Alkali Basalts Research Articles

Identification of carbonated eclogitic source for Cenozoic intraplate alkaline basalts from western Central Asia and its geodynamic implication

Carbonated eclogite has been identified as a significant component in the formation of intraplate alkaline basalts, typically attributed to stagnated subducted oceanic slabs, such as the Pacific plate beneath eastern China. However, it is unclear whether this component exists in other tectonic settings. Here, we present new zircon UPb geochronology, mineral chemistry, and geochemical analyses of Cenozoic Tuoyun basanites and alkaline basalts from western Central Asia, where stagnated subducted oceanic slabs are absent, to elucidate the source properties and associated geodynamic processes. Olivine compositions (e.g., moderate Ni concentrations, low Mn/Fe and Ni/(Mg/Fe) ratios) and whole-rock chemistry (e.g., high Fe/Mn, Ca/Al, and Zr/Hf ratios, TiO2 contents, and weak anomalies of Zr-Hf-Ti) suggest a carbonated eclogite in the mantle source of the Tuoyun basanites. Trace elements (positive NbTa anomalies and absence of positive Eu anomaly) and depleted to slightly enriched Sr-Nd-Hf isotopic compositions indicate that the basanites originated from mantle sources composed of variable proportions of altered oceanic crust (AOC) and carbonates. Synthesizing regional geochemical, geophysical studies and tectonic history, we propose that the continuous India-Eurasia collision triggered mantle upwelling, leading to the formation of a widespread carbonated eclogitic mantle source beneath western Central Asia. Our findings suggest that carbonate-rich mantle sources may also be present in areas without stagnated subduction slabs.

Intraplate alkali basalts related to end-Cretaceous Deccan magmatism: implications for tectonomagmatic processes

This study aims to investigate the earliest imprint of Deccan rift magmatism as preserved in alkali basalts from the northwestern Indian shield. The alkali basalts are petrographically classified as nephelinites and basanites. They are silica undersaturated and their high Mg numbers, CaO/Al 2 O 3 , Cr and Ni indicate their primitive character. Geochemically, they are similar to global ocean island basalts; their bulk rock trace elements and Sr–Nd–Hf isotopic signatures suggest their derivation from a garnet-bearing peridotite field. However, their elevated values of Sr/Sm, Sm/Hf, Zr/Hf, Nb/Ta; positive Ba, Sr and negative Zr, Hf spikes suggest that the magma source represents a mixture of garnet peridotites and carbonated melts. Estimated primary melt compositions closely follow the trajectory defined by the high-pressure experimental partial melting trend of a low-carbonated peridotite source. The melting environment approximates to a high mantle potential temperature. A low 87 Sr/ 86 Sr ratio and a negative correlation between 176 Hf/ 177 Hf and 143 Nd/ 144 Nd of the alkali basalts suggest that the mantle source is a mixture of a depleted Indian MORB-type mantle and an enriched mantle type 2. We correlate this event with the melting of the leading edge of the Réunion plume head during Gondwana break-up in a relatively short span of the Cretaceous/Paleogene boundary.

Bulk Rock and Olivine Chemistry and Isotopes of 106–58 Ma Basalts from Liaodong Peninsula and its Adjacent Areas: Implications for Secular Evolution of the Big Mantle Wedge in Eastern China

Abstract The subducting Pacific slab stagnates in the mantle transition zone and creates a big mantle wedge (BMW) system in East Asia. A similar BMW structure may have already existed since the Early Cretaceous (>120 Ma), but how such a structure evolved from Early Cretaceous to the present day remains unclear. We address this issue by comparing compositions and source heterogeneity of the 106–58 Ma basalts from Liaodong Peninsula and its adjacent areas (LPAA) in eastern China, with those formed in the modern BMW setting. The LPAA basalts display oceanic island basalts–like trace element patterns. Elemental and isotopic compositions of these basalts and their olivine phenocrysts point to peridotite and two recycled components in their source. One recycled component is altered lower oceanic crust given the low δ18Oolivine (2.8–5.2‰) of the ~99 Ma Liaoyuan alkali basalts. The second component consists of altered upper oceanic crust and pelagic sediments indicated by high δ18Oolivine (>6.0‰), represented by the ~58 Ma Luanshishanzi alkali basalts. The depleted mantle-like isotopes of these two components suggest derivation from a young HIMU source with characteristics of the Izanagi plate (e.g. Indian Ocean-type Sr-Nd-Pb-Hf isotopes), which may have resided in the mantle transition zone at that time. Our results reveal strong similarities between chemical and source characteristics of the mantle sampled by the 106–58 Ma LPAA basalts and those derived from the modern BMW. This implies that the BMW structure has been present since the Early Cretaceous, probably having lasted more than 120 Myr, and modulating the chemical properties of the upper mantle and influencing a variety of geological processes.

