsoon season data of 14 groundwater-quality variables measured in 'leaky confined' and 'confined' aquifers were analyzed for ten years (2012-2021). Mann-Kendall (M-K) test with the Sen's Slope Estimator, Spearman Rank Order Correlation (SROC) and Innovative Trend Analysis (ITA) tests were employed to assess decadal (2012-2021) trends. The analysis of the results indicated that the 'critical' water-quality parameters exceeding the acceptable limits for drinking are TDS, EC, TH, pH, Mg2+, Na+, K+, Fe2+, HCO3-, Cl- and NO3-. Weak negative correlations between rainfall and groundwater elevation for both the aquifers reveal poor rainfall recharge into the aquifers. Therefore, a reduction in groundwater abstraction and augmentation of groundwater recharge is recommended. Trend analysis results indicated that the concentrations of TH, Mg2+ and Fe2+ exhibit significant increasing trends in the 'leaky confined aquifer'. In contrast, significant rising trends in TH, Mg2+, Na+, Fe2+, HCO3- and NO3- concentrations are identified in the 'confined aquifer'. Further, the SROC test could not detect the trends in groundwater quality in most blocks and for many parameters. On the other hand, the ITA test revealed significant trends in most of the parameters of the two aquifers in almost all the blocks. Trend magnitudes of the groundwater-quality parameters based on the Sen's Slope Estimator and the ITA test vary from -63.7 to 58.65mg/L/year for TDS, -14 to 39.07mg/L/year for TH, -1.49 to 4.83mg/L/year for Mg2+, -7.14 to 22.96mg/L/year for Na+, -0.32 to 0.44mg/L/year for Fe2+, -8.33 to 20.75mg/L/year for HCO3-, -26.52 to 31.01mg/L/year for Cl- and 1.29 to 3.76mg/L/year for NO3- over the study area. The results of M-K and ITA tests were found in agreement in all the blocks for both the aquifers. Groundwater contamination in both the aquifers can be attributed to weathering, geogenic processes, mineral dissolution, seawater intrusion, poor recharge pattern and injudicious anthropogenic activities. It is strongly recommended that concerned authorities urgently formulate efficient strategies for managing groundwater quality in the 'leaky confined' and 'confined' aquifers which serve as vital sources of drinking and irrigationwater suppliesin the study area.

Remediation potential of arsenic in the alluvial aquifers in the Bengal Basin: insights from simulations and time estimates

ABSTRACT Arsenic is found in significant quantities within the alluvial aquifers. Bangladesh heavily relies on the alluvial aquifers of the Bengal Basin as a source of irrigation and drinking water. Due to the flat topography, arsenic within an aquifer is not easily flushed out of the system. Additionally, continuous, unregulated pumping causes arsenic from deeper aquifers to migrate to shallower levels. This study simulates groundwater and contaminant transport in the alluvial aquifers of the Bengal Basin by comparison between two scenarios prior to human intervention with different sea levels, employing a combination of MODFLOW, MODPATH and MT3DMS. The simulations demonstrate that the hydraulic gradient and flow rates were higher during periods of considerably lower sea levels than they are at present. Additionally, it would require 5,600 years for the Holocene aquifer and 3,300 years for the Last Glacial Period aquifer to flush arsenic to the Bangladesh standard concentrations in drinking water in a 100-m-thick contaminated aquifer. This implies that if the sea level continues to rise with climate change, it will be difficult to remove arsenic from the alluvial aquifers in the Bengal Basin by natural flushing, which means artificial interventions need to be done in that region in the interest of the nation's health.

2D model of groundwater flow and total dissolved HCH transport through the Gállego alluvial aquifer downstream the Sardas landfill (Huesca, Spain)

The organic pollutants disposed at the Sardas landfill in Sabiñánigo (Huesca, northeastern Spain) by the INQUINOSA lindane factory have reached the Gállego alluvial aquifer and could affect the Sabiñánigo reservoir. The daily oscillations of the reservoir water level produce a tidal effect on the piezometric heads of the aquifer. These oscillations are transmitted in a damped way with a time lag, thus attesting that the silting sediments of the reservoir and the natural silts of the Gállego alluvial are interposed between the reservoir water and the layer of sands and gravels. A 2D finite element groundwater flow and total dissolved hexachlorocyclohexane (HCH) transport model through the Gállego alluvial aquifer is presented here. The flow model was constructed to: (1) Quantify the tidal effect, produced by the daily fluctuations of the reservoir water level on the aquifer; (2) Estimate the hydrodynamic parameters of the layer of sands and gravels; and 3) Estimate the vertical hydraulic conductivity of the silting sediments and silts; and (4) Quantify aquifer/reservoir interactions. The flow model reproduces the dynamics of the tidal effect and attests that groundwater velocity and flow direction changes daily in response to the oscillations of the reservoir level. Model results reproduce the measured well hydrographs and the Darcy velocity derived from tracer tests and confirm the validity of the conceptual model. The transport model of total dissolved HCH simulates the time evolution of the contaminant plume. The computed concentrations of total dissolved HCH and the contaminant mass outflux are very sensitive to changes in the source terms and the distribution coefficient, Kd of HCH. The best fit to the measured HCH plumes in September 2010 and December 2020 is obtained with a Kd ranging from 1 to 3 L/kg. The computed flux of dissolved HCH leaving the Sardas site in 2020 towards the Sabiñánigo reservoir ranges from 0.6 kg/year for Kd = 3 L/kg to 3.1 kg/year for Kd = 1 L/kg. The findings of this study will be most useful for planning and designing remedial and containment actions at the Sardas site and other similar lindane-affected sites.