Geochemistry and magmatic petrology of meta-ophiolites from the Bajgan Complex (Makran Accretionary Prism, SE Iran): new insights on the nature of the Early Cretaceous Middle East Neotethys

The Bajgan Complex in the North Makran Domain (Makran Accretionary Prism) comprises disrupted meta-ophiolitic sequences originating from oceanic crust protoliths. They include ultramafic and mafic cumulates, isotropic gabbros, plagiogranites and basalts. Ultramafic–mafic cumulates and plagiogranites exhibit compositions akin to rocks formed in mid-ocean ridge settings. Isotropic gabbro and basalt protoliths can be subdivided into three distinct geochemical types. Type-1 rocks are sub-alkaline (Nb/Y < 0.1) with low Th, Nb and Ta contents and La N /Yb N ratios <1, resembling those of normal mid-ocean ridge basalts (N-MORB). Type-2 rocks display slight enrichment in Th, Ta, Nb (Nb/Y = 0.36–0.45) and La N /Yb N = 2.12–3.20, resembling the chemistry of enriched (E-) MORB. Type-3 basalts show an alkaline nature (Nb/Y = 0.88–1.82), significant Th, Ta and Nb enrichment, and high La N /Yb N ratios (7.01–20.08), resembling the chemistry of alkaline basalts (ocean island basalts, OIB). Petrogenetic modelling indicates that N-MORB protoliths originated from a depleted MORB mantle source, whereas E-MORB and OIB protoliths were generated from partial melting of sub-oceanic depleted sources that underwent varying degrees of OIB-type enrichment. The Bajgan meta-ophiolitic protoliths were formed within a Late Jurassic to Cretaceous oceanic basin influenced by mantle plume activity and plume–ridge interaction. Supplementary material : Field photographs, micrographs, rocks sampled, analytical methods and results, and supplementary tables are available at https://doi.org/10.6084/m9.figshare.c.7193937 Thematic collection: This article is part of the Ophiolites, melanges and blueschists collection available at: https://www.lyellcollection.org/topic/collections/ophiolites-melanges-and-blueschists

Geochemical processes in the roots of the Azores magmatic systems

The Azores archipelago, situated east of the Mid-Atlantic Ridge, comprises volcanic islands arranged along sub-parallel spreading systems and rests on a thick oceanic crust. Magma is supplied directly from the roots of the volcanic systems. Located at or nearby the boundary between the crust and the mantle, they consist of mafic cumulates and mafic mush layers. This work focuses on tephra samples and a submarine lava younger than 40.000 years, collected from both central volcanoes and fissure zones. Our report details a new dataset of major, trace, and volatile elements analysed in glassy melt inclusions trapped in olivine (Fo75.8–85.6) which are extracted from cumulative bodies at the vicinity of the crust-mantle boundary. Their compositions cover a range from subalkaline to mildly alkaline basalt, and trachybasalt, which match those of Azores lavas. They registered a chemical evolution through fractional crystallisation of olivine alone, as well as olivine and clinopyroxene, as both the FeOt/MgO (1.4–3.1) and CaO/Al2O3 (0.4–1.0) ratios of the melt decrease. Incompatible element ratios of Zr (40–352 ppm), Ba (135–612 ppm), and Rb (5–77 ppm), as compared to Nb (5–82 ppm), exhibit variability within a limited but significant range of values. The ranges in the Nb/Zr, Ba/Nb and Rb/Nb ratios recorded by melt inclusions possibly reveal distinct geochemical sources (at least two), and mixing between partial melts as they move upward. The halogen signature is characteristic of the shallow mantle. The majority of melt inclusions show Cl/K ratio (0.06) similar to E-MORB, although some of them are comparable to N-MORB (Cl/K = 0.03). Their F/Nd ratio may achieve a rather high value (27.8).

About this title - Alkaline Rocks: Economic and Geodynamic Significance through Geological Time

The term ‘alkaline rocks’ comprises alkali basalts, tephrites, phonolites, trachytes and their plutonic equivalents, including carbonatites and lamprophyres. Their study can aid the interpretation of ancient terranes and their geodynamic setting. Alkaline rocks may also host precious- and rare-metal mineralization, the latter representing critical commodities for modern green-energy technologies.

Origin of the Site U1504 alkaline basalts in the South China Sea continental margin: Insights on deep mantle diversity and subduction dynamics under continental arcs

Alkaline basalts produced in continental arcs should contain information different from the arc tholeiite-calc-alkaline-series magmas, and their origin could provide unique constraints on deep mantle composition and material cycling. However, due to their sparse occurrence, alkaline basalts in continental arcs have not been studied thoroughly, which hinders our understanding of the mantle diversity and subduction dynamics under continental arcs. In this study, we present new 40Ar/39Ar ages, major and trace elements, and Sr-Nd-Hf isotopic data for the International Ocean Discovery Program Site U1504 alkaline basalts in the continental arc developed on the South China Block (SCB). These alkaline basalts were generated at ca. 121 Ma and display typical oceanic-island basalt geochemical characteristics. Their relatively high εNd(t) (3.5−3.7) and low (87Sr/86Sr)i (0.7034−0.7040) and La/Nb (0.5−1.0) values suggest that they were mainly derived from an asthenosphere mantle source. Compared to alkaline basalts in the SCB inland, U1504 alkaline basalts exhibit lower K2O/Na2O, Zr/Sm, Zr/Y, εNd(t), and εHf(t) values, indicating the addition of minor sub-continental lithospheric mantle. The enrichment of Nb, Ta, light rare earth elements, and slight depletion of Zr, Hf, and Ti, as well as elevated Fe/Mn and Sm/Yb and low CaO, indicate that their mantle lithology was mainly garnet pyroxenite. Based upon these findings and previous studies, the garnet pyroxenite was probably formed by the interaction of upwelling asthenosphere with slab edges in the scenario of break-off of the Paleo-Pacific Plate, and such interaction diversified the mantle chemistry beneath continental arcs. In conjunction with other reported alkaline basalt data, it is proposed that the enriched asthenosphere mantle beneath the SCB had formed sequentially from inland to coastal since the late Mesozoic, and this may be related to lateral and vertical flow in the deep asthenosphere controlled by the break-off of subducted plates.

Deciphering magmatic processes from plagioclase, clinopyroxene and amphibole chemistry and textures: A case study of a basaltic lava flow in the Basque-Cantabrian Basin (Northern Spain)

This paper addresses the study of a pillow lava interbedded with Late Albian-Early Cenomanian sediments that crops out in Armintza (Bizkaia, Northern Spain). The lava flow is an alkaline basalt with abundant macrocrysts of clinopyroxene, kaersutite, Ca-rich plagioclase (50-86% An) and ilmenite, which display a variety of textures and complex zoning patterns indicative of open-system magmatic behaviour. Macrocryst cores are likely to be inherited antecrysts that underwent complex processes under deep pre-eruptive conditions (≈ 700-800 MPa). Microcrysts and macrocryst rims formed during magmatic ascent and emplacement at shallower levels (≈ 35 MPa). Hypothetical melts in equilibrium with clinopyroxenes and amphiboles have trace element compositions like metasomatic vein melts containing amphibole, and their patterns overlap with those of the Armintza pillow lava. This suggests a metasomatised lithospheric mantle with amphibole-rich veins as a potential source for the alkaline basaltic melt. It is even conceivable that the Armintza pillow lava and other alkaline volcanic manifestations of the Basque-Cantabrian Basin were part of the same magma plumbing system through which a series of time-limited eruptions of different batches of magma ascended from the lithospheric mantle to the upper crust during the Albian to the Santonian.