Multi-Facet analysis of analytical and numerical models to resolve sustainable artificial recharge rates in unconfined aquifers

Managed aquifer recharge (MAR) has emerged as a potential solution to resolve water insecurity, globally. However, integrated studies quantifying the surplus source water, suitable recharge sites and safe recharge capacity is limited. In this study, a novel methodology is presented to quantify transient injection rates in unconfined aquifers and generate MAR suitability maps based on estimated surplus water and permissible aquifer recharge capacity (PARC). Subbasin scale monthly surplus surface runoff was estimated at 75% dependability using a SWAT model. A linear regression model based on numerical solution was used to capture the aquifer response to injection and to calculate PARC values at subbasin level. The available surplus runoff and PARC values was then used to determine the suitable site and recharge rate during MAR operation. The developed methodology was applied in the semi-arid region of Lower Betwa River Basin (LBRB), India. The estimated surplus runoff was generally confined to the monsoon months of June to September and exhibited spatial heterogeneity with an average runoff rate of 5000 m3/d in 85% of the LBRB. Analysis of the PARC results revealed that thick alluvial aquifers had large permissible storage capacity and about 50% of the LBRB was capable of storing over 3500 m3/d of water. This study revealed that sufficient surplus runoff was generated in the LBRB, but it lacked the adequate safe aquifer storage capacity to conserve it. A total 65 subbasins was identified as the best suited sites for MAR which had enough surplus water and storage capacity to suffice 20% of the total water demand in the LBRB. The developed methodology was computationally efficient, could augment the field problem of determining scheduled recharge rates and could be used as a decision-making tool in artificial recharge projects.

Anthropogenic Gadolinium Anomalies in an Alluvial Plain with On-site Wastewater Treatment Systems in Campinas, SP, Brazil

Gadolinium anomalies have become a well-established marker for the pollution caused by wastewater, but there is not yet a standardized method to estimate the anomaly. Here, we compare four different published equations, distinct threshold values and reference normalizing values to estimate Gd anomalies by applying them to the results of a hydrochemical investigation in an alluvial aquifer with on-site sanitation systems. We measured traditional wastewater markers (such as electric conductivity, NO3_N, NH4–N, Cl-) and REE in groundwater samples collected from hand-dug wells in two seasons. The ratios of Gd normalized measured concentrations to Gd normalized geogenic concentrations (GdSN/Gd*) estimated with the various methods ranged from 0.7 to 2.8. It turned out that the choice of the equation and the threshold value can affect the decisions about anthropogenic pollution’s occurrence (or not). The normalizing values did not play a significant role in the decision. Based on measurement uncertainties and on the interpretation of hydrogeological conditions in the study area, a threshold value of 1.3 for defining anthropogenic Gd anomalies was deemed adequate for the study area. The occurrence of Gd anomalies higher than 1.8 in two wells, one in each season, reinforces the hypothesis that the groundwater is contaminated by the on-site sanitation systems in the study area, as intermittent detection of anthropogenic Gd is a characteristic of this pollution source.

Successive bootstrapping deep learning approach and airborne EM-borehole data fusion to understand salt water in the Mississippi River Valley Alluvial Aquifer

Increasing demands from agriculture and urbanization have decreased groundwater level and increased salinity worldwide. Better aquifer characterization and soil salinity mapping are important for proactive groundwater management. Airborne electromagnetic (AEM) is a powerful tool for aquifer characterization and salinity delineation. However, AEM needs to be interpreted with caution before being used for groundwater quality analysis. This study introduces a framework that utilizes the AEM data for both lithologic modeling and salinity delineation. A resistivity-to-lithology (R2L) model is developed to interpret AEM resistivity to lithology based a depth-dependent multi-resistivity thresholds. Then, a cokriging method is used to integrate AEM data from two different EM systems to predict resistivity at the aquifer. Finally, a resistivity-to-chloride concentration (R2C) model utilizes the resistivity model to estimate chloride concentrations at sand facies. A deep learning artificial neural network (DL-ANN) model is introduced with a successive bootstrapping approach to estimate total dissolved solids first and then use it together with resistivity data to estimate chloride concentration. The methodology was applied to delineating salinity plumes in the Mississippi River Valley alluvial aquifer (MRVA). This study found that the salinity distribution in MRVA is highly correlated with the Jurassic salt basin, salt domes, faulting, seismicity, and river water quality. The result indicates salinity upconing due to excessive pumping.