Geochemical and thermodynamic constraints on the genesis of coexisting alkaline and tholeiitic basalts from Datong, North China: Implication for compositional diversity of continental intraplate basalts

Continental intraplate basalts usually exhibit diverse compositions varying from silica-deficient alkaline basalts to silica-excess tholeiites. However, the mechanism of compositional diversity remains controversial. Here, we conducted comprehensive petrology, mineral chemistry, whole-rock geochemistry, and Sr–Nd–Hf isotopic compositions, as well as thermodynamic modeling for the coexisting Datong alkaline and tholeiitic basalts, North China, to put constraints on the source characteristics and melting conditions of these basalts. The alkaline basalts and tholeiites have contrasting major elemental and Sr–Nd–Hf isotopic compositions (87Sr/86Sr, 0.703431–0.703603 vs. 0.703912–0.704010; ƐNd, 5.5–7.0 vs. 2.9–4.8; ƐHf, 9.5–10.6 vs. 8.2–9.6) and trace-element patterns. The observed compositional differences could be explained by neither magmatic processes (e.g., assimilation and/or fractional crystallization), varying melting degrees due to lithospheric thickness variations, nor the melt-peridotite interaction. Instead, lithological heterogeneous mantle sources containing different types of pyroxenite should be considered to account for the compositional diversity, as indicated by olivine (high Ni, Zn/Fe, and low Mn/Zn) and whole-rock chemistry (low CaO, high Fe/Mn, FC3MS, and FCKANTMS ratios). The incompatible trace element-based thermodynamic modeling was carried out to put quantitative constraints on the mantle source characteristics and melting conditions. The modeling results suggest that the source of alkaline basalts contains 30% silica-deficient pyroxenite +70% lherzolite with melting pressure and temperatures of 2 GPa, 1370 °C, whereas the tholeiites have 15% silica-excess pyroxenite +85% harzburgite in the source with melting conditions of 1.5 GPa, 1425 °C. The estimations, together with the thermobarometric calculations using major-element compositions, suggest that the tholeiitic and alkaline basalts were generated by melting of lithological heterogeneous mantle sources under lithosphere with different thicknesses. The lithological heterogeneity originated from recycled components from historical peripheral subducted plates, and melting of such lithological heterogeneity is likely related to asthenosphere upwelling and convection induced by the deeply subducted Pacific slab. Our study emphasizes the fundamental role of source lithological heterogeneity in the generation of co-existing Datong alkaline and tholeiitic basalts and may provide insights into the origin of compositional diversity of other continental intraplate basalts.

Distinct mafic magmatism of the northeastern Longgang Block: Evidence for coexisting mantle plume and subduction during the Neoarchean North China Craton

The question of which specific tectonic regimes played an essential role in shaping the Neoarchean evolution of the North China Craton (NCC) has been a contentious and controversial topic. Mafic rocks, containing valuable geochemical information from the mantle and deep crust, serve as an important source of data to provide essential constraints on above issue. This study presents bulk-rock geochemistry, zircon U-Pb geochronology and Hf-Nd isotopes for the Neoarchean mafic rocks in the core area of the Longgang Block of the NCC. Petrographically, these mafic rocks are composed of the amphibolite and metadiabase. Zircon U-Pb dating results revealed that they were synchronously emplaced at ca. 2.5 Ga. Geochemically, the amphibolites belong to subalkaline tholeiite series, exhibiting enrichment in light rare earth elements (LREEs), intensely negative Nb, Ta and Ti anomalies, and slightly enriched Nd and relatively variable zircon Hf isotopic compositions. These geochemical and isotopic features show large affinity to arc-like magmatism, implying that they were derived from subduction-related metasomatized lithospheric mantle. In contrast, the metadiabases exhibit high-Ti alkaline basalt affinities, OIB-like REE, and trace element patterns. They also show clearly positive Nb, Ta and Ti anomalies, indicating that they originated from a mantle plume-related tectonic environment. The new geochemical and isotopic data reveal that these Neoarchean mafic rocks could have resulted from coexisting mantle plume and subduction processes. Combined with available regional structural, geochemical, and metamorphic data, it is likely that during the Neoarchean, both a mantle plume and subduction jointly controlled the crustal growth and tectonic evolution of the Longgang Block in the eastern NCC.

Olivine Megacrysts in Alkaline Basalt Dikes of the Western Sangilen Region, Southeastern Tuva

Olivine Megacrysts in Alkaline Basalt Dikes of the Western Sangilen Region, Southeastern Tuva

Deep mantle cycle of chalcophile metals and sulfur in subducted oceanic crust

Understanding the subduction-driven recycling of economically important chalcophile metals (e.g., Cu, Au, Ag, and platinum-group elements, PGEs) and volatiles (e.g., sulfur) is critical for assessing models of ore formation. However, whether the sulfide remains stable in recycled altered oceanic crust (AOC) in the mantle is unclear, and the influence of AOC-derived metasomatic agents on the extraction efficiency of chalcophile elements from the deep mantle remains poorly understood. Here we report whole-rock Cu-Ag-Au-Re-PGEs of Cenozoic alkaline basalts at Hannuoba, eastern China, which were derived from the interaction of carbonated eclogite (recycled AOC)-derived melts with lithospheric peridotites. Volatile-rich primitive melts from carbonated eclogite are poor in strongly chalcophile metals (e.g., ∑PGE < 1 ng/g, Au < 1 ng/g, Cu < 30 μg/g). Remarkably, primitive melts show significant fractionation of elements with variable chalcophile affinities, such as lower Cu/Ag ratios than those in primitive mantle and MORBs. These features reflect the sequestration of these metals in residual mono-sulfide solid solution (MSS) during low-degree melting of the AOC in the deep mantle. Given the retention of sulfides in the AOC, partial melts derived from it are rich in sulfur but poor in strongly chalcophile metals. The Hannuoba alkaline melts scavenged some strongly chalcophile metals from peridotites (especially PGEs) during their ascent. However, this did not necessarily lead to the formation of chalcophile metal-enriched melts (e.g., Au < 1 ng/g and Cu < 60 μg/g). These processes appear to be common in eastern China, as evidenced by the low abundances of Cu and Au found in many primitive intraplate alkaline basalts. We propose that strongly chalcophile elements in subducted AOC are efficiently transported into, and stored in, the deep mantle, with a small proportion returning to the exosphere through volcanism. Moreover, the chalcophile metal-poor and volatile-rich melts of subducted AOC could also explain the addition of abundant sulfur (secondary sulfides), but limited chalcophile metals to the metasomatized mantle.

Mineral carbonation of peridotite fueled by magmatic degassing and melt impregnation in an oceanic transform fault

Most of the geologic CO2 entering Earth's atmosphere and oceans is emitted along plate margins. While C-cycling at mid-ocean ridges and subduction zones has been studied for decades, little attention has been paid to degassing of magmatic CO2 and mineral carbonation of mantle rocks in oceanic transform faults. We studied the formation of soapstone (magnesite-talc rock) and other magnesite-bearing assemblages during mineral carbonation of mantle peridotite in the St. Paul's transform fault, equatorial Atlantic. Clumped carbonate thermometry of soapstone yields a formation (or equilibration) temperature of 147 ± 13 °C which, based on thermodynamic constraints, suggests that CO2(aq) concentrations of the hydrothermal fluid were at least an order of magnitude higher than in seawater. The association of magnesite with apatite in veins, magnesite with a δ13C of -3.40 ± 0.04‰, and the enrichment of CO2 in hydrothermal fluids point to magmatic degassing and melt-impregnation as the main source of CO2. Melt-rock interaction related to gas-rich alkali olivine basalt volcanism near the St. Paul's Rocks archipelago is manifested in systematic changes in peridotite compositions, notably a strong enrichment in incompatible elements with decreasing MgO/SiO2. These findings reveal a previously undocumented aspect of the geologic carbon cycle in one of the largest oceanic transform faults: Fueled by magmatism in or below the root zone of the transform fault and subsequent degassing, the fault constitutes a conduit for CO2-rich hydrothermal fluids, while carbonation of peridotite represents a vast sink for the emitted CO2.