Unraveling the Coupled Dynamics between DOM Transformation and Arsenic Mobilization in Aquifer Systems during Microbial Sulfate Reduction: Evidence from Sediment Incubation Experiment

Geogenic arsenic (As)-rich groundwater poses a significant environmental challenge worldwide, yet our understanding of the interplay between dissolved organic matter (DOM) transformation and arsenic mobilization during microbial sulfate reduction remains limited. This study involved microcosm experiments using As-rich aquifer sediments from the Singe Tsangpo River basin (STR) and Jianghan Plain (JHP), respectively. The findings revealed that microbial sulfate reduction remarkably increased arsenic mobilization in both STR and JHP sediments compared to that in unamended sediments. Moreover, the mobilization of As during microbial sulfate reduction coincided with increases in the fluorescence intensity of two humic-like substances, C2 and C3 (R = 0.87/0.87 and R = 0.73/0.66 in the STR and JHP sediments, respectively; p &lt; 0.05), suggesting competitive desorption between DOM and As during incubation. Moreover, the transformations in the DOM molecular characteristics showed significant increases in CHOS molecular and low-O/C-value molecular intensities corresponding to the enhancement of microbial sulfate reduction and the possible occurrence of methanogenesis processes, which suggests a substantial bioproduction contribution to DOM components that is conducive to As mobilization during the microbial sulfate reduction. The present results thus provide new insights into the co-evolution between As mobilization and DOM transformations in alluvial aquifer systems under strong microbial sulfate reduction conditions.

The comprehensive evaluation of nitrate origin and transformation pathways in the oxic alluvial aquifer in Serbia.

Accurate pollution source identification is essential for establishing adequate water management strategies, particularly in groundwater with slow flow and prolonged recharge process allowing long-term pollution retention. An integrated study based on hydrogeochemical, dual isotopic (δ15NNO3 and δ18ONO3), and microbiological approaches (DN, IRB, and SRB BART tests) along with the statistical data processing was conducted to determine nitrate origin and fate in oxic alluvial groundwater source Ključ in Serbia. The findings from a comprehensive investigation, encompassing 20 groundwater sampling locations during the period 2010-2019, delineated three distinct zones - the hinterland (anthropogenic impact area-untreated sewage inflow), the middle zone (area of mixed influence from fertilizer application, accompanied by a mitigated anthropogenic impact), and the zone of riparian denitrification. Significant linear relationship between anthropogenic impact parameters (Na, Cl, B, NO3-, NH4+, and electrical conductivity) along with the isotopic signatures (δ15N-NO3- ranking from + 10.01 to + 11.18‰ and δ18O-NO3- ranking from + 1.15 to + 6.24‰) and grouped sampling objects by cluster analysis indicated that hinterland is burdened by the nitrates originating from anthropogenic impact. The cross-section of groundwater flow data, concurrent increase of NH4+, and pH levels, along with the highest values of δ15N-NO3- (+ 12.90‰) and δ18O-NO3- (+ 9.70‰), indicated area of fertilizers (urea) impact. BART test results, pH increase, and low oxygen concentration, along with the groundwater flow data in riparian zone, indicated the unfolding of denitrification process. Presented research emphasizes the importance, necessities, and advantages of simultaneous and complementary use of hydrogeochemical, microbiological, and isotopic data.

GEOCRYOLOGICAL CONDITIONS OF THE FORMATION OF GIANT SPRING AUFEIS AT THE ANMANGYNDA RIVER (MAGADAN REGION) ACCORDING TO GEOPHYSICAL DATA

Giant aufeis fields, common in the Northeast of Russia, are the indicators of water exchange processes in cryosphere. The development of ideas about icing processes is relevant both from the fundamental point of view of studying the permafrost evolution, and from the practical point of view – for the development of aufeis hazard measures. The aufeis in the Anmangynda River basin (aufeis glade area 7 km2) is considered representative of the region, and its studies have been carried out since 1962. In 2022, during the period of maximum thawing of the active layer Electrical Resistivity Tomography (ERT) soundings were carried out at the aufeis glade aiming to identify underchannel taliks and flooded fault zones in bedrock, including local areas of groundwater discharge. It was found that within the main river channels there are underchannel taliks up to 30 m deep. According to the results of 2D inversion, local anomalies of low electrical resistivity mark groundwater filtration channels. In 3D geoelectrical models, pipe-like anomalies of low resistivity are identified in the areas of groundwater discharge, interpreted as filtration channels in the alluvium and the zone of exogenous fracturing in bedrock formed by sandy-clay shales, as well as linear vertical anomalies of low resistivity, interpreted as faults. On vertical sections of 3D resistive models, a connection between faults and filtration channels in alluvium and a layer of exogenous fracturing is traced. In the right bank of the valley, geoelectric signs of taliks in the bedrock, presumably associated with fault tectonics, have been established. It is assumed that the identified faults are the additional transit routes for groundwater in the Anmangynda River valley, along with the alluvial aquifer and the zone of exogenous fracturing of bedrock.