Pliocene to Pleistocene REE-P Metasomatism in the Subcontinental Lithosphere beneath Southeast Asia—Evidence from a Monazite- and REE-rich Apatite-bearing Peridotite Xenolith from Central Vietnam

Abstract Mantle rocks usually contain rare earth elements (REEs) in very low concentrations. Here, we document an occurrence of monazite associated with REE-rich apatites in a carbonate-bearing wehrlite xenolith from central Vietnam. The xenolith displays an equigranular matrix of rounded olivine grains while texturally primary orthopyroxene, clinopyroxene and spinel are notably absent. Scattered within the olivine matrix, two types of domains are present: domain-I contains blocky clinopyroxene grains within a matrix of quenched silicate melt and is associated with a second generation of olivine, small euhedral spinel, and rare grains of carbonates. Domain-II contains irregularly shaped patches of carbonate associated with silicate glass, secondary olivine, spinel, and clinopyroxene. Monazite and apatite occur only in domain-I: very small rounded to elongate monazite I grains are included in primary olivine, partly crosscut by fine glass veinlets, monazite II as large grains up to 300 × 200 μm in size and monazite III as small euhedral and needle-like crystals in silicate glass pools. Apatite I forms lath-shaped to rounded crystals up to 200 × 50 μm in size, whereas apatite II is present within silicate melt pools where it forms euhedral needle-like to equant grains. Monazites show compositional variation mainly with respect to ∑REE2O3 (63–69 wt %) and ThO2 (1.1–5.3 wt %) and only minor variations in P2O5 (29–32 wt %), SiO2 (&amp;lt;0.05–0.4 wt %), and CaO (0.2–0.4 wt %). Apatites are characterized by strongly variable and high REE2O3 and SiO2 contents (4–27 wt % ∑REE2O3, 0.6–6.8 wt % SiO2) as well as with significant Na2O (0.3–1.5 wt %), FeO (0.1–1.8 wt %), MgO (0.2–0.6 wt %) and SrO (0.2–0.9 wt %) contents. F and Cl contents are in the range 1.9–3.0 wt % and 0.2–0.8 wt %, respectively. The textures observed in this wehrlite xenolith are thought to be the result of an interaction of depleted (harzburgitic) mantle with cogenetic silicate and carbonatite melts formed by fractionation-driven immiscibility within a parental SiO2 undersaturated melt characterized by high P, CO2, and REE contents. The immiscibility occurred in the shallow subcontinental lithosphere at T of 700–800 °C and a depth of ~30 km and the melt–rock interaction occurred in two successive and most likely nearly simultaneous events: an initial stage of metasomatism was triggered by the P-REE-CO2-rich agent with low aH2O resulting in the co-precipitation of carbonates as patches and along micro-veins and of phosphates in a peridotitic assemblage. A second stage is characterized by pervasive infiltration of an alkali-rich basaltic melt into the carbonate + phosphate-bearing assemblage. Based on 232Th and 208Pb contents of monazite, a young age of ~2 Ma can be calculated for the timing of the monazite-forming metasomatic imprint. Based on 39Ar-40Ar extrusion ages of the xenolith-hosting alkali basalts of 2.6–5.4 Ma, this indicates that both carbonatite and basaltic melt infiltration must have occurred no more than a few hundred thousand years before extraction of the xenolith to the surface.

Magmatic Evolution of the Fossil Melanesian Island Arc: Evidence From Lower Miocene Lavas of Malekula Island (Vanuatu)

AbstractThe subduction zones in the SW Pacific Ocean are some of the most dynamic plate boundaries on Earth with changes in subduction polarity and subduction initiation processes. The New Hebrides island arc formed some 10 million years ago after the Melanesian island arc was abandoned due to the cessation of subduction of the Pacific Plate after collision of oceanic plateaus with the island arc. Parts of the Melanesian island arc occur within the New Hebrides island arc and we show that Miocene volcanic rocks exposed on Malekula island in the New Hebrides island arc consist of island arc tholeiites to alkaline basalts with variable slab contribution. The lava erupted between 22.5 and 16.3 Ma, similar to the Wainimala Group lavas on Fiji representing the eastern portion of the Melanesian island arc. Partial melts from subducted sediments affected a Pacific MORB‐type mantle, but we do not find evidence for a slab component derived from the Ontong Java Plateau or for assimilation of continental crust. Thus, no Miocene subduction of the Ontong Java Plateau occurred beneath Malekula and the basement of the island probably does not consist of continental crust rifted from Australia. The Malekula lava succession resembles that of other portions of the Miocene Melanesian island arc between New Britain and Fiji, indicating continuous subduction of the Pacific plate along this arc.

Geochronology, geochemistry and geological significance of multi-porphyritic alkaline basalt from Hala'alate Formation in Urho area, West Junggar, Xinjiang

Geochronology, geochemistry and geological significance of multi-porphyritic alkaline basalt from Hala'alate Formation in Urho area, West Junggar, Xinjiang

Geochronology, geochemistry, and tectonic setting of the Neoproterozoic magmatic rocks in Pan-African basement, West Ethiopia

The West Ethiopian plateau lies in the transition zone between the Arabian-Nubian shield and the Mozambique belt of the Pan-African orogen, underlain by Precambrian to Tertiary rocks in the Gimbi-Nejo area. The Precambrian basement consists mainly of intrusive-meta-intrusive and meta-sedimentary rocks with ice-rafting deposits. Based on the field survey, unique material records, deformation features, magmatism, and metamorphism indicate that the Gimbi-Nejo area likely underwent four tectonic stages during the Neoproterozoic era.The sedimentary formation of 980 ± 3.9 Ma rift valleys is represented by meta-clastic rocks, calc-silicate rocks, meta-basic rocks bearing marble in Chochi, and the Kata domain. Geochemically, meta-peridotite and meta-gabbros show tholeiitic features, while meta-granitoids are medium-K calc-alkaline peraluminous to metaluminous A-type (Ce/Nb 2.1–11.9; Y/Nb 1.2–8; Yb/Ta 2.6–14). Meta-gabbro samples with immobile HFSE (Th, Ta, Hf) and REE (La, Sm, Yb) fall in the within-plate alkaline basalt, oceanic island basalt (OIB), and continental rift basalt field. Meta-granitoid samples also fall in the within-plate granite field. The lithospheric subduction stage magmatic arc, composed of gabbros and granitoids, was emplaced around 827 ± 3.2 Ma. The granitoids include calcic tonalite and trondhjemite showing an adakitic signature with high Sr/Y (14.2–48.2) ratios. Gabbro samples fall in the island arc basalt and continental arc basalt field. Meta-peridotites and meta-gabbros to gabbros originated from the partial melting of garnet-spinel lherzolite to spinel lherzolite (<10 %) and garnet lherzolite to garnet-spinel lherzolite (<30 %) mantle source, respectively. The continental collisional area contains thrust folds and faults trending in a north–south direction. The ca. 797 ± 3.7 Ma calc-alkalic granitoid rocks along the suture zone are high-K peraluminous I-type granitoids (ASI < 1.1). The strike-slippage area is represented by sinistral ductile shearing deformation. The alkali-calcic granitoid rocks associated with shearing and decollements are low to high-K calc-alkaline peraluminous-metaluminous I-S type granitoids (ASI = 0.95–1.17). The U-Pb age of alkali-calcic granitoid is 564 ± 3.4 Ma. Syn-collisional calc-alkalic and late-post orogenic alkali-calcic granitoid samples both fall within the category of within the plate granite.The εHf (t) values of meta-granitoid (+9.4 to + 15.5), calcic granitoid (+7.6 to + 13.2), calc-alkalic granitoid (+7.4 to + 15.5), and alkali-calcic granitoid (+7.11 to + 17.12) suggest that these Neoproterozoic granitoids have been derived from a Meso-Neoproterozoic juvenile crust that formed through depleted mantle source. Depleted mantle magma likely ascended to the juvenile crust and remained there for a certain period (mean time = 122 Ma, 257 Ma, 248 Ma, and 256 Ma, respectively).

Fertile upper mantle peridotite xenoliths indicate no wholesale destruction of cratonic root in East Asia

A major question in geodynamic evolution of the Earth is whether the continental keel evolved geochemically or were delaminated and replaced by a new mantle. Here we present direct evidence for the geochemical evolution of continental keel from lherzolite xenoliths preserved in the Cenozoic alkali basalts from Jeju Island, Korea. Our findings, using detailed petrography and geochemical methods, reveal distinct textures and compositional changes (represented by olivine with magnesium number 91–87, 86–61 respectively) of two stages of geochemical alteration. The first stage involved a parental kimberlite melt that penetrated during the Paleozoic, and the second was caused by alkali basalt during Cenozoic. Our findings suggest that the Archean depleted harzburgitic upper mantle partially evolved to lherzolitic through interaction with melts/fluids that originated from the deep mantle, implying no wholesale delamination of the upper mantle root of East Asian continents.

Miocene Volcanism in the Slovenský Raj Mountains: Magmatic, Space, and Time Relationships in the Western Carpathians

The Miocene volcanic-intrusive complex in the Slovenský Raj Mountains, middle Slovakia, comprises a swarm of subalkaline basalts and basaltic andesites with alkaline basalts, trachybasalts and basaltic trachyandesites. Basaltic to doleritic feeder dykes and sporadic hyaloclastite lavas are exposed in contact with the Triassic Bódvaszilas Formation of the Silica Nappe. The primary clinopyroxene, plagioclase, and Fe-Ti oxide assemblage also contains calcite spheroids inferred to represent carbonatitic melt. These spheroids are associated with subsolidus chlorite, actinolite, magnetite, titanite, calcite, and epidote. Micropoikilitic clinopyroxene, albite, and Ti-magnetite formed due to rapid quenching. There was an incorporation of host rock carbonate during the eruption. The erupted products are the result of magmatic differentiation of the parental basaltic tholeiitic magma with a redox of ∆QFM = +1 to +3, affected by varying degrees of 0%–50% fractionation and the assimilation of carbonate material in a shallow magmatic reservoir. REE geochemistry shows N-MORB-like type patterns with both LaN/YbN and LaN/SmN &lt; 1 at near constant Eu/Eu* (~0.9). This is supported by εNd(t=13 Ma) values of +8.0 to +7.4 determined from the basaltic rocks. The REE values can be modeled by 1% fractional melting of garnet peridotite mixed with 7% melting of spinel peridotite of PM composition (1:9 proportions). SIMS and LA-ICP-MS U/Pb analysis of zircons yields a concordant age of 12.69 ± 0.24 Ma and a 13.3 ± 0.16 Ma intercept (Serravallian) age. The Middle Miocene volcanic activity was related to subduction-collision processes along the boundary of the Cenozoic ALCAPA (Alps–Carpathians–Pannonia) microplate and the southern margin of the European plate.

Thermodynamic modelling of continental arc-adjacent magmatism: the Loicas Trough, N. Patagonia, Argentina

Continental arcs are associated with volcanism concentrated into two main belts—the main arc and back arc, often separated by fold and thrust belts. The Loicas Trough, Argentina, is a post-orogenic extensional feature that obliquely cuts the fold and thrust belts. The trough hosts large Pliocene–Holocene volcanic centres, including Domuyo and Tromen, that lie between the main arc and back arc and thus provide a rare window into this setting. We present major and trace element data for the Loicas Trough, which we combine with geochemical modelling using the Magma Chamber Simulator (MCS) to explore the origin and evolution of the volcanism. The lavas display a wide continuous range from alkaline basalts to subalkaline rhyolites. Trace elements reveal variable extents of arc enrichment (2 < Nb/U < 28), which correlate with proximity to the trench and differentiation indices. Our results and MCS models indicate that the Loicas Trough parental magmas formed from compositionally zoned mantle. Best-fit models indicate that the differentiation occurs at middle and upper crustal levels, in sharp contrast to lower crustal hot zones beneath main arcs. Assimilation of partial crustal melts drives compositional evolution and obscures source signatures. Pure or high fraction end-member partial crustal melts are also identified at Domuyo based on their low Ba (~ 250 ppm) and moderate Sc contents (~ 8 ppm). We find evidence of similar lavas in transtensional settings adjacent to continental arcs worldwide, which do not adhere to the main versus back arc volcanism binary. We suggest the term arc-adjacent magmatism, where compositions are mainly controlled by extensive assimilation and reworking in the middle to upper crust.